EP1059360B1 - Verfahren zum Entschwefeln von Roheisen - Google Patents

Verfahren zum Entschwefeln von Roheisen Download PDF

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Publication number
EP1059360B1
EP1059360B1 EP00111691A EP00111691A EP1059360B1 EP 1059360 B1 EP1059360 B1 EP 1059360B1 EP 00111691 A EP00111691 A EP 00111691A EP 00111691 A EP00111691 A EP 00111691A EP 1059360 B1 EP1059360 B1 EP 1059360B1
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EP
European Patent Office
Prior art keywords
gas
molten iron
desulfurizing
desulfurizing agent
hydrocarbon
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00111691A
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English (en)
French (fr)
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EP1059360A3 (de
EP1059360A2 (de
Inventor
Naoki c/o Tech. Res. Lab. Kawas. S. Cor Kikuchi
Shuji c/o Tech.Res. Lab. Kawas. S. Cor Takeuchi
Akiharu Chiba Works Kawasaki Steel Corp. Takao
Mototatsu Chiba Works Kawasaki St. Co. Sugizawa
Shigeru Chiba Works Kawasaki Steel Corp. Ogura
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JFE Steel Corp
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JFE Steel Corp
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Publication of EP1059360A3 publication Critical patent/EP1059360A3/de
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00—Refining of pig-iron; Cast iron
    • C21C1/02—Dephosphorising or desulfurising
    • C21C1/025—Agents used for dephosphorising or desulfurising
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00—Refining of pig-iron; Cast iron
    • C21C1/02—Dephosphorising or desulfurising
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04—Removing impurities by adding a treating agent
    • C21C7/064—Dephosphorising; Desulfurising
    • C21C7/0645—Agents used for dephosphorising or desulfurising

Definitions

  • the present invention relates to a method of removing a sulfur component in molten iron, and more particularly to an improved desulfurizing method that provides enhanced desulfurization efficiency.
  • the desulfurizing process in steel manufacturing techniques is mainly of two types, i.e., one carried out in the molten iron stage, in a torpedo car or a molten-iron pan, and the other carried out in the molten-steel stage, on deoxidized molten steel downstream of a converter.
  • a CaO-based desulfurizing agent for the desulfurizing process carried out in the molten-iron stage, a CaO-based desulfurizing agent, an Na 2 O-based desulfurizing agent, an Mg-based desulfurizing agent, etc. are employed. More specifically, in the desulfurizing process carried out in the molten-iron stage, because the CaO-based desulfurizing agent is preferred from the viewpoints of slag treatment and cost, a technique of improving the efficiency of the process for desulfurizing molten iron by the use of the CaO-based desulfurizing agent is required.
  • Japanese Examined Patent Application Publication No. 5-43763 discloses a method of accelerating desulfurization with hydrogen gas. According to this Publication, by employing hydrogen gas as a carrier gas used for blowing a CaO-based desulfurizing agent, the desulfurizing reaction with the CaO-based desulfurizing agent is accelerated in comparison with the case of employing an inert gas as the carrier gas.
  • Japanese Examined Patent Application Publication No. 63-19562 discloses a method of accelerating the desulfurizing reaction by adding a desulfurizing agent to molten iron from above and blowing a hydrocarbon-based gas thereto from below in a molten-iron trough of a blast furnace.
  • Japanese Unexamined Patent Application Publication No. 60-26607 discloses a method of mixing, in a CaO-based desulfurizing agent, an organic material that contains 3 - 20 weight % of coal-based hydrocarbon.
  • an object of the present invention is to provide a desulfurizing method which, when the desulfurizing process is carried out by blowing a CaO-based desulfurizing agent into molten iron, can improve the desulfurization efficiency of the CaO-based desulfurizing agent, can increase the productivity of the desulfurizing process, and can reduce the amount of slag generated in the desulfurizing process.
  • the desulfurizing reaction of molten iron effected by a CaO-based desulfurizing agent is expressed by the following formula (1).
  • [S] denotes S (sulfur) in the molten iron.
  • [C] denotes C (carbon) in the molten iron and contributes, as a reductant, to the desulfurizing reaction in the formula (1).
  • (CaS) indicates that CaS is removed with slag.
  • the desulfurizing reaction effected by the hydrogen gas and the CaO-based desulfurizing agent occurs as expressed in the following formula (3).
  • the desulfurizing reaction of the formula (3) is more advantageous because of having higher reducing power than the reducing reaction effected by C in the molten iron.
  • hydrocarbon e.g., propane
  • the desulfurizing reaction (4) based on hydrocarbon is more advantageous than the desulfurizing reaction (3) based on hydrogen by an amount corresponding to decomposing reaction energy of the hydrocarbon.
  • blowing of the hydrocarbon-based gas causes a reduction in the temperature of the molten iron.
  • blowing a large amount of the hydrocarbon-based gas reduces the temperature of the molten iron and impedes the desulfurizing reaction. It is therefore required to limit the amount of the hydrocarbon-based gas used in an appropriate range.
  • the predetermined value of the sulfur concentration is preferably set to 0.01 wt%.
  • the inventors conducted experiments by using a 4-ton furnace in order to study the effect of a hydrocarbon-based gas upon the desulfurizing process.
  • the experiment conditions are listed in Tables 1 and 2.
  • a CaO-based desulfurizing agent in the form of powder was employed as a desulfurizing agent.
  • the blowing rate of the desulfurizing agent is indicated by the weight of the desulfurizing agent blown per unit time (kg/minute).
  • the sulfur concentration in the molten iron decreases with the progress of the desulfurizing reaction, the desulfurization efficiency obtained with the H 2 gas and the C 3 H 8 gas increases.
  • the sulfur concentration in the molten iron is less than 0.01 wt%, the difference in the desulfurization efficiency becomes especially noticeable.
  • using the C 3 H 8 gas, as the carrier gas provides a greater desulfurizing rate in the low-sulfur range than using the H 2 gas.
  • the inventors discovered for the first time the fact that the desulfurizing effect of a hydrocarbon-based gas is enhanced when the sulfur concentration level of molten iron is lowered and the desulfurizing rate is reduced correspondingly as a general rule.
  • the desulfurizing reaction is basically a reaction between a CaO-based flux, which is a solid material, and sulfur. Therefore, the oxygen potential at the reaction interface greatly affects the reaction rate.
  • the oxygen potential of the system is determined by the C content with respect to Fe in the molten iron where C is already in a saturated state, and the oxygen potential is constant. From the experiment results showing a difference in the desulfurization efficiency depending on the kind of carrier gas, however, the inventors made an entirely new finding that the oxygen potential of the system is determined depending on a simultaneous 3-phase state of the flux, carrier gas and molten iron, including the atmosphere under which the flux is blown in, and especially that the oxygen potential of the carrier gas remarkably affects the desulfurizing reaction.
  • the carrier gas were entirely a hydrocarbon gas, this would be advantageous in reducing the oxygen potential, but it would give rise to the drawback that the flow rate of the carrier gas cannot be changed to a large extent during the process because of transport characteristics of the flux in the form of powder.
  • a hydrogen gas can also be used instead of the hydrocarbon-based gas, but the hydrogen gas is inferior to the hydrocarbon-based gas in the following points.
  • a C 3 H 8 gas is employed as the hydrocarbon-based gas in the embodiment, a CH 4 gas or a C gas generated from a coke furnace may be employed instead.
  • the carrier gas is not limited to an N 2 gas, but may be any other inert gas such as Ar.
  • any type of smelting container can be used so long as it allows the hydrocarbon-based gas and the CaO-based flux to be blown into the molten iron at the same site.
  • a flux containing CaO as a main component is optimum because it is inexpensive and facilitates slag treatment after the desulfurizing process.
  • CaO that is a main component contributing to the desulfurizing reaction
  • CaCO 3 that produces CaO upon pyrolysis and promotes dispersion of the flux into the molten iron
  • CaF 2 and CaCl 2 that promote the production of slag from the flux
  • C and Al that keep the molten iron in a reducing condition around the blown-in flux, etc.
  • Na 2 CO 3 that is a similar oxide-based desulfurizing flux is also usable.
  • Mg can also be used especially for extremely-low-sulfur steel.
  • the metal Mg is effective to prevent oxidation loss due to the generation of a reducing atmosphere by the hydrocarbon-based gas, and to develop the desulfurizing reaction with priority.
  • a flux containing the metal Mg can also be used.
  • a method of employing a lance immersed into the molten iron held in a torpedo car, a molten-iron pan or the like and a method of blowing the flux through a bottom-blown tuyere into a smelting furnace such as a converter.
  • a smelting furnace such as a converter
  • Fig. 1 is a graph showing the relationship between the ratio of propane gas flow rate / desulfurizing agent (Nl/kg) and the desulfurizing rate K s when the blowing rate Q flux of the desulfurizing agent is not greater than 1.0 kg/minute per ton of the molten iron.
  • Fig. 2 is a graph showing the relationship between the ratio of propane gas flow rate /desulfurizing agent (Nl/kg) and the desulfurizing rate K s when the blowing rate Q flux of the desulfurizing agent is greater than 1.0 kg/minute per ton of the molten iron.
  • the propane gas accelerates the desulfurizing reaction in the range where the ratio of the propane gas to the desulfurizing agent (i.e., propane gas flow rate / desulfurizing agent) is not smaller than 2.0 Nl/kg.
  • propane gas accelerates the desulfurizing reaction is that the presence of propane lowers the oxygen potential at the reaction interface between the molten iron and the desulfurizing agent.
  • the blowing rate Q flux of the desulfurizing agent is greater than 1.0 kg/minute per ton of the molten iron
  • the desulfurizing rate is not improved even in the range where the ratio of the propane gas to the desulfurizing agent (i.e., propane gas flow rate / desulfurizing agent) is not smaller than 2.0 Nl/kg. This is because the effect of hydrocarbon is not sufficiently developed at the reaction interface for the reasons of insufficient dispersion of the desulfurizing agent into the molten iron and the small reaction interface between the molten iron and the desulfurizing agent.
  • the ratio of the propane gas to the desulfurizing agent i.e., propane gas flow rate /desulfurizing agent
  • propane gas flow rate /desulfurizing agent be not smaller than about 2.0 Nl/kg but not greater than about 50 Nl/kg, and that the blowing rate Q flux of the desulfurizing agent is not greater than about 1.0 kg/minute per ton of the molten iron.
  • the ratio of the propane gas to the desulfurizing agent is not smaller than about 2.0 Nl/kg but not greater than about 35 Nl/kg.
  • N 2 is preferably supplied at a flow rate not smaller than about 5 Nl/kg per ton of the molten iron. The reason is to maintain the effects of agitating the molten iron and promoting dispersion of the desulfurizing agent into the molten iron.
  • the desulfurizing process was performed by using a torpedo car 6 with a capacity of 250 tons.
  • a schematic construction of a desulfurizing apparatus is shown in Fig. 3.
  • a powdered desulfurizing agent 2 in a hopper 1 is blown into molten iron 5 through a lance 4 together with a carrier gas 2a.
  • the desulfurizing agent used in this Example, the particle size thereof, and the lance immersion depth are listed in Table 3.
  • the desulfurizing conditions such as the blowing rates of the carrier gas and the desulfurizing agent are as shown in Table 4.
  • Comparative Example 1 represents the case where an N 2 gas was used as the sole carrier gas.
  • Comparative Example 2 represents the case where a gas mixture of an N 2 gas and a propane gas was used as the carrier gas and the ratio of the propane gas to the desulfurizing agent was relatively small.
  • Comparative Example 3 represents the case where a gas mixture of an N 2 gas and a propane gas was used as the carrier gas and the blowing rate of the desulfurizing agent was relatively large. In these Comparative Examples 1 to 3, the desulfurizing rate K s was in the range of 0.08 - 0.16.
  • the desulfurizing rate K s in the present invention was 0.44, which is substantially and unexpectedly greater than the desulfurizing rates in the Comparative Examples 1 to 3.
  • a propane gas i.e., C 3 H 8 gas
  • a similar advantage can also be obtained by using another hydrocarbon-based gas (e.g., CH 4 gas) or a gas (so-called C gas) generated from a coke furnace.
  • another hydrocarbon-based gas e.g., CH 4 gas
  • a gas silica
  • an N 2 gas was employed in this Example as an inert gas mixed with the hydrocarbon-based gas to prepare the carrier gas
  • another inert gas e.g., Ar gas
  • any type of smelting container may be used so long as it has a construction allowing the carrier gas and the desulfurizing agent to be blown into the molten iron at the same position.
  • the powdery desulfurizing agent 2 in the hopper 1 was blown into molten iron 5 through the lance 4 together with the carrier gas 2a.
  • the hydrocarbon-based gas such as propane may be separately supplied in an independent manner by providing an inlet near a connecting portion between the lance and a hose extended from the hopper 1.
  • the separately supplied hydrocarbon gas may be mixed with the desulfurizing agent 2 gas feed together with the carrier gas 2a just before the lance 4, and the mixed gases may be blown into the molten iron 5 through the lance 4.
  • This modification is advantageous in that the supply amount of the hydrocarbon-based gas can be changed without affecting the gas-feed characteristics of the desulfurizing agent.
  • the present invention in a desulfurizing process, it is possible to improve the productivity of the molten-iron preliminary treatment, reduce the amount of the desulfurizing agent used, and to cut down the cost due to a reduction in the amount of slag generated.
  • FIG. 3 schematically shows the torpedo car used in the actual machine test.
  • a desulfurizing flux 2 (flux containing CaO as a main component) stored in a raw material hopper 1 was mixed with a carrier gas 2a, and a resulting mixture was blown into molten iron 5 in the torpedo car 6 through a top-blown lance 4.
  • the blown lance 4 is held on a lance fixed carriage 3.
  • Numeral 7 denotes a dust collecting hood.
  • Table 5 shows implementation conditions of the actual machine test for the present invention
  • Table 6 shows supply conditions of the carrier gas in implementation of the actual machine test.
  • Table 6 also shows the conditions of Comparative Examples 1 and 2 for comparison with the Example of the present invention.
  • Comparative Example 1 represents the case where the CaO-based flux was blown with an N 2 carrier gas.
  • Comparative Example 2 represents the case where the same flux was blown with a C 3 H 8 carrier gas.
  • the same flux was first blown together with a mixed carrier gas of N 2 and propane, and the flow rate of the propane gas was increased in a later period of the desulfurizing process.
  • Table 6 shows the flow rate conditions of the carrier gas in respective periods, and Table 7 shows test results.
  • the desulfurization efficiency per unit amount of the flux is improved with a lesser flow rate of the propane gas than that in Comparative Example 2.
  • the temperature of the molten iron was not changed significantly depending on the flow rate of the propane gas.
  • the desulfurizing rate in the process of desulfurizing molten iron can be efficiently accelerated with a small amount of reducing gas. It is therefore possible to realize an improvement of productivity in the molten-iron preliminary treatment and a cost reduction due to cut-down in the amount of a desulfurizing flux used.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Claims (17)

  1. Verfahren zur Entschwefelung von geschmolzenem Eisen, das das Einblasen eines Entschwefelungsmittels, das ein pulverförmiges festes Oxid umfasst, und eines Trägergases in geschmolzenes Eisen umfasst, wobei das Trägergas ein Gemisch aus einem Inertgas und einem Kohlenwasserstoffgas ist und wobei das Verhältnis des Kohlenwasserstoffgases zu dem Entschwefelungsmittel im Bereich von 2,0 bis 50 Nl/kg liegt.
  2. Verfahren nach Anspruch 1, wobei die Einblasrate des Entschwefelungsmittels höchstens 1,0 kg/min pro Tonne des geschmolzenen Eisens beträgt.
  3. Verfahren nach Anspruch 1 oder 2, wobei das pulverförmige feste Oxid CaO umfasst.
  4. Verfahren nach Anspruch 3, wobei CaO eine Hauptkomponente des Entschwefelungsmittels ist.
  5. Verfahren nach einem der Ansprüche 1 bis 4, wobei das Entschwefelungsmittel ferner mindestens einen Bestandteil von CaCO3, CaF2, CaCl2, C, Al, Na2CO3 und Mg umfasst.
  6. Verfahren nach Anspruch 1, das das Einblasen eines Entschwefelungsmittels, das ein pulverförmiges festes Oxid umfasst, zusammen mit einem Trägergas in geschmolzenes Eisen umfasst, um dadurch Schwefel in dem geschmolzenen Eisen zu entfernen, wobei das Trägergas zumindest am Anfang ein Gemisch aus einem Inertgas und einem Kohlenwasserstoffgas ist; und wobei die Zusammensetzung des Trägergases im Laufe der Entschwefelung derart geändert wird, dass in einem späteren Stadium der Entschwefelung relativ mehr Kohlenwasserstoffgas als in einem früheren Stadium verwendet wird und dass das Verhältnis des Kohlenwasserstoffgases zu dem Entschwefelungsmittel in dem späteren Stadium im Bereich von 2,0 bis 50 Nl/kg liegt.
  7. Verfahren nach Anspruch 6, wobei das Trägergas während des späteren Stadiums der Entschwefelung kein Inertgas mehr enthält.
  8. Verfahren nach Anspruch 6, wobei das spätere Stadium der Entschwefelung beginnt, wenn der Schwefelgehalt des geschmolzenen Eisens auf oder unter einen vorgegebenen Wert abnimmt.
  9. Verfahren nach Anspruch 6, wobei das spätere Stadium der Entschwefelung beginnt, wenn der Schwefelgehalt des geschmolzenen Eisens auf oder unter 0,01 Gew.-% abnimmt.
  10. Verfahren nach einem der Ansprüche 6 bis 9, wobei das pulverförmige feste Oxid CaO umfasst.
  11. Verfahren nach Anspruch 10, wobei CaO eine Hauptkomponente des Entschwefelungsmittels ist.
  12. Verfahren nach einem der Ansprüche 6 bis 11, wobei das Entschwefelungsmittel ferner mindestens einen Bestandteil von CaCO3, CaF2, CaCl2, C, Al, Na2CO3 und Mg umfasst.
  13. Verfahren nach Anspruch 1, das das Einblasen eines Entschwefelungsmittels, das ein pulverförmiges festes Oxid umfasst, zusammen mit einem Trägergas in geschmolzenes Eisen umfasst, um dadurch Schwefel in dem geschmolzenen Eisen zu entfernen, wobei das Trägergas am Anfang ein Inertgas ist; und wobei dem Inertgas ein Kohlenwasserstoffgas derart zugesetzt wird, dass das Verhältnis des Kohlenwasserstoffgases zu dem Entschwefelungsmittel im Bereich von 2,0 bis 50 Nl/kg liegt oder das Inertgas insgesamt durch das Kohlenwasserstoffgas ersetzt wird, wenn die Schwefelkonzentration in dem geschmolzenen Eisen nach Beginn der Entschwefelung auf oder unter einen vorgegebenen Wert verringert ist.
  14. Verfahren nach Anspruch 13, wobei der vorgegebene Wert 0,01 Gew.-% beträgt.
  15. Verfahren nach Anspruch 13 oder 14, wobei das pulverförmige feste Oxid CaO umfasst.
  16. Verfahren nach Anspruch 15, wobei CaO eine Hauptkomponente des pulverförmigen festen Oxids ist.
  17. Verfahren nach einem der Ansprüche 13 bis 16, wobei das pulverförmige feste Oxid ferner mindestens einen Bestandteil von CaCO3, CaF2, CaCl2, C, Al, Na2CO3 und Mg umfasst.
EP00111691A 1999-06-07 2000-05-31 Verfahren zum Entschwefeln von Roheisen Expired - Lifetime EP1059360B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP15936999 1999-06-07
JP15936999A JP3577997B2 (ja) 1999-06-07 1999-06-07 溶銑の脱硫方法

Publications (3)

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EP1059360A2 EP1059360A2 (de) 2000-12-13
EP1059360A3 EP1059360A3 (de) 2001-06-06
EP1059360B1 true EP1059360B1 (de) 2005-07-27

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US (1) US6379425B1 (de)
EP (1) EP1059360B1 (de)
JP (1) JP3577997B2 (de)
KR (1) KR100611834B1 (de)
CN (1) CN1218054C (de)
DE (1) DE60021482T2 (de)

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KR101012837B1 (ko) * 2003-07-08 2011-02-08 주식회사 포스코 탈황을 위한 용선 예비처리방법
KR101091935B1 (ko) * 2004-11-01 2011-12-09 주식회사 포스코 다공노즐을 포함한 탈류 랜스와 이를 이용한 예비처리탈류 방법
CN101886150A (zh) * 2010-07-07 2010-11-17 江苏沙钢集团有限公司 钢包浇余热态钢渣的回收利用方法及系统
US9481917B2 (en) * 2012-12-20 2016-11-01 United Technologies Corporation Gaseous based desulfurization of alloys
TWI570246B (zh) * 2015-04-07 2017-02-11 China Steel Corp Method for desulfurization of molten iron
CN115501741B (zh) * 2022-08-30 2023-11-03 四川轻化工大学 一种基于改性载体的高活性氧化铁脱硫剂及其制备方法和应用

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BE762837A (fr) * 1971-02-11 1971-08-11 Centre Rech Metallurgique Perfectionnements aux procedes d'affinage pneumatique de la fonte.
US3998625A (en) * 1975-11-12 1976-12-21 Jones & Laughlin Steel Corporation Desulfurization method
CA1240842A (en) * 1984-05-16 1988-08-23 Heinrich Rellermeyer Method, process and composition for desulfurizing pig-iron melts
US5873924A (en) * 1997-04-07 1999-02-23 Reactive Metals & Alloys Corporation Desulfurizing mix and method for desulfurizing molten iron
DE19833037A1 (de) * 1998-07-22 2000-01-27 Krupp Polysius Ag Verfahren zum Entschwefeln einer Roheisenschmelze
JP3496545B2 (ja) * 1998-12-09 2004-02-16 Ｊｆｅスチール株式会社 溶銑の脱硫方法

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KR100611834B1 (ko) 2006-08-11
KR20010007274A (ko) 2001-01-26
EP1059360A3 (de) 2001-06-06
DE60021482D1 (de) 2005-09-01
EP1059360A2 (de) 2000-12-13
US6379425B1 (en) 2002-04-30
JP2000345224A (ja) 2000-12-12
CN1276434A (zh) 2000-12-13
JP3577997B2 (ja) 2004-10-20
CN1218054C (zh) 2005-09-07
DE60021482T2 (de) 2006-05-24

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