EP0976335B1 - Tissu pour vêtements professionnels de protection contre la chaleur - Google Patents
Tissu pour vêtements professionnels de protection contre la chaleur Download PDFInfo
- Publication number
- EP0976335B1 EP0976335B1 EP99115023A EP99115023A EP0976335B1 EP 0976335 B1 EP0976335 B1 EP 0976335B1 EP 99115023 A EP99115023 A EP 99115023A EP 99115023 A EP99115023 A EP 99115023A EP 0976335 B1 EP0976335 B1 EP 0976335B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibre
- woven fabric
- fabric according
- weight
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 20
- 239000000835 fiber Substances 0.000 claims abstract description 67
- 229920000742 Cotton Polymers 0.000 claims abstract description 19
- 239000003063 flame retardant Substances 0.000 claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004640 Melamine resin Substances 0.000 claims abstract description 10
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 229920000728 polyester Polymers 0.000 claims abstract description 6
- 239000004952 Polyamide Substances 0.000 claims abstract description 4
- 229920002647 polyamide Polymers 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims description 12
- 230000001681 protective effect Effects 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 5
- 239000002759 woven fabric Substances 0.000 claims 10
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- -1 phosphorus compound Chemical class 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- BSBSDQUZDZXGFN-UHFFFAOYSA-N cythioate Chemical compound COP(=S)(OC)OC1=CC=C(S(N)(=O)=O)C=C1 BSBSDQUZDZXGFN-UHFFFAOYSA-N 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 230000006378 damage Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/08—Heat resistant; Fire retardant
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
- D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/20—Metallic fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/04—Heat-responsive characteristics
- D10B2401/041—Heat-responsive characteristics thermoplastic; thermosetting
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Definitions
- the invention relates to a fabric for work and protective clothing, in particular for heat and welding protective clothing.
- Such clothing must be one Meet a variety of different requirements. It has to be used by the user is accepted to be comfortable to wear. Play for comfort.
- a fabric for the above The purpose must continue to be resistant to abrasion or wear.
- On heat and Welder protective clothing are also considered from a safety point of view diverse, especially through the European standards EN 531: 1995 (protective clothing for industrial workers exposed to heat) and EN 470-1: 1995 (protective clothing for Welding and related processes). Both Standards require protection in the event of brief flame contact. Such a Protection is u. a.
- DE 196 17 634 A1 describes a flame-retardant fabric based on melamine resin fibers known, in addition to flame retardant fibers still normal Flammable fibers are provided for a particularly high level of comfort to enable.
- DE 195 23 081 A1 discloses a fiber mixture Melamine resin and natural fibers known. Even with these known fabrics or fiber blends, however, not all of the requirements mentioned, especially with regard to industrial washability.
- a fabric containing 10 to 90% by weight of permanently flame-retardant cotton or cotton fibers (fiber component A), 5 to 45% by weight of polyamide and / or polyester fibers (fiber component B), 5 to 45 %
- melamine resin fibers fiber component C
- auxiliary fibers fiber component D
- Such a fabric is characterized by a fire behavior corresponding to the standards mentioned above. In particular, it does not form burning melting drops that promote the spread of flames and can lead to fire injuries, but charred. Despite its high proportion of thermoplastic fibers, it shows a fire behavior known from thermoset fibers.
- thermoplastic fibers namely polyester and / or polyamide fibers with cotton
- the combination of the thermoplastic fibers and the melamine resin fibers improves in particular the water vapor permeability or the R et value of the fabric.
- the proposed fabric is also suitable for industrial washing and drying processes that require a fabric much more than is the case with "household laundry". The load of industrial washing machines is significantly higher than that of normal household washing machines. This leads to a much greater mechanical load on the material to be washed.
- Also used in the industrial washing process are detergents and auxiliaries which clean much more effectively and thus also put a greater strain on the material to be washed - the alkalinity of the washing liquor in the industrial washing process is known to always be significantly higher.
- drying is carried out, inter alia, by a so-called hot air finishing process.
- the clothing to be dried is subjected to a hot air flow of 160 ° C; this strain is also significantly higher than in the household care process.
- 25 to 50% by weight of fiber component A is 26 to 35% by weight of the fiber component B and 24 to 35% by weight of the fiber component C included. Particularly good results are obtained if the ratio of the proportion of fiber component B to the proportion of fiber component C in ranges from 3: 1 to 1: 1.
- Reactive phosphorus compounds are preferred as flame retardants used. Such compounds are under the brand names "Aflammit ®”, “Pyrovatex ® “or” Proban ® “available on the market. If necessary, it can Fabric auxiliary fibers, for example to increase wear resistance or for antistatic Equipment up to 5% by weight included. Fibers suitable for the latter purpose are, for example, plastic fibers or metal fibers steamed with metal. The amount such antistatic fibers is preferably 0.01 to 3% by weight. Prefers a fabric with a homogeneous fiber mixture is used. at such a mixture, the individual fibers are first mixed homogeneously and then threads or yarns are formed from this fiber mixture.
- a fabric with a twill 2/2 weave, with 37 warp threads and 20 weft threads per cm and a basis weight of 340 g / m 2 was produced from 50 parts by weight of cotton, 26 parts by weight of polyester and 24 parts by weight of melamine resin fibers.
- the threads were obtained in the usual way by initially intimately mixing the individual fibers and using them to produce a mixed fiber yarn or thread with a thread count of Ne 12.
- the cotton has been given a flame-retardant finish with Proban®.
- a fabric was produced with 40 parts by weight of cotton, 30 parts by weight of polyester and 30 parts by weight of melamine resin fibers.
- the cotton was treated with Aflammit® flame retardant.
- the warp and weft threads of the fabric had a yarn freedom of Nm 20, the weight per unit area was 320 g / m 2 with 30 warp threads and 28 weft threads per cm.
- a satin 4/1 (3) weave was chosen.
- a fabric with a twill 2/2 weave with 36 warp threads and 20 weft threads per cm and a basis weight of 355 g / m 2 was produced from 64 parts by weight of cotton, 25 parts by weight of polyester, 10 parts by weight of melamine resin and 1 part by weight of antistatic fiber.
- the threads were obtained in the usual way by first intimately mixing the individual fibers and using them to produce a mixed fiber yarn or thread with a thread count of Nm 20.
- the cotton has been given a flame-retardant finish with Proban®.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Details Of Garments (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Claims (10)
- Tissu pour revêtement professionnel et de protection ayant la composition de fibres suivante (en % en poids) :
Fibres de coton en tant que constituant de fibres A 10 à 90 % Fibres de polyamide et/ou de polyester en tant que constituant de fibres B 5 à 45 % Fibres de résine mélanine en tant que constituant de fibres C 5 à 45 % Fibres auxiliaires en tant que constituant de fibres D 0 à 5 % - Tissu suivant la revendication 1,
caractérisé par
les proportions de fibres suivantes (en % en poids) :Constituant de fibres A de 25 à 50 % Constituant de fibres B de 26 à 35 % Constituant de fibres C de 24 à 35 % - Tissu suivant la revendication 1 ou 2, caractérisé par un rapport de la proportion du constituant de fibres B à la proportion du constituant de fibres C de 3:1 à 1:1.
- Tissu suivant l'une des revendications 1 à 3, caractérisé en ce que les fibres de coton sont traitées par un agent ignifuge à base d'un composé réactif du phosphore.
- Tissu suivant l'une des revendications 1 à 4, caractérisé en ce qu'il contient de 0,01 à 3 % en poids de fibres antistatiques en tant que fibres auxiliaires.
- Tissu suivant l'une des revendications 1 à 5, qui présente un mélange homogène de fibres.
- Utilisation d'un tissu suivant l'une des revendications 1 à 6 pour produire un vêtement professionnel.
- Utilisation d'un tissu suivant l'une des revendications 1 à 6 pour produire un vêtement de protection vis-à-vis de la chaleur.
- Utilisation d'un tissu suivant l'une des revendications 1 à 6 pour produire un vêtement de protection pour les soudeurs.
- Utilisation d'un tissu suivant l'une des revendications 1 à 6 pour produire un vêtement, qui est prévu pour un procédé industriel de lavage et de séchage.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE29914564U DE29914564U1 (de) | 1998-07-31 | 1999-08-02 | Gewebe |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19834495 | 1998-07-31 | ||
DE19834495A DE19834495A1 (de) | 1998-07-31 | 1998-07-31 | Textiles Flächengebilde |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0976335A2 EP0976335A2 (fr) | 2000-02-02 |
EP0976335A3 EP0976335A3 (fr) | 2000-05-03 |
EP0976335B1 true EP0976335B1 (fr) | 2003-04-23 |
Family
ID=7875933
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99115023A Expired - Lifetime EP0976335B1 (fr) | 1998-07-31 | 1999-08-02 | Tissu pour vêtements professionnels de protection contre la chaleur |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0976335B1 (fr) |
AT (1) | ATE237962T1 (fr) |
DE (2) | DE19834495A1 (fr) |
ES (1) | ES2197553T3 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2605187C2 (ru) * | 2014-07-09 | 2016-12-20 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Ивановская пожарно-спасательная академия Государственной противопожарной службы МЧС России" | Огнезащитный состав для тканей специального назначения типа молескин на основе афламмита-sap и диоксида кремния |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10029334A1 (de) * | 2000-06-20 | 2002-01-03 | Basf Ag | Flammgeschützte Gewebe |
DE10038030A1 (de) * | 2000-08-02 | 2002-02-14 | Basf Ag | Flammhemmende Garne und daraus hergestellte Gewebe |
DE10133787A1 (de) * | 2001-07-16 | 2003-02-06 | Basf Ag | Flammfeste textile Flächengebilde |
FR2836932B1 (fr) * | 2002-03-06 | 2004-06-04 | Journe & Lefevre Ets | Fil pour la fabrication d'etoffes a proprietes non-feu antistatiques et bacteriostatiques et etoffes obtenues |
DE10334915A1 (de) * | 2003-07-29 | 2005-04-07 | Klaus Dieter Sakrowski | Hochtemperatur-Schutzdecke |
US7741233B2 (en) | 2006-08-10 | 2010-06-22 | Milliken & Company | Flame-retardant treatments for cellulose-containing fabrics and the fabrics so treated |
CN103349378A (zh) * | 2013-07-26 | 2013-10-16 | 吴江市金迪喷织厂 | 散湿散热面料纤维 |
CN103637407A (zh) * | 2013-11-28 | 2014-03-19 | 苏州工业园区友顺制衣厂 | 一种抗静电抗菌面料 |
RU2689600C1 (ru) * | 2018-03-27 | 2019-05-28 | Российская Федерация, от имени которой выступает ФОНД ПЕРСПЕКТИВНЫХ ИССЛЕДОВАНИЙ | Огнезащитный текстильный материал |
CA3131032A1 (fr) | 2019-02-22 | 2020-08-27 | Jess Black Inc. | Tissu double face de structure tricotee resistant au feu |
CN114541018A (zh) * | 2020-11-11 | 2022-05-27 | 中国石油化工股份有限公司 | 耐久舒适性阻燃织物 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4001477A (en) * | 1971-01-18 | 1977-01-04 | The Carborundum Company | Flame resistant cloth |
US4014829A (en) * | 1974-10-30 | 1977-03-29 | E. I. Du Pont De Nemours And Company | Flame resistant fiber blends |
DE2720633A1 (de) * | 1977-05-07 | 1978-11-16 | Iws Nominee Co Ltd | Flammenbestaendiges garn mit anorganischen textilen faeden (filamenten) |
US4865906A (en) * | 1988-01-22 | 1989-09-12 | Smith Novis W Jr | Flame retardant yard blend |
DE4440491A1 (de) * | 1994-11-12 | 1996-05-15 | Basf Ag | Brandschutzdecken aus Melamin-Formaldehyd-Harzfasern |
US5496625A (en) * | 1994-12-30 | 1996-03-05 | Norfab Corporation | Melamine thermal protective fabric and core-spun heat resistant yarn for making the same |
US5527597A (en) * | 1995-03-01 | 1996-06-18 | Southern Mills, Inc. | Stretchable flame resistant fabric |
DE19523081A1 (de) * | 1995-06-26 | 1997-01-02 | Basf Ag | Fasermischung aus Melaminharzfasern und Naturfasern |
DE19617634A1 (de) * | 1996-05-02 | 1997-11-06 | Basf Ag | Flammfeste Gewebe auf der Basis von Melamin-Harzfasern |
US5849648A (en) * | 1997-04-24 | 1998-12-15 | Basf Corporation | Comfort melamine fabrics and process for making them |
-
1998
- 1998-07-31 DE DE19834495A patent/DE19834495A1/de not_active Ceased
-
1999
- 1999-08-02 EP EP99115023A patent/EP0976335B1/fr not_active Expired - Lifetime
- 1999-08-02 AT AT99115023T patent/ATE237962T1/de active
- 1999-08-02 ES ES99115023T patent/ES2197553T3/es not_active Expired - Lifetime
- 1999-08-02 DE DE59905145T patent/DE59905145D1/de not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2605187C2 (ru) * | 2014-07-09 | 2016-12-20 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Ивановская пожарно-спасательная академия Государственной противопожарной службы МЧС России" | Огнезащитный состав для тканей специального назначения типа молескин на основе афламмита-sap и диоксида кремния |
Also Published As
Publication number | Publication date |
---|---|
DE19834495A1 (de) | 2000-03-02 |
ATE237962T1 (de) | 2003-05-15 |
EP0976335A2 (fr) | 2000-02-02 |
DE59905145D1 (de) | 2003-05-28 |
EP0976335A3 (fr) | 2000-05-03 |
ES2197553T3 (es) | 2004-01-01 |
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