EP0971868A1 - Procede de production de n-butyraldehyde et/ou de n-butanol - Google Patents

Procede de production de n-butyraldehyde et/ou de n-butanol

Info

Publication number
EP0971868A1
EP0971868A1 EP98913678A EP98913678A EP0971868A1 EP 0971868 A1 EP0971868 A1 EP 0971868A1 EP 98913678 A EP98913678 A EP 98913678A EP 98913678 A EP98913678 A EP 98913678A EP 0971868 A1 EP0971868 A1 EP 0971868A1
Authority
EP
European Patent Office
Prior art keywords
reaction
catalyst
butadiene
partial
liquid phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98913678A
Other languages
German (de)
English (en)
Inventor
Jürgen KANAND
Rocco Paciello
Michael Röper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP0971868A1 publication Critical patent/EP0971868A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/32—Preparation of ethers by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C07C41/50—Preparation of compounds having groups by reactions producing groups
    • C07C41/54—Preparation of compounds having groups by reactions producing groups by addition of compounds to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/515—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an acetalised, ketalised hemi-acetalised, or hemi-ketalised hydroxyl group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé de production de n-butyraldéhyde et/ou de n-butanol selon lequel a) on fait réagir du butadiène-1,3 ou des mélanges d'hydrocarbures contenant du butadiène avec un alcool de formule (I) ROH, dans laquelle le reste R est un groupe alkyle C2 à C20 ou alcényle non substitué ou substitué par 1 ou 2 groupes alcoxy C1 à C10 ou hydroxy, un groupe aryle C6 à C10 ou un groupe aralkyle C7 à C11 ou le groupe méthyle, à une température et une pression élevées en présence d'un acide de Brönsted ou en présence d'un complexe d'un élément du groupe IA, VIIA ou VIIIA de la classification périodique des éléments avec des ligands contenant du phosphore ou de l'azote afin de former un mélange des adduits de formules (II) et (III); b) on isomère l'adduit (III) en adduit (II); c) on fait réagir l'adduit (II) en acétal de formule (IV) en présence d'un volume - suffisant pour la formation de l'acétal (IV) - d'un alcool ROH I et d'un catalyseur d'élément de métal de transition homogène ou hétérogène différent de dicobaltoctacarbonyle ou de hydridocobalttétracarbonyle en phase liquide dans un environnement essentiellement exempt d'eau; d) on génère ensuite du n-butyraldéhyde et/ou du n-butanol à partir de cet acétal (IV) par réaction de ce dernier avec de l'hydrogène et de l'eau ou avec de l'eau en présence d'un catalyseur d'élément de métal de transition homogène ou hétérogène différent de dicobaltoctacarbonyle ou de hydridocobalttétracarbonyle en phase liquide et on libère à nouveau l'alcool ROH I. L'alcool ROH I libéré est ramené dans la réaction selon la réaction partielle a) et/ou c).
EP98913678A 1997-03-17 1998-03-06 Procede de production de n-butyraldehyde et/ou de n-butanol Withdrawn EP0971868A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19710994 1997-03-17
DE19710994A DE19710994A1 (de) 1997-03-17 1997-03-17 Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol
PCT/EP1998/001324 WO1998041494A1 (fr) 1997-03-17 1998-03-06 Procede de production de n-butyraldehyde et/ou de n-butanol

Publications (1)

Publication Number Publication Date
EP0971868A1 true EP0971868A1 (fr) 2000-01-19

Family

ID=7823624

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98913678A Withdrawn EP0971868A1 (fr) 1997-03-17 1998-03-06 Procede de production de n-butyraldehyde et/ou de n-butanol

Country Status (11)

Country Link
US (1) US6166265A (fr)
EP (1) EP0971868A1 (fr)
JP (1) JP2001515499A (fr)
KR (1) KR20000076304A (fr)
CN (1) CN1249738A (fr)
AU (1) AU6828998A (fr)
BR (1) BR9808001A (fr)
CA (1) CA2282538A1 (fr)
DE (1) DE19710994A1 (fr)
ID (1) ID22905A (fr)
WO (1) WO1998041494A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9823853D0 (en) 1998-10-30 1998-12-23 Bp Chem Int Ltd A process for making n-butyl esters from butadiene
GB9828338D0 (en) * 1998-12-22 1999-02-17 Bp Chem Int Ltd A process for making butyraldehyde from butadiene
US9024090B2 (en) 2012-12-19 2015-05-05 Celanese International Corporation Catalysts and processes for producing butanol
US8962897B2 (en) 2012-12-19 2015-02-24 Celanese International Corporation Catalysts and processes for producing butanol
US9018426B1 (en) 2013-12-19 2015-04-28 Celanese International Corporation Processes for producing multi-carbon alcohols
WO2017064064A1 (fr) * 2015-10-12 2017-04-20 Basf Se Procédé d'hydroformylation pour produire des dérivés 1,6-disubstitués d'hexane
EP3768802B1 (fr) * 2018-03-19 2023-03-29 SABIC Global Technologies B.V. Procédé de production d'un additif de carburant
CN110937745B (zh) * 2019-12-12 2022-07-12 万华化学集团股份有限公司 一种柠檬醛合成过程中高浓度废水的处理方法
CN113877635B (zh) * 2021-10-27 2024-02-06 南京延长反应技术研究院有限公司 一种铱基催化剂及其制备方法、醛化方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2922822A (en) * 1957-01-08 1960-01-26 Exxon Research Engineering Co Production of methyl butenyl ethers
DE2751766A1 (de) * 1977-11-19 1979-05-23 Basf Ag Verfahren zur isomerisierung von 3-buten-1-ol-verbindungen zu den entsprechenden 2-buten-1-ol-verbindungen
DE4400837A1 (de) * 1994-01-14 1995-07-20 Basf Ag Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9841494A1 *

Also Published As

Publication number Publication date
DE19710994A1 (de) 1998-09-24
CA2282538A1 (fr) 1998-09-24
JP2001515499A (ja) 2001-09-18
KR20000076304A (ko) 2000-12-26
BR9808001A (pt) 2000-03-08
US6166265A (en) 2000-12-26
ID22905A (id) 1999-12-16
AU6828998A (en) 1998-10-12
WO1998041494A1 (fr) 1998-09-24
CN1249738A (zh) 2000-04-05

Similar Documents

Publication Publication Date Title
EP0739332B1 (fr) PROCEDE DE PRODUCTION DE n-BUTYRALDEHYDE ET/OU DE n-BUTANOL
WO2004020380A1 (fr) Procede d'hydroformylation de composes olefiniquement insatures, en particulier d'olefines, en presence d'esters cycliques d'acide carbonique
EP0778819B1 (fr) Procede de fabrication d'aldehyde n-butyrique et/ou de n-butanol
EP0971868A1 (fr) Procede de production de n-butyraldehyde et/ou de n-butanol
EP0061791B1 (fr) Procédé de préparation d'aldéhyde glycolique
EP0761634B1 (fr) Procédé de préparation de penténales
DE10155520A1 (de) Verfahren zur Herstellung von n-Butyraldehyd, n-Butanol und 2-Ethylhexanol aus 1,3-butadienhaltigen Kohlenwasserstoffströmen
EP0191935A1 (fr) Procédé de préparation d'alkyl-2 butanedial-1,4
DE19964298C2 (de) Verfahren zur Herstellung von substituierten Arylhalophosphinen
EP0915839B1 (fr) Procede de preparation de 6-aminocapronitrile
EP0931046B1 (fr) PROCEDE POUR LA PREPARATION DE n-BUTYLALKYLETHERS
DE2154370C3 (de) Verfahren zur Herstellung von Äthern des 2,6-Dimethyl-2,7-octadien-1-ols und einige dieser Äther
EP0150943B1 (fr) Hydroformylation d'alcool allylique
EP0966418A1 (fr) Procede de production d'acetals
DE102005019237B4 (de) Verfahren zur Hydroformylierung von substituierten Allylbenzolen
MXPA99007576A (es) Preparacion de n-butiraldehido y/o n-butanol
CZ9903284A3 (cs) Způsob výroby n-butyraldehydu a/nebo n-butanolu
DE1793616A1 (de) Rhodiumkomplexe
DE3728981A1 (de) Verfahren zur herstellung von ethanol im gemisch mit propanol und butanol

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19990712

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FI FR GB IT LI NL SE

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Withdrawal date: 20020209