EP0831168A2 - Reserverdruck auf hydrophoben Fasermaterialien - Google Patents
Reserverdruck auf hydrophoben Fasermaterialien Download PDFInfo
- Publication number
- EP0831168A2 EP0831168A2 EP97810649A EP97810649A EP0831168A2 EP 0831168 A2 EP0831168 A2 EP 0831168A2 EP 97810649 A EP97810649 A EP 97810649A EP 97810649 A EP97810649 A EP 97810649A EP 0831168 A2 EP0831168 A2 EP 0831168A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dye
- printing
- printed
- eines
- printing paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000007639 printing Methods 0.000 title claims abstract description 57
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 16
- 239000002657 fibrous material Substances 0.000 title claims description 34
- 239000000975 dye Substances 0.000 claims abstract description 52
- 239000000986 disperse dye Substances 0.000 claims abstract description 19
- 239000003599 detergent Substances 0.000 claims abstract description 8
- 125000002091 cationic group Chemical group 0.000 claims abstract description 7
- 238000004043 dyeing Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 229920000728 polyester Polymers 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 28
- 239000000835 fiber Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 28
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
- 150000001298 alcohols Chemical class 0.000 description 13
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 12
- 229920002472 Starch Polymers 0.000 description 12
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 12
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- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 10
- 229910052736 halogen Inorganic materials 0.000 description 10
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- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 10
- 239000001488 sodium phosphate Substances 0.000 description 10
- 229910000162 sodium phosphate Inorganic materials 0.000 description 10
- 235000011008 sodium phosphates Nutrition 0.000 description 10
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 10
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 8
- -1 Hydroxy, Amino Chemical group 0.000 description 8
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- 239000003795 chemical substances by application Substances 0.000 description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 7
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
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- 125000004093 cyano group Chemical group *C#N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
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- 239000003995 emulsifying agent Substances 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229930188620 butyrolactone Natural products 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
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- 238000004140 cleaning Methods 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
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- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 239000003799 water insoluble solvent Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- MWQBXOFZQBEAQV-UHFFFAOYSA-N 1,3-diamino-1,3-dinitrourea Chemical compound [N+](=O)([O-])N(N)C(=O)N([N+](=O)[O-])N MWQBXOFZQBEAQV-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- WKVMOQXBMPYPGK-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].OC(=O)CN(CC(O)=O)CC(O)=O WKVMOQXBMPYPGK-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- HWTDMFJYBAURQR-UHFFFAOYSA-N 80-82-0 Chemical compound OS(=O)(=O)C1=CC=CC=C1[N+]([O-])=O HWTDMFJYBAURQR-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
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- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- VJMAITQRABEEKP-UHFFFAOYSA-N [6-(phenylmethoxymethyl)-1,4-dioxan-2-yl]methyl acetate Chemical compound O1C(COC(=O)C)COCC1COCC1=CC=CC=C1 VJMAITQRABEEKP-UHFFFAOYSA-N 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
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- 239000002518 antifoaming agent Substances 0.000 description 1
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- 239000000987 azo dye Substances 0.000 description 1
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- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
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- 238000010014 continuous dyeing Methods 0.000 description 1
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- 235000001671 coumarin Nutrition 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 238000010018 discharge printing Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- AAAUMZZBNYAFHL-UHFFFAOYSA-N nitro nitroformate Chemical compound [O-][N+](=O)OC(=O)[N+]([O-])=O AAAUMZZBNYAFHL-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical class [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229940045919 sodium polymetaphosphate Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229920006304 triacetate fiber Polymers 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/158—Locally discharging the dyes with other compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5242—Polymers of unsaturated N-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
- D06P1/6076—Nitrogen-containing polyethers or their quaternary derivatives addition products of amines and alkylene oxides or oxiranes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6136—Condensation products of esters, acids, oils, oxyacids with oxiranes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65131—Compounds containing ether or acetal groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
- D06P5/2077—Thermic treatments of textile materials after dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/922—Polyester fiber
Definitions
- the present invention relates to a method for printing hydrophobic Fiber materials with disperse dyes using the reserve printing process.
- the reserve printing process with disperse dyes is known for hydrophobic fiber materials.
- the printing of these materials, especially polyester fiber materials is mostly carried out with a so-called etching reserve process, in which the pre-dyed or pre-printed basic dye is locally destroyed by treatment with a strongly alkaline auxiliary and one or more other dyes, which are resistant to etching, are applied to these areas have to print.
- treatment with the etchant is associated with disadvantages both ecologically and economically; For example, the treated fiber material can be attacked and damaged by the action of strong alkali. There is therefore a need for a simpler and more gentle reserve printing process for printing on hydrophobic fiber materials, in particular polyester fiber materials.
- the process according to the invention can print the hydrophobic fiber material in a way that is gentle on the fibers, the resulting Print has good general fastness properties and in particular a very good hot light fastness.
- Suitable disperse dyes for the process according to the invention are those dyes which are in the Color Index, 3rd edition (3rd revision 1987 including additions and Amendments to No. 85) are described under "Disperse Dyes”.
- Disperse Dyes For example carbonic acid and / or sulfonic acid group-free nitro, amino, aminoketone, ketoninim, Methine, polymethine, diphenylamine, quinoline, benzimidazole, xanthene, oxazine or coumarin dyes and in particular anthraquinone and azo dyes, such as mono- or disazo dyes.
- the amounts in which the disperse dyes in the dye baths, respectively Printing pastes used can vary depending on the desired color depth; in the in general, amounts of 0.01 to 15 percent by weight, in particular 0.1 to 10 Percentage by weight, based on the total amount of dyes per 1 l of the liquor, respectively 0.01 to 400 g, in particular 0.2 to 300 g, especially 0.5 to 200 g of the dyes per kg of printing paste, proven to be advantageous.
- the hydrophobic fiber material is dyed in step A), a continuous dyeing process, such as the padding process, is usually used.
- the dyed material is optionally dried before further treatment.
- the dye liquor can contain other generally customary additives, for example acid donors, such as, for example, aliphatic amine chlorides or magnesium chloride, the aqueous solutions of inorganic salts, for example alkali metal chlorides or alkali metal sulfates, alkali metal hydroxides, urea, thickeners, for example alginate thickeners, water-soluble cellulose alkyl ethers and leveling agents Antifoam and / or deaerating agents, penetration accelerators, migration inhibitors, UV absorbers and wetting agents.
- acid donors such as, for example, aliphatic amine chlorides or magnesium chloride
- the aqueous solutions of inorganic salts for example alkali metal chlorides or alkali metal sulfates, alkali metal hydroxides, urea
- the printing paste optionally used in step A) is a printing paste which is customary in printing technology and which, apart from the dye, contains the customary auxiliaries, for example expedient thickeners of natural or synthetic origin, such as, for example, commercially available alginate thickeners, starch ether or locust bean gum ether, in particular sodium alginate or in a mixture with modified cellulose, in particular with preferably 20 to 25 percent by weight of carboxymethyl cellulose.
- expedient thickeners such as those based on poly (meth) acrylic acids, poly (meth) acrylamides, and their copolymers or terpolymers, are preferably used in the above printing paste.
- the printing paste may also contain acid donors such as butyrolactone or sodium hydrogen phosphate, preservatives, sequestering agents, emulsifiers, water-insoluble solvents, oxidizing agents, UV absorbers or deaerating agents.
- acid donors such as butyrolactone or sodium hydrogen phosphate
- preservatives such as butyrolactone or sodium hydrogen phosphate
- sequestering agents such as sodium hydrogen phosphate
- emulsifiers such as water-insoluble solvents
- oxidizing agents such as butyrolactone or sodium hydrogen phosphate
- UV absorbers or deaerating agents.
- Organic polymer compounds containing quaternized amines or salts of nitrogen-containing organic polymer compounds are particularly suitable as cationic auxiliaries in the printing paste used in step B). These include, in particular, organic polymer compounds based on the polymono- and polydiallylamines, such as, for example, polydiallylammonium hydrochloride or polydiallyldimethylammonium chloride.
- the printing paste usually contains 0.5 to 20, preferably 1 to 10 g of the cationic auxiliary per 1 kg of the printing paste.
- the non-ionic detergents used in the printing paste used in step B) are, for example Fatty acid polyglycol esters, or in particular those compounds used, by the addition of 4 to 80 ethylene and / or propylene oxide units to fatty alcohols, Fatty amines, fatty acids or alkylaryls, e.g. Nonyl- or octylphenol arise.
- these compounds are cetyl alcohol with 4-6 ethylene oxide units, Cetyl alcohol with 10-14 ethylene oxide units, tallow fatty alcohol with 10 to 25 ethylene oxide units, Lauryl alcohol with 5-8 ethylene oxide units, nonylphenol with 3 to 10 ethylene oxide units, Castor oil with 36 ethylene oxide units or oleic acid with 5 to 15 ethylene oxide units.
- Non-foaming or low-foaming nonionic detergents are advantageously used in the process according to the invention.
- the printing paste usually contains 1 to 60, preferably 5 to 40 g of the nonionic detergent per 1 kg of the printing paste.
- the printing paste used in step B) can in addition to the components mentioned above other common aids, e.g. expediently thickeners of natural or synthetic Origin, e.g. commercial alginate thickeners, starch ether or locust bean flour ether, especially sodium alginate alone or in a mixture with modified Cellulose, in particular with preferably 20 to 25 percent by weight carboxymethyl cellulose, contain.
- expediently thickeners of natural or synthetic Origin e.g. commercial alginate thickeners, starch ether or locust bean flour ether, especially sodium alginate alone or in a mixture with modified Cellulose, in particular with preferably 20 to 25 percent by weight carboxymethyl cellulose, contain.
- synthetic thickeners e.g. those based on poly (meth) acrylic acids, poly (meth) acrylamides, and their copolymers or terpolymers are used.
- the printing pastes can also be acid donors such as butyrolactone or Sodium hydrogen phosphate, preservatives, sequestering agents, emulsifiers, water-insoluble Contain solvents, oxidizing agents, UV absorbers or deaerating agents.
- acid donors such as butyrolactone or Sodium hydrogen phosphate
- preservatives such as butyrolactone or Sodium hydrogen phosphate
- sequestering agents such as butyrolactone or Sodium hydrogen phosphate
- emulsifiers such as water-insoluble Contain solvents
- oxidizing agents such as butyrolactone or Sodium hydrogen phosphate
- UV absorbers or deaerating agents.
- Particularly suitable preservatives are formaldehyde-releasing agents, such as paraformaldehyde and trioxane, especially aqueous, approximately 30 to 40 percent by weight formaldehyde solutions, UV absorbers, especially triazine UV absorbers, and sequestrants, such as sodium nitrilotriacetic acid and sodium ethylenediaminetetraacetic acid all sodium polymetaphosphate, especially sodium hexametaphosphate, as emulsifiers, especially adducts of an alkylene oxide and a fatty alcohol, especially an adduct of oleyl alcohol and ethylene oxide, as water-insoluble solvents, high-boiling, saturated hydrocarbons, especially paraffins with a boiling range of about 160 to 210 ° C (so-called mineral spirits), as an oxidizing agent, for example an aromatic nitro compound, especially an aromatic mono- or dinitrocarboxylic acid or sulfonic acid, which is optionally present as an alkylene oxide
- polyester fiber materials are preferred.
- Suitable polyester fiber materials are those materials which consist entirely or partially of polyester.
- cellulose ester fibers such as cellulose-21/2-acetate fibers and triacetate fibers, and particularly linear polyester fibers, which are also optionally acid-modified, which are obtained, for example, by condensation of terephthalic acid with ethylene glycol or of isophthalic acid or terephthalic acid with 1,4-bis (hydroxymethyl ) -cyclohexane are obtained, as well as fibers from copolymers of terephthalic and isophthalic acid with ethylene glycol.
- polyester-containing mixed fiber materials ie mixtures of polyester and other fibers, in particular cotton / polyester fiber materials. Mainly fabrics, knitted fabrics or webs of these fibers are used.
- the printing paste is applied over the entire surface or in places directly to the fiber material, printing machines of the usual type, for example gravure, rotary screen printing and flat film printing machines, being used expediently.
- the method according to the invention is preferably carried out in a “one step process" on the "HW Dyeing & Discharge Printing Line” apparatus from Johannes Zimmer, A-9020 Klagenfurt (patent applied No. A 468/95).
- the fiber material is preferably at temperatures up to 150 ° C. Dried 80 ° to 120 ° C.
- the prints are usually washed out after fixing and then opened usual way by cleaning in alkaline medium under reductive conditions, e.g. using sodium dithionite. After cleaning, the prints are rinsed again and dried.
- the prints on polyester fiber materials obtainable by the process according to the invention have good general fastnesses; e.g. they have high fiber-dye binding stability both in the acidic and in the alkaline range, good wet fastness, such as fastness to washing, water, sea water and sweat, good chlorine fastness, Rubbing fastness, ironing fastness and pleating fastness and are characterized in particular by a Extension of the brilliant colors with high light and hot light fastness.
- the treated polyester fabric is then dried and fixed with HT steam at 180 ° C. for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. You get a two-tone gray-blue reserve print with sharp contours and very good hot light fastness.
- the printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. You get a two-tone gray-red reserve print with sharp contours and very good fastness to hot light.
- the printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. A two-tone gray-violet reserve print with sharp contours and very good fastness to hot light is obtained.
- the printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. A tri-color gray-red-yellow reserve print with sharp contours and very good fastness to hot light is obtained.
- the treated polyester fabric is then dried and fixed with HT steam at 180 ° C. for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. A two-tone gray-yellow reserve print with sharp contours and very good fastness to hot light is obtained.
Abstract
Description
Es besteht daher ein Bedürfniss nach einem einfacheren und faserschonenden Reservedruckverfahren für das Bedrucken von hydrophoben Fasermaterialien, insbesondere Polyesterfasermaterialien.
- R8 und R9 voneinander unabhängig Wasserstoff, -(CH2)2-O-(CH2)2-OX oder
-(CH2)3-O-(CH2)4-OX, worin X Wasserstoff oder -COCH3 ist,
bedeutet,
- R10 Amino welches durch -(CH2)2-O-COCH3, -(CH2)2-CN, -CH(CH3)-COOCH3 oder -CH2-C(OH)CH3 mono- oder disubstituiert ist,
- R11 Wasserstoff, C1-C4-Alkyl oder Halogen,
- R12 Wasserstoff oder NHCOR15, worin R15 C1-C3-Alkyl ist,
- R13 Wasserstoff oder Halogen, und
- R14 Halogen, Nitro oder Cyano bedeutet,
Die Färbeflotte kann ausser dem Farbstoff weitere allgemein üblichen Zusätze enthalten, beispielsweise Säurespender, wie z.B. aliphatische Aminchloride oder Magnesiumchlorid, die wässrigen Lösungen anorganischer Salze, z.B. von Alkalichloriden oder Alkalisulfaten, Alkalihydroxide, Harnstoff, Verdickungen, wie z.B. Alginatverdickungen, wasserlösliche Cellulosealkyläther sowie Egalisier-, Antischaum- und/oder Entlüftungsmittel, Penetrationsbeschleuniger, Migrationsinhibitoren, UV-Absorber sowie Netzmittel.
Gewünschtenfalls kann die Druckpaste noch Säurespender wie Butyrolacton oder Natriumhydrogenphosphat, Konservierungsmittel, Sequestriermittel, Emulgatoren, wasserunlösliche Lösungsmittel, Oxidationsmittel, UV-Absorber oder Entlüftungsmittel enthalten.
Unter diesen sind insbesondere organische Polymerverbindungen auf Basis der Polymono- und Polydiallylamine zu nennen, wie z.B. Polydiallylammoniumhydrochlorid oder Polydiallyldimethylammoniumchlorid.
Die Druckpaste enthält üblicherweise 0,5 bis 20, vorzugsweise 1 bis 10 g des kationischen Hilfsmittels pro 1 kg der Druckpaste.
Die Druckpaste enthält üblicherweise 1 bis 60, vorzugsweise 5 bis 40 g des nichtionogenen Waschmittels pro 1 kg der Druckpaste.
Bevorzugt sind Polyesterfasermaterialien.
Als Polyesterfasermaterialien kommen solche Materialien in Betracht, die ganz oder teilweise aus Polyester bestehen. Beispiele sind Celluloseesterfasern, wie z.B. Cellulose-21/2-acetatfasern und -triacetatfasern, und besonders lineare Polyesterfasern, die gegebenenfalls auch sauer modifiziert sind, welche z.B. durch Kondensation von Terephthalsäure mit Ethylenglykol oder von Isophthalsäure oder Terephthalsäure mit 1 ,4-Bis(hydroxymethyl)-cyclohexan erhalten werden, sowie Fasern aus Mischpolymeren von Terephthal- und Isophthalsäure mit Ethylenglykol. Geeignet sind weiter polyesterhaltige Mischfasermaterialien, d.h. Mischungen aus Polyester und anderen Fasem, insbesondere Baumwolle/Polyesterfasermaterialien.
Hauptsächlich werden Gewebe, Gewirke oder Bahnen dieser Fasern verwendet.
Bevorzugt wird das erfindungsgemässe Verfahren in einem "one step process" auf der "H.W. Dyeing & Discharge Printing Line"-Apparatur der Fa. Johannes Zimmer, A-9020 Klagenfurt (Patent applied No. A 468/95) durchgeführt.
- HT-Fixierung:
- 5 bis 10 Minuten bei 170 bis 190°C
- Thermofixierung:
- 1 bis 2 Minuten bei 170 bis 220°C.
Man erhält einen zweifarbigen grau-blauen Reservedruck mit scharfen Konturen und einer sehr guten Heisslichtechtheit.
Man erhält einen zweifarbigen grau-roten Reservedruck mit scharfen Konturen und einer sehr guten Heisslichtechtheit.
- 256 g einer handelsüblichen 6%-igen Alginatverdickung,
- 64 g einer Formulierung enthaltend 10% eines Verdickungsmittels auf Basis von Stärkeäther,
- 8 g eines handelsüblichen Entlüfters auf Basis von aliphatischen Kohlenwasserstoffen und Alkoholen,
- 4 g Natriumphosphat,
- 8 g Natriumchlorat,
- 54 g einer handelsüblichen Formulierung enthaltend ca. 20% eines Triazin-UV-absorbers,
- 1,62 g des Farbstoffes der Formel (8),
- 2,37 g des Farbstoffes der Formel (6),
- 0,8 g des Farbstoffes der Formel (100),
- 0,61 g des Farbstoffes der Formel (101) und
- 9,29 g des Farbstoffes der Formel (102)
Man erhält einen zweifarbigen grau-violetten Reservedruck mit scharfen Konturen und einer sehr guten Heisslichtechtheit.
- 440 g einer Formulierung enthaltend 10% eines Verdickungsmittels auf Basis von Stärkeäther,
- 8 g eines handelsüblichen Entlüfters auf Basis von aliphatischen Kohlenwasserstoffen und Alkoholen,
- 4 g Natriumphosphat,
- 8 g Natriumchlorat,
- 54 g einer handelsüblichen Formulierung enthaltend ca. 20% eines Triazin-UV-absorbers,
- 25 g eines Anlagerungsproduktes von 36 Ethylenoxideinheiten an 1 Mol Ricinusöl,
- 3 g Polydiallyldimethylammoniumchlorid und
- 6 g des Farbstoffes der Formel (8)
Man erhält einen dreifarbigen grau-rot-gelben Reservedruck mit scharfen Konturen und einer sehr guten Heisslichtechtheit.
Man erhält einen zweifarbigen grau-gelben Reservedruck mit scharfen Konturen und einer sehr guten Heisslichtechtheit.
Claims (7)
- Verfahren zum Bedrucken von hydrophoben Fasermaterialien mit Dispersionsfarbstoffen, dadurch gekennzeichnet, dass man die FasermaterialienA) mit einem Dispersionsfarbstoff ganzflächig färbt oder ganzflächig bedruckt undB) mit einer Druckpaste enthaltendmindestens einen Dispersionsfarbstoff,mindestens ein kationisches Hilfsmittel, undmindestens ein nichtionogenes Waschmittel stellenweise bedruckt, wobei die Schritte A) und B) in beliebiger Reihenfolge erfolgen können und der Schritt B) mit unterschiedlichen Farbstoffen mehrmals wiederholt werden kann, das so behandelte Fasermaterial trocknet und anschliessend den Farbstoff auf dem Fasermaterial durch eine Hitzebehandlung fixiert.
- Verfahren gemäss Anspruch 1, dadurch gekennzeichnet, dass man die hydrophoben Fasermaterialien zuerst mit einem Dispersionsfarbstoff ganzflächig färbt oder ganzflächig bedruckt und anschliessend einmal oder mehrmals mit einer Druckpaste enthaltend mindestens einen Dispersionsfarbstoff, mindestens ein kationisches Hilfsmittel, und mindestens ein nichtionogenes Waschmittel stellenweise bedruckt.
- Verfahren gemäss Anspruch 1, dadurch gekennzeichnet, dass man die hydrophoben Fasermaterialien zuerst mit einer Druckpaste enthaltend mindestens einen Dispersionsfarbstoff, mindestens ein kationisches Hilfsmittel, und mindestens ein nichtionogenes Waschmittel einmal oder mehrmals stellenweise bedruckt und anschliessend mit einem Dispersionsfarbstoff ganzflächig färbt oder ganzflächig bedruckt.
- Verfahren gemäss einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass man das hydrophobe Fasermaterial im Schritt A) färbt.
- Verfahren gemäss einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass man das hydrophobe Fasermaterial im Schritt A) bedruckt.
- Verfahren gemäss einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass man als hydrophobe Fasermaterialien Polyesterfasermaterialien verwendet.
- Das mit dem Verfahren gemäss einem der Ansprüche 1 bis 6 behandelte Fasermaterial.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH231096 | 1996-09-20 | ||
CH2310/96 | 1996-09-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0831168A2 true EP0831168A2 (de) | 1998-03-25 |
EP0831168A3 EP0831168A3 (de) | 1998-09-02 |
Family
ID=4230815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97810649A Withdrawn EP0831168A3 (de) | 1996-09-20 | 1997-09-11 | Reserverdruck auf hydrophoben Fasermaterialien |
Country Status (7)
Country | Link |
---|---|
US (1) | US5917120A (de) |
EP (1) | EP0831168A3 (de) |
JP (1) | JPH10110393A (de) |
KR (1) | KR19980024726A (de) |
BR (1) | BR9704753A (de) |
ID (1) | ID18306A (de) |
PL (1) | PL322193A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999067459A1 (en) * | 1998-06-19 | 1999-12-29 | Ciba Specialty Chemicals Holding Inc. | Resist printing on hydrophobic fibre materials |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020124323A1 (en) * | 2001-01-09 | 2002-09-12 | Cliver James D. | Process for patterning textile materials and fabrics made therefrom |
US6759354B1 (en) | 2001-08-28 | 2004-07-06 | Intex Corporation | Printable synthetic fabric |
US20040214493A1 (en) * | 2001-08-28 | 2004-10-28 | Smith Garnett H. | Printable synthetic fabric |
DE102008039500A1 (de) * | 2008-08-23 | 2010-02-25 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Verfahren zum Färben von textilen Materialien |
ITSA20120006A1 (it) * | 2012-05-10 | 2013-11-11 | Oz Anadolu Kimya Sanayi Ve Ticaret Anonim Sirketi | Innovazione nelle paste corrodenti per la stampa tessile. |
CN104674568B (zh) * | 2015-01-23 | 2017-01-25 | 郎溪飞马工业织品有限公司 | 一种安全织带的染色方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2025158A1 (de) * | 1969-06-03 | 1970-12-10 | Ciba AG, Basel (Schweiz) | Verfahren zum Färben und Bedrucken von Textilmaterialien aus synthetischen organischen Fasern |
US4398914A (en) * | 1981-02-19 | 1983-08-16 | Basf Aktiengesellschaft | Process for discharge or reserve printing on synthetic fibers: formaldehyde sulfoxylate and hexamethylene tetramine |
EP0088996A1 (de) * | 1982-03-15 | 1983-09-21 | CASSELLA Aktiengesellschaft | Verfahren zur Herstellung von Ätzreservedrucken auf hydrophoben Textilmaterialien |
DE4310919A1 (de) * | 1993-04-02 | 1994-10-06 | Dlw Ag | Naß-auf-naß, Weiß- oder Buntreservedruck auf modifiziertem PES-Teppich im Übergießverfahren sowie Druckpaste dafür |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3964862A (en) * | 1969-06-03 | 1976-06-22 | Ciba-Geigy Ag | Process for dyeing and printing textile materials of synthetic organic fibers |
DE3065937D1 (en) * | 1979-06-01 | 1984-01-26 | Hoechst Ag | Process for the local "white discharging" or "coloured discharging" of dyes on textile materials |
CH658565GA3 (de) * | 1980-03-20 | 1986-11-28 | ||
EP0490814A1 (de) * | 1990-12-11 | 1992-06-17 | Ciba-Geigy Ag | Pastöse bis feste Farbstoff-Schmelzen |
-
1997
- 1997-09-11 EP EP97810649A patent/EP0831168A3/de not_active Withdrawn
- 1997-09-16 ID IDP973204A patent/ID18306A/id unknown
- 1997-09-19 PL PL97322193A patent/PL322193A1/xx unknown
- 1997-09-19 US US08/933,592 patent/US5917120A/en not_active Expired - Fee Related
- 1997-09-19 JP JP9254602A patent/JPH10110393A/ja active Pending
- 1997-09-19 KR KR1019970047636A patent/KR19980024726A/ko not_active Application Discontinuation
- 1997-09-19 BR BR9704753A patent/BR9704753A/pt not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2025158A1 (de) * | 1969-06-03 | 1970-12-10 | Ciba AG, Basel (Schweiz) | Verfahren zum Färben und Bedrucken von Textilmaterialien aus synthetischen organischen Fasern |
US4398914A (en) * | 1981-02-19 | 1983-08-16 | Basf Aktiengesellschaft | Process for discharge or reserve printing on synthetic fibers: formaldehyde sulfoxylate and hexamethylene tetramine |
EP0088996A1 (de) * | 1982-03-15 | 1983-09-21 | CASSELLA Aktiengesellschaft | Verfahren zur Herstellung von Ätzreservedrucken auf hydrophoben Textilmaterialien |
DE4310919A1 (de) * | 1993-04-02 | 1994-10-06 | Dlw Ag | Naß-auf-naß, Weiß- oder Buntreservedruck auf modifiziertem PES-Teppich im Übergießverfahren sowie Druckpaste dafür |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999067459A1 (en) * | 1998-06-19 | 1999-12-29 | Ciba Specialty Chemicals Holding Inc. | Resist printing on hydrophobic fibre materials |
US6616711B1 (en) | 1998-06-19 | 2003-09-09 | Ciba Speciality Chemicals Corporation | Resist printing on hydrophobic fiber materials |
Also Published As
Publication number | Publication date |
---|---|
ID18306A (id) | 1998-03-26 |
JPH10110393A (ja) | 1998-04-28 |
BR9704753A (pt) | 1998-11-17 |
EP0831168A3 (de) | 1998-09-02 |
PL322193A1 (en) | 1998-03-30 |
US5917120A (en) | 1999-06-29 |
KR19980024726A (ko) | 1998-07-06 |
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