EP0831168A2 - Reserve printing of hydrophobic fibrous materials - Google Patents
Reserve printing of hydrophobic fibrous materials Download PDFInfo
- Publication number
- EP0831168A2 EP0831168A2 EP97810649A EP97810649A EP0831168A2 EP 0831168 A2 EP0831168 A2 EP 0831168A2 EP 97810649 A EP97810649 A EP 97810649A EP 97810649 A EP97810649 A EP 97810649A EP 0831168 A2 EP0831168 A2 EP 0831168A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dye
- printing
- printed
- eines
- printing paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000007639 printing Methods 0.000 title claims abstract description 57
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 16
- 239000002657 fibrous material Substances 0.000 title claims description 34
- 239000000975 dye Substances 0.000 claims abstract description 52
- 239000000986 disperse dye Substances 0.000 claims abstract description 19
- 239000003599 detergent Substances 0.000 claims abstract description 8
- 125000002091 cationic group Chemical group 0.000 claims abstract description 7
- 238000004043 dyeing Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 229920000728 polyester Polymers 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 28
- 239000000835 fiber Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 28
- 239000006096 absorbing agent Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 26
- 239000002562 thickening agent Substances 0.000 description 23
- 238000009472 formulation Methods 0.000 description 22
- 239000004744 fabric Substances 0.000 description 21
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
- 150000001298 alcohols Chemical class 0.000 description 13
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 12
- 229920002472 Starch Polymers 0.000 description 12
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 12
- 239000008107 starch Substances 0.000 description 12
- 235000019698 starch Nutrition 0.000 description 12
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 11
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 10
- 229910052736 halogen Inorganic materials 0.000 description 10
- 150000002367 halogens Chemical class 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 10
- 239000001488 sodium phosphate Substances 0.000 description 10
- 229910000162 sodium phosphate Inorganic materials 0.000 description 10
- 235000011008 sodium phosphates Nutrition 0.000 description 10
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 10
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 8
- -1 Hydroxy, Amino Chemical group 0.000 description 8
- 229940072056 alginate Drugs 0.000 description 8
- 235000010443 alginic acid Nutrition 0.000 description 8
- 229920000615 alginic acid Polymers 0.000 description 8
- 239000004359 castor oil Substances 0.000 description 7
- 235000019438 castor oil Nutrition 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 7
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 125000004093 cyano group Chemical group *C#N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229930188620 butyrolactone Natural products 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 239000003799 water insoluble solvent Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- MWQBXOFZQBEAQV-UHFFFAOYSA-N 1,3-diamino-1,3-dinitrourea Chemical compound [N+](=O)([O-])N(N)C(=O)N([N+](=O)[O-])N MWQBXOFZQBEAQV-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- WKVMOQXBMPYPGK-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].OC(=O)CN(CC(O)=O)CC(O)=O WKVMOQXBMPYPGK-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- HWTDMFJYBAURQR-UHFFFAOYSA-N 80-82-0 Chemical compound OS(=O)(=O)C1=CC=CC=C1[N+]([O-])=O HWTDMFJYBAURQR-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- VJMAITQRABEEKP-UHFFFAOYSA-N [6-(phenylmethoxymethyl)-1,4-dioxan-2-yl]methyl acetate Chemical compound O1C(COC(=O)C)COCC1COCC1=CC=CC=C1 VJMAITQRABEEKP-UHFFFAOYSA-N 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010014 continuous dyeing Methods 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 238000010018 discharge printing Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- AAAUMZZBNYAFHL-UHFFFAOYSA-N nitro nitroformate Chemical compound [O-][N+](=O)OC(=O)[N+]([O-])=O AAAUMZZBNYAFHL-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical class [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229940045919 sodium polymetaphosphate Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229920006304 triacetate fiber Polymers 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/158—Locally discharging the dyes with other compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5242—Polymers of unsaturated N-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
- D06P1/6076—Nitrogen-containing polyethers or their quaternary derivatives addition products of amines and alkylene oxides or oxiranes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6136—Condensation products of esters, acids, oils, oxyacids with oxiranes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65131—Compounds containing ether or acetal groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
- D06P5/2077—Thermic treatments of textile materials after dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/922—Polyester fiber
Definitions
- the present invention relates to a method for printing hydrophobic Fiber materials with disperse dyes using the reserve printing process.
- the reserve printing process with disperse dyes is known for hydrophobic fiber materials.
- the printing of these materials, especially polyester fiber materials is mostly carried out with a so-called etching reserve process, in which the pre-dyed or pre-printed basic dye is locally destroyed by treatment with a strongly alkaline auxiliary and one or more other dyes, which are resistant to etching, are applied to these areas have to print.
- treatment with the etchant is associated with disadvantages both ecologically and economically; For example, the treated fiber material can be attacked and damaged by the action of strong alkali. There is therefore a need for a simpler and more gentle reserve printing process for printing on hydrophobic fiber materials, in particular polyester fiber materials.
- the process according to the invention can print the hydrophobic fiber material in a way that is gentle on the fibers, the resulting Print has good general fastness properties and in particular a very good hot light fastness.
- Suitable disperse dyes for the process according to the invention are those dyes which are in the Color Index, 3rd edition (3rd revision 1987 including additions and Amendments to No. 85) are described under "Disperse Dyes”.
- Disperse Dyes For example carbonic acid and / or sulfonic acid group-free nitro, amino, aminoketone, ketoninim, Methine, polymethine, diphenylamine, quinoline, benzimidazole, xanthene, oxazine or coumarin dyes and in particular anthraquinone and azo dyes, such as mono- or disazo dyes.
- the amounts in which the disperse dyes in the dye baths, respectively Printing pastes used can vary depending on the desired color depth; in the in general, amounts of 0.01 to 15 percent by weight, in particular 0.1 to 10 Percentage by weight, based on the total amount of dyes per 1 l of the liquor, respectively 0.01 to 400 g, in particular 0.2 to 300 g, especially 0.5 to 200 g of the dyes per kg of printing paste, proven to be advantageous.
- the hydrophobic fiber material is dyed in step A), a continuous dyeing process, such as the padding process, is usually used.
- the dyed material is optionally dried before further treatment.
- the dye liquor can contain other generally customary additives, for example acid donors, such as, for example, aliphatic amine chlorides or magnesium chloride, the aqueous solutions of inorganic salts, for example alkali metal chlorides or alkali metal sulfates, alkali metal hydroxides, urea, thickeners, for example alginate thickeners, water-soluble cellulose alkyl ethers and leveling agents Antifoam and / or deaerating agents, penetration accelerators, migration inhibitors, UV absorbers and wetting agents.
- acid donors such as, for example, aliphatic amine chlorides or magnesium chloride
- the aqueous solutions of inorganic salts for example alkali metal chlorides or alkali metal sulfates, alkali metal hydroxides, urea
- the printing paste optionally used in step A) is a printing paste which is customary in printing technology and which, apart from the dye, contains the customary auxiliaries, for example expedient thickeners of natural or synthetic origin, such as, for example, commercially available alginate thickeners, starch ether or locust bean gum ether, in particular sodium alginate or in a mixture with modified cellulose, in particular with preferably 20 to 25 percent by weight of carboxymethyl cellulose.
- expedient thickeners such as those based on poly (meth) acrylic acids, poly (meth) acrylamides, and their copolymers or terpolymers, are preferably used in the above printing paste.
- the printing paste may also contain acid donors such as butyrolactone or sodium hydrogen phosphate, preservatives, sequestering agents, emulsifiers, water-insoluble solvents, oxidizing agents, UV absorbers or deaerating agents.
- acid donors such as butyrolactone or sodium hydrogen phosphate
- preservatives such as butyrolactone or sodium hydrogen phosphate
- sequestering agents such as sodium hydrogen phosphate
- emulsifiers such as water-insoluble solvents
- oxidizing agents such as butyrolactone or sodium hydrogen phosphate
- UV absorbers or deaerating agents.
- Organic polymer compounds containing quaternized amines or salts of nitrogen-containing organic polymer compounds are particularly suitable as cationic auxiliaries in the printing paste used in step B). These include, in particular, organic polymer compounds based on the polymono- and polydiallylamines, such as, for example, polydiallylammonium hydrochloride or polydiallyldimethylammonium chloride.
- the printing paste usually contains 0.5 to 20, preferably 1 to 10 g of the cationic auxiliary per 1 kg of the printing paste.
- the non-ionic detergents used in the printing paste used in step B) are, for example Fatty acid polyglycol esters, or in particular those compounds used, by the addition of 4 to 80 ethylene and / or propylene oxide units to fatty alcohols, Fatty amines, fatty acids or alkylaryls, e.g. Nonyl- or octylphenol arise.
- these compounds are cetyl alcohol with 4-6 ethylene oxide units, Cetyl alcohol with 10-14 ethylene oxide units, tallow fatty alcohol with 10 to 25 ethylene oxide units, Lauryl alcohol with 5-8 ethylene oxide units, nonylphenol with 3 to 10 ethylene oxide units, Castor oil with 36 ethylene oxide units or oleic acid with 5 to 15 ethylene oxide units.
- Non-foaming or low-foaming nonionic detergents are advantageously used in the process according to the invention.
- the printing paste usually contains 1 to 60, preferably 5 to 40 g of the nonionic detergent per 1 kg of the printing paste.
- the printing paste used in step B) can in addition to the components mentioned above other common aids, e.g. expediently thickeners of natural or synthetic Origin, e.g. commercial alginate thickeners, starch ether or locust bean flour ether, especially sodium alginate alone or in a mixture with modified Cellulose, in particular with preferably 20 to 25 percent by weight carboxymethyl cellulose, contain.
- expediently thickeners of natural or synthetic Origin e.g. commercial alginate thickeners, starch ether or locust bean flour ether, especially sodium alginate alone or in a mixture with modified Cellulose, in particular with preferably 20 to 25 percent by weight carboxymethyl cellulose, contain.
- synthetic thickeners e.g. those based on poly (meth) acrylic acids, poly (meth) acrylamides, and their copolymers or terpolymers are used.
- the printing pastes can also be acid donors such as butyrolactone or Sodium hydrogen phosphate, preservatives, sequestering agents, emulsifiers, water-insoluble Contain solvents, oxidizing agents, UV absorbers or deaerating agents.
- acid donors such as butyrolactone or Sodium hydrogen phosphate
- preservatives such as butyrolactone or Sodium hydrogen phosphate
- sequestering agents such as butyrolactone or Sodium hydrogen phosphate
- emulsifiers such as water-insoluble Contain solvents
- oxidizing agents such as butyrolactone or Sodium hydrogen phosphate
- UV absorbers or deaerating agents.
- Particularly suitable preservatives are formaldehyde-releasing agents, such as paraformaldehyde and trioxane, especially aqueous, approximately 30 to 40 percent by weight formaldehyde solutions, UV absorbers, especially triazine UV absorbers, and sequestrants, such as sodium nitrilotriacetic acid and sodium ethylenediaminetetraacetic acid all sodium polymetaphosphate, especially sodium hexametaphosphate, as emulsifiers, especially adducts of an alkylene oxide and a fatty alcohol, especially an adduct of oleyl alcohol and ethylene oxide, as water-insoluble solvents, high-boiling, saturated hydrocarbons, especially paraffins with a boiling range of about 160 to 210 ° C (so-called mineral spirits), as an oxidizing agent, for example an aromatic nitro compound, especially an aromatic mono- or dinitrocarboxylic acid or sulfonic acid, which is optionally present as an alkylene oxide
- polyester fiber materials are preferred.
- Suitable polyester fiber materials are those materials which consist entirely or partially of polyester.
- cellulose ester fibers such as cellulose-21/2-acetate fibers and triacetate fibers, and particularly linear polyester fibers, which are also optionally acid-modified, which are obtained, for example, by condensation of terephthalic acid with ethylene glycol or of isophthalic acid or terephthalic acid with 1,4-bis (hydroxymethyl ) -cyclohexane are obtained, as well as fibers from copolymers of terephthalic and isophthalic acid with ethylene glycol.
- polyester-containing mixed fiber materials ie mixtures of polyester and other fibers, in particular cotton / polyester fiber materials. Mainly fabrics, knitted fabrics or webs of these fibers are used.
- the printing paste is applied over the entire surface or in places directly to the fiber material, printing machines of the usual type, for example gravure, rotary screen printing and flat film printing machines, being used expediently.
- the method according to the invention is preferably carried out in a “one step process" on the "HW Dyeing & Discharge Printing Line” apparatus from Johannes Zimmer, A-9020 Klagenfurt (patent applied No. A 468/95).
- the fiber material is preferably at temperatures up to 150 ° C. Dried 80 ° to 120 ° C.
- the prints are usually washed out after fixing and then opened usual way by cleaning in alkaline medium under reductive conditions, e.g. using sodium dithionite. After cleaning, the prints are rinsed again and dried.
- the prints on polyester fiber materials obtainable by the process according to the invention have good general fastnesses; e.g. they have high fiber-dye binding stability both in the acidic and in the alkaline range, good wet fastness, such as fastness to washing, water, sea water and sweat, good chlorine fastness, Rubbing fastness, ironing fastness and pleating fastness and are characterized in particular by a Extension of the brilliant colors with high light and hot light fastness.
- the treated polyester fabric is then dried and fixed with HT steam at 180 ° C. for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. You get a two-tone gray-blue reserve print with sharp contours and very good hot light fastness.
- the printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. You get a two-tone gray-red reserve print with sharp contours and very good fastness to hot light.
- the printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. A two-tone gray-violet reserve print with sharp contours and very good fastness to hot light is obtained.
- the printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. A tri-color gray-red-yellow reserve print with sharp contours and very good fastness to hot light is obtained.
- the treated polyester fabric is then dried and fixed with HT steam at 180 ° C. for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method. A two-tone gray-yellow reserve print with sharp contours and very good fastness to hot light is obtained.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
Description
Gegenstand der vorliegenden Erfindung ist ein Verfahren zum Bedrucken von hydrophoben Fasermaterialien mit Dispersionsfarbstoffen nach dem Reservedruckverfahren.The present invention relates to a method for printing hydrophobic Fiber materials with disperse dyes using the reserve printing process.
Das Reservedruckverfahren mit Dispersionsfarbstoffen ist für hydrophobe Fasermaterialien
bekannt. Das Bedrucken dieser Materialien, vor allem von Polyesterfasermaterialien, wird
aber meistens mit einem sogenannten Ätzreserveverfahren durchgeführt, bei dem man den
vorgefärbten oder vorgedruckten Grundfarbstoff durch eine Behandlung mit einem stark alkalischen
Hilfsmittel örtlich zerstört und auf diese Stellen einen oder mehrere andere Farbstoffe,
welche ätzresistent sein müssen, aufdruckt. Die Behandlung mit dem Ätzmittel ist
aber sowohl ökologisch als auch ökonomisch mit Nachteilen verbunden; so kann z.B. das
behandelte Fasermaterial durch die Einwirkung von starkem Alkali angegriffen und beschädigt
werden.
Es besteht daher ein Bedürfniss nach einem einfacheren und faserschonenden Reservedruckverfahren
für das Bedrucken von hydrophoben Fasermaterialien, insbesondere Polyesterfasermaterialien.The reserve printing process with disperse dyes is known for hydrophobic fiber materials. The printing of these materials, especially polyester fiber materials, is mostly carried out with a so-called etching reserve process, in which the pre-dyed or pre-printed basic dye is locally destroyed by treatment with a strongly alkaline auxiliary and one or more other dyes, which are resistant to etching, are applied to these areas have to print. However, treatment with the etchant is associated with disadvantages both ecologically and economically; For example, the treated fiber material can be attacked and damaged by the action of strong alkali.
There is therefore a need for a simpler and more gentle reserve printing process for printing on hydrophobic fiber materials, in particular polyester fiber materials.
Es hat sich überraschenderweise gezeigt, dass man mit dem erfindungsgemässen Verfahren das hydrophobe Fasermaterial faserschonend bedrucken kann, wobei der resultierende Druck gute Allgemeinechtheiten und insbesondere eine sehr gute Heisslichtechtheit aufweist.Surprisingly, it has been shown that the process according to the invention can print the hydrophobic fiber material in a way that is gentle on the fibers, the resulting Print has good general fastness properties and in particular a very good hot light fastness.
Gegenstand der vorliegenden Anmeldung ist somit ein Verfahren zum Bedrucken von hydrophoben
Fasermaterialien mit Dispersionsfarbstoffen, welches dadurch gekennzeichnet
ist, dass man die Fasermaterialien:
Als Dispersionsfarbstoffe eignen sich für das erfindungsgemässe Verfahren solche Farbstoffe, welche im Colour Index, 3. Auflage (3. Revision 1987 inclusive Additions and Amendments bis No. 85) unter "Disperse Dyes" beschrieben sind. Es sind beispielsweise carbonsäure- und/oder sulfosäuregruppenfreie Nitro-, Amino-, Aminoketon-, Ketoninim-, Methin-, Polymethin-, Diphenylamin-, Chinolin-, Benzimidazol-, Xanthen-, Oxazin- oder Cumarinfarbstoffe und insbesondere Anthrachinon- und Azofarbstoffe, wie Mono- oder Disazofarbstoffe.Suitable disperse dyes for the process according to the invention are those dyes which are in the Color Index, 3rd edition (3rd revision 1987 including additions and Amendments to No. 85) are described under "Disperse Dyes". For example carbonic acid and / or sulfonic acid group-free nitro, amino, aminoketone, ketoninim, Methine, polymethine, diphenylamine, quinoline, benzimidazole, xanthene, oxazine or coumarin dyes and in particular anthraquinone and azo dyes, such as mono- or disazo dyes.
Bevorzugt für das erfindungsgemässe Verfahren sind Farbstoffe der Formeln
worin
bedeutet,
means
Die Mengen, in denen man die Dispersionsfarbstoffe in den Färbebädern, beziehungsweise Druckpasten verwendet, können je nach der gewünschten Farbtiefe schwanken; im allgemeinen haben sich Mengen von 0,01 bis 15 Gewichtsprozent, insbesondere 0,1 bis 10 Gewichtsprozent, bezogen auf die Gesamtsumme der Farbstoffe pro 1 l der Flotte, beziehungsweise 0,01 bis 400 g, insbesondere 0,2 bis 300 g, vor allem 0,5 bis 200 g der Farbstoffe pro kg Druckpaste, als vorteilhaft erwiesen.The amounts in which the disperse dyes in the dye baths, respectively Printing pastes used can vary depending on the desired color depth; in the in general, amounts of 0.01 to 15 percent by weight, in particular 0.1 to 10 Percentage by weight, based on the total amount of dyes per 1 l of the liquor, respectively 0.01 to 400 g, in particular 0.2 to 300 g, especially 0.5 to 200 g of the dyes per kg of printing paste, proven to be advantageous.
Wird im Schritt A) das hydrophobe Fasermaterial gefärbt, verwendet man üblicherweise ein
Konti-färbeverfahren, wie z.B. das Foulardverfahren. Das gefärbte Material wird vor der weiteren
Behandlung gegebenenfalls getrocknet.
Die Färbeflotte kann ausser dem Farbstoff weitere allgemein üblichen Zusätze enthalten,
beispielsweise Säurespender, wie z.B. aliphatische Aminchloride oder Magnesiumchlorid,
die wässrigen Lösungen anorganischer Salze, z.B. von Alkalichloriden oder Alkalisulfaten,
Alkalihydroxide, Harnstoff, Verdickungen, wie z.B. Alginatverdickungen, wasserlösliche
Cellulosealkyläther sowie Egalisier-, Antischaum- und/oder Entlüftungsmittel, Penetrationsbeschleuniger,
Migrationsinhibitoren, UV-Absorber sowie Netzmittel.If the hydrophobic fiber material is dyed in step A), a continuous dyeing process, such as the padding process, is usually used. The dyed material is optionally dried before further treatment.
In addition to the dye, the dye liquor can contain other generally customary additives, for example acid donors, such as, for example, aliphatic amine chlorides or magnesium chloride, the aqueous solutions of inorganic salts, for example alkali metal chlorides or alkali metal sulfates, alkali metal hydroxides, urea, thickeners, for example alginate thickeners, water-soluble cellulose alkyl ethers and leveling agents Antifoam and / or deaerating agents, penetration accelerators, migration inhibitors, UV absorbers and wetting agents.
Bei der im Schritt A) gegebenenfalls verwendeten Druckpaste handelt es sich um eine in
der Drucktechnik übliche Druckpaste, welche ausser dem Farbstoff die üblichen Hilfsmittel,
z.B. zweckmässigerweise Verdickungsmittel natürlicher oder synthetischer Herkunft, wie
z.B. handelsübliche Alginatverdickungen, Stärkeether oder Johannisbrotkemmehlether,
insbesondere Natriumalginat für sich allein oder im Gemisch mit modifizierter Cellulose, insbesondere
mit vorzugsweise 20 bis 25 Gewichtsprozent Carboxymethylcellulose, enthält.
Vorzugsweise werden in der obigen Druckpaste synthetische Verdickungsmittel eingesetzt,
wie z.B. solche auf Basis von Poly(meth)acrylsäuren, Poly(meth)acrylamiden, sowie deren
Co-, bzw. Terpolymeren.
Gewünschtenfalls kann die Druckpaste noch Säurespender wie Butyrolacton oder Natriumhydrogenphosphat,
Konservierungsmittel, Sequestriermittel, Emulgatoren, wasserunlösliche
Lösungsmittel, Oxidationsmittel, UV-Absorber oder Entlüftungsmittel enthalten.The printing paste optionally used in step A) is a printing paste which is customary in printing technology and which, apart from the dye, contains the customary auxiliaries, for example expedient thickeners of natural or synthetic origin, such as, for example, commercially available alginate thickeners, starch ether or locust bean gum ether, in particular sodium alginate or in a mixture with modified cellulose, in particular with preferably 20 to 25 percent by weight of carboxymethyl cellulose. Synthetic thickeners, such as those based on poly (meth) acrylic acids, poly (meth) acrylamides, and their copolymers or terpolymers, are preferably used in the above printing paste.
If desired, the printing paste may also contain acid donors such as butyrolactone or sodium hydrogen phosphate, preservatives, sequestering agents, emulsifiers, water-insoluble solvents, oxidizing agents, UV absorbers or deaerating agents.
Als kationische Hilfsmittel in der im Schritt B) verwendeten Druckpaste kommen insbesondere
quaternierte Amine enthaltende organische Polymerverbindungen oder Salze von
stickstoffhaltigen organischen Polymerverbindungen in Betracht.
Unter diesen sind insbesondere organische Polymerverbindungen auf Basis der Polymono-
und Polydiallylamine zu nennen, wie z.B. Polydiallylammoniumhydrochlorid oder Polydiallyldimethylammoniumchlorid.
Die Druckpaste enthält üblicherweise 0,5 bis 20, vorzugsweise 1 bis 10 g des kationischen
Hilfsmittels pro 1 kg der Druckpaste.Organic polymer compounds containing quaternized amines or salts of nitrogen-containing organic polymer compounds are particularly suitable as cationic auxiliaries in the printing paste used in step B).
These include, in particular, organic polymer compounds based on the polymono- and polydiallylamines, such as, for example, polydiallylammonium hydrochloride or polydiallyldimethylammonium chloride.
The printing paste usually contains 0.5 to 20, preferably 1 to 10 g of the cationic auxiliary per 1 kg of the printing paste.
Als nichtionogene Waschmittel werden in der im Schritt B) verwendeten Druckpaste beispielsweise Fettsäurepolyglykolester, oder insbesondere solche Verbindungen verwendet, die durch Anlagerung von 4 bis 80 Ethylen- und/oder Propylenoxidenheiten an Fettalkohole, Fettamine, Fettsäuren oder Alkylaryle, wie z.B. Nonyl- oder Octylphenol, entstehen. Als Beispiele dieser Verbindungen seien genannt Cetylalkohol mit 4-6 Ethylenoxideinheiten, Cetylalkohol mit 10-14 Ethylenoxideinheiten, Talgfettalkohol mit 10 bis 25 Ethylenoxideinheiten, Laurylalkohol mit 5-8 Ethylenoxideinheiten, Nonylphenol mit 3 bis 10 Ethylenoxideinheiten, Ricinusöl mit 36 Ethylenoxideinheiten oder Oelsäure mit 5 bis 15 Ethylenoxideinheiten. The non-ionic detergents used in the printing paste used in step B) are, for example Fatty acid polyglycol esters, or in particular those compounds used, by the addition of 4 to 80 ethylene and / or propylene oxide units to fatty alcohols, Fatty amines, fatty acids or alkylaryls, e.g. Nonyl- or octylphenol arise. Examples of these compounds are cetyl alcohol with 4-6 ethylene oxide units, Cetyl alcohol with 10-14 ethylene oxide units, tallow fatty alcohol with 10 to 25 ethylene oxide units, Lauryl alcohol with 5-8 ethylene oxide units, nonylphenol with 3 to 10 ethylene oxide units, Castor oil with 36 ethylene oxide units or oleic acid with 5 to 15 ethylene oxide units.
Vorteilhafterweise werden in dem erfindungsgemässen Verfahren nichtschäumende oder
wenig schäumende nichtionogene Waschmittel eingesetzt.
Die Druckpaste enthält üblicherweise 1 bis 60, vorzugsweise 5 bis 40 g des nichtionogenen
Waschmittels pro 1 kg der Druckpaste.Non-foaming or low-foaming nonionic detergents are advantageously used in the process according to the invention.
The printing paste usually contains 1 to 60, preferably 5 to 40 g of the nonionic detergent per 1 kg of the printing paste.
Die im Schritt B) verwendete Druckpaste kann ausser den oben genannten Komponenten weitere übliche Hilfsmittel, z.B. zweckmässigerweise Verdickungsmittel natürlicher oder synthetischer Herkunft, wie z.B. handelsübliche Alginatverdickungen, Stärkeether oder Johannisbrotkemmehlether, insbesondere Natriumalginat für sich allein oder im Gemisch mit modifizierter Cellulose, insbesondere mit vorzugsweise 20 bis 25 Gewichtsprozent Carboxymethylcellulose, enthalten. Ebenfalls können in den erfindungsgemässen Druckpasten synthetische Verdickungsmittel, wie z.B. solche auf Basis von Poly(meth)acrylsäuren, Poly(meth)acrylamiden, sowie deren Co-, bzw. Terpolymeren eingesetzt werden. Gewünschtenfalls können die Druckpasten noch Säurespender wie Butyrolacton oder Natriumhydrogenphosphat, Konservierungsmittel, Sequestriermittel, Emulgatoren, wasserunlösliche Lösungsmittel, Oxidationsmittel, UV-Absorber oder Entlüftungsmittel enthalten.The printing paste used in step B) can in addition to the components mentioned above other common aids, e.g. expediently thickeners of natural or synthetic Origin, e.g. commercial alginate thickeners, starch ether or locust bean flour ether, especially sodium alginate alone or in a mixture with modified Cellulose, in particular with preferably 20 to 25 percent by weight carboxymethyl cellulose, contain. Likewise, in the printing pastes according to the invention synthetic thickeners, e.g. those based on poly (meth) acrylic acids, poly (meth) acrylamides, and their copolymers or terpolymers are used. If desired, the printing pastes can also be acid donors such as butyrolactone or Sodium hydrogen phosphate, preservatives, sequestering agents, emulsifiers, water-insoluble Contain solvents, oxidizing agents, UV absorbers or deaerating agents.
In Betracht kommen als Konservierungsmittel vor allem formaldehydabgebende Mittel, wie z.B. Paraformaldehyd und Trioxan, vor allem wässrige, etwa 30 bis 40-gewichtsprozentige Formaldehydlösungen, als UV-Absorber vor allem Triazin-UV-Absorber, als Sequestriermittel z.B. nitrilotriessigsaures Natrium, ethylendiamintetraessigsaures Natrium, vor allem Natrium-Polymetaphosphat, insbesondere Natrium-Hexametaphosphat, als Emulgatoren vor allem Addukte aus einem Alkylenoxid und einem Fettalkohol, insbesondere einem Addukt aus Oleylalkohol und Ethylenoxid, als wasserunlösliche Lösungsmittel hochsiedende, gesättigte Kohlenwasserstoffe, vor allem Paraffine mit einem Siedebereich von etwa 160 bis 210°C (sogenannte Lackbenzine), als Oxidationsmittel z.B. eine aromatische Nitroverbindung, vor allem eine aromatische Mono- oder Dinitrocarbonsäure oder -sulfonsäure, die gegebenenfalls als Alkylenoxidaddukt vorliegt, insbesondere eine Nitrobenzolsulfonsäure und als Entlüftungsmittel z.B. hochsiedende Lösungsmittel, vor allem Terpentinöle, höhere Alkohole, vorzugsweise C8- bis C10-Alkohole, Terpenalkohole oder Entlüftungsmittel auf Basis von Mineral- und/oder Silikonölen, insbesondere Handelsformulierungen aus etwa 15 bis 25 Gewichtsprozent eines Mineral- und Silikonölgemisches und etwa 75 bis 85 Gewichtsprozent eines C8-Alkohols wie z.B. 2-Ethyl-n-hexanol. Particularly suitable preservatives are formaldehyde-releasing agents, such as paraformaldehyde and trioxane, especially aqueous, approximately 30 to 40 percent by weight formaldehyde solutions, UV absorbers, especially triazine UV absorbers, and sequestrants, such as sodium nitrilotriacetic acid and sodium ethylenediaminetetraacetic acid all sodium polymetaphosphate, especially sodium hexametaphosphate, as emulsifiers, especially adducts of an alkylene oxide and a fatty alcohol, especially an adduct of oleyl alcohol and ethylene oxide, as water-insoluble solvents, high-boiling, saturated hydrocarbons, especially paraffins with a boiling range of about 160 to 210 ° C (so-called mineral spirits), as an oxidizing agent, for example an aromatic nitro compound, especially an aromatic mono- or dinitrocarboxylic acid or sulfonic acid, which is optionally present as an alkylene oxide adduct, in particular a nitrobenzenesulfonic acid and as a deaerating agent, for example high-boiling Solvents, especially turpentine oils, higher alcohols, preferably C 8 to C 10 alcohols, terpene alcohols or deaerating agents based on mineral and / or silicone oils, in particular commercial formulations of about 15 to 25 percent by weight of a mineral and silicone oil mixture and about 75 to 85 Weight percent of a C 8 alcohol such as 2-ethyl-n-hexanol.
Das erfindungsgemässe Verfahren kann für verschiedenartige hydrophobe Fasermaterialien
angewendet werden.
Bevorzugt sind Polyesterfasermaterialien.
Als Polyesterfasermaterialien kommen solche Materialien in Betracht, die ganz oder teilweise
aus Polyester bestehen. Beispiele sind Celluloseesterfasern, wie z.B. Cellulose-21/2-acetatfasern
und -triacetatfasern, und besonders lineare Polyesterfasern, die gegebenenfalls
auch sauer modifiziert sind, welche z.B. durch Kondensation von Terephthalsäure mit
Ethylenglykol oder von Isophthalsäure oder Terephthalsäure mit 1 ,4-Bis(hydroxymethyl)-cyclohexan
erhalten werden, sowie Fasern aus Mischpolymeren von Terephthal- und Isophthalsäure
mit Ethylenglykol. Geeignet sind weiter polyesterhaltige Mischfasermaterialien,
d.h. Mischungen aus Polyester und anderen Fasem, insbesondere Baumwolle/Polyesterfasermaterialien.
Hauptsächlich werden Gewebe, Gewirke oder Bahnen dieser Fasern verwendet.The method according to the invention can be used for various types of hydrophobic fiber materials.
Polyester fiber materials are preferred.
Suitable polyester fiber materials are those materials which consist entirely or partially of polyester. Examples are cellulose ester fibers, such as cellulose-21/2-acetate fibers and triacetate fibers, and particularly linear polyester fibers, which are also optionally acid-modified, which are obtained, for example, by condensation of terephthalic acid with ethylene glycol or of isophthalic acid or terephthalic acid with 1,4-bis (hydroxymethyl ) -cyclohexane are obtained, as well as fibers from copolymers of terephthalic and isophthalic acid with ethylene glycol. Also suitable are polyester-containing mixed fiber materials, ie mixtures of polyester and other fibers, in particular cotton / polyester fiber materials.
Mainly fabrics, knitted fabrics or webs of these fibers are used.
Beim Bedrucken der hydrophoben Fasermaterialien wird die Druckpaste ganzflächig oder
stellenweise direkt auf das Fasermaterial aufgebracht, wobei Druckmaschinen üblicher
Bauart, z.B. Tiefdruck-, Rotationssiebdruck- und Flachfilmdruckmaschinen zweckmässig
eingesetzt werden.
Bevorzugt wird das erfindungsgemässe Verfahren in einem "one step process" auf der
"H.W. Dyeing & Discharge Printing Line"-Apparatur der Fa. Johannes Zimmer, A-9020
Klagenfurt (Patent applied No. A 468/95) durchgeführt.When printing on the hydrophobic fiber materials, the printing paste is applied over the entire surface or in places directly to the fiber material, printing machines of the usual type, for example gravure, rotary screen printing and flat film printing machines, being used expediently.
The method according to the invention is preferably carried out in a "one step process" on the "HW Dyeing & Discharge Printing Line" apparatus from Johannes Zimmer, A-9020 Klagenfurt (patent applied No. A 468/95).
Das Fasermaterial wird nach dem Bedrucken bei Temperaturen bis 150°C, vorzugsweise 80° bis 120°C getrocknet.After printing, the fiber material is preferably at temperatures up to 150 ° C. Dried 80 ° to 120 ° C.
Die anschliessende Fixierung des Fasermaterials geschieht im allgemeinen durch Trockenhitze (Thermofixierung) oder überhitztem Wasserdampf unter atmosphärischem Druck (HT-Fixierung). Die Fixierung wird dabei unter folgenden Bedingungen durchgeführt:
- HT-Fixierung:
- 5 bis 10 Minuten bei 170 bis 190°C
- Thermofixierung:
- 1 bis 2 Minuten bei 170 bis 220°C.
- HT fixation:
- 5 to 10 minutes at 170 to 190 ° C
- Heat setting:
- 1 to 2 minutes at 170 to 220 ° C.
Die Drucke werden nach der Fixierung in der Regel ausgewaschen und anschliessend auf übliche Weise durch Reinigung in alkalischem Medium unter reduktiven Bedingungen, z.B. mittels Natriumdithionit, fertiggestellt. Nach der Reinigung werden die Drucke wiederum gespült und getrocknet.The prints are usually washed out after fixing and then opened usual way by cleaning in alkaline medium under reductive conditions, e.g. using sodium dithionite. After cleaning, the prints are rinsed again and dried.
Die nach dem erfindungsgemässen Verfahren erhältlichen Drucke auf Polyesterfasermaterialien weisen gute Allgemeinechtheiten auf; sie besitzen z.B. eine hohe Faser-Farbstoff-Bindungsstabilität sowohl im sauren als auch im alkalischen Bereich, gute Nassechtheiten, wie Wasch-, Wasser-, Seewasser- und Schweissechtheit, eine gute Chlorechtheit, Reibechtheit, Bügelechtheit und Plissierechtheit und zeichnen sich insbesondere durch eine Erweiterung der brillanten Farbtöne mit hohen Licht- und Heisslichtechtheiten aus.The prints on polyester fiber materials obtainable by the process according to the invention have good general fastnesses; e.g. they have high fiber-dye binding stability both in the acidic and in the alkaline range, good wet fastness, such as fastness to washing, water, sea water and sweat, good chlorine fastness, Rubbing fastness, ironing fastness and pleating fastness and are characterized in particular by a Extension of the brilliant colors with high light and hot light fastness.
Die nachfolgende Beispiele dienen der Erläuterung der Erfindung. Die Temperaturen sind in Celsiusgraden angegeben, Teile sind Gewichtsteile, und Prozentangaben beziehen sich auf Gew.-%, sofern nicht anders vermerkt. Gewichtsteile stehen zu Volumenteilen im Verhältnis von Kilogramm zu Liter.The following examples serve to explain the invention. The temperatures are in Celsius degrees, parts are parts by weight, and percentages relate to % By weight, unless stated otherwise. Parts by weight are in relation to parts by volume from kilogram to liter.
Ein Polyesterpolgewebe wird mit einer Flotte enthaltend
Das gefärbte Polyestergewebe wird bei 80 °C getrocknet und anschliessend mit einer
Druckpaste enthaltend pro 1 kg Druckpaste
Das behandelte Polyestergewebe wird anschliessend getrocknet und 8 Minuten bei 180° C
mit HT-Dampf fixiert. Nach der Fixierung wird das bedruckte Polyestergewebe nach üblichem
Verfahren ausgewaschen, reduktiv gereinigt und getrocknet.
Man erhält einen zweifarbigen grau-blauen Reservedruck mit scharfen Konturen und einer
sehr guten Heisslichtechtheit.The treated polyester fabric is then dried and fixed with HT steam at 180 ° C. for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method.
You get a two-tone gray-blue reserve print with sharp contours and very good hot light fastness.
Ein Polyesterpolgewebe wird mit einer Druckpaste enthaltend pro 1 kg Druckpaste
256 g einer handelsüblichen 6%-igen Alginatverdickung,
Das bedruckte Polyestergewebe wird anschliessend mit einer Druckpaste enthaltend pro
1 kg Druckpaste
Das bedruckte Polyestergewebe wird anschliessend getrocknet und 8 Minuten bei 180° C
mit HT-Dampf fixiert. Nach der Fixierung wird das bedruckte Polyestergewebe nach üblichem
Verfahren ausgewaschen, reduktiv gereinigt und getrocknet.
Man erhält einen zweifarbigen grau-roten Reservedruck mit scharfen Konturen und einer
sehr guten Heisslichtechtheit.The printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method.
You get a two-tone gray-red reserve print with sharp contours and very good fastness to hot light.
Ein Polyesterpolgewebe wird mit einer Druckpaste enthaltend pro 1 kg der Druckpaste
Das bedruckte Polyestergewebe wird anschliessend getrocknet und 8 Minuten bei 180° C
mit HT-Dampf fixiert. Nach der Fixierung wird das bedruckte Polyestergewebe nach üblichem
Verfahren ausgewaschen, reduktiv gereinigt und getrocknet.
Man erhält einen zweifarbigen grau-violetten Reservedruck mit scharfen Konturen und einer
sehr guten Heisslichtechtheit.The printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method.
A two-tone gray-violet reserve print with sharp contours and very good fastness to hot light is obtained.
Ein Polyesterpolgewebe wird mit einer Druckpaste enthaltend pro 1 kg Druckpaste
Das bedruckte Polyestergewebe wird dann mit einer Druckpaste enthaltend pro 1 kg
Druckpaste
Das bedruckte Polyestergewebe wird anschliessend getrocknet und 8 Minuten bei 180° C
mit HT-Dampf fixiert. Nach der Fixierung wird das bedruckte Polyestergewebe nach üblichem
Verfahren ausgewaschen, reduktiv gereinigt und getrocknet.
Man erhält einen dreifarbigen grau-rot-gelben Reservedruck mit scharfen Konturen und einer
sehr guten Heisslichtechtheit. The printed polyester fabric is then dried and fixed with HT steam at 180 ° C for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method.
A tri-color gray-red-yellow reserve print with sharp contours and very good fastness to hot light is obtained.
Ein Polyesterpolgewebe wird mit einer Flotte enthaltend
Das gefärbte Polyestergewebe wird bei 80° C getrocknet und anschliessend mit einer
Druckpaste enthaltend pro 1 kg Druckpaste
Das behandelte Polyestergewebe wird anschliessend getrocknet und 8 Minuten bei 180° C
mit HT-Dampf fixiert. Nach der Fixierung wird das bedruckte Polyestergewebe nach üblichem
Verfahren ausgewaschen, reduktiv gereinigt und getrocknet.
Man erhält einen zweifarbigen grau-gelben Reservedruck mit scharfen Konturen und einer
sehr guten Heisslichtechtheit.The treated polyester fabric is then dried and fixed with HT steam at 180 ° C. for 8 minutes. After fixation, the printed polyester fabric is washed out, reductively cleaned and dried using the usual method.
A two-tone gray-yellow reserve print with sharp contours and very good fastness to hot light is obtained.
Claims (7)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH231096 | 1996-09-20 | ||
CH2310/96 | 1996-09-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0831168A2 true EP0831168A2 (en) | 1998-03-25 |
EP0831168A3 EP0831168A3 (en) | 1998-09-02 |
Family
ID=4230815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97810649A Withdrawn EP0831168A3 (en) | 1996-09-20 | 1997-09-11 | Reserve printing of hydrophobic fibrous materials |
Country Status (7)
Country | Link |
---|---|
US (1) | US5917120A (en) |
EP (1) | EP0831168A3 (en) |
JP (1) | JPH10110393A (en) |
KR (1) | KR19980024726A (en) |
BR (1) | BR9704753A (en) |
ID (1) | ID18306A (en) |
PL (1) | PL322193A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999067459A1 (en) * | 1998-06-19 | 1999-12-29 | Ciba Specialty Chemicals Holding Inc. | Resist printing on hydrophobic fibre materials |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020124323A1 (en) * | 2001-01-09 | 2002-09-12 | Cliver James D. | Process for patterning textile materials and fabrics made therefrom |
US20040214493A1 (en) * | 2001-08-28 | 2004-10-28 | Smith Garnett H. | Printable synthetic fabric |
US6759354B1 (en) | 2001-08-28 | 2004-07-06 | Intex Corporation | Printable synthetic fabric |
DE102008039500A1 (en) * | 2008-08-23 | 2010-02-25 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Process for dyeing textile materials |
ITSA20120006A1 (en) * | 2012-05-10 | 2013-11-11 | Oz Anadolu Kimya Sanayi Ve Ticaret Anonim Sirketi | INNOVATION IN CORRODENT PASTES FOR TEXTILE PRINTING. |
CN104674568B (en) * | 2015-01-23 | 2017-01-25 | 郎溪飞马工业织品有限公司 | Dyeing method of safety braid |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2025158A1 (en) * | 1969-06-03 | 1970-12-10 | Ciba AG, Basel (Schweiz) | Process for dyeing and printing textile materials made from synthetic organic fibers |
US4398914A (en) * | 1981-02-19 | 1983-08-16 | Basf Aktiengesellschaft | Process for discharge or reserve printing on synthetic fibers: formaldehyde sulfoxylate and hexamethylene tetramine |
EP0088996A1 (en) * | 1982-03-15 | 1983-09-21 | CASSELLA Aktiengesellschaft | Process for the production of discharge resist prints on hydrophobic textile materials |
DE4310919A1 (en) * | 1993-04-02 | 1994-10-06 | Dlw Ag | Wet-on-wet, white or colored reserve printing on modified PES carpet using the pouring process and printing paste therefor |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3964862A (en) * | 1969-06-03 | 1976-06-22 | Ciba-Geigy Ag | Process for dyeing and printing textile materials of synthetic organic fibers |
EP0021055B1 (en) * | 1979-06-01 | 1983-12-21 | Hoechst Aktiengesellschaft | Process for the local "white discharging" or "coloured discharging" of dyes on textile materials |
CH658565GA3 (en) * | 1980-03-20 | 1986-11-28 | ||
EP0490814A1 (en) * | 1990-12-11 | 1992-06-17 | Ciba-Geigy Ag | Pastry to solid dyestuff-melt |
-
1997
- 1997-09-11 EP EP97810649A patent/EP0831168A3/en not_active Withdrawn
- 1997-09-16 ID IDP973204A patent/ID18306A/en unknown
- 1997-09-19 US US08/933,592 patent/US5917120A/en not_active Expired - Fee Related
- 1997-09-19 BR BR9704753A patent/BR9704753A/en not_active Application Discontinuation
- 1997-09-19 JP JP9254602A patent/JPH10110393A/en active Pending
- 1997-09-19 PL PL97322193A patent/PL322193A1/en unknown
- 1997-09-19 KR KR1019970047636A patent/KR19980024726A/en not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2025158A1 (en) * | 1969-06-03 | 1970-12-10 | Ciba AG, Basel (Schweiz) | Process for dyeing and printing textile materials made from synthetic organic fibers |
US4398914A (en) * | 1981-02-19 | 1983-08-16 | Basf Aktiengesellschaft | Process for discharge or reserve printing on synthetic fibers: formaldehyde sulfoxylate and hexamethylene tetramine |
EP0088996A1 (en) * | 1982-03-15 | 1983-09-21 | CASSELLA Aktiengesellschaft | Process for the production of discharge resist prints on hydrophobic textile materials |
DE4310919A1 (en) * | 1993-04-02 | 1994-10-06 | Dlw Ag | Wet-on-wet, white or colored reserve printing on modified PES carpet using the pouring process and printing paste therefor |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999067459A1 (en) * | 1998-06-19 | 1999-12-29 | Ciba Specialty Chemicals Holding Inc. | Resist printing on hydrophobic fibre materials |
US6616711B1 (en) | 1998-06-19 | 2003-09-09 | Ciba Speciality Chemicals Corporation | Resist printing on hydrophobic fiber materials |
Also Published As
Publication number | Publication date |
---|---|
US5917120A (en) | 1999-06-29 |
KR19980024726A (en) | 1998-07-06 |
BR9704753A (en) | 1998-11-17 |
JPH10110393A (en) | 1998-04-28 |
EP0831168A3 (en) | 1998-09-02 |
ID18306A (en) | 1998-03-26 |
PL322193A1 (en) | 1998-03-30 |
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