EP0806299B1 - Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren - Google Patents

Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren Download PDF

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Publication number
EP0806299B1
EP0806299B1 EP97106976A EP97106976A EP0806299B1 EP 0806299 B1 EP0806299 B1 EP 0806299B1 EP 97106976 A EP97106976 A EP 97106976A EP 97106976 A EP97106976 A EP 97106976A EP 0806299 B1 EP0806299 B1 EP 0806299B1
Authority
EP
European Patent Office
Prior art keywords
ink
printing material
material according
recording material
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97106976A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0806299A2 (de
EP0806299A3 (de
Inventor
Gerhard Dr. Dipl.-Ing. Dransmann
Horst Dipl.-Ing. Westfal
Claudia Dr. Dipl.-Chem. Jünger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP0806299A2 publication Critical patent/EP0806299A2/de
Publication of EP0806299A3 publication Critical patent/EP0806299A3/de
Application granted granted Critical
Publication of EP0806299B1 publication Critical patent/EP0806299B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256—Heavy metal or aluminum or compound thereof

Definitions

  • the invention relates to a recording material for the Ink jet printing process (ink jet printing process).
  • droplets of a recording liquid are applied to the surface of the recording material using various techniques.
  • a recording liquid ink
  • an ink jet is ejected from the nozzle, which dissolves into microscopic drops due to the surface tension.
  • the drops are charged electrically and placed on the base or deflected into a reservoir by means of downstream deflection plates which are controlled by the digital signals.
  • the image signal triggers a mechanical impulse that ejects the drop.
  • the first "drop-on-demand” printers used the piezoelectric effect to cause the drops to be ejected.
  • the method is largely replaced by thermal ink jet, also called bubble jet.
  • the image signal activates a heating element, which creates a vapor bubble in the aqueous ink. The resulting vapor pressure expels the drop.
  • the recording material (image receiving material) used for such recording systems generally consists of a support and an ink-receiving layer and, if appropriate, further auxiliary layers.
  • a polyester resin, diacetate or paper can be used as the carrier.
  • the ink-receiving layers are mostly hydrophilic coatings which are particularly well suited for the absorption of aqueous inks.
  • the ink-receiving layers usually consist of a pigment / binder mixture. In addition to increasing the whiteness of the material, the pigments serve to retain the dyes from the recording liquid on the surface of the sheet.
  • Natural or synthetic polymers are used as binders, for example gelatin, starch, pectin, casein, carboxymethyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and the like.
  • cationic substances are often used in the ink receiving layer to fix the ink dyes.
  • the backing of which is paper and the ink-receiving layer is a water-soluble binder contains problems such as insufficient water resistance or curling (cockle) of the material.
  • JP 61-041585 a recording material known, the one Has polyvinyl alcohol / polyvinyl pyrrolidone mixture and itself in addition to the above-mentioned lack of water resistance due to a bad wet rub resistance.
  • a recording material is known from Japanese laid-open publication JP 06-297831, which has a porous layer with a pseudoboehmite / polyvinyl alcohol mixture. This enables fast drying times.
  • a disadvantage is the high layer application quantity (35-45 g / m 2 ) required here for rapid absorption of even large amounts of ink.
  • the object of the present invention is therefore a recording material to provide the above mentioned Does not have disadvantages, in particular very good water resistance, has a very high resolution and color density.
  • the task is carried out by a carrier and a receiving layer containing recording material dissolved, wherein an upper layer is arranged on the receiving layer, the one fine porous inorganic cationic charge centers Contains pigment and / or filler particles according to claim 1.
  • Aluminum oxides are particularly well suited for this purpose, pyrrogenic aluminum hydroxides and aluminum oxide hydrates, in particular however, the ⁇ -alumina monohydrate or the metahydroxide ⁇ -AlO (OH) (boehmite) with a pore radius distribution between 1.0 to 3.5 nm.
  • the Invention can be a finely divided silica in the upper layer how pyrrogenic silica are used. The amount of finely divided silica can vary between 30 and 70 % By weight, based on the total amount of the pigment.
  • a polyvinyl alcohol top layer is used as a binder.
  • a partially saponified polyvinyl alcohol is particularly suitable with a degree of saponification between 70 and 90 mol%.
  • cationically modified binders such as, for example, are well suited a cationic polyvinyl alcohol or cationic modified starch.
  • other water-soluble polymers can be used as binders.
  • the amount of binder can be 20 to 90% by weight. The quantitative range is preferred 40 to 90% by weight, but in particular 50 to 80% by weight (based on the dried layer).
  • the quantitative ratio of inorganic pigment and / or filler particles to binder can be 1: 0.4 to 1: 100, but especially 1: 2 to 1: 100.
  • the Top layer additionally at least one cationic polymer such as for example a cationically modified polyvinyl alcohol, a cationically modified starch, a cationically modified starch Polystyrene, a cationically modified polyvinyl pyrrolidone and similar polymers. Quaternary, Hydroxy- or amino-functional acrylate homo- and / or acrylate copolymers.
  • the amount of the cationic polymer is 1 to 30% by weight, in particular 5 to 20% by weight, based on the dried Layer.
  • the top layer can be an additional cationic dye fixative Contain agents, for example a quaternary Polyammonium salt from the group of polyvinylbenzyltrimethyl, Polydiallyldimethyl, polymethacryloxyethyldimethylhydroxyethyl, Polyhydroxypropyldimethylammonium chlorides.
  • additional dye fixative Contain agents for example a quaternary Polyammonium salt from the group of polyvinylbenzyltrimethyl, Polydiallyldimethyl, polymethacryloxyethyldimethylhydroxyethyl, Polyhydroxypropyldimethylammonium chlorides.
  • dye-fixing agents such as cationic cationic Polyamines, cationic polyacrylamides, cationic polyethyleneimines can be used.
  • the amount of dye fixative Up to 5% by weight, in particular from 0.5 up to 3% by weight.
  • the ink-receiving layer can contain binders, color-fixing compounds, Contain hardening agents and other aids.
  • Binders can be modified, for example, polyvinyl alcohol Polyvinyl alcohol, cationically modified polystyrene, carboxymethyl cellulose, Polyvinylpyrrolidone, polyvinyl acetate, Starch, gelatin or mixtures thereof can be used
  • a preferred embodiment of the invention is in the ink receiving layer Gelatin used. To be particularly advantageous turned out a pork rind gelatin with a Gelatin strength of 200 to 300 bloom (measured according to BS 757, 1975), but a bovine bone gelatin can also be used become.
  • Binder is a modified polyvinyl alcohol, Carboxymethyl cellulose or polyvinyl pyrrolidone. Particularly good ones Results are achieved if in addition to the binder and the in an amount of up to 5% by weight of dye-fixing agents Means additionally a cationic polymer is used.
  • the cationic polymer can be a quaternary, hydroxy or amino-functional acrylate homo- and / or acrylate copolymer his. But also other cationic polymers such as a cationic polystyrene or a cationically modified Starch can be used.
  • the quantitative ratio cat. Polymer / binder in the receiving layer is 1: 2 to 1:20.
  • a plastic film (film) or preferably an uncoated or coated base paper can be used as the carrier.
  • Paper that is coated on both sides with synthetic resin and has a weight per unit area of 50 to 250 g / m 2 is particularly suitable.
  • Polyolefins or polyester, for example, can be used as the synthetic resin.
  • the application amount of the synthetic resin coating, which may also contain pigments, dyes and other auxiliaries, is at least 5 g / m 2 .
  • a polyethylene-coated paper is used.
  • a coated base paper, in particular a barite-coated paper, is also suitable as a carrier.
  • the back of the recording material can also have a functional layer have, for example an anti-curl and / or Antistatic layer.
  • Both the ink absorption and the top layer are applied from an aqueous dispersion (coating composition) and dried.
  • the coating composition can be applied to the carrier using all customary application and metering methods, such as roller application, engraving or nipping methods and air brushes or roller doctor metering.
  • the application amount of the ink-receiving layer can be 1.0 to 20 g / m 2 , preferably 8 to 14 g / m 2 .
  • the application amount of the top layer can be 0.5 to 5.0 g / m 2 , preferably 1.0 to 4.0 g / m 2 .
  • Tables 1 and 2 below show some of the many possible embodiments of the invention: Components of the ink-receiving layer A A1 A2 A3 A4 A5 A6 A7 Gelatin, 264 Bloom 91.8 81.8 73.6 73.4 82.6 - - Polyvinyl alcohol, degree of saponification: 98 mol% - - 8.2 - 9.2 31.6 41.0 Polyvinylpyrrolidone, Molgew .: 630,000 daltons - - - 18.4 - 31.6 41.0 Vinyl acetate / butyl acrylate cop. - - - - - 31.6 - Aminomethyl methacrylate 5.0 15.0 15.0 5.0 5.0 - 15.0 quat.
  • the quantities are expressed in% by weight and relate on dried layers.
  • the front side of a base paper neutrally sized with alkyl ketene dimer and coated on both sides with polyethylene 1) of 80 g / m 2 basis weight was first coated with an ink absorption layer according to A1 (Tab. 1) and then with an upper layer according to B1, B2, B6, B7 and B8 ( Tab. 2).
  • corresponding aqueous coating compositions were first prepared, which were then applied to the substrate to be coated using a roller doctor blade and dried.
  • the back of the base paper was coated with a mixture of LDPE and HDPE (high-density polyethylene).
  • the application weight was 20 g / m 2 .
  • the recording material obtained was in a so-called. "Thermal Jet” process printed and then analyzed.
  • the front of the base paper from Example 1 was first provided with an ink-receiving layer in accordance with A2 (Table 1) and then with an upper layer in accordance with B2, B6 and B8 (Table 2).
  • the order weights were: Ink receiving layer 12 g / m 2
  • a base paper provided with a baryta layer on the front side (basis weight: 80 g / m 2 ) was first provided with an ink absorption layer in accordance with A7 and then with an upper layer in accordance with B9.
  • the barite layer contained 85% by weight of BaSO 4 and 15% by weight of gelatin.
  • test conditions were as in Example 1.
  • the base paper from Example 1 was coated with an ink absorption layer according to A2 (12 g / m 2 ) and then provided with an upper layer according to B6 (4 g / m 2 ), but without boehmite with a narrow pore radius distribution, instead with aluminum hydroxide with a pore radius distribution of 2.8 to 100.0 nm (V1a) and 2.0 to 14.0 nm (V1b).
  • the base paper from Example 1 was only coated with an ink receiving layer in accordance with A2 and A6 without and with the addition of aluminum hydroxide.
  • the quantities are expressed in% by weight and relate on dried layers.
  • the recording material obtained in the comparative examples was printed in a so-called "thermal jet” process and then analyzed.
  • the results are summarized in Table 4.
  • the recording material was by means of a Bubble jet principle (thermal jet) working inkjet printer HP Deskjet 550 C from Hewlett Packard printed.
  • the density measurements were made using an "original Reflection densitometer SOS-45 "performed. The measurements took place for the basic colors cyan, magenta, yellow and black.
  • the recording material was used for the investigation of the water resistance submerged in water. The after 60 s in Water bath 25 ° C remaining density (%) is used as a measure of the Water stability used.
  • the gloss values were measured with the laboratory reflectometer RL3 from Dr. Long according to DIN 67530.
  • the drying behavior of the recording material becomes as follows determined:
  • Black ink (pure black) is placed on a sheet of paper a bar is printed out and after a waiting time of 120 seconds Paper (20 sheets) loaded.
  • the color transfer is used as a measure taken for drying.
  • the drying time can be ⁇ 120, 120-240 and be> 240 seconds.
  • the recording materials produced according to the invention are distinguished by better water resistance, shorter drying times and better bleed behavior. Even if the water resistance and drying times of the papers produced according to V1a and V1b are also good, the bleed behavior is unsatisfactory. With regard to the gloss, too, the values in Example 2.2 are higher than in the corresponding Comparative Examples V1a and V1b.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paper (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)
EP97106976A 1996-05-09 1997-04-26 Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren Expired - Lifetime EP0806299B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19618607 1996-05-09
DE19618607A DE19618607C2 (de) 1996-05-09 1996-05-09 Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren

Publications (3)

Publication Number Publication Date
EP0806299A2 EP0806299A2 (de) 1997-11-12
EP0806299A3 EP0806299A3 (de) 1998-04-08
EP0806299B1 true EP0806299B1 (de) 2001-10-31

Family

ID=7793782

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97106976A Expired - Lifetime EP0806299B1 (de) 1996-05-09 1997-04-26 Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren

Country Status (8)

Country Link
US (1) US5911855A (da)
EP (1) EP0806299B1 (da)
JP (1) JP4024902B2 (da)
AT (1) ATE207816T1 (da)
DE (2) DE19618607C2 (da)
DK (1) DK0806299T3 (da)
ES (1) ES2166931T3 (da)
PT (1) PT806299E (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1747901A1 (de) 2005-07-26 2007-01-31 Kanzan Spezialpapiere GmbH Tintenstrahlaufzeichnungsmaterial

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BRPI0820120B1 (pt) 2007-12-17 2019-01-02 Technocell Dekor Gmbh & Co Kg impregnado de papel decorativo para materiais de revestimento decorativos, método para produzir um impregnado de papel decorativo compressível e uso do impregnado de papel decorativo
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JP2015527217A (ja) * 2012-06-15 2015-09-17 シェラー テクノチェル ゲー エムベー ハー ウント コンパニー コマンディートゲゼルシャフトＳｃｈｏｅｌｌｅｒ Ｔｅｃｈｎｏｃｅｌｌ ＧｍｂＨ ＆ Ｃｏ． ＫＧ ナノフィブリル化セルロースを有するデジタル印刷方法用受容層
CN102991175A (zh) * 2012-12-27 2013-03-27 天津海华科技发展有限公司 一种环保医用喷墨打印胶片
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JP6152279B2 (ja) * 2013-02-19 2017-06-21 三菱製紙株式会社 化粧シート用原紙およびそれを用いた化粧シートおよび化粧板

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EP0806299A2 (de) 1997-11-12
EP0806299A3 (de) 1998-04-08
DK0806299T3 (da) 2002-02-18
ATE207816T1 (de) 2001-11-15
JPH10100532A (ja) 1998-04-21
JP4024902B2 (ja) 2007-12-19
DE19618607C2 (de) 1999-07-08
PT806299E (pt) 2002-04-29
DE19618607A1 (de) 1997-11-20
US5911855A (en) 1999-06-15
ES2166931T3 (es) 2002-05-01
DE59705136D1 (de) 2001-12-06

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