EP0804659A1 - Dacheindeckung aus zink - Google Patents
Dacheindeckung aus zinkInfo
- Publication number
- EP0804659A1 EP0804659A1 EP95942113A EP95942113A EP0804659A1 EP 0804659 A1 EP0804659 A1 EP 0804659A1 EP 95942113 A EP95942113 A EP 95942113A EP 95942113 A EP95942113 A EP 95942113A EP 0804659 A1 EP0804659 A1 EP 0804659A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polyester
- paint
- acrylic
- micrometers
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 40
- 239000011701 zinc Substances 0.000 title claims abstract description 40
- 238000000576 coating method Methods 0.000 claims abstract description 38
- 239000011248 coating agent Substances 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims description 26
- 239000003973 paint Substances 0.000 claims description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 239000002313 adhesive film Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 13
- 229920002635 polyurethane Polymers 0.000 claims description 11
- 239000004814 polyurethane Substances 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000008397 galvanized steel Substances 0.000 claims description 6
- 229920001684 low density polyethylene Polymers 0.000 claims description 6
- 239000004702 low-density polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 239000002033 PVDF binder Substances 0.000 claims description 5
- 229920001944 Plastisol Polymers 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- 239000004999 plastisol Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920002620 polyvinyl fluoride Polymers 0.000 claims description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 5
- 238000004381 surface treatment Methods 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
- E04D3/24—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like
- E04D3/30—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like of metal
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
- E04D3/02—Roof covering by making use of flat or curved slabs or stiff sheets of plane slabs, slates, or sheets, or in which the cross-section is unimportant
- E04D3/16—Roof covering by making use of flat or curved slabs or stiff sheets of plane slabs, slates, or sheets, or in which the cross-section is unimportant of metal
Definitions
- the present invention relates to a zinc or galvanized steel covering consisting essentially of an assembly of sheets of said materials and placed on a non-ventilated roofing support, said sheets therefore having one side facing said support.
- Zinc covers are traditionally placed on ventilated fir battens. Because of the high cost of this traditional support, it is sought to replace it with less expensive supports, in particular non-ventilated supports possibly not compatible with zinc or galvanized steel such as particle boards, plywood, concrete and rigid insulation. However, numerous corrosion phenomena of zinc coverings placed on these non-ventilated supports have been reported. To solve these problems it would be necessary, according to document EP-B-0410822, to improve the ventilation between the sub-roof and the zinc plates to avoid condensation and to isolate the zinc from the non-ventilated support, in particular if the support is concrete.
- the object of the present invention is to provide a blanket as defined above, which avoids the drawbacks mentioned above.
- said face of the sheets is provided with an organic coating with a thickness of at least 50 micrometers, which is elastic, durable and impermeable to water vapor, the other face of the sheets being either uncoated or coated by any surface treatment process applied for purely aesthetic purposes.
- the coating must be hard enough so that the various manipulations, that the coated sheet must undergo until it is finally placed on the support, do not leave traces in the coating or in any case not deep traces.
- the thickness of at least 50 micrometers is essential to avoid for sure that possible small scratches suffered as a result of the above manipulations can not discover zinc.
- galvanized sheets covered either with a layer of paint based on a thermosetting resin, or with a film of polyvinyl chloride and / or poiyacrylate are not always suitable from the economic point of view and in that which concerns their resistance for the production of exterior building materials.
- the coating may comprise a layer of polyester-based paint (standard symbol SP), silicone polyester (SPSI), polyester polyamide (SPPA), epoxy (EP), polyurethane (PUR), fluoride vinylidene (PVDF) vinyl chloride organosol (PVCO), vinyl chloride plastisol (PVCP), acrylic (AY) or silicone acrylic (AYS), the thickness of the layer in the dry state is advantageously from 50 to 70 micrometers.
- the painting is advantageously carried out continuously at the producer of sheets or in a painting workshop by depositing the paint in the liquid state or in the form of powder and subsequent baking by passing through an oven. Preference is given to a polyester paint deposited in the form of powder.
- Such a paint is marketed under the name "Beckryspeed" by the firm BICHON SA
- the coating can also consist of an adhesive film of polyvinyl chloride (PVCF), polyvinyl fluoride (PVFF), acrylic (PMMAF), polyethylene (PEF), polyurethane or polyester, the thickness of the film being advantageously from 80 to 150 micrometers.
- PVCF polyvinyl chloride
- PVFF polyvinyl fluoride
- PMMAF acrylic
- PETF polyethylene
- the film application is advantageously carried out continuously by the sheet producer. Preference is given to polyethylene film.
- An example of such a film is the low-density polyethylene adhesive film with a thickness of 100 micrometers, which is marketed under the reference 4118 by the company NO ACEL SA.
- coating with adhesive film is preferable to coating. by painting.
- the coating may further consist of a layer of paint as defined above, which is itself covered with an adhesive film as defined above. Needless to say, such a coating is even more effective than coating with paint or adhesive film.
- the other face of the sheet is either uncoated or coated by any surface treatment process applied for purely aesthetic purposes.
- this face can be prepatinated.
- the present invention also relates to the use of zinc or galvanized steel sheets, one side of which is provided with a coating as defined and described above and the other side of which is either uncoated or coated for purely aesthetic purposes, for the realization of the cover according to the invention, this embodiment comprising the operations of shaping the sheets necessary for their laying and the laying proper of the shaped sheets.
- the shaping and laying of coated sheets, supplied by the sheet producer, can be done according to current practice.
- the techniques described in "Engineering techniques”, C1040, 1 can be used.
- C1040, 1 can be used.
- C1041, 1-5 to place such blankets on a wooden support, except that the cleats or clips will be fixed to the support by screwing instead of by nailing.
- the film After unwinding, the film is plated on the rolled zinc by means of a set of pressure rollers and the whole is rewound into a reel. This coil will then be cut in width and length suitable for use on construction sites.
- the thickness of zinc is that commonly used for roofing, between 0.65 and 1 mm.
- the plastic film is made of low density polyethylene 100 micrometers thick.
- the adhesive is a mixture of rubber and resin 10 micrometers thick.
- the film has remained well adhered to the laminate.
- the samples then undergo an accelerated corrosion test, known as the Kesternich test according to DIN 50017, comprising a cycle per day consisting in depositing water vapor by condensation and then allowing the sample to dry. After 20 days (20 cycles) the plastic film is removed and it is found that the face protected by the film is not corroded. The other side is excessively corroded by condensation, by the formation of zinc oxide, called white rust.
- Zinc samples coated with the film were placed in an oven for 60 days either at 90 ° C or 100 ° C. Beforehand, folds and stampings were made on the samples to simulate the deformations that the product will undergo on a site.
- a zinc coil After rolling, a zinc coil is subjected to a surface treatment operation by conversion, giving on both sides a surface layer of zinc phosphate, either light gray in color or dark gray in color, the zinc thus obtained being called pre-patinated zinc.
- Pre-patinated zinc is rewound into a coil.
- the pre-weathered zinc coil undergoes the same operations as the rolled zinc coil in Example 1 and the material thus obtained is subjected to the same tests as the material obtained in Example 1: the same results are obtained as in Example 1.
- EXAMPLE 3 The zinc coil coated with example 1 was used to make a cover above a room in which steam was produced.
- the interior of the room is maintained at 30 ° C with a relative humidity of 100% and its walls are thermally insulated so that the humidity condenses preferentially on the underside of the laminated zinc protected by the film. These conditions are chosen to considerably accelerate the condensation phenomena under the cover that we usually obtain.
- This coil will then be cut in width and length suitable for use on construction sites.
- the thickness of rolled zinc is that commonly used for roofing, between 0.65 and 1 mm.
- the powder is a BECKRYSPEED polyester powder specially manufactured to combine the performance and advantages of the powder with the technology of continuous application.
- test pieces underwent the accelerated salt spray corrosion test according to the NFX standard.
- test pieces have undergone the Kesternich test, according to DIN 50017 for 1000 hours
- Example 5 The operations and tests of Example 4 are repeated, but starting this time with a coil of prepatinated zinc and the same results are obtained as in Example 4.
- Example 6 The operations and tests of Example 4 are repeated, but in the powder installation, between the cooler and the rewinder, a film is continuously deposited on the coated side. low density polyethylene adhesive 50 micrometers thick. The same results are obtained as in Example 4.
- Example 7 The operations and tests of Example 6 are repeated, but starting this time with a coil of pre-patinated zinc. The same results are obtained as in Example 4.
- EXAMPLE 8 The operations of example 3 are repeated, but this time using the zinc coil coated with example 4. The same result is obtained as in example 3.
Landscapes
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Glass Compositions (AREA)
- Roof Covering Using Slabs Or Stiff Sheets (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Non-Insulated Conductors (AREA)
- Primary Cells (AREA)
- Physical Vapour Deposition (AREA)
- Coating With Molten Metal (AREA)
- Building Environments (AREA)
- Arc Welding In General (AREA)
- Electroplating Methods And Accessories (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9415568 | 1994-12-23 | ||
| FR9415568A FR2728604A1 (fr) | 1994-12-23 | 1994-12-23 | Couverture en zinc pour toiture |
| PCT/EP1995/004886 WO1996020320A1 (fr) | 1994-12-23 | 1995-12-07 | Couverture en zinc pour toiture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0804659A1 true EP0804659A1 (de) | 1997-11-05 |
| EP0804659B1 EP0804659B1 (de) | 1999-03-17 |
Family
ID=9470183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP95942113A Expired - Lifetime EP0804659B1 (de) | 1994-12-23 | 1995-12-07 | Dacheindeckung aus zink |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0804659B1 (de) |
| JP (1) | JP3803778B2 (de) |
| CN (1) | CN1079476C (de) |
| AT (1) | ATE177810T1 (de) |
| AU (1) | AU4343096A (de) |
| CZ (1) | CZ287617B6 (de) |
| DE (1) | DE69508437T2 (de) |
| DK (1) | DK0804659T3 (de) |
| ES (1) | ES2133178T3 (de) |
| FR (1) | FR2728604A1 (de) |
| GR (1) | GR3030503T3 (de) |
| HU (1) | HU220542B1 (de) |
| NO (1) | NO310118B1 (de) |
| PL (1) | PL320788A1 (de) |
| SK (1) | SK284822B6 (de) |
| WO (1) | WO1996020320A1 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU7643200A (en) * | 1999-09-02 | 2001-04-10 | Nanogate Gmbh | A roofing material exposed to weather hazards, especially roof tile or other smooth or porous and/or microstructured roofing materials |
| EP1460196A1 (de) * | 2003-03-21 | 2004-09-22 | Icopal A/S | Dachelement aus Metallprofilblech |
| CN102409810A (zh) * | 2011-12-07 | 2012-04-11 | 常熟市东涛金属复合材料有限公司 | 一种复合金属瓦 |
| ES2544006B2 (es) * | 2015-03-31 | 2016-01-12 | Asturiana De Laminados, S.A. | Productos laminados basados en zinc y utilización de los mismos |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH634120A5 (en) * | 1979-03-01 | 1983-01-14 | Neomat Ag | Process for surface coating a roof snow guard |
| GB2065155B (en) * | 1979-12-17 | 1984-02-29 | Toyo Kohan Co Ltd | Coated or laminated metal sheet for use as a building material |
| IT8123129U1 (it) * | 1981-10-06 | 1983-04-06 | Fiorio Guido | Elemento di copertura per tetti di edifici |
| DE3444669A1 (de) * | 1984-12-07 | 1986-06-12 | Karl 6920 Sinsheim Serwane | Deckung fuer daecher, gebaeudefassaden u.a. |
| FR2650319B1 (fr) * | 1989-07-26 | 1991-11-08 | Vieille Montagne France Sa | Couverture metallique pour toiture et supports pour une telle couverture |
| DE4014711A1 (de) * | 1990-05-08 | 1990-11-29 | Gerhard Fabritz | Dachdeckungselement |
-
1994
- 1994-12-23 FR FR9415568A patent/FR2728604A1/fr active Granted
-
1995
- 1995-12-07 HU HU9702105A patent/HU220542B1/hu not_active IP Right Cessation
- 1995-12-07 CN CN95197622A patent/CN1079476C/zh not_active Expired - Lifetime
- 1995-12-07 WO PCT/EP1995/004886 patent/WO1996020320A1/fr not_active Ceased
- 1995-12-07 PL PL95320788A patent/PL320788A1/xx unknown
- 1995-12-07 CZ CZ19971949A patent/CZ287617B6/cs not_active IP Right Cessation
- 1995-12-07 AT AT95942113T patent/ATE177810T1/de active
- 1995-12-07 EP EP95942113A patent/EP0804659B1/de not_active Expired - Lifetime
- 1995-12-07 JP JP52015196A patent/JP3803778B2/ja not_active Expired - Fee Related
- 1995-12-07 DE DE69508437T patent/DE69508437T2/de not_active Expired - Lifetime
- 1995-12-07 DK DK95942113T patent/DK0804659T3/da active
- 1995-12-07 AU AU43430/96A patent/AU4343096A/en not_active Abandoned
- 1995-12-07 SK SK822-97A patent/SK284822B6/sk not_active IP Right Cessation
- 1995-12-07 ES ES95942113T patent/ES2133178T3/es not_active Expired - Lifetime
-
1997
- 1997-06-20 NO NO19972918A patent/NO310118B1/no not_active IP Right Cessation
-
1999
- 1999-06-10 GR GR990401578T patent/GR3030503T3/el unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9620320A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69508437D1 (de) | 1999-04-22 |
| HUT77267A (hu) | 1998-03-02 |
| PL320788A1 (en) | 1997-10-27 |
| NO972918L (no) | 1997-08-25 |
| ATE177810T1 (de) | 1999-04-15 |
| SK284822B6 (sk) | 2005-12-01 |
| HK1008232A1 (en) | 1999-05-07 |
| AU4343096A (en) | 1996-07-19 |
| FR2728604B1 (de) | 1997-02-21 |
| DE69508437T2 (de) | 1999-10-28 |
| NO310118B1 (no) | 2001-05-21 |
| CN1175297A (zh) | 1998-03-04 |
| CN1079476C (zh) | 2002-02-20 |
| GR3030503T3 (en) | 1999-10-29 |
| JP3803778B2 (ja) | 2006-08-02 |
| HU220542B1 (hu) | 2002-03-28 |
| FR2728604A1 (fr) | 1996-06-28 |
| SK82297A3 (en) | 1998-02-04 |
| WO1996020320A1 (fr) | 1996-07-04 |
| EP0804659B1 (de) | 1999-03-17 |
| ES2133178T3 (es) | 1999-09-01 |
| CZ287617B6 (en) | 2001-01-17 |
| JPH11503500A (ja) | 1999-03-26 |
| NO972918D0 (no) | 1997-06-20 |
| CZ194997A3 (en) | 1997-11-12 |
| DK0804659T3 (da) | 1999-10-11 |
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