EP0804644A1 - Selbstliegender bodenbelag und dessen herstellungsverfahren - Google Patents

Selbstliegender bodenbelag und dessen herstellungsverfahren

Info

Publication number
EP0804644A1
EP0804644A1 EP96900242A EP96900242A EP0804644A1 EP 0804644 A1 EP0804644 A1 EP 0804644A1 EP 96900242 A EP96900242 A EP 96900242A EP 96900242 A EP96900242 A EP 96900242A EP 0804644 A1 EP0804644 A1 EP 0804644A1
Authority
EP
European Patent Office
Prior art keywords
fibers
layer
textile
binder
floor covering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96900242A
Other languages
German (de)
English (en)
French (fr)
Inventor
Vitezslav Vorel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ekotex SRO
Original Assignee
Ekotex SRO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ekotex SRO filed Critical Ekotex SRO
Publication of EP0804644A1 publication Critical patent/EP0804644A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/0026Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
    • B29B17/0042Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting for shaping parts, e.g. multilayered parts with at least one layer containing regenerated plastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0047Special extra layers under the surface coating, e.g. wire threads
    • D06N7/0049Fibrous layer(s); Fibre reinforcement; Fibrous fillers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0052Compounding ingredients, e.g. rigid elements
    • D06N7/0055Particulate material such as cork, rubber particles, reclaimed resin particles, magnetic particles, metal particles, glass beads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/732Floor coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/70Scrap or recycled material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Definitions

  • the invention relates to a self-laying floor covering consisting of an outer textile layer and at least one lower layer, and a method for the production thereof,
  • the self-laying flooring is characterized by the fact that it lies on a flat surface, e.g. Concrete floor that can be laid out without having to be glued to it.
  • Their relatively heavy, flexible underlayer adheres to the surface and does not slip.
  • a plate for floor and wall covering which consists of a granulate of waste tire material and a two-component Hazr binder.
  • the filler is mixed with the binder, which mixes both components in a stoichiometric Ratio includes, the mixture is spread on the bottom of a flat form, which is placed in a press, in which the mass can be cured under pressure and at room temperature.
  • the plate produced in this way has only limited use, ie in open areas, in riding schools and the like. The surface formed from these panels does not meet the aesthetic requirements placed on interior spaces and also exudes the smell of the rubber used.
  • the stoichiometric reaction of the resin binder dissolves toxic reaction products.
  • the first part of the endless belt is warmed up from below, while the second part is cooled.
  • the two technologies do not result in a self-laying floor covering, the worn textile is difficult to separate from the underlayer, in both cases production is complicated by an additional intermediate connecting layer, the connection being unsolvable, which means the separate recycling of both layers difficult.
  • the object of the invention is therefore to create a self-laying floor covering which utilizes secondary raw materials to a large extent, enables their further recycling and thereby fulfills aesthetic requirements, including the necessary mechanical properties, including water permeability.
  • this object is achieved by a self-lying floor covering which consists of an outer textile layer and at least one sub-layer composed of a granulate and / or fiber filler and a polymer binding material, the binding material, which contains 10 to 30% of the Mass of the underlayer is involved, a film forms on the granules and / or the fibers of the filler, pores are formed between the individual grains and / or fibers of the filler coated with binding agent and fibers are immersed in the binding agent adhering to the surface of the underlayer, that protrude from the bottom surface of the fabric.
  • the filler of the underlayer is preferably granules of waste tire material, grain size from 0.5 to 5 mm, the underlayer contains polyurethane as a binder, and the outer textile layer is made of a textile composite made of polypropylene fibers.
  • An advantageous embodiment of the floor covering can consist of an outer textile layer and at least two lower layers, the composition of which is different.
  • the process according to the invention consists in that the granules and / or fibers of the filler are coated with a film of the polymerizing binder in the liquid state, the binder being 10 to 30 parts by mass of the Mixture means that the mixture is spread out on a flat underlayer to form an underlayer and comes into contact with the underside of the textile material, the binder in the underlayer can be polymerized, both layers with a pressure of 20 to 200 kPa are pressed together. The polymerization can then be completed, and the coating is cut into desired shapes if necessary.
  • the outer textile layer can be placed on the surface of the lower layer, or the textile material is first placed on the base with the underside facing upwards, and the mixture of granules and / or fibers and binding agent is then spread on this.
  • the polymerization in the lower layer and the pressing of the two layers onto one another can either take place in the static state or when the two layers stacked one on top of the other, which is the principle of a discontinuous or continuous process according to the invention.
  • the granules and the polyurethane binder are preferably heated to a temperature of 100 to 150 ° C. before mixing, in the course of mixing and / or in the layer.
  • the grains or fibers of the filler are coated with a thin film of the polymerizing binding agent in the liquid state.
  • the grains and / or fibers are only connected by the polymerization at points of common contact, with pores being retained between them.
  • the fact that the grains and / or fibers are only coated with the binding material has a further advantage that only a small amount of liquid binding material is present on the contact surface of the two layers at the moment of contact. The polymer therefore does not penetrate into the textile material, but only the textile fibers protruding from the surface of the textile material are immersed in the liquid binding material and are held in place by the polymerisation. In this way, a connection is achieved which excludes the mutual pushing movement of the two layers, but which enables a clean separation of the textile material from the lower layer and a subsequent recycling of both layers.
  • Fig. 1 is a discontinuous and
  • Fig. 2 schematically represent a continuous production of flooring.
  • Self-laying floor coverings have been developed, the textile outer layer 1 of which is formed by a textile composite made of polypropylene fibers and the lower layer by granules of old tire material and by polyurethane binding material.
  • the grain size of the granulate is 0.5 to 5.0 mm.
  • the mass of the covering per square meter is approx. 4 kg, the covering has good wear resistance, and its resistance to wear by a wheelchair is at least twice as high in comparison with the same textile material without an underlayer.
  • the filler in the lower layer textile fibers different from used tire material wood splinters are used alone or in combination, optionally also with the addition of inorganic granules such as sand, slag sand and other or inorganic fibers such as glass and asbestos fibers
  • the polymers come into consideration as binding agents, which enable the filler particles to be coated with a thin film, and after the underlayer has been formed, they form a viscous film on the contact surface in which the fibers protruding from the textile material to be applied be held.
  • binding agents which enable the filler particles to be coated with a thin film, and after the underlayer has been formed, they form a viscous film on the contact surface in which the fibers protruding from the textile material to be applied be held.
  • other polymers are also possible, e.g. Polyvinilethylene, butyl rubber, fluoroelastomer, etc.
  • the granulate and the liquid polyurethane binder are fed from a container 3 of the granulate and from a container 4 of the binder to a mixing device 5.
  • the mixture is discharged from this into a flat form 6 , here spread with a squeegee to form a regular layer 2, a textile blank is placed on the surface thereof, and the mold 6 with both layers 1, 2 is placed in a hot press 7, the table 8 of which is at a temperature of 140 ° C. and the bear 9 warmed up to a temperature of 90 ° C.
  • the polymerization of the binder is complete, and the mold is pushed out of the press, the floor covering is removed, it is allowed to cool, and it is cut into desired shapes.
  • the individual components are already warmed up in containers 3, 4, the heating is continued in the mixing device 5, and from this the mixture is turned into a slurry 10 regular layer pressed onto the surface of an endless belt 11.
  • a textile layer 1 is rolled onto the lower layer 2 from above. Both layers 1, 2 are carried between calender rolls 12, the temperature of the lower rolls being 140 ° C. and the upper 90 ° C. After max. After a 5-minute walk through the warm part 13 of the production line, the polymerization in the lower layer 2 is essentially complete.
  • a cooling section 14 follows and then the floor covering is cut into desired shapes.
  • the upper calender rolls are heated to a higher temperature than the lower ones.
  • the floor covering according to the invention produced by the production method described, is widely used indoors and on open terrain, preferably in the form of self-lying squares which can be laid for a limited time and then simply moved to another area. After the lifetime, the layers can easily be separated for recycling.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Floor Finish (AREA)
  • Laminated Bodies (AREA)
EP96900242A 1995-01-19 1996-01-18 Selbstliegender bodenbelag und dessen herstellungsverfahren Withdrawn EP0804644A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CZ95130A CZ282777B6 (cs) 1995-01-19 1995-01-19 Samoležící podlahová krytina a způsob její výroby
CZ13095 1995-01-19
PCT/CZ1996/000002 WO1996022413A1 (de) 1995-01-19 1996-01-18 Selbstliegender bodenbelag und dessen herstellungsverfahren

Publications (1)

Publication Number Publication Date
EP0804644A1 true EP0804644A1 (de) 1997-11-05

Family

ID=5461261

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96900242A Withdrawn EP0804644A1 (de) 1995-01-19 1996-01-18 Selbstliegender bodenbelag und dessen herstellungsverfahren

Country Status (4)

Country Link
EP (1) EP0804644A1 (cs)
AU (1) AU4383596A (cs)
CZ (1) CZ282777B6 (cs)
WO (1) WO1996022413A1 (cs)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2338975B (en) * 1997-03-11 2002-03-06 Baker Hughes Inc Glycol derivatives and blends thereof as gas hydrate inhibitors in water base drilling, drill-in, and completion fluids
WO1999028375A1 (de) * 1997-11-26 1999-06-10 Sms Sondermaschinen Gmbh Recyclingtechnik Verfahren zur herstellung einer sandwichartigen struktur
DE19921989A1 (de) * 1999-05-12 2000-11-16 Schmid Baukunststoffe Gmbh Verfahren zum Herstellen einer Platte sowie nach diesem Verfahren hergestellte Platte
WO2003014462A1 (en) * 2001-08-10 2003-02-20 Royal Rubber Manufacturing Rubber and textile mat
GB0214103D0 (en) * 2002-06-13 2002-07-31 Milliken Ind Ltd Mat
EP1511893A1 (en) * 2002-06-13 2005-03-09 Milliken Industrials Limited Mat
EP1511894B1 (en) 2002-06-13 2005-12-28 Milliken Industrials Limited Method of making a mat
WO2006066191A1 (en) * 2004-12-16 2006-06-22 Milliken & Company Textile surface coverings and methods for making them
WO2006127873A1 (en) * 2005-05-24 2006-11-30 Milliken & Company Carpet tile and related methods
US20070286982A1 (en) * 2006-06-12 2007-12-13 Higgins Kenneth B Surface coverings and methods
KR101976405B1 (ko) * 2014-07-31 2019-08-28 유니린 비브이비에이 플로어 커버링 제품을 제조하기 위한 방법 및 설비 및 이로 인해 얻어지는 플로어 커버링 제품

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2496739A1 (fr) * 1980-12-24 1982-06-25 Boussac Saint Freres Bsf Revetement a forte isolation thermique et phonique pour l'interieur de locaux, et procede de fabrication
AU5030690A (en) * 1989-02-01 1990-08-24 Mrp Elastomerics Inc. Mat
WO1993012283A1 (de) * 1991-12-12 1993-06-24 Alletto Rothhaar Verfahren zur herstellung von dekorativen beflockten fussbodenbelägen aus altgummi-recyclinggranulat
DE4224702A1 (de) * 1992-07-25 1994-01-27 P & H Kunststoff Recycling Gmb Verfahren zur Herstellung einer elastischen Rückenschicht für einen Teppichboden und nach dem Verfahren hergestellter, elastischer Teppichbodenrücken
DE4318630C1 (de) * 1993-06-04 1994-05-26 Zschimmer & Schwarz Gmbh & Co Verwendung von Braunkohlenpulver als Füllstoff für Teppichrückenbeschichtungen sowie dieses enthaltendes Mittel zum Beschichten von Teppichrücken

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9622413A1 *

Also Published As

Publication number Publication date
AU4383596A (en) 1996-08-07
WO1996022413A1 (de) 1996-07-25
CZ13095A3 (en) 1997-10-15
CZ282777B6 (cs) 1997-10-15

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