EP0753039B1 - Produit nettoyant dispersible pour tapis, a particules capables de rouler - Google Patents

Produit nettoyant dispersible pour tapis, a particules capables de rouler Download PDF

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Publication number
EP0753039B1
EP0753039B1 EP95912256A EP95912256A EP0753039B1 EP 0753039 B1 EP0753039 B1 EP 0753039B1 EP 95912256 A EP95912256 A EP 95912256A EP 95912256 A EP95912256 A EP 95912256A EP 0753039 B1 EP0753039 B1 EP 0753039B1
Authority
EP
European Patent Office
Prior art keywords
cleaning
weight
powder
carpet
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95912256A
Other languages
German (de)
English (en)
Other versions
EP0753039A1 (fr
Inventor
Theo Fleckenstein
Alexander Ditze
Franz Kresse
Thomas Hahn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0753039A1 publication Critical patent/EP0753039A1/fr
Application granted granted Critical
Publication of EP0753039B1 publication Critical patent/EP0753039B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0031—Carpet, upholstery, fur or leather cleansers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the present invention is in the field of scatterable cleaning agents for textiles.
  • dry cleaning agents For cleaning certain textiles, such as carpets and upholstered furniture, which are generally inaccessible to laundry and therefore on site and Are cleaned in place, used in addition to shampoo-like agents all powdered cleaners, also called dry cleaning agents become.
  • These dry cleaning agents consist of a solid Substance that acts as an adsorbent and a volatile liquid that is in the adsorbent is stored and serves to keep the dirt on the To loosen textile.
  • These agents are sprinkled on the textiles for cleaning and after the liquid evaporates from the textile together with the dirt components that have deposited on the adsorbent, brushed or vacuumed. Both as an adsorbent and as a liquid there are already many substances in the literature for these agents been proposed.
  • adsorbents such as wood flour, starch and cork powder, inorganic materials such as diatomaceous earth and bentonite, as well as various synthetic organic polymers proposed in powder form.
  • suitable cleaning fluids have been organic solvents such as gasoline or chlorinated hydrocarbons as well such as aqueous surfactant solutions or water-alcohol mixtures.
  • organic solvents such as gasoline or chlorinated hydrocarbons
  • aqueous surfactant solutions or water-alcohol mixtures For example only at this point I would like to refer to the German published documents DE 38 42 152, DE 34 37 629 and DE 40 27 004 pointed out in which the use relatively large synthetic polymer particles respectively short-fiber cellulose, each together with aqueous or non-aqueous Cleaning fluids is described.
  • the scatterable carpet cleaning agents provide an adequate cleaning effect only achieved when they are sprinkled with the help of brushes worked into the carpet either manually or mechanically so that they are in contact with all dirt-bearing fibers come.
  • Brushing in the cleaning powder represents because of the transferred Forces special requirements for the strength of the carpet fibers. A Roughening the surface and the loss of carpet fibers can be often not avoid. There is formation of fluff, which under certain Circumstances may also hinder the incorporation of the powder itself, because a Part of the loose fiber wraps around the bottom of the brush and the working process must be interrupted.
  • the invention therefore relates to a carpet cleaning agent in the form a scatterable preparation, which is an aqueous cleaning liquid powdery solid adsorbent and additionally rollable particles Viscose sponge is included, being the longest dimension of these particles is more than 1 mm and up to 50 mm and the dimensions in two other spatial directions that are perpendicular to each other and along this length stand, is at least 10% of this greatest length.
  • a carpet cleaning agent in the form a scatterable preparation, which is an aqueous cleaning liquid powdery solid adsorbent and additionally rollable particles Viscose sponge is included, being the longest dimension of these particles is more than 1 mm and up to 50 mm and the dimensions in two other spatial directions that are perpendicular to each other and along this length stand, is at least 10% of this greatest length.
  • Particularly preferred are carpet cleaning agents in which the rollable particles are made of deformable Material, especially absorbent sponge-like material are formed.
  • Powdery adsorbents are therefore suitable for the inventive Carpet cleaning agents such as wood flour in bleached and unbleached version, cellulose powder, starch, cork powder, synthetic organic polymers in powder form, such as polyethylene powder, polypropylene powder, Polyurethane powder, polystyrene powder, with the powder here too finely divided polymer fibers and ground polymer foams are understood, for example ground polyurethane foam, ground polystyrene foam, ground urea formaldehyde resin foam and ground phenolic resin foam.
  • carpet cleaning agents such as wood flour in bleached and unbleached version, cellulose powder, starch, cork powder, synthetic organic polymers in powder form, such as polyethylene powder, polypropylene powder, Polyurethane powder, polystyrene powder, with the powder here too finely divided polymer fibers and ground polymer foams are understood, for example ground polyurethane foam, ground polystyrene foam, ground urea formaldehyde resin foam and ground phenol
  • Inorganic materials can also serve as powdered adsorbents, for example silicon dioxide in various forms, such as precipitated Silica, diatomaceous earth and even fine sand, aluminum oxide in powder form, ground pumice, clays such as bentonite and others Aluminum silicates such as zeolites X, Y and A, faujasite and Hydrotalcite, still ground foam glass and also finely divided soluble Salts such as sodium borate and sodium chloride.
  • the particle size of this powdery Adsorbents are preferably between about 0.01 mm and 1 mm, in particular between 0.02 and 0.3 mm.
  • Adsorbents are preferred from the group wood flour, cellulose powder, water-insoluble cellulose derivatives, Silicic acid, zeolite, ground polyurethane foam and ground Urea formaldehyde resin foam.
  • the rollable particles of viscose sponge contained in the agents according to the invention can be regular or irregularly shaped bodies.
  • Crucial is that the shape is designed so that the body when incorporated of the carpet cleaning agent under the one running over the carpet Can roll brush.
  • the size of the rollable particles should on average be significantly larger than the particle size of powdered adsorbents.
  • the longest spatial dimension of the particles more than 1 mm and preferably more than 3 mm and can range up to 50 mm, preferably up to 10 mm.
  • the particle dimensions should be at least 10%, preferably at least 20% of this greatest length.
  • the rollable particles consist of viscose sponge.
  • the production of the particles can be done by crushing larger pieces of material, for example by cutting or grinding respectively. So in particular the particle obtained by crushing larger pieces.
  • Viscose sponge is preferably made of foamed material or fleece or Pieces of fabric.
  • the macroscopic pore volume of the rollable Viscose sponge particles are preferably between about 0.3 and 50 ml / g, in particular between 1 and 30 ml / g.
  • the content of rollable particles in the agents according to the invention can be relatively small, since only a few particles are sufficient for the to achieve the desired effect.
  • the proportion of rollable particles is thus in the agents according to the invention preferably about 0.1 to 10 % By weight, in particular 0.1 to 2% by weight, based on the total agent.
  • the cleaning liquid contained in the agents according to the invention is, in the simplest case, it can be water alone, however, the cleaning liquid often contains other aids that enhance cleaning performance or otherwise in use the means are useful.
  • the amount of liquid is measured so that it can still be absorbed by the fixed components of the funds and thus the spreadability of the funds is guaranteed.
  • the water content in the compositions is preferably 25 to 75% by weight, in particular 30 to 70 wt .-%, each based on the total agent.
  • the agents according to the invention can be used as cleaning-enhancing additives in the cleaning liquid preferably organic solvents and / or Contain surfactants.
  • organic solvents and / or Contain surfactants Both water-miscible are suitable as organic solvents as well as water-immiscible solvents, insofar as they do not attack the textiles and are sufficiently volatile to remove them after the Application of the agent to evaporate on the textiles in a short time.
  • Farther When selecting solvents, make sure that they are in the finished product mixture have sufficiently high flash points and toxicologically are harmless.
  • Alcohols, ketones, glycol ethers are particularly suitable and hydrocarbons, for example isopropanol, acetone, ether of mono- and diethylene glycol and of mono-, di- and tripropylene glycol with Boiling points between 120 ° C and 250 ° C and petrol with a boiling range from 130 to 200 ° C, especially low-aromatic fractions, and mixtures from these solvents.
  • Alcohols with 2 to 3 carbon atoms, Propylene glycol ether, gasolines and mixtures thereof are used.
  • the amount organic solvents are present in the agents according to the invention, preferably not more than 20% by weight, in particular between 2 and 15% by weight.
  • the detergents are very good for surface cleaning without the addition of surfactants, not the result when using commercial means in the majority of cases can also be achieved by the Addition of surfactants to improve the removal of stains.
  • a surfactant addition of up to 10% by weight is sufficient; preferably the agents contain 0.05 to 5% by weight, especially not more than 1% by weight of surfactants.
  • the large number of known surfactants are particularly suitable those substances that may be non-volatile together with other substances Dry components of the agent to a solid, brittle residue.
  • the surfactants can be of the anionic or nonionic classes Surfactants originate, but anionic surfactants are preferably used.
  • Addition products of are particularly suitable as nonionic surfactants 1 to 30, preferably 4 to 15 moles of ethylene oxide per 1 mole of a long chain Compound with 10 to 20 carbon atoms from the group of alcohols, Alkylphenols, carboxylic acids and carboxamides. Besides that come too corresponding compounds into consideration, in which instead of part of the Ethylene oxide is attached to propylene oxide.
  • the attachment products are particularly important from ethylene oxide to long chain primary or secondary Alcohols, such as fatty alcohols or oxo alcohols, as well as on mono- or dialkylphenols with 6 to 14 carbon atoms in the alkyl groups.
  • Other suitable non-ionic surfactants are the long-chain amine oxides and the Fatty alkyl (poly) glycosides with 1 to 3 glycose units in the molecule.
  • Suitable anionic surfactants are, in particular, those of sulfate or Sulfonate type, but other types such as soaps, long chain N-acyl sarcosinates, Salts of fatty acid cyanamides or salts of ether carboxylic acids, such as those from long-chain alkyl or alkylphenyl polyglycol ethers and chloroacetic acid are available.
  • the anionic Surfactants are preferably used in the form of the sodium salts.
  • Particularly suitable surfactants of the sulfate type are the sulfuric acid monoesters of long-chain primary alcohols of natural and synthetic origin with 10 to 20 carbon atoms, that is to say of fatty alcohols, such as, for example, coconut fatty alcohols, tallow fatty alcohols, oleyl alcohol, or the C 10 to C 20 oxo alcohols and those of secondary alcohols of this chain length.
  • fatty alcohols such as, for example, coconut fatty alcohols, tallow fatty alcohols, oleyl alcohol, or the C 10 to C 20 oxo alcohols and those of secondary alcohols of this chain length.
  • sulfuric acid monoesters of the aliphatic primary alcohols, secondary alcohols or alkylphenols ethoxylated with 1 to 6 mol of ethylene oxide come into consideration.
  • Sulfated fatty acid alkanolamides and sulfated fatty acid monoglycerides are also suitable.
  • the surfactants of the sulfonate type are primarily sulfosuccinic acid monoesters and diesters with 6 to 22 carbon atoms in the alcohol parts, the alkylbenzenesulfonates with C 9 to C 15 alkyl groups and the esters of ⁇ -sulfo fatty acids, for example the ⁇ -sulfonated methyl or ethyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • alkanesulfonates which can be obtained from C 12 -C 18 -alkanes by sulfochlorination or sulfoxidation and subsequent hydrolysis or neutralization or by bisulfite addition to olefins
  • olefinsulfonates which are mixtures of alkene and hydroxyalkanesulfonates and Disulfonates as obtained, for example, from long-chain monoolefins with a terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products.
  • the fatty alcohol sulfates with 12 to 18 carbon atoms are particularly preferred, the salts of sulfosuccinic acid monoesters with 16 to 20 carbon atoms in the alcohol part and mixtures of these surfactants are used.
  • the agents of this invention can other auxiliary materials commonly used in textile and carpet cleaning agents and additives in a small amount.
  • antistatic components such as inorganic salts and quaternary ammonium compounds, optical brighteners, the re-pollution reducing substances, such as polyacrylates, the spreadability and spreadability-enhancing additives, preservatives and perfume.
  • auxiliary materials and additives are usually no more than 10% by weight used; preferably the content is not more than 5 percent by weight, in particular between 0.01 and 2 wt .-%, each based on the total funds.
  • a particularly preferred agent contains cellulose powder as powdered adsorbent, preferably in amounts of about 40 to 50 wt .-%, as rollable Particles flakes of viscose sponge, preferably in amounts of about 0.1 to 2 wt .-%, as surfactant sodium olefin sulfonate, preferably in Quantities of about 0.2 to 1.5% by weight, low-aromatic gasoline solvent, preferably in amounts of about 1 to 10 wt .-%, and water.
  • cellulose powder as powdered adsorbent, preferably in amounts of about 40 to 50 wt .-%, as rollable Particles flakes of viscose sponge, preferably in amounts of about 0.1 to 2 wt .-%, as surfactant sodium olefin sulfonate, preferably in Quantities of about 0.2 to 1.5% by weight, low-aromatic gasoline solvent, preferably in amounts of about 1 to 10 wt .-%, and water.
  • the preparation of the agents according to the invention does not require a major one technical effort.
  • simple mixing devices such as shovel or drum mixer in which the rollable particles, the powdered Adsorbent and, if necessary, other finely divided solid Components and then moving with the cleaning liquid, which optionally contains other constituents dissolved, sprayed.
  • the cleaning of the textiles and carpets takes place in such a way that the cleaning agents according to the invention are sprinkled onto the textiles manually or with the aid of a suitable spreading device and then rubbed more or less intensively into the textiles, for example with the aid of a sponge, a brush or a corrugated board .
  • a suitable spreading device for example, a sponge, a brush or a corrugated board.
  • training times of 0.3 to 5 minutes, preferably 0.5 to 3 minutes per square meter are chosen.
  • the residues are removed from the textiles mechanically, for example by brushing and / or vacuuming.
  • the agents listed in the following table with details of the individual components were each produced in amounts of 10 kg in a paddle mixer, the adsorbents and the rollable particles being introduced and then sprayed with a solution of the other components in water. Mixing was continued until a homogeneous, free-flowing product was obtained.
  • composition of the funds (in percent by weight) 1 2nd 3rd 4th 5 6 Beech wood cellulose powder 43.0 46.0 42.5 47.0 Urea-formaldehyde resin foam powdered (75% moisture) 72.0 88.0 Sliced viscose fleece 0.3 0.6 1.0 3.0 Zeolite agglomerate 2.5 4.7 Na lauryl sulfate 0.8 0.3 Na olefin sulfonate 0.8 1.1 Ethanol 5.0 Isoparaffin 1.0 Water, perfume preservative to 100 wt .-%
  • Beech wood cellulose powder
  • Powdered urea-formaldehyde resin foam
  • Moist material with 75% by weight H 2 O, maximum grain distribution at approx. 0.03 mm, bulk density 70 g / l.
  • Sponge cloth material used for kitchen cleaning (Cotton content 50%) was cut with a cross-cut machine Cut flakes with the dimensions 2.5 x 2.0 x 2 - 8 mm. Bulk density approx. 90 g / l.
  • Type Baylith W 894 granules made of zeolite X-Na, binder-free, spherical, Grain size 1 - 4 mm.
  • the cleaning agents 1, 2, 4 and 5 according to the invention were in their cleaning ability against artificial pigment soiling and hairy Coverings and with regard to the roughening of the treated carpet material checked and compared with such means that instead of Rollable particles of viscose fleece or zeolite agglomerate not according to Examples 3 and 6 according to the invention Additional amount of the powdered adsorbent contained; but were otherwise composed the same.
  • the cleaning performance against artificial pigment soiling was used on polyamide velor carpets checked.
  • the agents according to the invention showed practically the same cleaning performance as the agents without rollable Particle. Compared to hairy toppings (sprinkled mixture of cotton wool, Hair and wool fibers) the agents according to the invention were clearly shown think.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)

Claims (4)

  1. Produit de nettoyage de tapis sous forme de préparation dispersible, qui renferme un liquide aqueux de nettoyage et un adsorbant solide pulvérulent,
    caractérisé en ce qu'
    en supplément des particules capables de rouler, en éponge de viscose sont contenues, dont la dimension la plus longue s'élève à plus de 1 mm de préférence à plus de 3 mm et allant jusqu'à 50 mm, de préférence à pas plus de 10 mm, pour lesquelles les dimensions dans les deux autres directions spatiales qui sont placées l'une par rapport à l'autre verticalement sur cette longueur, représente au moins 10 %, de préférence au moins 20 % de cette plus grande longueur.
  2. Produit de nettoyage de tapis selon la revendication 1, dans lequel l'adsorbant solide pulvérulent est choisi dans le groupe de la sciure de bois, de la poudre de cellulose, des dérivés insolubles dans l'eau de la cellulose, de l'acide silicique, de la zéolite, de la mousse de polyuréthane broyées et de la mousse de résine urée-formaldéhyde broyée.
  3. Produit de nettoyage de tapis selon une des revendications 1 à 2,
    contenant :
    de 40 à 50 % en poids de poudre de cellulose
    de 0,1 à 2 % en poids de flocons en éponge de viscose
    de 0,2 à 1,5 % en poids d'oléfine sulfonate de sodium
    de 1 à 10 % en poids d'essence pauvre en aromatique
    ainsi que de l'eau.
  4. Procédé de nettoyage de tapis
    dans lequel
    on répand de 2 à 150 g d'un produit de nettoyage conforme à l'une des revendications 1 à 3 par mètre carré de textile, on répand en frottant le produit pendant 0,3 à 5 minutes sur les surfaces du textile et ensuite on l'élimine par brossage et/ou par aspiration à nouveau du textile.
EP95912256A 1994-03-30 1995-03-21 Produit nettoyant dispersible pour tapis, a particules capables de rouler Expired - Lifetime EP0753039B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4411047A DE4411047A1 (de) 1994-03-30 1994-03-30 Streufähiges Teppichreinigungsmittel mit rollfähigen Partikeln
DE4411047 1994-03-30
PCT/EP1995/001040 WO1995027023A1 (fr) 1994-03-30 1995-03-21 Produit nettoyant dispersible pour tapis, a particules capables de rouler

Publications (2)

Publication Number Publication Date
EP0753039A1 EP0753039A1 (fr) 1997-01-15
EP0753039B1 true EP0753039B1 (fr) 1999-03-03

Family

ID=6514242

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95912256A Expired - Lifetime EP0753039B1 (fr) 1994-03-30 1995-03-21 Produit nettoyant dispersible pour tapis, a particules capables de rouler

Country Status (9)

Country Link
US (1) US5783543A (fr)
EP (1) EP0753039B1 (fr)
JP (1) JPH09511010A (fr)
AT (1) ATE177142T1 (fr)
CA (1) CA2186909A1 (fr)
DE (2) DE4411047A1 (fr)
DK (1) DK0753039T3 (fr)
ES (1) ES2129813T3 (fr)
WO (1) WO1995027023A1 (fr)

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GB9600547D0 (en) * 1996-01-11 1996-03-13 Reckitt & Colman Inc Improved compositions containing organic compounds
JPH09255992A (ja) * 1996-03-26 1997-09-30 Johnson Kk カーペット用の粉末洗浄剤
DE19648852A1 (de) * 1996-10-02 1998-04-16 Richard Reichmann Reinigungsmittel sowie Verfahren zu seiner Herstellung
US6689740B1 (en) 1999-06-15 2004-02-10 Givaudan Sa Method for preparing fragrance products
US6827792B2 (en) 1999-06-25 2004-12-07 Strategic Environmental Solutions, Llc Liquid waste absorbing compositions
US6326344B1 (en) 2000-01-27 2001-12-04 Ecolab Inc. Carpet spot removal composition
ATE327306T1 (de) * 2000-06-19 2006-06-15 Procter & Gamble Verfahren zur behandlung von geweben durch wärmeerzeugung
EP1184449A1 (fr) * 2000-09-04 2002-03-06 The Procter & Gamble Company Composition de nettoyage de tapis contenant un matériau gélifiant absorbant
US20030087589A1 (en) * 2001-10-31 2003-05-08 Earthstone International Llc Foamed glass and ground glass surface or object treating agent, use therefor, and method of making same
US7494512B2 (en) * 2004-02-20 2009-02-24 Brown Steven E Compositions and methods for cleaning textile substrates
US7135449B2 (en) * 2004-02-20 2006-11-14 Milliken & Company Composition for removal of odors and contaminants from textiles and method
US20050187123A1 (en) * 2004-02-20 2005-08-25 Shulong Li Composition for removal of odors and contaminants from carpet and method
US20050183207A1 (en) * 2004-02-20 2005-08-25 Chan Marie S. Compositions and methods for cleaning textile substrates
US7326672B2 (en) * 2004-07-29 2008-02-05 Vivek Subramanian Substantially enzyme free personal wash compositions comprising non-silicates with basal layer cationic charge
US7407922B2 (en) * 2005-10-13 2008-08-05 S.C. Johnson & Son, Inc. Deodorizing compositions
US7261742B2 (en) 2005-10-13 2007-08-28 S.C. Johnson & Son, Inc. Method of deodorizing a textile
GB0702291D0 (en) * 2007-02-07 2007-03-14 Reckitt Benckiser Nv Composition and process
WO2010078413A1 (fr) 2008-12-31 2010-07-08 Apinee, Inc. Conservation du bois, compositions et procédés correspondants
US8138135B2 (en) * 2009-03-27 2012-03-20 Milliken & Company Powder cleaning composition
CN102817208B (zh) * 2011-06-09 2017-03-01 塞罗斯有限公司 洗涤用固体颗粒及其洗涤方法
US9878464B1 (en) 2011-06-30 2018-01-30 Apinee, Inc. Preservation of cellulosic materials, compositions and methods thereof
DE102015107637B4 (de) * 2015-05-15 2024-06-20 Alfred Kärcher SE & Co. KG Pulverförmiges Reinigungsmittel

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Publication number Priority date Publication date Assignee Title
DE3437629A1 (de) * 1984-10-13 1986-04-17 Henkel KGaA, 4000 Düsseldorf Teppichreinigungsmittel
DE3707409A1 (de) * 1987-03-07 1988-09-15 Henkel Kgaa Verfahren zur fleckentfernung von textilien
DE3842152A1 (de) * 1988-12-15 1990-06-21 Henkel Kgaa Teppichreinigungsmittel
DE3927975A1 (de) * 1989-04-13 1990-10-18 Vorwerk Co Interholding Pulverfoermiges reinigungsmittel
US5714449A (en) * 1990-02-16 1998-02-03 Unilever Patent Holdings B.V. Non-aqueous liquid cleaning products which contain modified silica
DE4027004A1 (de) * 1990-08-27 1992-03-05 Henkel Kgaa Teppichreinigungsmittel
EP0559472B1 (fr) * 1992-03-06 1996-05-15 Unilever Plc Compositions de nettoyage liquides, peu moussantes
US5286400A (en) * 1993-03-29 1994-02-15 Eastman Kodak Company Flowable powder carpet cleaning formulations
GB9600547D0 (en) * 1996-01-11 1996-03-13 Reckitt & Colman Inc Improved compositions containing organic compounds

Also Published As

Publication number Publication date
WO1995027023A1 (fr) 1995-10-12
EP0753039A1 (fr) 1997-01-15
US5783543A (en) 1998-07-21
DE4411047A1 (de) 1995-10-05
DE59505206D1 (de) 1999-04-08
JPH09511010A (ja) 1997-11-04
DK0753039T3 (da) 1999-10-04
ES2129813T3 (es) 1999-06-16
CA2186909A1 (fr) 1995-10-12
ATE177142T1 (de) 1999-03-15

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