EP0750226B1 - Procédé de traitement d'un produit photographique couleur à l'halogénure d'argent sensible à la lumière - Google Patents

Procédé de traitement d'un produit photographique couleur à l'halogénure d'argent sensible à la lumière Download PDF

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Publication number
EP0750226B1
EP0750226B1 EP96109200A EP96109200A EP0750226B1 EP 0750226 B1 EP0750226 B1 EP 0750226B1 EP 96109200 A EP96109200 A EP 96109200A EP 96109200 A EP96109200 A EP 96109200A EP 0750226 B1 EP0750226 B1 EP 0750226B1
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Prior art keywords
group
processing
solution
sensitive material
silver halide
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Expired - Lifetime
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EP96109200A
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German (de)
English (en)
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EP0750226A1 (fr
Inventor
Yasuhiro C/O Fuji Photo Film Co. Ltd. Katsuoka
Hiroyuki C/O Fuji Photo Film Co. Ltd. Seki
Hisashi C/O Fuji Photo Film Co. Ltd. Okada
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Fujifilm Holdings Corp
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Fuji Photo Film Co Ltd
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Priority to EP03014550A priority Critical patent/EP1365285B1/fr
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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/3046—Processing baths not provided for elsewhere, e.g. final or intermediate washings
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/407—Development processes or agents therefor
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/42—Bleach-fixing or agents therefor ; Desilvering processes
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C2200/00—Details
    • G03C2200/10—Advanced photographic system
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C2200/00—Details
    • G03C2200/19—Colour negative
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/22—Subtractive cinematographic processes; Materials therefor; Preparing or processing such materials
    • G03C7/24—Subtractive cinematographic processes; Materials therefor; Preparing or processing such materials combined with sound-recording
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials

Definitions

  • a compound represented by general formula (X) for use in the present invention is described in detail below.
  • the number of carbon atoms hereinafter referred to means carbon atoms, excluding a substituent.
  • methanesulfonylamino a sulfamoyl group having preferably 0 to 10, more preferably 0 to 6, and particularly preferably 0 to 4 carbon atoms (e.g. sulfamoyl and methylsulfamoyl); a carbamoyl group having preferably 1 to 10, more preferably 1 to 6, and particularly preferably 1 to 4 carbon atoms (e.g. carbamoyl and methylcarbamoyl); an alkylthio group having preferably 1 to 8, more preferably 1 to 6, and particularly preferably 1 to 4 carbon atoms (e.g.
  • heterocyclic groups is a 5-or 6-membered aromatic heterocyclic group, with a more preferred example being a 5- or 6-membered nitrogen atom-containing aromatic heterocyclic group. Still more preferred is a 5- or 6-membered aromatic heterocyclic group containing one or two nitrogen atoms.
  • the compound represented by general formula (X) has an asymmetric carbon atom in its molecule, it is preferred, from the spontaneous decomposability point of view, that at least one asymmetric carbon atom is a L type (L form). Further, when the compound has at least two asymmetric carbon atoms, the more L-type asymmetric carbon atoms there are in the molecule, the more the compound is preferred.
  • the compound of general formula (X) for use in the present invention may be used singly or in a combination of two or more kinds thereof.
  • each of R 5 and R 6 is preferably a hydrogen atom.
  • n is preferably 0.
  • Z 1 preferably represents a group of non-metallic atoms necessary to complete an unsubstituted 4-thiazolyl ring.
  • the compounds represented by general formulae (A) to (I) include compounds described in, for example, JP-A-263938/1985, ibid. 228247/1984, ibid. 27424/1979, and ibid. 211751/1989, in addition to the above-exemplified compounds.
  • the compounds represented by general formulae (G) and (H) and gentamicins are preferred in the present invention.
  • the compounds represented by general formulae (G) and (H) are particularly preferred.
  • the washing water and/or the stabilizing solution preferably contains other additives, such as ammonium compounds (e.g. ammonium chloride, ammonium sulfite), metal compounds (e.g. a bismuth compound, an aluminum compound), a fluorescent brightening agent, a hardener; alkanolamines, as described in U.S. patent No. 4,786,583; and sulfinic acid compounds, as described in JP-A-231051/1989, according to the occasion.
  • ammonium compounds e.g. ammonium chloride, ammonium sulfite
  • metal compounds e.g. a bismuth compound, an aluminum compound
  • a fluorescent brightening agent e.g. a bismuth compound, an aluminum compound
  • a hardener e.g. a bismuth compound, an aluminum compound
  • any of known stabilizing techniques described, for example, in JP-A-8543/1982, ibid. 14834/1983, and ibid. 220345/1985 can be utilized.
  • p represents 0 or 1, preferably 0.
  • the cation represented by Ma is an organic or inorganic cation.
  • the cation include an alkali metal ion (e.g. Li + , Na + , K + , Cs + ), an alkali earth metal ion (e.g. Ca 2+ , Mg 2+ ), an ammonium ion (e.g. ammonium, tetraethylammonium), a pyridium ion, and a phosphonium ion (e.g. tetrabutylphosphonium, tetraphenylphosphonium).
  • an alkali metal ion e.g. Li + , Na + , K + , Cs +
  • an alkali earth metal ion e.g. Ca 2+ , Mg 2+
  • an ammonium ion e.g. ammonium, tetraethylammonium
  • pyridium ion e.g.
  • the nitrogen-containing heterocyclic residue may have a substituent in addition to the (CH 2 ) p CO 2 Ma group.
  • substituents are the same as exemplified above as a substituent for the heterocyclic residue completed by Q in general formula (J).
  • a black-and-white developing solution to be used for black-and-white development contains one or more of known black-and-white developing agents.
  • Representative black-and-white developing agents include dihydroxybenzenes, such as hydroquinone and hydroquinone monosulfonate; 3-pyrazolidones, such as 1-phenyl-3-pyrazolidone and 1-phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone; and aminophenols, such as N-methyl-p-aminophenol.
  • the above-mentioned black-and-white developing solution can be also used in the process of a black-and-white light-sensitive material.
  • development-accelerating agents are also preferably used in a color-developing solution.
  • the above-described color-developing agent may be used as it is, as a color-developing solution or a replenishing solution, but preferably it is used as a mixture with water, for dilution.
  • a starter containing a pH adjuster, a bromide, and the like in addition to water.
  • the magnetic recording layer is formed by coating, on a support, an aqueous or organic solvent coating solution having dispersed particles of a magnetic substance in a binder.
  • the magnetic substance include ferromagnetic iron oxide, such as ⁇ Fe 2 O 3 , Co-coated ⁇ Fe 2 O 3 , Co-coated magnetite, Co-doped magnetite, ferromagnetic chromium dioxide, ferromagnetic metal, ferromagnetic alloy, hexagonal system Ba ferrite, Sr ferrite, Pb ferrite, and Ca ferrite.
  • Preferred among these magnetic substances are Co-coated ferromagnetic iron oxides, such as Co-coated ⁇ Fe 2 O 3 .
  • any of an acicular, a rice grain-like, a spherical, a cubic, or a tabular form may be used.
  • a specific surface area is preferably S BET of 20 m 2 /g or more, particularly preferably 30 m 2 /g or more.
  • Saturated magnetization ( ⁇ s) of the ferromagnetic substance is preferably from 3.0 x 10 4 to 3.0 x 10 5 A/m, particularly preferably from 4.0 x 10 4 to 2.5 x 10 5 A/m.
  • the surface of the ferromagnetic substance grains may be treated with silica and/or alumina, or with an organic material.
  • a ultraviolet absorber may be kneaded into this polyester. Further, light-piping can be prevented by kneading into the polyester a dye or pigment for the polyester, examples of which that are commercial products are Diaresin (trade name, manufactured by Mitsubishi Chemicals Co., Ltd.) and Kayaset (trade name, manufactured by Nippon Kayaku Co., Ltd.).
  • a main material of the patrone to be used may be a metal or a synthetic plastic, and preferred are such plastics as polystyrene, polyethylene, polypropylene, and polyphenylether.
  • a BO-type vibration ball mill manufactured by Chuo Koki Co., Ltd., was employed. After the dispersion, the mixture was taken out and added to 8 g of a 12.5% aqueous gelatin solution, and then the beads were removed by filtration, to obtain a gelatin dispersion of the dye.
  • the average grain size of the dye in the form of fine grains was 0.44 ⁇ m.
  • Silica grains (0.3 ⁇ m), as a matting agent, and 3-poly(polymerization degree: 15) oxyethylene-propyloxytrimethoxysilan (15 weight%)-coated aluminum oxide (0.15 ⁇ m), as an abrasive, were each added thereto, to give a coverage of 10 mg/m 2 .
  • Drying was conducted at 115 °C for 6 min (the roller and the transportation apparatus in the drying zone all were set at 115 °C).
  • the increment of the color density of D B of the magnetic recording layer was about 0.1 when X-light (blue filter) was used.
  • the saturation magnetization moment of the magnetic recording layer was 4.2 emu/g, -the coercive force was 7.3 x 10 4 A/m, and the squareness ratio was 65%.
  • sample 102 having magnetic information recorded as mentioned above, was processed with sample 101, which was cut, processed and exposed to light -in the same manner as in Example 1, according to the same method described in Example 1, except that the developing solution, the bleaching solution, and the fixing solution were replaced by the following solutions. At this time, the ratio of processing amounts between sample 101 and sample 102 was 5:1.
  • the present invention is also excellent in magnetic output.
  • each processing solution was as follows, respectively: (Color-developer) Tank Solution (g) Replenisher (g) Diethylenetriaminepentaacetic acid 3.0 3.0 Disodium catecol-3,5-disulfonate 0.3 0.3 Sodium sulfite 3.9 5.3 Potassium carbonate 39.0 39.0 Hydroxylamine sulfate 5.0 6.5 Potassium bromide 1.3 - Potassium iodide 1.3 mg - 4-Hydroxy-6-methyl-1,3,3a,7-tetrazaindene 0.05 - 2-Methyl-4-[N-ethyl-N-( ⁇ -hydroxyethyl)-amino]aniline sulfate 4.5 6.5 Water to make 1.0 liter 1.0 liter pH 10.05 10.21 (pH was adjusted by potassium hydroxide and sulfuricacid (Bleaching solution) Tank solution (g) Replenisher (g) Exemplified Comound 40 0.25 mol 0.38
  • the processing method of the present invention provided excellent effects on the adhesive property, the wet-heat fading, and the magnetic output of the processed light-sensitive material, as were seen in Example 2.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)

Claims (9)

  1. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent, lequel procédé comprend les étapes consistant en le développement en couleur d'un matériau photosensible photographique en couleur à halogénure d'argent, et ensuite de désargentage, et en outre le lavage et/ou la stabilisation de celui-ci, dans lequel la solution de traitement ayant une capacité de blanchiment dans l'étape de désargentage contient un sel ferrique complexe d'au moins un composé représenté par la formule générale (X) :
    Figure 01740001
       dans laquelle R représente un atome d'hydrogène un groupement hydrocarbure aliphatique, un groupement aryle ou un groupement hétérocyclique, L1 et L2 représentent chacun un groupement alkylène et M1 et M2 représentent chacun un atome d'hydrogène ou un cation,
       caractérisé en ce qu'une solution de traitement utilisée dans l'étape de désargentage ou les étapes suivantes de celle-ci contient au moins un composé représenté par les formules générales (A) à (I) :
    Figure 01750001
    Figure 01750002
    Figure 01750003
    Figure 01750004
    Figure 01750005
    dans lesquelles R1, R2, R3, R4, R5, R7, et R8 représentent chacun un atome d'hydrogène, un groupement alkyle ou un groupement aryle, R6 représente un atome d'hydrogène, un groupement alkyle, un groupement aryle, un groupement nitro, un groupement carboxyle, un groupement sulfo, un groupement sulfamoyle, un groupement hydroxyle, un atome d'halogène, un groupement alcoxy ou un groupement thiazolyle, L3 et L4 représentent chacun un groupement alkylène ou un groupement arylène, R9, R10 et R11 représentent chacun un atome d'halogène ou un groupement alkyle, R12 et R13 représentent chacun un atome d'hydrogène, un groupement alkyle, un groupement aryle ou un groupement résidu hétérocyclique contenant de l'azote, R14 et R15 représentent chacun un atome d'hydrogène, un atome d'halogène, un groupement alkyle ou un groupement aryle, à condition que R14 et R15 puissent se lier ensemble pour former un cycle benzénique, R16 représente un atome d'hydrogène ou un groupement alkyle, R17 représente un groupement alkyle ou un groupement aryle, Y représente un atome d'halogène Z1 représente un groupe d'atomes non métalliques nécessaires pour achever un cycle thiazolyle, Z2 représente un groupe d'atomes non métalliques nécessaires pour achever un cycle hydrocarbure à 6 chaínons, n vaut 0 ou 1, m vaut 1 ou 2 et k est un nombre entier de 3 à 20,
       ou au moins un aminoglycoside choisi parmi le groupe constitué des gentamycines, de l'amikacine, de la tobramycine, de la dibékacine, de l'albékacine, de la micronomycine, de l'isépamycine, de la sisomycine, de la nétilmycine et de l'astromycine,
       et la solution de traitement présentant une capacité de blanchiment contient en outre au moins un composé représenté par la formule générale (J) :
    Figure 01760001
       dans laquelle Q représente un groupe d'atomes non métalliques nécessaires pour achever un cycle hétérocyclique, p vaut 0 ou 1 et Ma représente un atome d'hydrogène ou un cation.
  2. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 1, dans lequel la solution de traitement contenant au moins un composé de formule générale (A), (B), (C), (D), (E), (F), (G), (H) ou (I), ou au moins un aminoglycoside, est une solution de traitement présentant une capacité de blanchiment, une eau de lavage ou une solution de stabilisation.
  3. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 1, dans lequel R, dans la formule générale (X), représente un atome d'hydrogène ou un groupement alkyle comprenant 1 à 8 atomes de carbone.
  4. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la. revendication 3, dans lequel R, dans la formule générale (X), représente un atome d'hydrogène.
  5. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 1, dans lequel le composé représenté par la formule générale (X) est un composé représenté par la formule générale (1-a) :
    Figure 01770001
       dans laquelle L1 représente un groupement alkylène, M1 représente un atome d'hydrogène ou un cation et Ma1 et Ma2 représentent chacun un atome d'hydrogène ou un cation.
  6. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 1, dans lequel le sel ferrique complexe d'au moins un composé représenté par la formule générale (X) est contenu dans une solution de blanchiment.
  7. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 1, 2, 3, 4, 5 ou 6, dans lequel le matériau photosensible photographique en couleur à halogénure d'argent est un film négatif en couleur.
  8. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 1, 2, 3, 4, 5, 6 ou 7, dans lequel le matériau photosensible photographique en couleur à halogénure d'argent comprend une couche d'enregistrement magnétique.
  9. Procédé de traitement d'un matériau photosensible photographique en couleur à halogénure d'argent selon la revendication 8, dans lequel la couche d'enregistrement magnétique contient de l'oxyde de fer ferromagnétique revêtu de Co.
EP96109200A 1995-06-09 1996-06-07 Procédé de traitement d'un produit photographique couleur à l'halogénure d'argent sensible à la lumière Expired - Lifetime EP0750226B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP03014550A EP1365285B1 (fr) 1995-06-09 1996-06-07 Procédé de traitement d'un produit photographique couleur à l'halogénure d'argent sensible à la lumière

Applications Claiming Priority (3)

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JP167100/95 1995-06-09
JP16710095 1995-06-09
JP16710095A JP3544245B2 (ja) 1995-06-09 1995-06-09 ハロゲン化銀カラー写真感光材料の処理方法

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EP03014550A Expired - Lifetime EP1365285B1 (fr) 1995-06-09 1996-06-07 Procédé de traitement d'un produit photographique couleur à l'halogénure d'argent sensible à la lumière

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US5935767A (en) * 1998-01-29 1999-08-10 Eastman Kodak Company Process of producing color negative image at shortened development times
US5928844A (en) * 1998-05-27 1999-07-27 Eastman Kodak Company Method of photographic processing using spray wash after bleaching
US6448281B1 (en) 2000-07-06 2002-09-10 Boehringer Ingelheim (Canada) Ltd. Viral polymerase inhibitors
EP1513009A1 (fr) 2003-08-29 2005-03-09 AgfaPhoto GmbH Récipient pour composés photographiques
ES2431314T3 (es) 2004-02-20 2013-11-26 Boehringer Ingelheim International Gmbh Inhibidores de polimerasa vírica

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JPS6150140A (ja) * 1984-08-19 1986-03-12 Konishiroku Photo Ind Co Ltd ハロゲン化銀カラ−写真感光材料の処理方法
JPH0695318A (ja) * 1992-09-11 1994-04-08 Konica Corp ハロゲン化銀カラー感光材料の処理方法
JP2886748B2 (ja) * 1992-09-17 1999-04-26 富士写真フイルム株式会社 写真用処理組成物及び処理方法
US5543272A (en) * 1993-02-17 1996-08-06 Fuji Photo Film Co., Ltd. Photographic composition having fixing capacity and a method for processing using the same

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DE69636681D1 (de) 2006-12-14
EP0750226A1 (fr) 1996-12-27
EP1365285A1 (fr) 2003-11-26
DE69630419D1 (de) 2003-11-27
DE69636681T2 (de) 2007-09-06
EP1365285B1 (fr) 2006-11-02
JPH08339063A (ja) 1996-12-24
JP3544245B2 (ja) 2004-07-21
DE69630419T2 (de) 2004-07-15

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