EP0740110B1 - Procédé et appareil pour le traitement de résidus solides de combustion d'un incinérateur - Google Patents

Procédé et appareil pour le traitement de résidus solides de combustion d'un incinérateur Download PDF

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Publication number
EP0740110B1
EP0740110B1 EP96100180A EP96100180A EP0740110B1 EP 0740110 B1 EP0740110 B1 EP 0740110B1 EP 96100180 A EP96100180 A EP 96100180A EP 96100180 A EP96100180 A EP 96100180A EP 0740110 B1 EP0740110 B1 EP 0740110B1
Authority
EP
European Patent Office
Prior art keywords
deslagger
combustion residues
process according
inlet shaft
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP96100180A
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German (de)
English (en)
Other versions
EP0740110A3 (fr
EP0740110A2 (fr
Inventor
Walter Josef Martin
Johannes Josef Edmund Martin
Oliver Dr. Gohlke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Martin GmbH fuer Umwelt und Energietechnik
Original Assignee
Martin GmbH fuer Umwelt und Energietechnik
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Martin GmbH fuer Umwelt und Energietechnik filed Critical Martin GmbH fuer Umwelt und Energietechnik
Publication of EP0740110A2 publication Critical patent/EP0740110A2/fr
Publication of EP0740110A3 publication Critical patent/EP0740110A3/fr
Application granted granted Critical
Publication of EP0740110B1 publication Critical patent/EP0740110B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J1/00Removing ash, clinker, or slag from combustion chambers
    • F23J1/02Apparatus for removing ash, clinker, or slag from ash-pits, e.g. by employing trucks or conveyors, by employing suction devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2900/00Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
    • F23J2900/01021Removing ashes from the ash pit using reciprocating means, e.g. pushers

Definitions

  • the invention relates to a method and an apparatus for the treatment of solid combustion residues a waste incineration plant.
  • the combustion residues are known from DE 711 606 C. in one, a chute and a purification container with increasing discharge chute To promote detoxification and from there by means of a To push out the push rod.
  • EP-C-0 304 412 discloses combustion residues at least one basic and advantageous then also undergo an acid wash to not just the water-soluble components, but also the heavy metals loosely bound into the slag remove.
  • an acid wash to not just the water-soluble components, but also the heavy metals loosely bound into the slag remove.
  • the equipment provided for this downstream of the detoxifier is a relatively large apparatus Effort necessary, the equipment provided for this downstream of the detoxifier.
  • DE-C-524 207 discloses slag in one Damming the shaft and sprinkling it with water from above.
  • This shaft has an obliquely arranged, water-permeable Wall through which the fire water is drained can.
  • the aim of this invention is to reduce the slag as much as possible pre-dried to be removed from the shaft and onto a conveyor belt bring to dirt by dripping of the extinguishing water during the subsequent removal avoid. The result is that there is only so much water for sprinkling is fed as it is for quenching the slag is required.
  • GB-A-379 508 is a discharge device for Combustion residues are known in which the effluent Multiple wash gases through water bath and shower heads is subjected to, while the solid residues by means of a scraper conveyor from a shaft into a liquid container introduced and deleted there.
  • a Slag washing in a chute in which the Wash liquid trickles down from the top to the to be able to wash all slag in this chute is not provided there.
  • the object of the invention is to minimize the outlay on equipment to avoid and still treat the solid Allow combustion residues to be satisfactory Slag properties with regard to landfill ability and further processing lead to building materials.
  • heavy metals are achieved by that a chemical, preferably acid, e.g. Hydrochloric acid or phosphoric acid is used, whereby by the Accumulation or piling of solid combustion residues, especially beyond the liquid surface, especially good ones Requirements for washing with a chemical, especially acid, as created by the piling up of the Combustion residues have to travel long distances for the washing liquid through these combustion residues and thus large Residence times are available without additional containers or reactors a satisfactory washout of Heavy metals from solid combustion residues guarantee.
  • a chemical preferably acid, e.g. Hydrochloric acid or phosphoric acid
  • That kind of peeling the resulting sludge is particularly special advantageous if starting with washing liquid in countercurrent is worked by the expeller, since in the area of Liquid surface at the bottom of the chute the two Currents meet within the detoxifier so that on the one hand, the one already trickling down in the chute Washing liquid separated components and on the other hand those Components that can be removed from the combustion residues can be removed have accumulated again and by the end of the extension imported washing liquid are rinsed off.
  • Detoxifying water can be used in a further embodiment of the invention either one downstream of the combustion process Emission control device or a washing stage Neutralization of acidic, coming from the combustion process Exhaust gases are supplied.
  • this will be Detoxifying water evaporates in the exhaust gas stream, being acidic on the one hand Exhaust gases can be neutralized and on the other hand around the To expel water content. The dry part the other Filter dusts from the exhaust gas of the incinerator were deposited.
  • the second option is the use of the detoxifying water to neutralize acidic Exhaust gases in wet scrubbers.
  • the applied in the area of the upper end of the fall shaft amount of washing liquid is 0.2 per tonne of combustion residues to 20 m 3, while the fed in countercurrent at the Ausschubende of the ash amount of the washing liquid is 0.2 to 4 m 3 per ton of combustion residues.
  • the device for carrying out the method is marked through a detoxifier, in the area of the upper end of the chute a device for feeding Wash liquid are provided through which the wash liquid can be distributed over the entire cross section of the chute.
  • This Washing liquid can either be circulated Detoxifying water and / or a chemical, preferably one Acid.
  • the device for supplying washing liquid can in advantageously comprise spray nozzles in the side walls of the chute are provided. This configuration allows not just an even sprinkling of the combustion residues with washing liquid but also enables trouble-free Failure of solid combustion residues.
  • the device for supplying washing liquid can also include perforated tubes that cross the chute.
  • the Holes in the tubes act as spray nozzles. Since one with few tubes is a disability within the Falling way of the combustion residues practically not exist.
  • the detoxifier in a further embodiment of the invention one of its liquid level inside the chute or of the detoxifying outlet duct with an airtight one locked sedimentation tank is connected, so a safe and controllable removal of the in the detoxifier due to the Washing process of the detoxifying water including the suspended fine particles without the risk of that false air in the combustion chamber operated with negative pressure can penetrate.
  • FIG. 1 shows a known detoxifier, which has a total of 1 is designated, the one chute 2, an extension chute 3rd and one in the rear area 4 of the detoxifier driven swivel arm 5 includes articulated push rod 6, that falling from a grate, not shown Slag over the rising chute 3 into one Extends chute 7.
  • an inlet 8 fresh water supplied becomes a constant in the detoxifier 1 Liquid level 9 observed, which is set so high that the lower edge 2a of the chute 2 is immersed in the water.
  • This known detoxifier does indeed Slag washing by water, with waste water via a drain 10 is withdrawn at the rear end 4 of the detoxifier 1, however is a large proportion of the fine ingredients that are not under the Immerse the lower edge of the chute together with the Slag discharged into the discharge chute, which is the reason for the unsatisfactory properties of the slag already explained above represents.
  • the light essential components of the detoxifier 1 the same conditions before as in Fig. 1. For this reason, only the Deviations explained.
  • Embodiment is the regulation of the extension of the Push rod 6 set so that the slag 11 in Inlet chute 2 piled up.
  • the washing liquid that Water and / or a chemical, preferably an acid can, is supplied via a ring line 12, the spray nozzles 13 is connected, which in the side walls of the Inlet chute 2 are provided.
  • These spray nozzles 13 allow sprinkling of the piled up slag 11 within the chute 2 over the entire cross section the same.
  • the deduction of the one loaded with washout products Detoxifying water takes place via a discharge line 10, which runs from rear area 4 of the detoxifier 1 goes out.
  • Fig. 3 shows the same structure of the essential parts of the Detoxifies an amendment to the execution form Fig. 2.
  • a washing liquid, the Water or a chemical, especially a base or Phosphate compounds can be via the inlet 8 in Discharge shaft 7 of the deslagger 1 is supplied. That about the Discharge line 10 from the rear room 4 of the detoxifier drawn off detoxifying water loaded with washout products is by means of a pump 14 leading to the spray nozzles 13 Ring line 12 pumped via a line 12 a.
  • FIG Device for performing the method is fresh water or a chemical, preferably a base or a substance from the Group of the phosphates via the inlet 8 into the discharge shaft 7 introduced.
  • a chemical preferably an acid and / or in circulation guided detoxifying water.
  • the latter becomes a sedimentation basin 17 removed, which is sealed airtight and over a Extraction channel 18 is connected to the detoxifier 1, wherein the exhaust duct 18 from an area at the level of Liquid level 9 within the chute 2 or the underlying detoxifier goes out.
  • the one labeled 19 Return line leading to the spray nozzles 13 in the upper area of the The chute 2 leads is fed by a pump 20, which Detox water from the settling tank 17 at a near the there aspirating liquid level 17a, if possible suck in little solid particles.
  • a Return line 19 opening line 19a can the spray nozzles 13 a chemical in addition to the detoxifying water, preferably an acid can be supplied.
  • the chemical can but can also be supplied instead of the detoxifying water if this requires treatment of the combustion residues.
  • the amount withdrawn is regulated by the pump 23 in such a way that in the discharge channel 18 with the liquid level 9th is connected within the chute 2, such Pull-off speed is reached that only solid parts up to a grain size of 2 mm are subtracted.
  • the in Diameter parts above are with the rest coarse slag parts through the push rod 6 over the Extension chute 3 pushed out.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Processing Of Solid Wastes (AREA)

Claims (19)

  1. Procédé de traitement de résidus de combustion solides d'une installation d'incinération des déchets, lors duquel les substances combustibles sont brûlées sur une grille de calcination, sont ensuite transportées dans une installation de décrassage (1) remplie d'un liquide, de laquelle elles sont évacuées par l'intermédiaire d'une goulotte d'évacuation (3) inclinée vers le haut, les résidus de combustion étant accumulés dans le puits d'admission (2) de l'installation de décrassage (1) grâce à un réglage correspondant de la vitesse de décharge et étant lavés à l'aide du liquide de lavage, qui s'écoule du haut vers le bas à travers les résidus de combustion.
  2. Procédé selon la revendication 1, caractérisé en ce que les résidus de combustion solides sont accumulés dans le puits d'admission bien au-delà du niveau du liquide.
  3. Procédé selon la revendication 1 ou 2, caractérisé en ce que l'on utilise pour le lavage un produit chimique, de préférence un acide.
  4. Procédé selon l'une quelconque des revendications 1 à 3, caractérisé en ce que l'on alimente, à l'extrémité d'évacuation de l'installation de décrassage, à contre-courant par rapport au liquide de lavage s'écoulant d'en haut à travers les résidus de combustion, de l'eau fraíche ou un produit chimique, de préférence une base ou un composé phosphaté.
  5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé en ce que l'eau de l'installation de décrassage se trouvant dans celle-ci, chargée de produits de lavage, est retirée à la surface du liquide ajustée à l'extrémité inférieure du puits d'admission au sein de la zone limitée par le puits d'admission ou hors de l'installation de décrassage.
  6. Procédé selon la revendication 5, caractérisé par une vitesse de retrait, rendant possible un entraínement de particules solides ayant un diamètre de grains allant jusqu'à 2 mm.
  7. Procédé selon la revendication 5, caractérisé en ce que l'eau de l'installation de décrassage chargée de produits de lavage est conduite, après son retrait de l'installation de décrassage, vers un équipement de nettoyage des gaz de rejet intercalé à la suite du processus de combustion.
  8. Procédé selon la revendication 5, caractérisé en ce que l'eau de l'installation de décrassage chargée de produits de lavage est conduite, après son retrait de l'installation de décrassage, vers une étape de lavage en vue de la neutralisation des gaz de rejet acides provenant du processus de combustion.
  9. Procédé selon l'une quelconque des revendications 5 à 8, caractérisé en ce qu'au moins une partie de l'eau de l'installation de décrassage retirée est reconduite, en vue du lavage des résidus de combustion, en circuit fermé dans le puits d'admission.
  10. Procédé selon la revendication 5, caractérisé en ce que l'on ajoute par mélange, à l'eau de l'installation de décrassage retirée à l'extrémité inférieure du puits d'admission ou hors de la zone de l'installation de décrassage, les résidus de combustion qui tombent à travers la grille de calcination.
  11. Procédé selon l'une quelconque des revendications 1 à 10, caractérisé en ce que la quantité de liquide de lavage conduite dans la zone de l'extrémité supérieure du puits d'admission est de 0,2 à 20 m3 par tonne de résidus de combustion.
  12. Procédé selon l'une quelconque des revendications 1 à 7, caractérisé en ce que la quantité de liquide de lavage conduite à contre-courant à l'extrémité d'évacuation de l'installation de décrassage est de 0,2 à 4 m3 par tonne de résidus de combustion.
  13. Dispositif d'exécution du procédé selon l'une quelconque des revendications 1 à 12, caractérisé par une installation de décrassage (1), pour laquelle l'on prévoit dans la zone de l'extrémité supérieure du puits d'admission (2), un dispositif (13) pour l'alimentation du liquide de lavage, grâce auquel l'on peut répartir le liquide de lavage sur l'ensemble de la section transversale du puits d'admission (2).
  14. Dispositif selon la revendication 13, caractérisé en ce que le dispositif pour l'alimentation de liquide de lavage comprend des buses de pulvérisation (13), qui sont prévues dans les parois latérales du puits d'admission (2).
  15. Dispositif selon la revendication 13, caractérisé en ce que le dispositif pour l'alimentation de liquide de lavage comprend des tubes perforés, qui traversent le puits d'admission (2).
  16. Dispositif selon l'une quelconque des revendications 13 à 15, en particulier en vue de l'exécution du procédé selon la revendication 3, caractérisé en ce que les pièces de l'installation de décrassage (1), particulièrement sollicitées du point de vue mécanique par le poussoir d'évacuation (6), se composent d'un matériau résistant à l'abrasion, sans être toutefois résistant aux acides, et en ce que les pièces moins sollicitées du point de vue mécanique, en particulier les parois du puits d'admission (2), se composent d'un matériau résistant aux acides.
  17. Dispositif selon l'une quelconque des revendications 13 à 16, caractérisé en ce que l'on prévoit, sur le côté d'évacuation (7) de l'installation de décrassage (1), des buses de pulvérisation pour l'eau fraíche ou pour le liquide de lavage sous la forme d'un produit chimique, de préférence une base ou des composés phosphatés, lesquelles buses permettent une répartition uniforme du liquide sur les résidus de combustion qui se trouvent sur la goulotte d'évacuation.
  18. Dispositif selon l'une quelconque des revendications 13 à 17, caractérisé en ce que l'installation, de décrassage (1) est reliée à un bassin de sédimentation (17), fermé de manière étanche à l'air, par l'intermédiaire d'un canal d'évacuation (18) issu de son niveau de liquide (9) au sein du puits d'admission (2) ou de l'installation de décrassage.
  19. Dispositif selon la revendication 18, caractérisé en ce que le bassin de sédimentation (17) est relié, par l'intermédiaire d'écluses à dépression, aux trémies de collecte pour les résidus de combustion qui passent à travers la grille de calcination.
EP96100180A 1995-03-09 1996-01-08 Procédé et appareil pour le traitement de résidus solides de combustion d'un incinérateur Expired - Lifetime EP0740110B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19508488A DE19508488C3 (de) 1995-03-09 1995-03-09 Verfahren und Vorrichtung zum Erzeugen von deponiefähigen oder weiterverarbeitbaren Verbrennungsrückständen aus einer Abfallverbrennungsanlage
DE19508488 1995-03-09

Publications (3)

Publication Number Publication Date
EP0740110A2 EP0740110A2 (fr) 1996-10-30
EP0740110A3 EP0740110A3 (fr) 1998-03-11
EP0740110B1 true EP0740110B1 (fr) 2001-06-27

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ID=7756206

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EP96100180A Expired - Lifetime EP0740110B1 (fr) 1995-03-09 1996-01-08 Procédé et appareil pour le traitement de résidus solides de combustion d'un incinérateur

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Country Link
US (1) US5711233A (fr)
EP (1) EP0740110B1 (fr)
JP (1) JP2931551B2 (fr)
AT (1) ATE202627T1 (fr)
CA (1) CA2171245C (fr)
DE (2) DE19508488C3 (fr)
DK (1) DK0740110T3 (fr)
ES (1) ES2160183T3 (fr)
RU (1) RU2103605C1 (fr)
SG (1) SG42351A1 (fr)
TW (1) TW289790B (fr)

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DE102007057106A1 (de) * 2007-11-26 2009-05-28 Hanseatisches Schlackenkontor Gmbh Verfahren zur Herstellung eines verdichtungsfähigen Schlackegranulats
US9557115B2 (en) 2010-10-28 2017-01-31 General Electric Technology Gmbh Orifice plate for controlling solids flow, methods of use thereof and articles comprising the same
US9617087B2 (en) * 2010-10-28 2017-04-11 General Electric Technology Gmbh Control valve and control valve system for controlling solids flow, methods of manufacture thereof and articles comprising the same
US9885478B1 (en) 2011-02-28 2018-02-06 Recycling Solutions Technology, Llc Process for generating combustible gas from organic feedstock and reactors therefor
DE102011013034A1 (de) * 2011-03-04 2012-09-06 Alexandra Beckmann Gewinnung von verwertbaren Stoffen aus Müllverbrennungsasche
DE102011013033A1 (de) * 2011-03-04 2012-09-06 Alexandra Beckmann Aufbereiten von Müllverbrennungsasche
EP3022489B1 (fr) * 2013-07-17 2017-09-06 Georg Schons Procédé permettant de traiter une scorie dans des installations d'incinération de déchets et installation d'incinération de déchets
JP6417617B1 (ja) * 2018-02-09 2018-11-07 三菱重工環境・化学エンジニアリング株式会社 灰押出装置
JP6752988B1 (ja) * 2020-04-27 2020-09-09 三菱重工環境・化学エンジニアリング株式会社 灰押出装置及び灰押出装置の改造方法

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Also Published As

Publication number Publication date
EP0740110A3 (fr) 1998-03-11
TW289790B (fr) 1996-11-01
DE59607150D1 (de) 2001-08-02
DE19508488C3 (de) 2001-03-15
JPH08261438A (ja) 1996-10-11
DE19508488C2 (de) 1997-05-07
SG42351A1 (en) 1997-08-15
CA2171245C (fr) 1999-12-21
JP2931551B2 (ja) 1999-08-09
RU2103605C1 (ru) 1998-01-27
ATE202627T1 (de) 2001-07-15
DE19508488A1 (de) 1996-09-19
EP0740110A2 (fr) 1996-10-30
US5711233A (en) 1998-01-27
CA2171245A1 (fr) 1996-09-10
ES2160183T3 (es) 2001-11-01
DK0740110T3 (da) 2001-10-15

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