EP0596968A1 - Produit de traitement de linge pour seche-linge - Google Patents

Produit de traitement de linge pour seche-linge

Info

Publication number
EP0596968A1
EP0596968A1 EP92916357A EP92916357A EP0596968A1 EP 0596968 A1 EP0596968 A1 EP 0596968A1 EP 92916357 A EP92916357 A EP 92916357A EP 92916357 A EP92916357 A EP 92916357A EP 0596968 A1 EP0596968 A1 EP 0596968A1
Authority
EP
European Patent Office
Prior art keywords
component
fatty
composition according
mixtures
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92916357A
Other languages
German (de)
English (en)
Inventor
Rolf Puchta
Peter Sandkühler
Jutta Schreiber
Theodor Völkel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0596968A1 publication Critical patent/EP0596968A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243—Mono-, di-, or triglycerides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2352—Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric

Definitions

  • the present invention relates to an agent for treating washed laundry in a tumble dryer consisting of a flexible surface that is loaded with an active substance mixture for laundry treatment.
  • Treating washed laundry in this way generally aims to give the laundry a pleasantly soft and full feel, as well as anti-electrostatic properties and a good fragrance.
  • the treatment of the laundry in the rinsing bath relied on the use of active substances which are transferred as completely as possible to the textiles to be treated in an aqueous liquor, the fact that the treatment process was relocated to the tumble dryer made it possible to also use such active substances which were difficult or impossible to use in an aqueous liquor.
  • DE-A 1967470 the disadvantages described are to be avoided by using substrates with a medium adsorption capacity as carriers for the quaternary ammonium compounds. It was later found, however, that under certain conditions it is also possible to use substrates with a low adsorption capacity, which have the advantage of the high release of active ingredient, without the formation of stains.
  • DE-A 3003249 relates to agents for treating washed laundry in a laundry dryer, the carriers of which for the softening active ingredients comprise a substrate with a low adsorption capacity.
  • Another object is to provide a textile-softening active substance or mixture of active substances which, during production after application to the flexible fabric, solidifies quickly, that is to say at a relatively high temperature, to a dry-feeling active substance layer and the textiles treated therewith have good antielectrostatic properties Gives properties.
  • the present invention therefore relates to agents for treating washed laundry in a tumble dryer, consisting of a flexible sheet loaded with active ingredient mixtures for laundry treatment, the active ingredient mixtures containing a fat component which are characterized in that the mono-, di Fat component a) in a mixture with b) fatty alcohol alkoxylates and / or fatty acid esters of monohydric alcohols is present - or trifatty acid glycerides and / or fatty acids and / or fatty alcohols.
  • the constituents of the fat component a) are known per se as softening active ingredients, but these alone or in combination do not meet the requirements which are described in more detail in the description of the object of the present invention. They are either difficult to process because they solidify too slowly or too quickly when they are applied to the flexible surface; or they do not impart sufficient softness or sufficient anti-electrostatic properties to the textiles treated with them; or the flexible sheets coated with it feel uncomfortable, which prevents the consumer from using them; or the drug delivery rate is too low.
  • the fat component a) with component b), the monovalent of fatty alcohol alkoxylates and / or Fettklaestern alcohols is, in such a way that the active ingredient mixtures formed have a crystallization onset is r at a temperature of 40 ° C or higher.
  • the start of crystallization in the sense of this patent application is determined by DSC measurement using a device from Mettler, type FP 84.
  • the active substance mixture to be tested is heated at a heating rate of 2 ° C. per minute until the melting end temperature is reached.
  • the Temperature at which crystallization begins the heat of crystallization given off.
  • the temperature at which the heat of crystallization begins to be given is called the start of crystallization below.
  • Mixtures of active ingredients from components a) and b) which are suitable for the treatment agents according to the invention have an onset of crystallization at a temperature of 40 ° C. or higher.
  • the active ingredient mixtures contain a fat component a) which contains mono- and di-fatty acid glyceride, preferably mono-fatty acid glycerides.
  • the fatty acid residue of these mono- and diglycerides is derived from fatty acids which can be straight-chain or branched, saturated or unsaturated and contain 10 to 24 carbon atoms.
  • a typical example of suitable glyceride mixtures is, for example, a mixture consisting of mono- and di-fatty acid glyceride which predominantly contains mono-fatty acid glyceride and whose fatty acid residue is derived from stearic acid.
  • a glycerol mono-di-palmitate / stearate is also suitable, the proportion of monoglyceride being 40 to 60%.
  • a preferred embodiment of the agents according to the invention contains in fatty component a) fatty acids with a melting point in the range from 40 to 80, preferably in the range from 45 to 65 ° C.
  • the fatty acids can be of natural and synthetic origin and are generally straight-chain and in particular saturated. Natural fatty acids are derived from triglycerides, for example from coconut oil, palm kernel oil, olive oil or also from animal fats such as beef tallow, fish oil or lard. Depending on their origin, the fatty acids derived therefrom are mixtures of different fatty acids and are also preferred if, after hydrogenation if necessary, they have a melting point in the range from 40 to 80, in particular in the range from 45 to 65 ° C.
  • the fat component a) can also contain fatty alcohols.
  • Fatty alcohols preferred for the agents according to the invention have 10 to 22 carbon atoms in the molecule.
  • the fatty alcohol alkoxylates suitable for component b) are generally based on the fatty alcohols, as are also suitable for the fatty component a). They contain 1 to 15 moles of ethylene oxide and / or 1 to 15 moles of propylene oxide per mole of fatty alcohol. Fatty alcohol alkoxylates in which ethylene oxide and propylene oxide are simultaneously attached to the fatty alcohol are preferred. In particular, suitable fatty alcohol alkoxylates contain 2 to 8 moles of ethylene oxide and / or propylene oxide per mole of fatty alcohol.
  • component b) may contain fatty acid esters of monohydric alcohols.
  • Preferred fatty acid esters of monohydric alcohols contain a total of 15 to 44 carbon atoms.
  • Monovalent "alcohol component in particular methyl alcohol, ethyl alcohol are n-propyl and iso-propyl alcohol in question.
  • Fettklarekompo ⁇ the appropriate fatty acid ester component of monovalent alcohols, the same applies as already explained above for the fatty acids.
  • fatty acid ester of monohydric alcohols are within the scope of The present invention is also understood to mean mixtures of fatty acid esters of various compositions, for example carnauba wax obtainable from the leaves of the Brazilian fan palm Copernica prunivera, candeliol wax obtained from the leaves of Euphorbiaceae, jojoba oil and natural or synthetic beeswax ⁇ a mixture in question, the 40 parts by weight of a fatty acid onoglyceride, the acid component of which is a 3: 1 mixture of hydroxystearic acid and hardened castor oil, and 35 parts by weight of palmitic acid, 20 Parts by weight of micro wax, 10 parts by weight of hydroxystearic acid and other constituents in minor amounts.
  • Such natural ester mixtures are also counted among the fatty acid esters of monohydric alcohols in the context of the present invention.
  • Mixtures have the preferred start of crystallization at a temperature of 40 ° C or higher, the active ingredient mixtures consist of component a) and component b) in a weight ratio of 3: 1 to 1: 3, preferably in a weight ratio of 2: 1 to 1: 2.
  • Agents according to the invention in which the active compound mixtures contain component a) and component b) in the weight ratio mentioned are preferred moves.
  • the addition of an effective amount of glycerol which generally makes up 1 to 15% by weight, based on the active ingredient mixtures, is particularly suitable for this purpose.
  • the flexible sheet materials used as carriers for the active substance mixture may contain an amount of the active substance mixtures which is sufficient for a single application or for repeated use, it is preferred that the agents have an amount which is sufficient for a single application contain components a) + b). This is preferably an amount of 1 to 5 g, which is applied to the flexible fabric on one or both sides.
  • the active ingredient mixtures are liquefied by heating.
  • Particularly suitable mixtures of active ingredients have a viscosity of 5 to 100 mPas at 60 ° C .; they are therefore preferred.
  • the flash point of the active substance mixtures is significantly higher than that for the known compositions for the treatment of washed laundry in general Dryer mixtures used active ingredients.
  • Agents according to the invention the active ingredient mixtures of which have a flash point of more than 55 ° C., preferably more than 100 ° C., are therefore particularly preferred.
  • Such a high flash point has a particularly favorable effect on the production of the agents according to the invention, in which the active substance mixtures are applied to the flexible fabric at elevated temperature.
  • the flexible surface structure of the agents according to the invention can be a fibrous surface structure and accordingly a woven, a knitted one textile material or a non-woven fabric.
  • Foam or sponge-like materials of natural or synthetic origin such as foamed synthetic polymers, which are preferably in sheet form, are also suitable as flexible fabrics.
  • the textile fabrics generally have a lower adsorption capacity than the foam or sponge-like materials. The lower adsorption capacity is usually associated with a high rate of release of the active ingredient mixtures, whereas the foam or sponge-like materials can absorb more of the active ingredient mixture, but generally release it less completely when used in the tumble dryer. Above all, the flexible textile fabrics, and in particular the non-woven fabrics, have proven successful.
  • a carrier for the active ingredient mixtures are flexible fabrics which are a nonwoven made of synthetic and natural fiber materials.
  • compositions according to the invention do not contain any salt-like constituents, such as quaternary ammonium salts, in their active ingredient mixtures
  • the textiles treated with the compositions according to the invention have surprisingly good antielectrostatic properties after treatment in a tumble dryer, which takes place at temperatures of about 50 to 80 ° C. ⁇ shafts.
  • the agents according to the invention convince through the sum of the desirable properties present. They are easy to manufacture, do not feel uncomfortable after manufacture, have the property of releasing the active substance mixtures almost completely when used in the tumble dryer and transferring them to the textiles to be treated, and they give the textiles to be treated a pleasantly soft and full grip and excellent anti-electrostatic properties.
  • the active ingredient mixtures are also free of quaternary ammonium compounds, the environmental impact from the active ingredients which enter the sewer system with the washing water of the laundry following treatment in the tumble dryer is extremely low.
  • Another advantage of the agents according to the invention is the fact that the in the components present in the active ingredient mixture are produced from natural and renewable raw materials.
  • the active substance mixtures can additionally contain customary auxiliaries and additives in agents for treating washed laundry in a tumble dryer. These are, for example, fragrances, dyes, heavy metal complexing agents, clay materials or finely divided silica.
  • the start of crystallization for mixture A was 42 ° C, that for mixture B at 46 ° C.
  • DMDMAC distearyldimethylammonium chloride
  • the flash point of mixture A was 166 ° C, for mixture B 156 ° C, whereas for the DSDMAC mixture it was 28 ° C. Accordingly, the DSDMAC mixture is to be treated as dangerous goods, but the active substance mixtures A and B of the agents according to the invention are not. Textiles treated with this had an approximately equally good grip in all cases.
  • the anti-electrostatic properties measured as the half-life of the dissipation of an applied electrical charge, were 7.6 seconds (A) and 10.6 seconds (B) and 36 seconds DSDMAC.
  • the toxicological, ecological and ecotoxicological behavior of the active substance mixtures A and B was better than that of DSDMAC in every respect.

Abstract

Un produit contient sur un support plat flexible une combinaison de glycérides d'acides gras, d'acides gras et/ou d'alcools gras d'une part et d'alcoxylates d'alcools gras et/ou d'esters d'acides gras d'alcools monovalents d'autre part, servant de mélange adoucissant de matières textiles.
EP92916357A 1991-08-03 1992-07-27 Produit de traitement de linge pour seche-linge Withdrawn EP0596968A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4125847 1991-08-03
DE4125847A DE4125847A1 (de) 1991-08-03 1991-08-03 Mittel zum behandeln gewaschener waesche in einem waeschetrockner
PCT/EP1992/001701 WO1993003132A1 (fr) 1991-08-03 1992-07-27 Produit de traitement de linge pour seche-linge

Publications (1)

Publication Number Publication Date
EP0596968A1 true EP0596968A1 (fr) 1994-05-18

Family

ID=6437696

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92916357A Withdrawn EP0596968A1 (fr) 1991-08-03 1992-07-27 Produit de traitement de linge pour seche-linge

Country Status (4)

Country Link
US (1) US5399271A (fr)
EP (1) EP0596968A1 (fr)
DE (1) DE4125847A1 (fr)
WO (1) WO1993003132A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4224067A1 (de) * 1992-07-21 1994-01-27 Henkel Kgaa Tumblerhilfsmittel
WO1997026316A1 (fr) * 1996-01-19 1997-07-24 Unilever Plc Systemes non cationiques destines a des feuilles pour seche-linge
FR2745013B1 (fr) * 1996-02-19 1998-04-03 James River Composition pour une lotion adoucissante, utilisation de la lotion pour le traitement de fibres et produit papetier absorbant ainsi traite
EP0831147A3 (fr) * 1996-09-19 1998-12-16 Unilever Plc Systèmes non-cationiques pour feuilles pour sèche-linge
US5919750A (en) * 1997-07-24 1999-07-06 Akzo Nobel Nv Fabric softener composition
EP1930500A1 (fr) * 2006-12-08 2008-06-11 Cognis IP Management GmbH Emulsions d'avivage pour du textile et du papier

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3442692A (en) * 1965-08-13 1969-05-06 Conrad J Gaiser Method of conditioning fabrics
US3686025A (en) * 1968-12-30 1972-08-22 Procter & Gamble Textile softening agents impregnated into absorbent materials
US4000340A (en) * 1973-10-29 1976-12-28 The Procter & Gamble Company Clothes dryer additive containing crisping agents
US4209549A (en) * 1974-02-08 1980-06-24 The Procter & Gamble Company Process for treating fabrics with fabric treatment compositions
US4022938A (en) * 1974-04-16 1977-05-10 The Procter & Gamble Company Fabric treatment compositions
AU510901B2 (en) * 1976-01-09 1980-07-17 Procter & Gamble Company, The Fabric softening method and device
DE3003249A1 (de) * 1980-01-30 1981-08-06 Henkel KGaA, 4000 Düsseldorf Mittel zum nachbehandeln gewaschener waesche in einem waeschetrockner
ZA914152B (en) * 1990-06-01 1993-01-27 Unilever Plc Liquid fabric conditioner and dryer sheet fabric conditioner containing fabric softener,aminosilicone and bronsted acid compatibiliser
US5145595A (en) * 1990-10-03 1992-09-08 Vista Chemical Company Anti-static fabric softening article for use in an automatic clothes dryer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9303132A1 *

Also Published As

Publication number Publication date
DE4125847A1 (de) 1993-02-04
WO1993003132A1 (fr) 1993-02-18
US5399271A (en) 1995-03-21

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