EP0575794B1 - Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé - Google Patents
Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé Download PDFInfo
- Publication number
- EP0575794B1 EP0575794B1 EP93108989A EP93108989A EP0575794B1 EP 0575794 B1 EP0575794 B1 EP 0575794B1 EP 93108989 A EP93108989 A EP 93108989A EP 93108989 A EP93108989 A EP 93108989A EP 0575794 B1 EP0575794 B1 EP 0575794B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- mixtures
- isopropanol
- partially fluorinated
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5018—Halogenated solvents
Definitions
- EP-A 454 490 describes ternary mixtures Isopropanol, water and a perfluorocarbon with one Boiling point of 30 to 70 ° C known as Serve cleaning solutions.
- Preferred compounds of the above formula are in which x is 1 to 3, w is 4 to 6 and y is 7 to 13.
- Particularly preferred compounds are 3,4-dihydroperfluoro (2-methylpentane), 3,4,4-trihydroperfluoro (2-methylpentane), Mixtures of these two compounds by weight ratio from about 95: 5 to about 5: 95, preferably 90: 10 to 10:90, 2,2,2-trifluoroethyl-1,1,2,2-tetrafluoroethyl ether and especially 1H-perfluorohexane.
- a mixture of 6.76 parts by weight of isopropanol is added and 1 part by weight of water 20% by weight, based on this Mixture, to one of the compounds mentioned, so obtained a flash point (according to DIN 51 758) of over 50 ° C.
- a flash point (according to DIN 51 758) of over 50 ° C.
- 1H-perfluorohexane already causes an addition of 10% by weight a flash point of 50 to 52 ° C and with a mixture about 90% by weight 3,4-dihydro-perfluoro (2-methyl-pentane) and 10 wt .-% 3,4,4-trihydro-perfluoro (2-methyl-pentane) a Flash point above 55 ° C.
- the invention therefore relates in particular to mixtures of predominantly isopropanol and smaller, approximately equal amounts Water and fluorinated compound.
- Preferred mixtures contain 70 to 80% by weight isopropanol, 10 to 12% by weight water and 9 to 18% by weight fluorinated compound.
- a preferred mixture consists of, for example 72.6% by weight of isopropanol, 10.7% by weight of water and 16.7% by weight Trifluoroethyl tetrafluoroethyl ether.
- Particularly preferred mixtures consist of 79.2% by weight Isopropanol, 11.7% by weight water and 9.1% by weight fluorinated Hydrocarbon.
- the fluorinated hydrocarbons are known Links. You can, for example, by hydrogenation of the corresponding olefins [V.F. Snegirev et al., Izv. Akad. Nauk SSSR, Ser. Khim. (12), 2775 to 2781 (1983)].
- the fluorinated ether is obtained one, for example, by the addition of alcohols fluorinated olefins (Houben-Weyl, 'Methods of Organic Chemie ', 4th edition, volume V / 3 (1962), halogen compounds, Page 280).
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Claims (9)
- Utilisation, comme constituants d'un mélange à base d'isopropanol et d'eau, d'hydrocarbures ou d'éthers partiellement fluorés de formule CwHxFyOz, dans laquelle x < y, la somme de x + y = 2w +2 et z est égal à zéro ou 1, et qui présentent un point d'ébullition dans la gamme de 40 à 100°C.
- Mélanges à base principalement d'isopropanol et d'une quantité mineure d'eau et d'un ou de plusieurs hydrocarbures ou éthers partiellement fluorés de formule CwHxFyOz, dans laquelle x < y, la somme de x + y = 2w +2 et z est égal à zéro ou 1, et qui présentent un point d'ébullition dans la gamme de 40 à 100°C.
- Mélanges à base de 70 à 80 % en poids d'isopropanol, de 10 à 12 % en poids d'eau et de 9 à 18 % en poids d'un ou de plusieurs hydrocarbures ou éthers partiellement fluorés de formule CwHxFyOz, dans laquelle x < y, la somme de x + y = 2w +2 et z est égal à zéro ou 1, et qui présentent un point d'ébullition dans la gamme de 40 à 100°C.
- Mélanges selon la revendication 2 ou 3, caractérisés en ce que, dans la formule CwHxFyOz, x signifie 1 à 3.
- Mélanges selon les revendications 2 à 4, caractérisés en ce que, dans la formule CwHxFyOz, w signifie 4 à 6.
- Mélanges selon les revendications 2 à 5, caractérisés en ce que, dans la formule CwHxFyOz, y signifie 7 à 13.
- Mélanges selon les revendications 2 à 6, caractérisés en ce que les hydrocarbures ou éthers partiellement fluorés sont choisis parmi le 3,4-dihydro-perfluor-(2-méthyl-pentane), le 3,4,4-trihydro-perfluor-(2-méthyl-pentane), le 2,2,2-trifluoréthyl-1,1,2,2-tétrafluoroéthyl-éther, le 1H-perfluorhexane et leurs mélanges.
- Mélanges selon la revendication 7, caractérisés en ce que l'hydrocarbure ou l'éther partiellement fluoré est le 1H-perfluorhexane.
- Mélanges selon la revendication 7, caractérisés en ce que l'hydrocarbure ou l'éther partiellement fluoré est le 2,2,2-trifluoréthyl-1,1,2,2-tétrafluoroéthyl-éther.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4218966 | 1992-06-10 | ||
DE4218966A DE4218966A1 (de) | 1992-06-10 | 1992-06-10 | Isopropanolhaltige Reinigungslösungen mit erhöhtem Flammpunkt |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0575794A1 EP0575794A1 (fr) | 1993-12-29 |
EP0575794B1 true EP0575794B1 (fr) | 1998-10-14 |
Family
ID=6460703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93108989A Expired - Lifetime EP0575794B1 (fr) | 1992-06-10 | 1993-06-04 | Solutions de nettoyage contenant de l'isopropanol à point d'inflammation élevé |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0575794B1 (fr) |
JP (1) | JPH0657296A (fr) |
AT (1) | ATE172239T1 (fr) |
CA (1) | CA2098057A1 (fr) |
DE (2) | DE4218966A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3123695B2 (ja) * | 1993-01-22 | 2001-01-15 | キヤノン株式会社 | 混合溶剤組成物、及びそれを利用する洗浄方法と洗浄処理装置 |
IT1271075B (it) | 1994-11-21 | 1997-05-26 | Ausimont Spa | Miscele ternarie di solventi, e loro uso per la rimozione di sostanze oleose |
US6008179A (en) | 1995-05-16 | 1999-12-28 | 3M Innovative Properties Company | Azeotrope-like compositions and their use |
DE69637691D1 (de) | 1995-05-16 | 2008-11-06 | Minnesota Mining & Mfg | Azeotropähnliche zusammensetzungen und ihre verwendung |
US5827446A (en) * | 1996-01-31 | 1998-10-27 | E. I. Du Pont De Nemours And Company | Nonafluoromethoxybutane compositions |
US6030934A (en) * | 1997-02-19 | 2000-02-29 | 3M Innovative Properties Company | Azeotropic compositions of methoxy-perfluoropropane and their use |
US6159917A (en) * | 1998-12-16 | 2000-12-12 | 3M Innovative Properties Company | Dry cleaning compositions containing hydrofluoroether |
WO2004005445A1 (fr) | 2002-07-03 | 2004-01-15 | Asahi Glass Company, Limited | Composition de solvant |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2008882A1 (fr) * | 1989-02-01 | 1990-08-01 | Takamasa Tsumoto | Agent et methode de lavage et processus de fabrication de dispositifs a semiconducteur a circuits integres utilisant cet agent et cette methode |
GB9009504D0 (en) * | 1990-04-27 | 1990-06-20 | Isc Chemicals Ltd | Reduced flammability mixture based on isopropanol |
-
1992
- 1992-06-10 DE DE4218966A patent/DE4218966A1/de not_active Withdrawn
-
1993
- 1993-06-04 AT AT93108989T patent/ATE172239T1/de not_active IP Right Cessation
- 1993-06-04 EP EP93108989A patent/EP0575794B1/fr not_active Expired - Lifetime
- 1993-06-04 DE DE59309054T patent/DE59309054D1/de not_active Expired - Fee Related
- 1993-06-08 JP JP5137943A patent/JPH0657296A/ja not_active Withdrawn
- 1993-06-09 CA CA002098057A patent/CA2098057A1/fr not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
DE4218966A1 (de) | 1993-12-16 |
CA2098057A1 (fr) | 1993-12-11 |
ATE172239T1 (de) | 1998-10-15 |
DE59309054D1 (de) | 1998-11-19 |
EP0575794A1 (fr) | 1993-12-29 |
JPH0657296A (ja) | 1994-03-01 |
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