EP0538714B2 - Biologisch abbaubare Faserpräparationsmittel - Google Patents
Biologisch abbaubare Faserpräparationsmittel Download PDFInfo
- Publication number
- EP0538714B2 EP0538714B2 EP92117479A EP92117479A EP0538714B2 EP 0538714 B2 EP0538714 B2 EP 0538714B2 EP 92117479 A EP92117479 A EP 92117479A EP 92117479 A EP92117479 A EP 92117479A EP 0538714 B2 EP0538714 B2 EP 0538714B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- compounds
- agents
- fiber preparation
- formula
- treating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 title claims description 24
- 239000003795 chemical substances by application Substances 0.000 title description 19
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 description 18
- 238000012360 testing method Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000008030 elimination Effects 0.000 description 3
- 238000003379 elimination reaction Methods 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 231100000209 biodegradability test Toxicity 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- -1 ester salts Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 125000005483 neopentyl alcohol group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000012207 thread-locking agent Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
- Y10T428/2907—Staple length fiber with coating or impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
Definitions
- polyoxyalkylene glycols which are used in a heat treatment of prepared synthetic fibers, such as texturing, evaporate without residue, so that when used in Fiber preparation agents, the cleaning intervals of the texturing devices used are relatively long apart in time lie.
- end-capped polyoxyalkylene glycols which have good properties, are known from EP-B-162 530 possess as a fiber preparation agent and also due to low residue formation on the fiber after heating processes.
- biodegradable is to be understood to mean that the constituents of fiber preparation agents, such as lubricants, surfactants, thread-closing agents or even antistatic agents, are completely or at least 70% by weight in a biological way, for example by the enzymes or contained in the sewage sludge of a sewage treatment plant Bacteria are broken down.
- the invention relates to the use of a fiber preparation agent, characterized by a content of compounds of the general formula HO (CH 2 CH 2 O) x -RO- (CH 2 CH 2 O) y H wherein R represents a 1-methylpropylene radical, 2-methylpropylene radical or a 1-methylethylene radical and the sum of x and y is 10 to 20, where x and y are different from zero, for fibers made of polyester, polyamides, polyacrylonitrile, polyolefins or the Copolymers of the aforementioned compounds.
- the compounds of the formula I are well suited as fiber preparation agents.
- the compounds of formula I are generally water-soluble or water-dispersible. They can be used as fiber preparation agents either alone or in a mixture with one another or with other fiber preparation agents known per se, such as surfactants, antistatic agents, such as P 2 O 5 ester salts, lubricants, such as ester oils or thread-locking agents, such as ethoxylated castor oils, which must also be biodegradable .
- the fiber preparation agents can be applied from an aqueous solution, dispersion or emulsion, optionally with the use of suitable solvents or dispersing agents. Since most of the compounds of formula I are readily water-soluble, no additional emulsifiers are required when applied to the fiber, in contrast to mineral or ester oils.
- the application is carried out according to the usual methods, for example by splashing or dipping. Spraying, padding or gear pumps.
- polyester fibers e.g. Polyester fibers, Polyamides, polyacrylonitrile.
- Polyolefins or the copolymers of the above compounds e.g. Polyester fibers, Polyamides, polyacrylonitrile.
- Polyolefins or the copolymers of the above compounds e.g. Polyester fibers, Polyamides, polyacrylonitrile.
- Polyolefins or the copolymers of the above compounds e.g. Polyester fibers, Polyamides, polyacrylonitrile.
- the amount of glycol and alkaline catalyst are in a reaction vessel redesigned with a stirrer submitted. After purging with nitrogen to remove the oxygen, the mixture is heated to and at 120 to 125 ° C The temperature was kept under stirring under a water jet vacuum for 2 hours. After removing the water jet vacuum is heated to 130 to 140 ° C with stirring, whereupon the required at this temperature in a time of about 3 h Amount of gaseous ethylene oxide is metered in. The end of the ethylene oxide addition will decrease and essentially constant pressure recognizable. To clean the reaction product from any present volatile components this is for half an hour with stirring at about 80 ° C and a vacuum of 2 kPa held.
- Table I summarizes the glycols and alkaline catalysts presented and the amount of ethylene oxide metered in at the reaction temperature and pressure.
- Biodegradability is determined using the OECD 303 A test.
- the biological elimination [% DOC] is determined depending on the time [d] (day, English: day). Table III shows the maximum biological elimination after 28 days.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
- Biological Depolymerization Polymers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4134610 | 1991-10-19 | ||
DE4134610 | 1991-10-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0538714A1 EP0538714A1 (de) | 1993-04-28 |
EP0538714B1 EP0538714B1 (de) | 1997-03-12 |
EP0538714B2 true EP0538714B2 (de) | 1999-09-01 |
Family
ID=6443017
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92117479A Expired - Lifetime EP0538714B2 (de) | 1991-10-19 | 1992-10-13 | Biologisch abbaubare Faserpräparationsmittel |
Country Status (12)
Country | Link |
---|---|
US (1) | US5266221A (ja) |
EP (1) | EP0538714B2 (ja) |
JP (1) | JP3258724B2 (ja) |
KR (1) | KR930008233A (ja) |
AR (1) | AR247432A1 (ja) |
AT (1) | ATE150108T1 (ja) |
BR (1) | BR9204029A (ja) |
CA (1) | CA2080741A1 (ja) |
DE (1) | DE59208170D1 (ja) |
ES (1) | ES2100997T5 (ja) |
MX (1) | MX9205982A (ja) |
TR (1) | TR26747A (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW225562B (ja) * | 1991-10-15 | 1994-06-21 | Hoechst Ag | |
DE4304354A1 (de) * | 1993-02-13 | 1994-08-18 | Hoechst Ag | Esterverbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE4410708C1 (de) * | 1994-03-28 | 1995-07-13 | Hoechst Ag | Präparationshaltige Aramidfasern und deren Verwendung |
JP3045238B1 (ja) * | 1999-03-24 | 2000-05-29 | 日華化学株式会社 | 繊維用処理油剤及び繊維の油剤処理方法 |
KR20160108856A (ko) | 2015-03-09 | 2016-09-21 | 한국전자통신연구원 | 전자파 센서 및 전자파 센서의 생성 방법 |
CN115852683B (zh) * | 2022-11-30 | 2024-06-14 | 上海丰泽源科技有限公司 | 一种可降解型pla纺丝油剂及其制备方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4179544A (en) * | 1977-12-05 | 1979-12-18 | Basf Wyandotte Corporation | Fiber finish compositions |
US4256589A (en) * | 1978-02-16 | 1981-03-17 | Eastman Kodak Company | Fiber treating compositions comprising (a) blend of random copoly(oxyethylene-oxypropylene)butanols (b) alkali metal sulfur compound and (c) alkali metal organic phosphate compound |
DE2812443C2 (de) * | 1978-03-22 | 1982-12-02 | Hoechst Ag, 6000 Frankfurt | Polyglykoläthermischformale sowie deren Verwendung als Faserpräparationsmittel |
US4198464A (en) * | 1978-05-26 | 1980-04-15 | Basf Wyandotte Corporation | Fiber lubricants based upon ethylene oxide capped polyethers of tetrahydrofuran and ethylene oxide |
GB2109403B (en) * | 1981-11-27 | 1985-07-17 | Shell Int Research | Alkoxylate textile processing oils |
JPS60215873A (ja) * | 1984-04-06 | 1985-10-29 | 竹本油脂株式会社 | ポリエステル又はポリアミド繊維糸の紡糸油剤用組成物 |
DE3420708C1 (de) * | 1984-06-02 | 1985-07-18 | Hoechst Ag, 6230 Frankfurt | Modifizierte Polyethylenglykole |
US4622038A (en) * | 1985-01-28 | 1986-11-11 | Basf Corporation | Low residue fiber spin finishes |
US4789381A (en) * | 1987-04-27 | 1988-12-06 | Kao Corporation | Fiber treating process and composition used therefor |
DE3723349C1 (de) * | 1987-07-15 | 1988-08-11 | Goldschmidt Ag Th | Mittel zum Ausruesten von Fasern oder Faserprodukten |
US5066414A (en) * | 1989-03-06 | 1991-11-19 | The Procter & Gamble Co. | Stable biodegradable fabric softening compositions containing linear alkoxylated alcohols |
DE3936975C1 (en) * | 1989-11-07 | 1991-01-24 | Tudapetrol Mineraloelerzeugnisse Nils Hansen Kg, 2000 Hamburg, De | Spooling oil to treat textured fibres or yarns - comprises vegetable oil, ester of vegetable fatty acid, fatty alcohol polyglycol ether, fatty alcohol methacrylate, etc. |
US5079076A (en) * | 1990-03-15 | 1992-01-07 | The Lubrizol Corporation | Composition and polymer fabrics treated with the same |
US5126060A (en) * | 1991-01-09 | 1992-06-30 | Colgate-Palmolive Co. | Biodegradable fabric softening compositions based on pentaerythritol esters and free of quaternary ammonium compounds |
-
1992
- 1992-10-13 DE DE59208170T patent/DE59208170D1/de not_active Expired - Fee Related
- 1992-10-13 AT AT92117479T patent/ATE150108T1/de not_active IP Right Cessation
- 1992-10-13 ES ES92117479T patent/ES2100997T5/es not_active Expired - Lifetime
- 1992-10-13 EP EP92117479A patent/EP0538714B2/de not_active Expired - Lifetime
- 1992-10-15 JP JP27752192A patent/JP3258724B2/ja not_active Expired - Fee Related
- 1992-10-15 US US07/961,445 patent/US5266221A/en not_active Expired - Fee Related
- 1992-10-15 AR AR92323430A patent/AR247432A1/es active
- 1992-10-16 BR BR929204029A patent/BR9204029A/pt not_active Application Discontinuation
- 1992-10-16 TR TR92/1087A patent/TR26747A/xx unknown
- 1992-10-16 MX MX9205982A patent/MX9205982A/es not_active IP Right Cessation
- 1992-10-16 CA CA002080741A patent/CA2080741A1/en not_active Abandoned
- 1992-10-19 KR KR1019920019161A patent/KR930008233A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
BR9204029A (pt) | 1994-03-22 |
CA2080741A1 (en) | 1993-04-20 |
EP0538714A1 (de) | 1993-04-28 |
DE59208170D1 (de) | 1997-04-17 |
JPH05279924A (ja) | 1993-10-26 |
JP3258724B2 (ja) | 2002-02-18 |
KR930008233A (ko) | 1993-05-21 |
ES2100997T5 (es) | 1999-12-01 |
AR247432A1 (es) | 1994-12-29 |
TR26747A (tr) | 1995-05-15 |
ES2100997T3 (es) | 1997-07-01 |
US5266221A (en) | 1993-11-30 |
ATE150108T1 (de) | 1997-03-15 |
MX9205982A (es) | 1993-04-01 |
EP0538714B1 (de) | 1997-03-12 |
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