EP0514633B1 - Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren - Google Patents

Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren Download PDF

Info

Publication number
EP0514633B1
EP0514633B1 EP92103969A EP92103969A EP0514633B1 EP 0514633 B1 EP0514633 B1 EP 0514633B1 EP 92103969 A EP92103969 A EP 92103969A EP 92103969 A EP92103969 A EP 92103969A EP 0514633 B1 EP0514633 B1 EP 0514633B1
Authority
EP
European Patent Office
Prior art keywords
printing material
material according
ink
groups
polyvinyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92103969A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0514633A1 (de
Inventor
Reiner Dr. Jahn
Jürgen Dipl.-Ing.(FH) Graumann
Horst Dipl.-Ing.(Fh) Westfal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felex Schoeller Jr and GmbH and Co KG
Original Assignee
Felex Schoeller Jr and GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felex Schoeller Jr and GmbH and Co KG filed Critical Felex Schoeller Jr and GmbH and Co KG
Publication of EP0514633A1 publication Critical patent/EP0514633A1/de
Application granted granted Critical
Publication of EP0514633B1 publication Critical patent/EP0514633B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants

Definitions

  • the invention relates to a recording material for the ink jet printing process.
  • An ink-jet recording system is a noiseless, high-speed recording requiring no development or fixation, and droplets of a recording liquid (ink) are applied to the recording material by various techniques.
  • the ink-jet recording process is not only found in the office area, e.g. B. in the creation of color graphics, a wide application, but also in full color copying.
  • a common uncoated paper plain paper
  • the increasing improvement of the functioning of the ink-jet printers and the resulting higher demands on the recordings require the use of specially coated papers.
  • a recording material for the ink-jet method usually consists of a support and an ink-receiving layer arranged thereon. But other layers, such as. B. intermediate layers, protective layers can be applied.
  • a polyester resin, diacetate resin, paper and the like can be used as the carrier. be used.
  • the ink-receiving layers basically consist of a pigment / binder mixture.
  • the pigments serve to retain the dyes from the recording liquid on the surface of the sheet.
  • Natural or synthetic polymers are used as binders, such as. B. gelatin, corn starch, potato starch, pectin, casein, carboxylmethyl cellulose, polyvinyl alcohol, polyacrylamides, polyvinyl pyrrolidone and the like.
  • the pigments from the ink are drawn into the inside of the recording material, which deteriorates the color density of the image.
  • Multilayer construction is also used to try to achieve the desired properties.
  • JP 61-035 275 two layers are applied to a carrier.
  • the top microporous layer made of vinyl acetate copolymer, lets the ink through quickly, ensuring good smudge resistance.
  • the inner layer which contains a hydrophilic binder, is intended to ensure high sharpness of the recorded image.
  • the disadvantage of this recording material is the multiple operations: two layers have to be applied separately.
  • JP-A-1-186 372 describes a recording material for the ink jet recording method, consisting of a support and an ink receiving layer arranged thereon, which contains a polyvinyl alcohol with a degree of saponification of at least 87 mol%, a cationic polyacrylamide and an amorphous silica, the silica being one specific surface area of at least 180 m 2 / g and a particle size of 1 to 40 microns.
  • JP-A-61-61 887 describes a recording sheet for the ink jet recording process with selected polyallylamine derivatives as binders in addition to synthetic silicas.
  • An exemplary list of binders also mentions maleic anhydride resin, among others.
  • the claimed good properties with regard to light stability and water resistance are attributed to the mixture of polyvinyl alcohol, silica and the polyallylamine derivative.
  • the object of the present invention is to produce a recording material for ink-jet processes which does not have the disadvantages of the prior art and is distinguished in particular by a high color density and small, exact drop size.
  • the ink-receiving layer arranged on a support comprises a polyvinyl alcohol, a cationic polymer containing no crosslinking groups, an amorphous silica with a specific surface area of 200 to 400 m 2 / g and a particle size of 2 to 12 ⁇ m and poly ( contains methyl vinyl ether) maleic anhydride and / or a benzotriazole derivative.
  • the cationic polymer containing no crosslinking groups according to the invention is in particular a polymer from the group consisting of the cationic polyamides, polyacrylamides or polyamines.
  • the polyvinyl alcohol contained in the binder mixture of the receiving layer is preferably a polyvinyl alcohol with a degree of saponification of at least 80 mol%.
  • the amount of polyvinyl alcohol is 10 to 60% by weight, but in particular 20 to 50% by weight.
  • the amount of the cationic polymer added is at most 10% by weight, in particular 3 to 6% by weight.
  • the amorphous silica according to the invention can be added to the ink receiving layer in an amount of 20 to 70% by weight, in particular 30 to 60% by weight.
  • the ink-receiving layer can additionally contain a maleic anhydride copolymer, in particular a poly (methyl vinyl ether) maleic anhydride, the amount of which is between 0 and 30% by weight.
  • a maleic anhydride copolymer in particular a poly (methyl vinyl ether) maleic anhydride, the amount of which is between 0 and 30% by weight.
  • the benzotriazole derivative according to the invention is, in particular, a compound from the group of the benzotriazole derivatives containing alkyl, cycloalkyl, phenyl, phenylalkyl, hydroxyl, alkoxy or amino groups.
  • the amount of the benzotriazole derivative is 1 to 15% by weight, but in particular 2 to 5% by weight.
  • the ink-receiving layer can also contain all other usual additives, such as.
  • B. inorganic or organic pigments polymethyl methacrylate, polystyrene, CaCO 3 , TiO 2 , BaSO 4 and the like
  • wetting agents polymethyl methacrylate, polystyrene, CaCO 3 , TiO 2 , BaSO 4 and the like
  • wetting agents wetting agents, shading dyes, antistatic agents and other auxiliaries.
  • the aqueous dispersion of the ink-receiving layer (coating composition) can be applied to the carrier by all customary application and metering methods, such as e.g. B. roller application, engraving or nipping processes and air brush or roller doctor metering.
  • An uncoated or coated base paper can be used as a carrier for the ink-receiving layer, such as e.g. B. a polyolefin coated, barite, coated or surface sized base paper.
  • the front of a base paper sized with alkyl ketene dimer and additionally surface-sized with a basis weight of 170 g / m 2 was coated with an aqueous coating composition and then dried.
  • the ink-receiving layer obtained after drying has the following composition: Components Composition,% by weight 1a 1b 1c 1d 1e 1f
  • test conditions - machine speed 100 m / min - drying temperature 100 ° C - drying time 1 - 2 min
  • a 135 g / m 2 basis weight paper sized with stearic acid, alkyl ketene dimer and epoxidized fatty acid amide was coated on both sides with polyethylene (front side 20 g / m 2 , back side 25 g / m 2 ) in the melt extrusion process. After a corona pretreatment, an aqueous coating composition was applied to the front and then dried.
  • the ink-receiving layer obtained after drying has the following composition: Components Composition,% by weight 2a 2 B 2c Polyvinyl alcohol (Mowiol 4-98) degree of saponification: 98.4 mol% 40 38.5 28.5 amorphous silica (Syloid ED50) average Particle size: 5 ⁇ 40 55 55.0 Cationic polyacrylamide (Multifloc 15332, Protex) 5 4th 4.0 Benzotriazole derivative (Tinuvin 328, Ciba-Geigy) 15 2.5 2.5 2.5 Poly (methyl vinyl ether) maleic anhydride (Gantrez AN 149, GAF) - - 10.0 Order quantity, g / m 2 8th 10th 8th
  • a base paper with a basis weight of 100 g / m 2 which was acid-sized with stearin, alum and resin glue, was coated with an aqueous coating composition and then dried.
  • the ink-receiving layer obtained after drying has the following composition: Components Composition,% by weight 3a 3b Polyvinyl alcohol (Mowiol 4-98) degree of saponification: 98.4 mol% 38.5 28.5 amorphous silica (Syloid ED50) average Particle size: 5 ⁇ m 55.0 55.0 cationic polyacrylamide (Multifloc 15332, Protex) 4.0 4.0 Benzotriazole derivative (Tinuvin 328, Ciba-Geigy) 2.5 2.5 Poly (methyl vinyl ether) maleic anhydride (Gantrez AN 149, GAF) - 10.0 Order quantity, g / m 2 8th 8th
  • Example 2 The procedure was as in Example 1.
  • the binder used was a polyvinyl alcohol, the degree of saponification of which was only 80.4 mol%.
  • the base paper from Example 1 was coated with a receiving layer which, instead of amorphous silica, contains a compact crystalline silica.
  • the base paper from Example 1 was provided with a receiving layer in which the use of a cationic polymer containing no crosslinking groups was dispensed with.
  • the ink-receiving layers according to Comparative Examples V1 to V3 were applied from an aqueous medium and had the following compositions after drying: Components Composition,% by weight V1 V2 V3 Polyvinyl alcohol (Mowiol 4-80) degree of saponification: 80.4 mol% 40 - - Polyvinyl alcohol (Mowiol 4-98 saponification degree: 98.4 mol% - 60 45 amorphous silica (Syloid ED50) average Particle size: 5 ⁇ m 55 - 55 crystalline silica (Sorbsil 644) average Particle size: 3 ⁇ m - 35 - cationic polyacrylamide 5 5 - Order quantity, g / m 2 10th 8th 8th
  • the recording material obtained in the comparative examples was printed in a continuous ink-jet process and then analyzed.
  • the results are summarized in Table 3.
  • the recording material obtained was printed with the aid of an Excelerator 4/1120 inkjet printer from Stork X-cel, which works according to the Hertz inkjet printing principle, using the inks developed by Stork.
  • the density measurements were carried out before and after a 24-hour exposure of the images using a xenon lamp.
  • the device used for this was an original reflection densitometer SOS-45. The measurements were carried out for the basic colors cyan, magenta, yellow and black.
  • the recording material was immersed in water to investigate the water resistance.
  • the loss of density after 60 s in a water bath is used as a measure of the water stability.
  • the droplet size is determined with the aid of a thread counter, the diameter of the droplet being read first and then the area being calculated in mm 2 .

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)
  • Paper (AREA)
EP92103969A 1991-05-22 1992-03-09 Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren Expired - Lifetime EP0514633B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4116595A DE4116595A1 (de) 1991-05-22 1991-05-22 Aufzeichnungsmaterial fuer das tintenstrahlaufzeichnungsverfahren
DE4116595 1991-05-22

Publications (2)

Publication Number Publication Date
EP0514633A1 EP0514633A1 (de) 1992-11-25
EP0514633B1 true EP0514633B1 (de) 1996-07-03

Family

ID=6432116

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92103969A Expired - Lifetime EP0514633B1 (de) 1991-05-22 1992-03-09 Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren

Country Status (7)

Country Link
EP (1) EP0514633B1 (enrdf_load_stackoverflow)
JP (1) JPH05131741A (enrdf_load_stackoverflow)
AT (1) ATE139946T1 (enrdf_load_stackoverflow)
DE (2) DE4116595A1 (enrdf_load_stackoverflow)
DK (1) DK0514633T3 (enrdf_load_stackoverflow)
ES (1) ES2089264T3 (enrdf_load_stackoverflow)
GR (1) GR3020769T3 (enrdf_load_stackoverflow)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07179032A (ja) * 1993-10-27 1995-07-18 Eastman Kodak Co インキジェット記録媒体
EP0672539B1 (en) * 1994-02-24 2000-05-10 Canon Kabushiki Kaisha Printing medium, production process thereof, and ink jet printing method using the same
GB2301844A (en) * 1995-06-05 1996-12-18 Rexam Coated Products Limited A recording sheet
GB2301845B (en) * 1995-06-06 1998-08-19 Rexam Coated Products Limited Natural tracing paper for use with pigment-based inks
EP0824077A3 (en) * 1996-08-12 1999-06-02 TOYO BOSEKI KABUSHIKI KAISHA Trading under the name of Toyobo Co., Ltd. Ink-receptive recording material
US5882388A (en) * 1996-10-16 1999-03-16 Brady Usa, Inc. Water resistant ink jet recording media topcoats
DE19715187C2 (de) * 1997-04-11 2000-06-29 Few Chemicals Gmbh Aufzeichnungsmaterial für wasserverdünnbare Tinten
JPH1178218A (ja) * 1997-09-17 1999-03-23 Oji Paper Co Ltd インクジェット記録体
JP3495930B2 (ja) * 1997-12-09 2004-02-09 キヤノン株式会社 インクジェット用吸着剤、該吸着剤を用いた吸着部材を備えたインク保持容器及び吸着部材を備えたインク供給システム
US6596378B2 (en) * 2000-05-22 2003-07-22 Seiko Epson Corporation Recording medium and aqueous ink composition
JP2002067475A (ja) * 2000-08-23 2002-03-05 Mitsubishi Paper Mills Ltd インクジェット用記録材料
JP2004529054A (ja) * 2001-02-19 2004-09-24 フンダソン・デ・アンパロ・ア・ペスキサ・ド・エスタド・デ・サンパウロ 植物性材料から抽出される酸化物と抽出方法
JP2002332419A (ja) * 2001-05-09 2002-11-22 Nippon Kayaku Co Ltd 新規アントラピリドン化合物、水性マゼンタインク組成物及びインクジェット記録方法
US6759106B2 (en) * 2002-12-04 2004-07-06 Eastman Kodak Company Ink jet recording element
JP4018674B2 (ja) 2003-08-04 2007-12-05 キヤノン株式会社 インク用被記録媒体の製造方法
US7575314B2 (en) 2004-12-16 2009-08-18 Agfa Graphics, N.V. Dotsize control fluid for radiation curable ink-jet printing process
EP1671805B1 (en) 2004-12-16 2009-03-11 Agfa Graphics N.V. Radiation curable ink-jet printing process using dotsize control fluid
JP6701755B2 (ja) * 2016-01-25 2020-05-27 セイコーエプソン株式会社 油性インクジェット記録用インクセット及び油性インクジェット記録方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6161887A (ja) * 1984-08-31 1986-03-29 Mitsubishi Paper Mills Ltd インクジエツト記録シ−ト

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59185690A (ja) * 1983-04-07 1984-10-22 Jujo Paper Co Ltd インクジエツト記録用紙
JPS6285983A (ja) * 1985-10-14 1987-04-20 Canon Inc 記録媒体および記録方法
JPS62170381A (ja) * 1986-01-24 1987-07-27 Canon Inc 被記録材
JPS62292476A (ja) * 1986-06-13 1987-12-19 Mizusawa Ind Chem Ltd インクジエツト記録紙用填料
US4926190A (en) * 1987-02-18 1990-05-15 Ciba-Geigy Corporation Ink jet recording process using certain benzotriazole derivatives as light stabilizers
JP2633671B2 (ja) * 1989-01-18 1997-07-23 日本製紙 株式会社 インクジェット記録用シート
JPH01225585A (ja) * 1988-03-04 1989-09-08 Canon Inc 被記録材及びそれを用いた記録方法
JP2988941B2 (ja) * 1989-07-12 1999-12-13 王子製紙株式会社 インクジェット記録用紙
EP0439153B1 (en) * 1990-01-24 1995-06-14 Canon Kabushiki Kaisha Color ink jet recording method
JPH04272888A (ja) * 1991-02-27 1992-09-29 Asahi Glass Co Ltd 記録媒体用塗工液および記録媒体

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6161887A (ja) * 1984-08-31 1986-03-29 Mitsubishi Paper Mills Ltd インクジエツト記録シ−ト

Also Published As

Publication number Publication date
DE59206685D1 (de) 1996-08-08
DE4116595C2 (enrdf_load_stackoverflow) 1993-05-13
ATE139946T1 (de) 1996-07-15
GR3020769T3 (en) 1996-11-30
EP0514633A1 (de) 1992-11-25
ES2089264T3 (es) 1996-10-01
DE4116595A1 (de) 1992-11-26
DK0514633T3 (da) 1996-11-18
JPH05131741A (ja) 1993-05-28

Similar Documents

Publication Publication Date Title
EP0806299B1 (de) Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren
EP0514633B1 (de) Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren
EP0631880B1 (de) Aufzeichnungsblatt für Ink-Jet-Druckverfahren
DE69310107T3 (de) Aufzeichnungsblatt für Tintenstrahlschreiber und Verfahren zu seiner Herstellung
DE4322178C2 (de) Aufzeichnungsmaterial für Ink-Jet-Druckverfahren
EP0445327B1 (de) Aufzeichnungsmaterial für das Tintenstrahldruck-Verfahren
DE69921258T2 (de) Tintenstrahlaufzeichnungselement, das kolloidales Kieselgel enthält
DE3024205C2 (de) Aufzeichnungspapier für Tintenspritzaufzeichnungsverfahren
EP1048480B1 (de) Ink-Jet-Aufzeichnungspapier mit Pigmentschichten
DE19955081C1 (de) Basispapier für ein Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
DE69911157T2 (de) Tintenstrahlaufzeichnungsmaterial, das Polyäthylenglykol und Polyvinylalkohol enthält
DE3886440T2 (de) Aufzeichnungsmittel.
DE69504142T2 (de) Tintenstrahl-Aufzeichnungsfolie und Aufzeichnungsmethode mittels diesem
DE69428871T2 (de) Aufzeichnungsmaterial und Bildaufzeichnungsverfahren, das dieses Material benutzt
DE69923114T2 (de) Tintenstrahlaufzeichnungsmaterial, das kationisches Harz enthält, und Aufzeichnungsverfahren
DE3434256C2 (enrdf_load_stackoverflow)
EP0812697B1 (de) Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
DE69825509T2 (de) Aufzeichnungsmedium und Aufzeichnungsverfahren unter Verwendung desselben
EP0539678B1 (de) Aufzeichnungsmaterial für das ink jet-Verfahren
DE3518854C2 (enrdf_load_stackoverflow)
DE69607819T2 (de) Tintenstrahlaufzeichnungsschicht die Kieselerde enthält
DE69805470T2 (de) Aufzeichnungsmaterial für mehrfarbiges Tintenstrahldruckverfahren mit wässerigen Tinten
EP2076398B1 (de) Ink-jet-aufzeichnungsmaterial mit perforierter rückseitenkunstharzschicht
DE602005002335T2 (de) Tintenstrahl-Aufzeichnungsmedium und Verfahren zu seiner Herstellung
DE60014834T2 (de) Aufzeichnungsmaterial, das auf der Rückseite bedruckt wird, für Tintenstrahldruck

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU MC NL PT SE

17P Request for examination filed

Effective date: 19930105

17Q First examination report despatched

Effective date: 19940614

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU MC NL PT SE

REF Corresponds to:

Ref document number: 139946

Country of ref document: AT

Date of ref document: 19960715

Kind code of ref document: T

REF Corresponds to:

Ref document number: 59206685

Country of ref document: DE

Date of ref document: 19960808

ET Fr: translation filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19960816

ITF It: translation for a ep patent filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2089264

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: GR

Ref legal event code: FG4A

Free format text: 3020769

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2089264

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

SC4A Pt: translation is available

Free format text: 960819 AVAILABILITY OF NATIONAL TRANSLATION

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20060223

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: MC

Payment date: 20060313

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20060314

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20060315

Year of fee payment: 15

Ref country code: DK

Payment date: 20060315

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20060323

Year of fee payment: 15

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070310

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070910

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 20070910

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

EUG Se: european patent has lapsed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070309

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070331

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20060314

Year of fee payment: 15

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070402

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071003

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20090324

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20090317

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20090316

Year of fee payment: 18

Ref country code: GB

Payment date: 20090325

Year of fee payment: 18

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070309

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20090325

Year of fee payment: 18

Ref country code: DE

Payment date: 20090320

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20090430

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20090312

Year of fee payment: 18

BERE Be: lapsed

Owner name: FELIX *SCHOELLER JR. PAPIERFABRIK G.M.B.H. & CO. K

Effective date: 20100331

REG Reference to a national code

Ref country code: NL

Ref legal event code: V1

Effective date: 20101001

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20100309

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20101130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101001

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100331

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100331

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100331

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101001

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100309

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100309

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20110418

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110404

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100310