EP0504561B1 - Abstandhalter für ein Mehrscheiben-Isolierglas - Google Patents
Abstandhalter für ein Mehrscheiben-Isolierglas Download PDFInfo
- Publication number
- EP0504561B1 EP0504561B1 EP92101598A EP92101598A EP0504561B1 EP 0504561 B1 EP0504561 B1 EP 0504561B1 EP 92101598 A EP92101598 A EP 92101598A EP 92101598 A EP92101598 A EP 92101598A EP 0504561 B1 EP0504561 B1 EP 0504561B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- spacer
- glass
- layer
- strip
- insulating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 125000006850 spacer group Chemical group 0.000 title claims abstract description 56
- 239000011521 glass Substances 0.000 claims abstract description 39
- 239000004814 polyurethane Substances 0.000 claims abstract description 8
- 229920002635 polyurethane Polymers 0.000 claims abstract description 8
- 238000005266 casting Methods 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000004033 plastic Substances 0.000 claims description 19
- 229920003023 plastic Polymers 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 2
- 238000010292 electrical insulation Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 3
- 239000011810 insulating material Substances 0.000 description 11
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002274 desiccant Substances 0.000 description 7
- 238000009413 insulation Methods 0.000 description 6
- 230000007774 longterm Effects 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 2
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- LULCPJWUGUVEFU-UHFFFAOYSA-N Phthiocol Natural products C1=CC=C2C(=O)C(C)=C(O)C(=O)C2=C1 LULCPJWUGUVEFU-UHFFFAOYSA-N 0.000 description 1
- 229920001079 Thiokol (polymer) Polymers 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000003000 extruded plastic Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/663—Elements for spacing panes
- E06B3/66309—Section members positioned at the edges of the glazing unit
- E06B3/66323—Section members positioned at the edges of the glazing unit comprising an interruption of the heat flow in a direction perpendicular to the unit
Definitions
- the invention is in the field of heatable multi-pane insulating glass consisting of at least two glass panes which are kept at a distance by a spacer and have a gas-filled or evacuated intermediate space.
- a multi-pane insulating glass of this type on the interspace-side surface of one of the two glass panes there are wafer-thinly applied electrical conductor tracks designed as resistance heating elements with corresponding connections for the passage of an electrical current.
- the glass pane is heated when an electrical current is applied to the conductor tracks, absorbs heat and is said to emit the heat to the air of a room in a building by convection and / or radiation.
- the spacer must ensure special properties in the construction of the multi-pane insulating glass.
- the plastic in the intermediate space forms an insulating web, which consists of a mixture of a fully formulated, phase-unstable, low-viscosity polyol formulation that contains a water-binding additive (Baydur VP PU 1397) with a liquid, solvent-free diphenylmethane-4,4'-diisocyanate with a Content of isomers and higher functional homologues (Desmodur 44 V10 B or Desmodur 44 V20 B) is produced (Baydur: manufacturer Bayer AG; Desmodur: manufacturer Bayer AG).
- the insulating web is e.g.
- the hollow profiles of the spacer are filled with a desiccant.
- a water vapor-impermeable putty in particular made of butyl, is arranged between the outer walls of the spacer and the intermediate surfaces of the glass panes.
- the space below the spacer is filled with a more or less plastically elastic putty, especially with Thiocol.
- the success described in the applicant's older proposal is essentially based on the choice of material for the insulating material between the spacer tubes.
- the selected insulating material is in some cases not gas-impermeable, in particular water vapor-impermeable, so that moisture penetrates into the interior of the insulating glass and affects both the thermal insulation of the insulating glass and the electrical insulation of the insulating material.
- attempts e.g. to get to the insulating material by adding.
- success has not yet been recorded.
- the object of the invention is to improve the spacer known from DE-GM 88 12 216.6 for a heatable multi-pane insulating glass so that it ensures long-term gas tightness, but in particular water vapor tightness in the installed state and maintains its excellent electrical insulating ability.
- the heatable multi-pane insulating glass is placed in a frame of a window or a door (not shown). It essentially consists of the two glass panes 1 and 2 arranged parallel to one another and at a distance from one another, between which an intermediate space 3 is provided. Conductor tracks 5 of a resistance heating element (not shown) are e.g. evaporated. The electrical connections and the overall structure of the resistance heating element need not be described, because they belong to the prior art and are not critical for the purposes of the invention.
- a spacer 6 bridges the intermediate space 3, which is shown frontally in FIG. 2 and whose structure is essential to the invention.
- the spacer 6 preferably consists of two aluminum hollow profiles 7 and 8 arranged parallel to one another and at a distance from one another, with side walls 7a, 7b and 8a, 8b parallel to the glass pane surfaces, a bottom wall 7c, 8c and a top wall 7d, 8d.
- Through holes 9 are made in the ceiling wall which, as is known, create a connection between the interior 10 of the hollow profiles 7, 8 filled with drying agent 11 and the intermediate space 3.
- a butyl layer 12 is expediently arranged as a connecting element and as a water vapor barrier.
- other connecting substances can also be provided there that serve the same purpose.
- the space 13 under the spacer 6 is expediently filled with a putty 14, for example with Thiokol.
- the putty serves as a plastic-elastic connection and adhesive.
- the intermediate space 15 between the two hollow profiles 7, 8 is filled with a product that results in a hard material that firmly bonds with aluminum or adheres firmly to the aluminum and creates a uniformly rigid, torsion-resistant spacer, and above all Excellent electrical insulation and also an extremely low one
- the product or substance must be UV and heat resistant. A substance has been found for this purpose through an inventive selection.
- insulating web 16 which consists of an unfoamed, hardened polyurethane casting compound.
- the raw material for this insulating material web 16 is traded under the trade name "Baydur VP PU 1397" from Bayer AG. It is a fully formulated, phase-unstable, low-viscosity polyol formulation that contains a water-binding additive. The mixture must be homogenized well before processing. Stir slowly during processing.
- the formulation has the following properties:
- the lower limit of the processing temperature is 23 ° C.
- the activity of Baydur VPPU 1397 can be changed at temperatures above 35 ° C.
- the processing temperature of the raw materials should be at least 23 ° C.
- Baydur VP PU 1397 is a preparation based on polyols.
- the insulating web 16 has, for example, the following properties:
- the processing shrinkage is only 0.8 ⁇ 0.1% manufacturing tolerance. This value applies to the manufacture of an up to 100 mm thick insulating material web 16 with a bulk density of 1180 kg / m3 if the specified processing recipe with Desmodur 44 V 10 B and a mold retention time of 1 minute are maintained in a mold tempered to 75 ° C.
- the width of the solid insulating material web 16 is preferably 1/3 to 1/6 of the total width of the spacer 6.
- the selected material for the insulating web 16 fulfills all the required properties.
- two 5.5 mm wide welded spacer profiles 7.8 - which are outstandingly suitable due to their great inherent stability - can be combined with the selected plastic, which is supposed to effect the thermal and electrical separation, in order to achieve optimum separation properties in the corner area as well.
- the new spacer profile can be bent in the corner area to the corner without the plastic hindering the bending.
- Another favorable property of the selected polyurethane plastic is that it can be permanently combined with the lacquers already developed for aluminum spacers, so that colored spacers can also be created.
- the use of UV-resistant paints is possible.
- Another particularly important option is to color the polyurethane plastic and thus create a decorative spacer.
- the electrical insulation of the insulating material web 16 is also perfect.
- the insulating material web 16 made of the special material is permeable to water vapor if the water vapor partial pressure exceeds a certain size.
- the water vapor can reach the insulating web 16 from the outside through the room 13 or through the cement 14 in the room 13. If water vapor penetrates the insulating material web 16, the electrical insulating capacity is reduced or electrical conductivity can occur. If the water vapor penetrates the insulating material web 16, it reaches the space between the panes 3 and is adsorbed by the desiccant 11 located in the spacer hollow profiles 7, 8 until the desiccant is used up.
- the invention solves the problem in an astonishingly simple manner by providing a spacer 6 in which the outer surface 16a facing the space 13 is covered with a layer 17 impermeable to water vapor.
- This layer 17 consists e.g. made of butyl, a material that is also used on the side of the spacer 6 as a water vapor impermeable and sticky layer 12.
- the spacer 6 can be handled - spacers are supplied cut to length in the form of bars to insulating glass manufacturers - the free surface 17a of the sticky butyl layer 17 is covered with a paper and / or plastic tape 18, so that the stickiness of the butyl does not interfere with handling and the free surface of the butyl layer 17 is not dirty.
- the tape 18 is removed shortly before the spacer 6 is installed between the glass panes 1, 2 and the butyl layer 17 is contacted with the putty 14.
Landscapes
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Joining Of Glass To Other Materials (AREA)
- Securing Of Glass Panes Or The Like (AREA)
- Laminated Bodies (AREA)
- Insulating Bodies (AREA)
- Control Of Vending Devices And Auxiliary Devices For Vending Devices (AREA)
- Specific Sealing Or Ventilating Devices For Doors And Windows (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE9103448U DE9103448U1 (de) | 1991-03-20 | 1991-03-20 | Abstandhalter für ein Mehrscheiben-Isolierglas |
DE9103448U | 1991-03-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0504561A1 EP0504561A1 (de) | 1992-09-23 |
EP0504561B1 true EP0504561B1 (de) | 1994-05-18 |
Family
ID=6865514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92101598A Revoked EP0504561B1 (de) | 1991-03-20 | 1992-01-31 | Abstandhalter für ein Mehrscheiben-Isolierglas |
Country Status (10)
Country | Link |
---|---|
US (1) | US5125195A (es) |
EP (1) | EP0504561B1 (es) |
JP (1) | JPH05133168A (es) |
AT (1) | ATE105911T1 (es) |
CA (1) | CA2043915A1 (es) |
DE (2) | DE9103448U1 (es) |
DK (1) | DK0504561T3 (es) |
ES (1) | ES2054512T3 (es) |
FI (1) | FI97414C (es) |
NO (1) | NO920443L (es) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9218150D0 (en) | 1992-08-26 | 1992-10-14 | Pilkington Glass Ltd | Insulating units |
US5401706A (en) * | 1993-01-06 | 1995-03-28 | Semco Incorporated | Desiccant-coated substrate and method of manufacture |
US5300138A (en) * | 1993-01-21 | 1994-04-05 | Semco Incorporated | Langmuir moderate type 1 desiccant mixture for air treatment |
US5424111A (en) * | 1993-01-29 | 1995-06-13 | Farbstein; Malcolm N. | Thermally broken insulating glass spacer with desiccant |
US5581971A (en) * | 1994-09-16 | 1996-12-10 | Alumet Manufacturing, Inc. | Glass spacer bar for use in multipane window construction and method of making the same |
US5630306A (en) * | 1996-01-22 | 1997-05-20 | Bay Mills Limited | Insulating spacer for creating a thermally insulating bridge |
US5813191A (en) | 1996-08-29 | 1998-09-29 | Ppg Industries, Inc. | Spacer frame for an insulating unit having strengthened sidewalls to resist torsional twist |
CA2206938C (en) | 1997-06-02 | 2005-07-26 | Luc Lafond | Strip applying hand tool with corner forming apparatus |
BE1011279A3 (nl) * | 1997-07-14 | 1999-07-06 | Iq Glass | Verwarmende dubbele beglazing. |
US6055783A (en) | 1997-09-15 | 2000-05-02 | Andersen Corporation | Unitary insulated glass unit and method of manufacture |
DE19828565B4 (de) * | 1998-06-26 | 2005-01-20 | Schott Ag | Mehrscheibenisolierglas für Geräte mit einer gegenüber der Umgebungstemperatur herabgesetzten Innenraumtemperatur |
KR100472039B1 (ko) * | 2002-06-21 | 2005-03-10 | 한국아존 주식회사 | 유리창용 간봉의 제조방법 |
DE102006007472B4 (de) | 2006-02-17 | 2018-03-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Photovoltaisches Konzentratormodul mit Multifunktionsrahmen |
US7886986B2 (en) | 2006-11-08 | 2011-02-15 | Semco Inc. | Building, ventilation system, and recovery device control |
DE102009051319A1 (de) * | 2009-10-29 | 2011-02-10 | Rosenheimer Glastechnik Gmbh | Glasverbundscheibe |
EP2516576B1 (en) * | 2009-12-21 | 2018-05-16 | Dow Global Technologies LLC | Polyurethane-based sealant for insulated glass units |
DE102010006127A1 (de) * | 2010-01-29 | 2011-08-04 | Technoform Glass Insulation Holding GmbH, 34277 | Abstandshalterprofil mit Verstärkungsschicht |
DE102010049806A1 (de) * | 2010-10-27 | 2012-05-03 | Technoform Glass Insulation Holding Gmbh | Abstandshalterprofil und Isolierscheibeneinheit mit einem solchen Abstandshalterprofil |
DE102011009359A1 (de) | 2011-01-25 | 2012-07-26 | Technoform Glass Insulation Holding Gmbh | Abstandshalterprofil und Isolierscheibeneinheit mit einem solchen Abstandshalterprofil |
EP2626496A1 (en) | 2012-02-10 | 2013-08-14 | Technoform Glass Insulation Holding GmbH | Spacer profile for a spacer frame for an insulating glass unit with interspace elements and insulating glass unit |
US9260907B2 (en) * | 2012-10-22 | 2016-02-16 | Guardian Ig, Llc | Triple pane window spacer having a sunken intermediate pane |
WO2015043848A1 (de) * | 2013-09-30 | 2015-04-02 | Saint-Gobain Glass France | Abstandshalter für isolierverglasungen |
WO2015086457A2 (de) | 2013-12-12 | 2015-06-18 | Saint-Gobain Glass France | Isolierverglasung mit verbesserter abdichtung |
CN105793511A (zh) | 2013-12-12 | 2016-07-20 | 法国圣戈班玻璃厂 | 具有经挤出的密封型材的用于绝缘窗玻璃的距离保持件 |
TR201815606T4 (tr) | 2014-06-27 | 2018-11-21 | Saint Gobain | Mesafe parçasına sahip yalıtım cam kaplaması ve bunun imal edilmesi için yöntem ve ayrıca bunun bina cam kaplaması olarak kullanımı. |
US10301868B2 (en) | 2014-06-27 | 2019-05-28 | Saint-Gobain Glass France | Insulated glazing comprising a spacer, and production method |
CA2958613C (en) | 2014-09-25 | 2019-05-07 | Saint-Gobain Glass France | Spacer for insulating glazing units |
BR112017017652B1 (pt) | 2015-03-02 | 2022-10-18 | Saint-Gobain Glass France | Espaçador reforçado com fibra de vidro para unidade de vidro isolante |
US10920480B2 (en) | 2017-09-05 | 2021-02-16 | Ged Integrated Solutions, Inc. | Thermally efficient window frame |
CZ308078B6 (cs) * | 2018-11-30 | 2019-12-18 | Thermo Glass.eu s.r.o. | Topné bezpečnostní zasklení |
CN110454047A (zh) * | 2019-08-29 | 2019-11-15 | 定西中庆玄和玻璃科技有限公司 | 一种低辐射节能双钢玻璃 |
DE102019129331A1 (de) * | 2019-10-30 | 2021-05-06 | Atec Gmbh & Co. Kg | Tür, Klappe und/oder Fenster zum Einbau in ein sich bewegendes Objekt |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2838810A (en) * | 1954-07-09 | 1958-06-17 | Pittsburgh Plate Glass Co | Multiple glazed unit |
FR1206377A (fr) * | 1958-08-14 | 1960-02-09 | Perfectionnements aux dispositifs à doubles vitrages | |
US2974377A (en) * | 1959-03-10 | 1961-03-14 | Pittsburgh Plate Glass Co | Polybutene sealing compound for glazing purposes |
US3791910A (en) * | 1972-03-07 | 1974-02-12 | Ppg Industries Inc | Multiple glazed unit |
US3919023A (en) * | 1973-09-24 | 1975-11-11 | Ppg Industries Inc | Multiple glazed unit |
DE2512168A1 (de) * | 1974-03-25 | 1975-10-09 | Ppg Industries Inc | Verglasungseinheit und verfahren zu deren installation als zusatz zu einer bestehenden verglasung |
DE2445332B2 (de) * | 1974-09-23 | 1976-12-09 | GGN Glashandels-Gesellschaft Nördlingen mbH & Co KG, 8860 Nördlingen | Schalldaemmendes mehrscheibenisolierglas |
DE2518205A1 (de) * | 1975-04-24 | 1976-11-04 | Flachglasveredelung Conzelmann | Isolierglasscheibe |
DE2526438A1 (de) * | 1975-06-13 | 1976-12-23 | Arnold Alfred | Isolierglasscheibe |
US4335166A (en) * | 1980-11-21 | 1982-06-15 | Cardinal Insulated Glass Co. | Method of manufacturing a multiple-pane insulating glass unit |
US4807419A (en) * | 1987-03-25 | 1989-02-28 | Ppg Industries, Inc. | Multiple pane unit having a flexible spacing and sealing assembly |
DE8812216U1 (de) * | 1988-09-27 | 1990-02-08 | Helmut Lingemann GmbH & Co, 5600 Wuppertal | Mehrscheibenisolierglas-Element |
-
1991
- 1991-03-20 DE DE9103448U patent/DE9103448U1/de not_active Expired - Lifetime
- 1991-04-24 US US07/690,772 patent/US5125195A/en not_active Expired - Fee Related
- 1991-06-05 CA CA002043915A patent/CA2043915A1/en not_active Abandoned
-
1992
- 1992-01-31 DK DK92101598.8T patent/DK0504561T3/da active
- 1992-01-31 EP EP92101598A patent/EP0504561B1/de not_active Revoked
- 1992-01-31 AT AT92101598T patent/ATE105911T1/de not_active IP Right Cessation
- 1992-01-31 DE DE59200165T patent/DE59200165D1/de not_active Revoked
- 1992-01-31 ES ES92101598T patent/ES2054512T3/es not_active Expired - Fee Related
- 1992-02-04 NO NO92920443A patent/NO920443L/no unknown
- 1992-03-19 JP JP4092401A patent/JPH05133168A/ja active Pending
- 1992-03-20 FI FI921198A patent/FI97414C/fi not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US5125195A (en) | 1992-06-30 |
FI97414C (fi) | 1996-12-10 |
DE59200165D1 (de) | 1994-06-23 |
ES2054512T3 (es) | 1994-08-01 |
ATE105911T1 (de) | 1994-06-15 |
FI921198A0 (fi) | 1992-03-20 |
NO920443L (no) | 1992-09-21 |
DE9103448U1 (de) | 1992-07-16 |
EP0504561A1 (de) | 1992-09-23 |
DK0504561T3 (da) | 1994-09-26 |
FI97414B (fi) | 1996-08-30 |
JPH05133168A (ja) | 1993-05-28 |
CA2043915A1 (en) | 1992-09-21 |
FI921198A (fi) | 1992-09-21 |
NO920443D0 (no) | 1992-02-04 |
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