EP0459603B1 - Verfahren und Anlage zur kontinuierlichen Trocknung von Holzspänen, Holzfasern oder anderen Schüttgütern - Google Patents
Verfahren und Anlage zur kontinuierlichen Trocknung von Holzspänen, Holzfasern oder anderen Schüttgütern Download PDFInfo
- Publication number
- EP0459603B1 EP0459603B1 EP91250134A EP91250134A EP0459603B1 EP 0459603 B1 EP0459603 B1 EP 0459603B1 EP 91250134 A EP91250134 A EP 91250134A EP 91250134 A EP91250134 A EP 91250134A EP 0459603 B1 EP0459603 B1 EP 0459603B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- combustion chamber
- dryer
- flue gases
- heat exchanger
- vapour
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000000463 material Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000001035 drying Methods 0.000 title claims abstract description 17
- 239000002023 wood Substances 0.000 title claims description 8
- 229920002522 Wood fibre Polymers 0.000 title claims description 7
- 238000002485 combustion reaction Methods 0.000 claims abstract description 39
- 239000003546 flue gas Substances 0.000 claims abstract description 31
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims 2
- 238000010981 drying operation Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000002912 waste gas Substances 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 9
- 231100000719 pollutant Toxicity 0.000 abstract description 9
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 238000004880 explosion Methods 0.000 abstract description 4
- 238000011144 upstream manufacturing Methods 0.000 abstract description 4
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 6
- 239000002025 wood fiber Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000567 combustion gas Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000019733 Fish meal Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004467 fishmeal Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
- F26B21/02—Circulating air or gases in closed cycles, e.g. wholly within the drying enclosure
- F26B21/04—Circulating air or gases in closed cycles, e.g. wholly within the drying enclosure partly outside the drying enclosure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B23/00—Heating arrangements
- F26B23/02—Heating arrangements using combustion heating
- F26B23/022—Heating arrangements using combustion heating incinerating volatiles in the dryer exhaust gases, the produced hot gases being wholly, partly or not recycled into the drying enclosure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B2200/00—Drying processes and machines for solid materials characterised by the specific requirements of the drying good
- F26B2200/24—Wood particles, e.g. shavings, cuttings, saw dust
Definitions
- the invention relates to a method and a plant for the continuous drying of wood chips, wood fibers or other bulk materials, in which the heat of flue gases generated in a combustion chamber is used in a dryer charged with the material to be dried.
- DE-A-24 61 415 discloses a drying system with a dryer heated directly by flue gases, the flue gases being generated in a combustion chamber upstream of the dryer.
- the mixture of flue gases and vapors leaving the dryer, which is contaminated with pollutants, is cleaned by means of cyclone dusting and then divided into two partial flows.
- One part of the stream is returned to the combustion chamber and injected into the hottest zone for the combustion of the pollutants, so that there is intensive mixing with the flue gases, which are then fed back to the dryer.
- the other partial flow is released into the atmosphere via an exhaust pipe.
- This method has the advantage of a reduced amount of exhaust gas, which means that fewer pollutants leave the system, but, with due regard to the legal regulations on emission limitation, it also does not manage without the additional cleaning methods described above.
- a method and a device for drying solids contained in liquid with two independent combustion chambers is known. Part of the vapors is fed to the main combustion chamber, from which the combustion gases are led into the atmosphere.
- the auxiliary combustion chamber which contains its own burner, is supplied with a portion of the vapors after preheating by the exhaust gases from the first combustion chamber in a heat exchanger, the combustion gases being introduced from the auxiliary combustion chamber into the dryer charged with the material to be dried.
- oxygen-containing combustion gases are used for drying, so that there is an increased risk of explosion when drying wood chips or wood fibers.
- the object of the invention is to provide a method and a system of the type mentioned, whereby pollutant emission limit values can be maintained with less effort than previously, which are smaller than previously prescribed, and which increases the efficiency and at the same time the Risk of explosion is reduced.
- this object is achieved by a method according to the teaching of claim 1 and by a system according to claim 9.
- the vapors which are polluted with pollutants but are free of flue gas, are returned to the dryer in the circuit and used as a drying agent for direct heating of the dryer.
- the heat content required for this is obtained by indirect heating before entering the dryer. It is heated with smoke gases that are generated in a combustion chamber.
- this combustion chamber is the 'lock' for a vapor partial flow which has to be removed from the circuit due to the mass balance to be maintained, i.e. pollutants can only leave the circuit via the combustion chamber. There they are burned and in this way provide part of the energy required to heat the circuit.
- a further vapor partial flow can be generated after the indirect heating of the Circuit branched from this and introduced into the combustion chamber. Since this vapor partial flow is heated, it can be mixed more effectively with the flue gases. In this case, the first vapor partial flow is reduced by the volume of the second vapor partial flow due to the mass balance to be maintained in the circuit.
- the invention is explained in more detail below using an exemplary embodiment.
- the accompanying drawing shows a basic circuit diagram of a system for the continuous drying of wood chips, wood fibers or the like.
- a dryer 8, a separator 10, a fan 11, one or more cyclones 12 and a recuperative heat exchanger 7 are connected together in a circuit via pipes. Design measures ensure that the leakage in this circuit is low.
- the system also has a combustion chamber 1 with a burner 2, which is connected to the heat exchanger 7 on the flue gas side, but is not part of the circuit.
- Supply lines for air 3, light oil or gas 4 and wood dust 5 lead to burner 2.
- the fuels can be burned individually or in any mixture.
- the material to be dried is entered between the heat exchanger 7 and dryer 8 via a material lock, not shown, for example a rotary valve, and a pipeline 9 into the circuit.
- the material can also be fed directly into the entrance area of the dryer 8, which, as is customary for this application, can be a nozzle tube dryer, single-pass, multi-pass drum dryer or the like.
- a pipeline 6 branches off in the flow direction upstream of the heat exchanger 7 to the combustion chamber 1.
- the flue gases generated in the combustion chamber 1 are fed to the heat exchanger 7.
- the hot vapor stream is fed to the dryer 8 for direct heating via the section of the pipeline 13 arranged between the heat exchanger 7 and the dryer 8.
- further vapors and harmful ingredients are released from the material to be dried, which are removed from the dryer 8 together with the dried material.
- the coarser fractions of the dried material are separated in the subsequent separator.
- the fine fractions of the dried material remaining in the vapors are then fed together with the vapors via a blower 11 to one or more cyclones 12. This is where the fine fractions of the dried material are separated.
- the vapors leaving the cyclone (s) 12 are contaminated with fine dust and the pollutants formed during drying. They are returned to the dryer 8 via the pipeline 13, passing through the heat exchanger 7 and being heated up. This closes the almost inert vapor cycle.
- the cooled flue gases leaving the heat exchanger 7 are conveyed by means of a fan 15 into a filter device 16, which is designed as a dry filter in the form of a bag filter or the like, where they are cleaned.
- This filter device can be omitted if ash-free fuel is used.
- the flue gases are passed into a heat exchanger 17 and used there to preheat the combustion air. This is fed to the burner 2 via the pipeline 19.
- the flue gases are passed into the atmosphere via a chimney 18.
- the invention is not only limited to the drying of wood chips, wood fibers or the like, but also for other bulk materials, e.g. Fish meal, peat, coal, grain and sewage sludge, applicable.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Drying Of Solid Materials (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Radio Relay Systems (AREA)
- Mechanical Coupling Of Light Guides (AREA)
- Treatment Of Sludge (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Debarking, Splitting, And Disintegration Of Timber (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT91250134T ATE97225T1 (de) | 1990-06-01 | 1991-05-15 | Verfahren und anlage zur kontinuierlichen trocknung von holzspaenen, holzfasern oder anderen schuettguetern. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4017806A DE4017806A1 (de) | 1990-06-01 | 1990-06-01 | Verfahren und anlage zur kontinuierlichen trocknung von holzspaenen, holzfasern oder anderen schuettguetern |
| DE4017806 | 1990-06-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0459603A1 EP0459603A1 (de) | 1991-12-04 |
| EP0459603B1 true EP0459603B1 (de) | 1993-11-10 |
Family
ID=6407697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91250134A Revoked EP0459603B1 (de) | 1990-06-01 | 1991-05-15 | Verfahren und Anlage zur kontinuierlichen Trocknung von Holzspänen, Holzfasern oder anderen Schüttgütern |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5237757A (cs) |
| EP (1) | EP0459603B1 (cs) |
| JP (1) | JPH04227464A (cs) |
| AT (1) | ATE97225T1 (cs) |
| AU (1) | AU7806091A (cs) |
| CA (1) | CA2043681A1 (cs) |
| CZ (1) | CZ280448B6 (cs) |
| DE (2) | DE4017806A1 (cs) |
| ES (1) | ES2046848T3 (cs) |
| FI (1) | FI912615A7 (cs) |
| RU (1) | RU2023964C1 (cs) |
| ZA (1) | ZA914130B (cs) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1363097A1 (de) | 2002-05-13 | 2003-11-19 | Robert Dr. Bankwitz | Pneumatischer Schleudertrockner |
| EP3759056A4 (en) * | 2018-03-01 | 2022-05-11 | Steve Macchio | Systems and methods for environmentally-clean thermal drying |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2654811B1 (fr) * | 1989-11-20 | 1994-11-04 | Kurt Gisiger | Procede et installation pour secher des matieres organiques, notamment des particules de bois. |
| NL9100606A (nl) * | 1991-04-08 | 1992-11-02 | Vandenbroek Int Bv | Drooginrichting. |
| CA2163305A1 (en) * | 1994-11-24 | 1996-05-25 | Werner Kunz | Method for drying a substance, in particular wood shavings |
| US5603751A (en) * | 1995-06-02 | 1997-02-18 | Mac Equipment, Inc. | Method and apparatus for removing particulate material from a wood drying system |
| CA2154405A1 (en) * | 1995-07-21 | 1997-01-22 | Rene Besnard | Apparatus for drying crop materials |
| SE507409C2 (sv) * | 1995-10-19 | 1998-05-25 | Vattenfall Ab | Förfarande för bränslebehandling |
| US5758434A (en) * | 1996-11-12 | 1998-06-02 | Georgia-Pacific Corporation | Wood drying system |
| DE19654043C2 (de) * | 1996-12-23 | 1998-05-28 | Martin Dipl Ing Knabe | Trockner mit Abgasreinigung mittels thermischer Nachverbrennung |
| ATE288065T1 (de) * | 1998-06-11 | 2005-02-15 | Universal Dynamics Inc | Verfahren und vorrichtung zur trocknung von körnigen feststoffen durch venturigetriebene gaszirkulation |
| DE10011177A1 (de) * | 2000-03-08 | 2001-09-20 | Valmet Panelboard Gmbh | Verfahren und Vorrichtung zum direkten Trocknen von Teilchen |
| FI4752U1 (fi) * | 2000-08-24 | 2000-12-18 | Pauli Matias Haukka | Puutavaran kuivaus- ja lämpökäsittelylaitteisto |
| DE10056459C1 (de) * | 2000-11-14 | 2002-04-04 | Fraunhofer Ges Forschung | Verfahren zum Aufbereiten faseriger Substanzen |
| WO2002053995A1 (en) * | 2001-01-08 | 2002-07-11 | Advanced Dryer Systems, Inc. | Drying system with heat pipe heat recovery |
| DE10157596C1 (de) * | 2001-11-23 | 2003-03-20 | Fraunhofer Ges Forschung | Verfahren zum Aufbereiten faseriger Substanzen |
| EP1843114A1 (en) * | 2006-04-06 | 2007-10-10 | Swedish Exergy Consulting AB | Dryer plant |
| AU2008247574B2 (en) * | 2007-05-03 | 2012-03-22 | Archer-Daniels-Midland Company | A system for using heat to process an agricultural product, a fluidized bed combustor system, and methods of employing the same |
| ATE520939T1 (de) * | 2008-01-10 | 2011-09-15 | Douglas Technical Ltd | Verfahren zur kontinuierlichen trocknung von schüttgut, insbesondere von holzfasern und/oder holzspänen |
| RU2373467C1 (ru) * | 2008-07-14 | 2009-11-20 | Открытое акционерное общество "Сахпроект" (институт по проектированию предприятий сахарной, пищекислотной и других отраслей агропромышленного комплекса) | Устройство для рециркуляции агента сушки |
| EP2202474B1 (de) * | 2008-12-23 | 2011-06-29 | Kronotec AG | Holzzerkleinerungsprodukt-Trocknungsanlage |
| EP2230477B1 (de) * | 2009-03-10 | 2014-12-31 | Kronotec AG | Holzspantrocknungsanlage zum Trocknen von Holzspänen und zugehöriges Verfahren zum Trocknen von Holzspänen |
| EP2411749A4 (en) * | 2009-03-25 | 2016-01-20 | Saxlund Internat Holding Ab | SYSTEM AND METHOD FOR DRYING |
| RU2446371C2 (ru) * | 2010-06-09 | 2012-03-27 | Научно-производственная фирма с ограниченной ответственностью "Экополимер" | Устройство для сушки осадка, активного ила или отстоя промышленных и бытовых сточных вод |
| DE102010036425A1 (de) * | 2010-07-15 | 2012-01-19 | Polysius Ag | Vorrichtung und Verfahren zur Trocknung und Torrefizierung von wenigstens einem kohlenstoffhaltigen Stoffstrom in einem Etagenofen |
| CN101915497B (zh) * | 2010-08-13 | 2012-07-04 | 李相荣 | 用废热汽体制备过热蒸汽的褐煤干燥提质工艺 |
| RU2467269C1 (ru) * | 2011-05-20 | 2012-11-20 | Федеральное государственное образовательное учреждение высшего профессионального образования "Красноярский государственный аграрный университет" | Автономное устройство для сушки высоковлажного растительного сырья |
| US20150267963A1 (en) * | 2012-10-14 | 2015-09-24 | Applied Cleantech Inc. | Systems and devices for feedstock production from sewage |
| CN103148690B (zh) * | 2013-04-07 | 2015-01-21 | 江苏快乐木业集团有限公司 | 一种刨花干燥设备 |
| CN103722754B (zh) * | 2013-12-19 | 2016-05-04 | 中材科技股份有限公司 | 一种适用于中空复合材料生产线的固化装置 |
| ES3008104T3 (en) | 2017-03-03 | 2025-03-21 | Kronoplus Ltd | Apparatus and method for continuously drying bulk goods, in particular wood chips and/or wood fibers comprising a solid fired hot gas generator |
| CN110382958A (zh) * | 2017-03-03 | 2019-10-25 | 道格拉斯科技有限公司 | 用于连续干燥散装物品、特别是木屑和/或木纤维的包括热交换器的设备和方法 |
| EA201991750A1 (ru) | 2017-03-03 | 2020-02-28 | Дуглас Текникал Лимитед | Устройство и способ непрерывной сушки сыпучих продуктов, в частности древесной стружки и/или древесных волокон, включающие циклон для горячего газа |
| HUE071509T2 (hu) * | 2017-03-03 | 2025-09-28 | Kronoplus Ltd | Berendezés és eljárás ömlesztett áru, különösen faforgács és/vagy fa anyagú szálak folyamatos szárítására, többféle tüzelõanyaggal mûködõ égõvel és tokos hûtõberendezéssel |
| EA039585B1 (ru) | 2017-06-06 | 2022-02-14 | Дуглас Текникал Лимитед | Устройство и способ для непрерывной сушки насыпных материалов |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2254848B2 (de) * | 1972-11-09 | 1976-08-05 | Böhler-Zenkner GmbH & Co KG Strömungstechnik, 4005 Meerbusch | Anordnung zur thermischen nachverbrennung |
| CH559151A5 (cs) * | 1972-12-06 | 1975-02-28 | Seiler Hermann & Sohn Ag | |
| GB1429972A (en) * | 1973-08-24 | 1976-03-31 | Duur Kg Otto | Process of and apparatus for heating circulating air in drying quipment |
| DE2461415A1 (de) * | 1974-12-24 | 1976-07-08 | Hans Roos | Bruedenrueckfuehrungs- und verbrennungsanlage |
| US4231165A (en) * | 1977-06-22 | 1980-11-04 | Bruckner Apparatebau Gmbh | Process for heat-treating a fabric web |
| US4132007A (en) * | 1977-08-17 | 1979-01-02 | Voorheis James T | Single burner heater and incinerator |
| US4218832A (en) * | 1979-04-27 | 1980-08-26 | Champion International Corporation | Apparatus for processing wood products using heat from a boiler for indirectly heating drying gas |
| US4276835A (en) * | 1979-10-04 | 1981-07-07 | Von Roll Ag | method for processing sewage sludge |
| US4926567A (en) * | 1985-07-04 | 1990-05-22 | Fuji Photo Film Co., Ltd. | Process and apparatus for drying coated web |
| DE3605100A1 (de) * | 1986-02-18 | 1987-08-27 | Monforts Gmbh & Co A | Textilmaschine mit kontinuierlicher konvektiver waermebehandlung |
| DE3616333C1 (de) * | 1986-05-15 | 1987-04-16 | Krantz H Gmbh & Co | Verfahren zum thermischen Reinigen der Abgase einer Waermebehandlungsvorrichtung |
| US4715965A (en) * | 1986-05-19 | 1987-12-29 | Sigerson Adam L | Method for separating and recovering volatilizable contaminants from soil |
| DE3715668A1 (de) * | 1987-05-11 | 1988-12-01 | Baehre & Greten | Verfahren und anlage zum reinigen von trocknungsabgasen beim trocknen von holzspaenen, holzfasern oder dergleichen |
| US4759777A (en) * | 1987-11-10 | 1988-07-26 | Bact Engineering, Inc. | Decontamination of wood chip dryer gas |
| FR2654811B1 (fr) * | 1989-11-20 | 1994-11-04 | Kurt Gisiger | Procede et installation pour secher des matieres organiques, notamment des particules de bois. |
| CH676500A5 (cs) * | 1990-05-18 | 1991-01-31 | Werner Kunz |
-
1990
- 1990-06-01 DE DE4017806A patent/DE4017806A1/de not_active Withdrawn
-
1991
- 1991-05-15 AT AT91250134T patent/ATE97225T1/de not_active IP Right Cessation
- 1991-05-15 DE DE91250134T patent/DE59100574D1/de not_active Revoked
- 1991-05-15 ES ES199191250134T patent/ES2046848T3/es not_active Expired - Lifetime
- 1991-05-15 EP EP91250134A patent/EP0459603B1/de not_active Revoked
- 1991-05-28 US US07/706,687 patent/US5237757A/en not_active Expired - Fee Related
- 1991-05-30 AU AU78060/91A patent/AU7806091A/en not_active Abandoned
- 1991-05-30 ZA ZA914130A patent/ZA914130B/xx unknown
- 1991-05-30 JP JP3127930A patent/JPH04227464A/ja active Pending
- 1991-05-31 CZ CS911635A patent/CZ280448B6/cs unknown
- 1991-05-31 FI FI912615A patent/FI912615A7/fi not_active Application Discontinuation
- 1991-05-31 CA CA002043681A patent/CA2043681A1/en not_active Abandoned
- 1991-05-31 RU SU914895596A patent/RU2023964C1/ru active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1363097A1 (de) | 2002-05-13 | 2003-11-19 | Robert Dr. Bankwitz | Pneumatischer Schleudertrockner |
| DE10221367B4 (de) * | 2002-05-13 | 2006-05-11 | Bankwitz, Robert, Dr. | Pneumatischer Schleudertrockner |
| EP3759056A4 (en) * | 2018-03-01 | 2022-05-11 | Steve Macchio | Systems and methods for environmentally-clean thermal drying |
Also Published As
| Publication number | Publication date |
|---|---|
| AU7806091A (en) | 1991-12-05 |
| CZ280448B6 (cs) | 1996-01-17 |
| JPH04227464A (ja) | 1992-08-17 |
| CA2043681A1 (en) | 1991-12-02 |
| DE4017806A1 (de) | 1991-12-05 |
| DE59100574D1 (de) | 1993-12-16 |
| ZA914130B (en) | 1992-03-25 |
| FI912615A7 (fi) | 1991-12-02 |
| ES2046848T3 (es) | 1994-02-01 |
| CS163591A3 (en) | 1992-02-19 |
| EP0459603A1 (de) | 1991-12-04 |
| US5237757A (en) | 1993-08-24 |
| ATE97225T1 (de) | 1993-11-15 |
| FI912615A0 (fi) | 1991-05-31 |
| RU2023964C1 (ru) | 1994-11-30 |
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