EP0409191B1 - Reinigungsmittel für Epoxidharzbeschichtung auf Platten, Fliesen etc. - Google Patents
Reinigungsmittel für Epoxidharzbeschichtung auf Platten, Fliesen etc. Download PDFInfo
- Publication number
- EP0409191B1 EP0409191B1 EP90113752A EP90113752A EP0409191B1 EP 0409191 B1 EP0409191 B1 EP 0409191B1 EP 90113752 A EP90113752 A EP 90113752A EP 90113752 A EP90113752 A EP 90113752A EP 0409191 B1 EP0409191 B1 EP 0409191B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- epoxy resin
- soap
- organic solvent
- cleaning agent
- ceramic tiles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 11
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 11
- 239000012459 cleaning agent Substances 0.000 title description 2
- 239000000919 ceramic Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 239000000344 soap Substances 0.000 claims abstract description 13
- 239000003960 organic solvent Substances 0.000 claims abstract description 12
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002148 esters Chemical group 0.000 claims description 3
- 159000000001 potassium salts Chemical class 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims 1
- 239000012895 dilution Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011440 grout Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000013043 chemical agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
Definitions
- Epoxy resin has the property of reacting very quickly. For this reason, one must work very carefully on the one hand, i.e. care must be taken to ensure that the epoxy grout only reaches the joint to be processed and not the tiles immediately adjacent to it. If the grout is still on the tile, it must be removed immediately, because otherwise it can no longer be removed or only with great effort. But even if the processor responds immediately, removal is only possible with great difficulty.
- CH-PS 670 832 describes an organic, chlorohydrocarbon-free stripping, solvent and paint remover which is composed of a resin solvent from the group of the esters, a swelling agent from the group of oxygen heterocycles, a solvent for surfactants and thickeners, one or more surfactants from the group of alkylbenzenesulfonates and one or more thickeners from the group of alkylhydroxyalkylcelluloses, the agent containing one or more aprotic or non-aprotic polar solubilizers. Only organic solvents or solubilizers are used to achieve homogeneous mixing of the components. However, these organic solvents are undesirable for reasons of environmental protection and efforts are being made in the development of cleaning agents to greatly reduce their proportion or to dispense with them entirely.
- US-A-2,064,725 relates to an aqueous detergent composition which contains a soap and at least one organic solvent, for example ethyl acetate, butyl acetate, pentyl acetate, which serves as a paint solvent.
- This detergent composition is suitable for removing cellulose lacquer layers, paints, enamel lacquers, glazes, printing inks and similar materials from the skin without affecting them too much when the agent is used.
- the composition In order to achieve a suitable cleaning effect, the composition must additionally contain an abrasive.
- Such an abrasive-containing detergent composition can only be used for purposes in which the abrasive effect of the abrasive cannot cause any damage to the surface to be cleaned.
- the invention has for its object to facilitate the cleaning of smeared with epoxy resin tiles.
- aqueous emulsion which contains a soap and a suitable organic solvent for hardened epoxy resins, the proportion of the soap being 10 to 30% by weight, based on the organic solvent.
- esters of lower fatty acids with lower alcohols are preferred.
- Butyl acetate proved to be particularly suitable.
- Soaps suitable for the purposes of the invention are the sodium or potassium salts of saturated and unsaturated higher fatty acids, resin acids, rosin and naphthenic acids, which are commercially available as solid or semi-solid mixtures.
- the potassium salts of higher fatty acids, the so-called soft soaps or potassium soaps have proven to be particularly suitable. Their proportion is significantly higher than is necessary only for the emulsification of the organic solvent and is about 10 to 30%, in particular 15 to 25% by weight of the amount of the organic solvent.
- a mixture which has been found to be very suitable for removing epoxy resins from plates or tiles has been obtained by diluting a mixture of 100 liters of butyl acetate and 20 kg of soft soap with 500 liters of cold water.
- the product thus produced can be filled into canisters and is ready for use in this form.
- epoxy resins can be removed easily and effectively without any residues and thus free of fog. It can also be used to remove spots that were discovered afterwards. This removal of any residues of epoxy grout is achieved in a much shorter time than with the previously known methods. The time saved compared to the conventional way of working is more than 50%.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
- Epoxy Resins (AREA)
- Finishing Walls (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3923905 | 1989-07-19 | ||
DE3923905A DE3923905C1 (enrdf_load_stackoverflow) | 1989-07-19 | 1989-07-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0409191A2 EP0409191A2 (de) | 1991-01-23 |
EP0409191A3 EP0409191A3 (en) | 1991-07-31 |
EP0409191B1 true EP0409191B1 (de) | 1996-03-06 |
Family
ID=6385394
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90113752A Expired - Lifetime EP0409191B1 (de) | 1989-07-19 | 1990-07-18 | Reinigungsmittel für Epoxidharzbeschichtung auf Platten, Fliesen etc. |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0409191B1 (enrdf_load_stackoverflow) |
AT (1) | ATE135039T1 (enrdf_load_stackoverflow) |
DE (2) | DE3923905C1 (enrdf_load_stackoverflow) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9592476B2 (en) | 2014-05-30 | 2017-03-14 | Pall Corporation | Membrane comprising self-assembled block copolymer and process for producing the same by hybrid casting (IIb) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE87274C (enrdf_load_stackoverflow) * | ||||
US2064725A (en) * | 1936-03-06 | 1936-12-15 | Thurlow G Gregory | Detergent composition |
DE2910807C2 (de) * | 1979-03-20 | 1982-07-15 | Basf Ag, 6700 Ludwigshafen | Poliermittelmischung zum Polieren der Oberflächen von Magnetspeicherplatten |
CH670832A5 (en) * | 1987-03-19 | 1989-07-14 | Rico S A Lausanne | Paint and varnish stripping compsn. - comprising chloro-hydrocarbon free resin solubiliser, swelling agent, solvent for surfactant, surfactant, thickener and dissolving assistant |
-
1989
- 1989-07-19 DE DE3923905A patent/DE3923905C1/de not_active Expired - Lifetime
-
1990
- 1990-07-18 EP EP90113752A patent/EP0409191B1/de not_active Expired - Lifetime
- 1990-07-18 DE DE59010172T patent/DE59010172D1/de not_active Expired - Fee Related
- 1990-07-18 AT AT90113752T patent/ATE135039T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE3923905C1 (enrdf_load_stackoverflow) | 1991-02-07 |
EP0409191A2 (de) | 1991-01-23 |
ATE135039T1 (de) | 1996-03-15 |
DE59010172D1 (de) | 1996-04-11 |
EP0409191A3 (en) | 1991-07-31 |
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