EP0388444A1 - Verwendung eines silikons als überzug für die mit der menschlichen haut in direktem kontakt stehenden oberflächen metallischer gegenstände - Google Patents
Verwendung eines silikons als überzug für die mit der menschlichen haut in direktem kontakt stehenden oberflächen metallischer gegenständeInfo
- Publication number
- EP0388444A1 EP0388444A1 EP89907077A EP89907077A EP0388444A1 EP 0388444 A1 EP0388444 A1 EP 0388444A1 EP 89907077 A EP89907077 A EP 89907077A EP 89907077 A EP89907077 A EP 89907077A EP 0388444 A1 EP0388444 A1 EP 0388444A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silicone
- coating
- metallic objects
- direct contact
- human skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 20
- 239000011248 coating agent Substances 0.000 title claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 16
- 206010020751 Hypersensitivity Diseases 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000007815 allergy Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000011505 plaster Substances 0.000 description 4
- 239000004447 silicone coating Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000006223 plastic coating Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 208000010201 Exanthema Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000013566 allergen Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 231100000046 skin rash Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C27/00—Making jewellery or other personal adornments
- A44C27/001—Materials for manufacturing jewellery
- A44C27/005—Coating layers for jewellery
- A44C27/007—Non-metallic coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Definitions
- Nail polish on the other hand, is not what i expected.
- the plasticizers are required in order to give the coating obtained after the application and drying of the nail polish the necessary elasticity and sufficient adhesive strength on the nail surface.
- plasticizers have the disadvantage that they gradually "exude”, i.e. detaching itself from the coating This ultimately leads to the coating becoming porous, no longer adhering to the metal surface and finally chipping off. The protective function of such a coating is accordingly low.
- plasticizers are sometimes all genes themselves, which then trigger corresponding reactions on the skin.
- Measures which are suitable for protecting human skin when we come into direct contact with the surfaces of metallic objects are as little known as coatings, which are effective for protecting human skin when we come into direct contact with the surfaces of metallic objects. There is therefore no doubt that there is a great need for such measures or coatings.
- the object of the invention is therefore the production of metallic objects with effective protection against allergic reactions of the organism.
- the object is achieved in that a silicone as a coating is in direct contact with human skin Surfaces of metallic objects is used. Surprisingly, it was found that the silicone used in accordance with the invention leads to metallic objects which have an adherent and effective protection against allergic reactions.
- the silicone is applied to the surfaces of the metallic objects in direct contact with the skin in a thin liquid form and the coating thus obtained is allowed to air dry.
- the silicone is applied advantageously and preferably with a small brush or with a spray device, the silicone flowing onto the surfaces in question to form a coherent thin protective film.
- the application of the silicone coating is thus carried out in a particularly simple manner and nevertheless ensures that the coating extends into the corners, over edges and into the turns of the surface.
- the applied silicone coating adheres firmly to the surfaces concerned after drying and this represents a transparent and impermeable protective film.
- the plastic is also used here for a coating on metal surfaces, but that it has a completely different purpose in that it is not intended to protect against allergies from metal objects which are in direct contact with the skin, but rather the nails , Skin, etc. from allergies that come into contact with nickel particles that are contained in nail polish and come from metal objects that are not in direct contact with the skin.
- the problems that arise are very different to be judged as that of the present case.
- the plastic used as a coating is resistant to the solvents contained in the nail polish, not that the plastic does not trigger any allergic reactions on the skin (which, as is well known, many plastics do) , and simply not because the plastic does not come into direct contact with the skin at all.
- the selection criteria for the plastic are therefore completely different than for the plastic in the present invention.
- the silicone coatings adhere very well to the metal surfaces, although they do not contain any plasticizers, and that the plastic used for the coating is an allergen.
- the silicone used for the coating is a silicone rubber, namely a dimethylpolysiloxane with an addition of pyrogenic
- the density of the rubber at 23 ° C. was 1.066 g / ml and that Viscosity at 23 ° C, measured in a Brookfield rotary viscometer: 10,000 mPa s.
- the silicone rubber used is a commercially available product.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Materials Engineering (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19883822141 DE3822141C1 (enrdf_load_stackoverflow) | 1988-06-30 | 1988-06-30 | |
DE3822141 | 1988-06-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0388444A1 true EP0388444A1 (de) | 1990-09-26 |
Family
ID=6357655
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89907077A Ceased EP0388444A1 (de) | 1988-06-30 | 1989-06-24 | Verwendung eines silikons als überzug für die mit der menschlichen haut in direktem kontakt stehenden oberflächen metallischer gegenstände |
Country Status (5)
Country | Link |
---|---|
US (1) | US5075126A (enrdf_load_stackoverflow) |
EP (1) | EP0388444A1 (enrdf_load_stackoverflow) |
JP (1) | JPH03502709A (enrdf_load_stackoverflow) |
DE (1) | DE3822141C1 (enrdf_load_stackoverflow) |
WO (1) | WO1990000185A1 (enrdf_load_stackoverflow) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4214304A1 (de) * | 1992-04-30 | 1993-11-04 | Deutsche Nickel Ag | Nickelfreie buntmetallegierung und deren verwendung |
US5535603A (en) * | 1994-11-30 | 1996-07-16 | Twallje Co., Ltd. | Accessorial device |
DE19708162A1 (de) * | 1997-02-28 | 1998-09-03 | Brock Werner Dr Ing | Verfahren zur Erzeugung von Beschichtungsmaterialien als Diffusionsbarriere für Schwermetalle |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3187752A (en) * | 1962-04-27 | 1965-06-08 | American Cyanamid Co | Non-absorbable silicone coated sutures and method of making |
GB1264228A (enrdf_load_stackoverflow) * | 1969-05-17 | 1972-02-16 | ||
GB1447254A (en) * | 1973-08-16 | 1976-08-25 | Ici Ltd | Pharmaceutical compositions |
DE2556665C3 (de) * | 1975-12-16 | 1978-08-03 | Titmus Eurocon Kontaktlinsen Kg, 8750 Aschaffenburg | Intraokulare künstliche Augenlinse |
DE2737146A1 (de) * | 1977-08-17 | 1979-03-01 | Marwitz & Hausner | Buegel fuer brillen |
US4324712A (en) * | 1978-11-30 | 1982-04-13 | General Electric Company | Silicone resin coating composition |
GB2043040B (en) * | 1978-12-07 | 1982-12-15 | Tokyo Ohka Kogyo Co Ltd | Method for preventing leaching of contaminants from solid surfaces |
JPS6053057B2 (ja) * | 1979-03-22 | 1985-11-22 | 信越化学工業株式会社 | シリコ−ン系ゴム成形体を支持体に固着する方法 |
DE7916275U1 (de) * | 1979-06-06 | 1980-11-20 | Marwitz & Hauser, 7000 Stuttgart | Brille mit einer Schicht |
DE2938241C2 (de) * | 1979-09-21 | 1982-06-03 | Ludwig 7920 Heidenheim Nutz | Verfahren zum Bearbeiten von Brillengestellen, um diese rutschfest zu machen |
US4495254A (en) * | 1981-05-18 | 1985-01-22 | Westinghouse Electric Corp. | Protectively-coated gold-plated article of jewelry or wristwatch component |
DE3212686A1 (de) * | 1982-04-05 | 1983-10-06 | Marwitz & Hausner | Brillen-sattelsteg |
JPS5943070A (ja) * | 1982-09-02 | 1984-03-09 | Seiko Epson Corp | 硬化膜を有する複合体 |
DE3407093A1 (de) * | 1984-02-28 | 1985-08-29 | Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt | Verfahren zur passivierung einer metallischen oberflaeche |
-
1988
- 1988-06-30 DE DE19883822141 patent/DE3822141C1/de not_active Expired
-
1989
- 1989-06-24 JP JP1506647A patent/JPH03502709A/ja active Pending
- 1989-06-24 US US07/490,663 patent/US5075126A/en not_active Expired - Fee Related
- 1989-06-24 WO PCT/DE1989/000421 patent/WO1990000185A1/de not_active Application Discontinuation
- 1989-06-24 EP EP89907077A patent/EP0388444A1/de not_active Ceased
Non-Patent Citations (1)
Title |
---|
See references of WO9000185A1 * |
Also Published As
Publication number | Publication date |
---|---|
JPH03502709A (ja) | 1991-06-20 |
WO1990000185A1 (de) | 1990-01-11 |
US5075126A (en) | 1991-12-24 |
DE3822141C1 (enrdf_load_stackoverflow) | 1989-05-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19900701 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH FR GB IT LI LU NL |
|
17Q | First examination report despatched |
Effective date: 19930413 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
18R | Application refused |
Effective date: 19931008 |