EP0372471B1 - Verfahren zur Herstellung von niedrigen aliphatischen Kohlenwasserstoffen - Google Patents

Verfahren zur Herstellung von niedrigen aliphatischen Kohlenwasserstoffen Download PDF

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Publication number
EP0372471B1
EP0372471B1 EP89122377A EP89122377A EP0372471B1 EP 0372471 B1 EP0372471 B1 EP 0372471B1 EP 89122377 A EP89122377 A EP 89122377A EP 89122377 A EP89122377 A EP 89122377A EP 0372471 B1 EP0372471 B1 EP 0372471B1
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EP
European Patent Office
Prior art keywords
catalyst
reaction
carbon atoms
hydrocarbon
paraffin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89122377A
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English (en)
French (fr)
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EP0372471A1 (de
Inventor
Kazunori Mitsui Petrochem. Ind. Ltd. Takahata
Toshihiro Mitsui Petrochem. Ind. Ltd. Murashige
Yukimasa Mitsui Petrochem. Ind. Ltd. Shigemura
Hiroshi Mitsui Petrochem. Ind. Ltd. Takaki
Akihiko Mitsui Petrochem. Ind. Ltd. Okano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Research Association for Utilization of Light Oil
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Research Association for Utilization of Light Oil
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Filing date
Publication date
Priority claimed from JP63307271A external-priority patent/JPH02151689A/ja
Priority claimed from JP63307270A external-priority patent/JPH02151688A/ja
Priority claimed from JP1051546A external-priority patent/JPH02231436A/ja
Priority claimed from JP1135364A external-priority patent/JPH02311426A/ja
Application filed by Research Association for Utilization of Light Oil filed Critical Research Association for Utilization of Light Oil
Priority to AT89122377T priority Critical patent/ATE102914T1/de
Publication of EP0372471A1 publication Critical patent/EP0372471A1/de
Application granted granted Critical
Publication of EP0372471B1 publication Critical patent/EP0372471B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B11/00—Recovery or refining of other fatty substances, e.g. lanolin or waxes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Claims (6)

  1. Verfahren zur Herstellung eines niedrigen aliphatischen Kohlenwasserstoffes, umfassend ein Olefin mit 3 oder 4 Kohlenstoffatomen als die Hauptkomponente, von einem Paraffin mit 5 bis 10 Kohlenstoffatomen oder einem Kohlenwasserstoff, umfassend dieses Paraffin als die Hauptkomponente, umfassend das katalytische Cracken eines Paraffins mit 5 bis 10 Kohlenstoffatomen oder eines Kohlenwasserstoffes, umfassend dieses Paraffin als die Hauptkomponente, in der Gegenwart eines katalytischen Crackkatalysators mit einer starken Azidität, der sich aus einem Mordenit zusammensetzt, umfassend eine Seltenerdmetallkomponente, eingeführt durch Ionenaustausch, oder eine feste superstakre Säure, gebildet durch Tragen eines Schwefelsäureions auf einem Träger, der sich aus Zr(OH)₄, ZrO₂, H₄TiO₄, TiO₂ oder Fe₂O₃ zusammensetzt, und das Dehydrieren des Kohlenwasserstoffes, umfassend ein Paraffin mit 3 oder 4 Kohlenstoffatomen, als die Hauptkomponente, erhalten bei dem katalytischen Cracken, mit einem Dehydrierungskatalysator in ein Olefin mit 3 oder 4 Kohlenstoffatomen als die Hauptkomponente.
  2. Verfahren nach Anspruch 1, worin die Seltenerdmetallkomponente in einer Menge von 0,1 bis 10 Gew.% als das Oxid enthalten ist.
  3. Verfahren nach Anspruch 1, worin die Seltenerdmetallkomponente Lanthan oder Cer ist.
  4. Verfahren nach Anspruch 1, worin der Dehydrierungskatalysator ein Aluminiumoxid/Chromoxid-Katalysator, ein Eisenoxid/Chromoxid-Katalysator oder ein edelmetallhaltiger Katalysator ist.
  5. Verfahren nach Anspruch 1, worin die katalytische Crack-Reaktion bei einer Temperatur von 250 bis 580°C durchgeführt wird, und die Dehydrierungsreaktion bei einer Temperatur von 450 bis 600°C durchgeführt wird.
  6. Verfahren nach Anspruch 1, worin die katalytische Crack-Reaktion durch Kontaktieren des Ausgangskohlenwasserstoffes mit dem katalytischen Crackkatalysator in einem Fließbett bewirkt wird.
EP89122377A 1988-12-05 1989-12-05 Verfahren zur Herstellung von niedrigen aliphatischen Kohlenwasserstoffen Expired - Lifetime EP0372471B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89122377T ATE102914T1 (de) 1988-12-05 1989-12-05 Verfahren zur herstellung von niedrigen aliphatischen kohlenwasserstoffen.

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP307271/88 1988-12-05
JP63307271A JPH02151689A (ja) 1988-12-05 1988-12-05 低級脂肪族炭化水素の製造方法
JP307270/88 1988-12-05
JP63307270A JPH02151688A (ja) 1988-12-05 1988-12-05 低級脂肪族炭化水素の製造方法
JP1051546A JPH02231436A (ja) 1989-03-03 1989-03-03 低級脂肪族炭化水素の製造方法
JP51546/89 1989-03-03
JP135364/89 1989-05-29
JP1135364A JPH02311426A (ja) 1989-05-29 1989-05-29 オレフィンを主成分とする低級脂肪族炭化水素の製造方法

Publications (2)

Publication Number Publication Date
EP0372471A1 EP0372471A1 (de) 1990-06-13
EP0372471B1 true EP0372471B1 (de) 1994-03-16

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EP89122377A Expired - Lifetime EP0372471B1 (de) 1988-12-05 1989-12-05 Verfahren zur Herstellung von niedrigen aliphatischen Kohlenwasserstoffen

Country Status (5)

Country Link
US (1) US5191131A (de)
EP (1) EP0372471B1 (de)
KR (1) KR920002241B1 (de)
CA (1) CA2004584A1 (de)
DE (1) DE68913922T2 (de)

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US6696388B2 (en) * 2000-01-24 2004-02-24 E. I. Du Pont De Nemours And Company Gel catalysts and process for preparing thereof
ES2585891T3 (es) 2004-04-28 2016-10-10 Headwaters Heavy Oil, Llc Métodos y sistemas de hidroprocesamiento en lecho en ebullición
ES2583505T3 (es) * 2004-04-28 2016-09-21 Headwaters Heavy Oil, Llc Método de hidroprocesamiento y sistema para mejorar aceite pesado
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
RU2393203C2 (ru) 2004-04-28 2010-06-27 Хедуотерс Хэви Ойл, Ллс Способы и системы водородообработки и способы улучшения существующей системы с неподвижным слоем
CN100338186C (zh) * 2005-04-29 2007-09-19 中国石油化工股份有限公司 一种石油烃类裂化催化剂
CN101348409B (zh) * 2007-07-19 2011-06-15 中国石油化工股份有限公司 一种生产低碳烯烃的方法
US8034232B2 (en) * 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) * 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US9150465B2 (en) * 2010-09-21 2015-10-06 Uop Llc Integration of cyclic dehydrogenation process with FCC for dehydrogenation of refinery paraffins
WO2012088025A2 (en) 2010-12-20 2012-06-28 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
CN104530984B (zh) * 2014-12-02 2016-10-05 铜仁学院 一种固体超强酸催化裂解松香的方法
WO2017003812A1 (en) 2015-07-02 2017-01-05 Saudi Arabian Oil Company Dual catalyst system for propylene production
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
WO2018047093A1 (en) * 2016-09-12 2018-03-15 Sabic Global Technologies B.V. Hydrocracking process
US10329225B2 (en) 2017-01-20 2019-06-25 Saudi Arabian Oil Company Dual catalyst processes and systems for propylene production
US10550048B2 (en) 2017-01-20 2020-02-04 Saudi Arabian Oil Company Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking
US10934231B2 (en) * 2017-01-20 2021-03-02 Saudi Arabian Oil Company Multiple-stage catalyst systems and processes for propene production
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
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US10961171B2 (en) 2018-10-10 2021-03-30 Saudi Arabian Oil Company Catalysts systems that include metal co-catalysts for the production of propylene
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Also Published As

Publication number Publication date
KR900009947A (ko) 1990-07-06
US5191131A (en) 1993-03-02
DE68913922D1 (de) 1994-04-21
KR920002241B1 (ko) 1992-03-20
DE68913922T2 (de) 1994-07-21
CA2004584A1 (en) 1990-06-05
EP0372471A1 (de) 1990-06-13

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