EP0329705B1 - Verfahren und vorrichtung zur kühlung und entstaubung von hochtemperaturkoks - Google Patents
Verfahren und vorrichtung zur kühlung und entstaubung von hochtemperaturkoks Download PDFInfo
- Publication number
- EP0329705B1 EP0329705B1 EP87907757A EP87907757A EP0329705B1 EP 0329705 B1 EP0329705 B1 EP 0329705B1 EP 87907757 A EP87907757 A EP 87907757A EP 87907757 A EP87907757 A EP 87907757A EP 0329705 B1 EP0329705 B1 EP 0329705B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coke
- immersion
- water
- cooling
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000571 coke Substances 0.000 title claims abstract description 109
- 238000001816 cooling Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000000428 dust Substances 0.000 title claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 238000001704 evaporation Methods 0.000 claims abstract description 19
- 238000007654 immersion Methods 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 7
- 239000013505 freshwater Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 description 7
- 239000000112 cooling gas Substances 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000002309 gasification Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 241000273930 Brevoortia tyrannus Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
- C10B39/02—Dry cooling outside the oven
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
- C10B39/04—Wet quenching
Definitions
- the invention relates to a method of cooling and dedusting of Kochtemperaturkoks in at least two stages, where the coke is cooled in the first stage to below about 800 o C, and to apparatus for performing the method with the features in the preamble of claim. 8
- DE-OS 25 33 606 a two-step process is described for cooling of coke, wherein said coke is cooled initially in giving current with the aid of an inert gas in a first closed container of 1100 o C to about 315-425 o C and thereafter in a sprayed closed container with water and the evaporation of the water to reduce the temperature of the coke to 95 to 150 o C.
- the steam rises and entrains dust particles, so that the exhaust gases have to be cleaned before being released into the atmosphere.
- the object of the invention is to improve the generic method for cooling and dedusting high-temperature coke and the device for carrying out the method in such a way that the environmental problems, in particular the dust problems when loading the coke, are largely eliminated and that the method is furthermore for coke dry cooling is simplified in view of a cheaper design.
- the energy of the coke is sometimes used considerably less in the first stage and therefore less steam is generated than in other known processes.
- This is particularly useful for coke oven plants, at who lack the ability to deliver large quantities of high-tension steam to external consumers.
- the actual coke dry cooling chamber can be provided smaller and in particular with a much lower overall height.
- the coke temperature is lowered so far in the first stage before the water immersion that the gasification reactions proceeding accelerated at higher temperatures are largely suppressed in the process according to the invention.
- the hot coke can expediently only be indirectly cooled to approx. 600 o C and either give off the heat to cooling surfaces installed in the shaft or on a continuously rotating hot coke conveyor belt to radiation cooling surfaces arranged above and below the conveyor belt.
- a direct cooling with cooling gas counter-current of coke can be appropriately selected depending are cooled to about 400 o C by the quantity and temperature of the cooling gas under certain circumstances.
- the coke can be rapidly cooled below 800 o C, preferably to about 600-650 o C, by introducing hot steam at about 120 ° C., so that there is no gasification of the coke.
- the steam drawn off at approx. 500 to 600 o C can either be used for preheating coal or for generating high-pressure steam in a waste heat boiler.
- the coke can be continuously cooled in the first stage to the temperature of 200 to 800 ° C., preferably 400-650 ° C., mentioned above , and then added to the subsequent immersion container in a closed system.
- the coke is conveyed through a water bath in a short time, whereby due to the short dwell time of the coke in the water bath there is generally no complete heat exchange within the coke pieces between the grain surface and the grain interior. Therefore, the coke is then kept in a third stage in a closed post-evaporation tank.
- there is an intensive heat exchange within the coke bed between the interior of the grain and the grain surface whereby a large part of the water adhering to the surface is evaporated and drawn off.
- the intensive heat exchange is promoted by the released water vapor, which then flows through the coke bed and can also be circulated.
- the coke leaves the post-evaporation tank with a uniform temperature and water content which does not change significantly during further loading.
- dust particles can no longer loosen during the further treatment of the coke, so that dust emissions are avoided. Dipping times of less than 3 minutes, preferably 10 to 60 seconds, are sufficient to almost completely detach the coke dust adhering to the coke piece and to discharge it to the sewage treatment plant with the rinse water. The adhering coke dust is no longer carried into the subsequent evaporation container.
- the coke has a relatively low water content after leaving the post-evaporation tank, which is favorable for later use in the blast furnace.
- the temperature of the coke after leaving the Nachverdampfungs constituteers is preferably to 70 - 80 o C, so that an undesirable steam development during the further transport of the coke can be turned to open conveyors substantially below the evaporation temperature.
- the water vapor formation is relatively low in direct immersion.
- the water vapor can be drawn off from the closed container and processed in a simple manner on the raw gas cleaning side of the coking plant, preferably by introducing it into the raw gas receiver.
- Even in the immersion tank a large part of the water vapor is condensed again by constant sprinkling over the entire surface of the water basin. The same happens when the steam is introduced into the receiver with the help of the water sprinkling there.
- cold fresh water and cooled circulating water from the sewage treatment plant keep the water temperature in the plunge pool at approx. 60 to 80 o C, so that as much of the heat contained in the coke as possible is dissipated via the heating of the water and thus little water vapor is generated.
- a device according to claim 8 is proposed, wherein the coke discharge from the coke drying chute or the hot coke conveyor belt and the immersion tank and the downstream post-evaporation tank are each connected to one another in a gastight manner, so that no emissions occur when the coke is transferred from one tank to another can.
- the lower end of the filler neck can be immersed in the water of the immersion container and a dense coke bed can be kept in the entire filler neck and the outlet funnel.
- a backflow of water vapor can be prevented with the help of a butterfly valve in the absence of coke.
- the coke discharge device from the coke dry cooling can also be designed without the usual lock bunkers or gas-tight discharge locks.
- the discharge on non-gas-tight conveying bodies, such as. B. discharge rockers are limited.
- the antechamber (19) in the figure is filled with one or more coke transport bucket fillings in a manner known per se and the coke slides continuously over the coke feed (2) into the coke drying cooling shaft (1). There it gives off heat either indirectly to the cooling walls (6) and / or directly to the cooling gases, which are supplied or discharged via the connections (3/5) in countercurrent (solid arrows) or in direct current (dashed arrows). In the latter case, the Connection (3) about 120 o C hot water vapor for direct current cooling of the coke, which is drawn off at the lower end of the cooling chamber below the discharge rockers (20) via the cooling gas suction (5) at a temperature of 500 to 600 o C. After leaving the dry cooling zone, the coke has a temperature of approx.
- the residence time of the coke in the water immersion bath is determined by the speed of the coke conveyor (13), which is circulated around the deflection rollers (11) and expediently consists of a plate conveyor with sieve-shaped plates.
- the coke conveyor (13) there is a scraper conveyor (18), with the help of which the coke particles separated from the coke are transported to the water outlet (16).
- the coke conveyor (13) With the coke conveyor (13) the coke is brought directly into the gas-tight adjoining the immersion tank (8) subsequent evaporation tank (14), from which the coke after a certain time in a manner known per se, for. B. is withdrawn via locks or cellular wheels on the coke discharge (15).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Coke Industry (AREA)
- Processing Of Solid Wastes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87907757T ATE88209T1 (de) | 1986-11-08 | 1987-11-09 | Verfahren und vorrichtung zur kuehlung und entstaubung von hochtemperaturkoks. |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19863638165 DE3638165A1 (de) | 1986-11-08 | 1986-11-08 | Verfahren zur kuehlung und entstaubung von koks nach verlassen einer kokstrockenkuehlung |
DE3638166 | 1986-11-08 | ||
DE3638166 | 1986-11-08 | ||
DE3638165 | 1986-11-08 | ||
DE19873715355 DE3715355A1 (de) | 1986-11-08 | 1987-05-08 | Verfahren und vorrichtung zur kuehlung und entstaubung von hochtemperaturkoks |
DE3715355 | 1987-05-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0329705A1 EP0329705A1 (de) | 1989-08-30 |
EP0329705B1 true EP0329705B1 (de) | 1993-04-14 |
Family
ID=27195080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87907757A Expired - Lifetime EP0329705B1 (de) | 1986-11-08 | 1987-11-09 | Verfahren und vorrichtung zur kühlung und entstaubung von hochtemperaturkoks |
Country Status (9)
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100960379B1 (ko) * | 2008-07-18 | 2010-05-28 | 주식회사 포스코 | 코크스 분진 집진설비의 분진 처리장치 |
ITMI20130826A1 (it) * | 2013-05-21 | 2014-11-22 | Ambiente E Nutrizione Srl | Procedimento per lo spegnimento di coke |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE377006C (de) * | 1923-06-09 | Georgs Marien Bergwerks Und Hu | Koksloesch- und Verladewagen mit endlosem Foerderband | |
US3959084A (en) * | 1974-09-25 | 1976-05-25 | Dravo Corporation | Process for cooling of coke |
US4100034A (en) * | 1976-07-19 | 1978-07-11 | Peabody Coal Company | Quenching method |
DE3523897C1 (de) * | 1985-02-21 | 1986-08-14 | Carl Still Gmbh & Co Kg, 4350 Recklinghausen | Verfahren zur Kuehlung und Entstaubung von Koks nach Verlassen der Kokstrockenkuehlung |
-
1987
- 1987-11-09 AT AT87907757T patent/ATE88209T1/de not_active IP Right Cessation
- 1987-11-09 WO PCT/EP1987/000693 patent/WO1988003549A1/de active IP Right Grant
- 1987-11-09 AU AU82770/87A patent/AU8277087A/en not_active Abandoned
- 1987-11-09 KR KR1019880700801A patent/KR950006548B1/ko not_active Expired - Fee Related
- 1987-11-09 BR BR8707867A patent/BR8707867A/pt not_active IP Right Cessation
- 1987-11-09 JP JP63500038A patent/JP2532636B2/ja not_active Expired - Lifetime
- 1987-11-09 EP EP87907757A patent/EP0329705B1/de not_active Expired - Lifetime
- 1987-11-09 DE DE8787907757T patent/DE3785456D1/de not_active Expired - Fee Related
-
1988
- 1988-04-22 IN IN325/CAL/88A patent/IN170882B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP0329705A1 (de) | 1989-08-30 |
KR890700155A (ko) | 1989-03-10 |
KR950006548B1 (ko) | 1995-06-16 |
WO1988003549A1 (en) | 1988-05-19 |
AU8277087A (en) | 1988-06-01 |
DE3785456D1 (de) | 1993-05-19 |
ATE88209T1 (de) | 1993-04-15 |
BR8707867A (pt) | 1989-10-03 |
IN170882B (enrdf_load_stackoverflow) | 1992-06-06 |
JP2532636B2 (ja) | 1996-09-11 |
JPH02500752A (ja) | 1990-03-15 |
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