EP0317599A1 - Fireproof sealbag and process for the production of thermo-swelling pad - Google Patents
Fireproof sealbag and process for the production of thermo-swelling padInfo
- Publication number
- EP0317599A1 EP0317599A1 EP88904601A EP88904601A EP0317599A1 EP 0317599 A1 EP0317599 A1 EP 0317599A1 EP 88904601 A EP88904601 A EP 88904601A EP 88904601 A EP88904601 A EP 88904601A EP 0317599 A1 EP0317599 A1 EP 0317599A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gel
- fireproof
- volume
- grains
- dried
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 15
- 230000008569 process Effects 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000000463 material Substances 0.000 claims abstract description 32
- 230000008961 swelling Effects 0.000 claims abstract description 22
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 10
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- 239000004576 sand Substances 0.000 claims abstract description 4
- 239000011734 sodium Substances 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000011780 sodium chloride Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 239000004753 textile Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 4
- 235000019362 perlite Nutrition 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 229960002668 sodium chloride Drugs 0.000 claims description 3
- 235000002639 sodium chloride Nutrition 0.000 claims description 3
- 238000009423 ventilation Methods 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 239000012212 insulator Substances 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 4
- 239000008187 granular material Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000003063 flame retardant Substances 0.000 abstract 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 2
- 239000011152 fibreglass Substances 0.000 abstract 1
- 239000011810 insulating material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 description 8
- 238000007789 sealing Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 239000010425 asbestos Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052895 riebeckite Inorganic materials 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
Definitions
- the present invention relates to a fireproof sealbag provided with an external fireproof fabric cover, preferably made of textile glass, and in given case with a second, internal cover made of damp-proof foil, and filled with a stuffing containing a fireproof filling material and an intumescent material to be primarily used for the temporary and/or permanent fireproof sealing of cable passages or other holes and ducts. Furthermore the invention relates to a process for the production of said intumescent material capable of swelling on elevated temperatures.
- thermo-foaming US-PS 4 493 173
- expanding US-PS 4 376 230
- flame arresting gas generating material DE-OS 34 19 352
- thermo- foaming material In order to eliminate this drawback, the covering material of the bag partially or completely was coated with thermo- foaming material.
- the drawback of this method was that it had no adequate swelling capacity for penetration into the gaps, moreover the foaming or swelling layer gradually lost its swelling capacity upon the effect of microbes, fungi or moisture.
- the main feature of the currently used sealbags is that they are made of textile glass and the filling material or part of it swells upon the effect of heat generated during fire (see DE-PS 35 35 625).
- This fireproof sealbag is mineral cotton treated as to swell by about 50 volume% at 280 °C. This swelling however, occurs only in open space, which means that when the sealbag is packed into the passage, it is not capable to swell into the gaps and necks, because the compressive strength of the swelling material is low. Hence it does not provide the required tight sealing.
- the fireproof sealing pad described in the HU-AS T/26619 is provided with a fireproof cover, in which an easily melting internal cover is arranged and 50-99 mass% of its stuffing is fireproof granular filling material and 1-20 mass's is loose, retarding material inclined to swelling.
- the fire-proof granular material may be quartzsand, fluedust, swollen perlite or other mineral filling material.
- the retarding material inclined to swelling contains 15-25 volume% ammonium phosphate, 5-15 mass% polyalcohol and 4-14 mass% carbamide, urotropine and/or melanine.
- the object of the present invention is therefore to profide a fireproof sealbag, which expands its volume upon heat effect at a much lower temperature and to a considerably greater extent, than those used so far, and the compressive strength of the swelling material is sufficiently high to provide tight sealing by penetrating into the gaps of the passages. Further object of the present invention is to provide a process for production of swelling pad for said sealbags.
- a fireproof sealbag is provided with an external cover made of fireproof fabric, preferably textile glass and in given case with an internal cover made of damp-proof foil and filled with fireproof filling material, as well as with a thermo-swelling pad, wherein the stuffing contains 25-45 volume% sand or granular fireproof material of similar specific weight, and 20-40 volume% perlite or other heat insulator as filling material, and 20-40 volume% sodium enriched and dried silicic acid gel grains as swelling pad.
- the stuffing may contain 2-5 % betonite to improve the density and space filling.
- the external textile glass layer of the cover may be impregnated with a conventional fireproof paint to improve the fire proofness and to fix the textile fibres against slipping apart.
- first silicic acid gel is prepared by mixing 60-80 % waterglass and 40-20 % gelforming additive, e.g. sodiumchloride or sodium carbonate, then the gel is dried and grains are formed.
- the grains can be prepared by crushing the dried gel, or in given case by granulation of the still liquid gel in air jet or by other means.
- the silicic acid gel is dried at room temperature, or max. 80°C for at least 5 hours. The drying requires adequate ventilation.
- the pad used in the bags begins to expand its volume at a temperature lower by more than 100°C, than the best versions of the traditional bags.
- the pad swells at a lower temperature and to a considerably greater extent than the earlier ones. Upon the effect of heat, it expands to 6-10 times its original volume.
- Composition of the filling material ensures the optimal mechanical and heat insulation properties of the stuffing.
- Silicic acid gel was prepared with 80 % waterglass and 20 % sodium chloride. The gel was dried at room temperature for 48 hours, then crushed to about 3 mm diameter grains in a hammer mill.
- the grains were put into a furnace, the temperature of which was gradually increased. The grains began to swell at 140°C and were swollen to eight-ten times their original size upon reaching 150°C temperature in 3 minute.
- Silicic acid gel was prepared with 60 % waterglass and 40 % sodium carbonate. The gel was dried at 75°C for 8 hours, then broken up between crushing rolls. The size of the obtained fragments was about 4 mm. The grains were put into a furnace and while heating, the grains were swollen to 6-8 times their original size at 150°C.
- Fire resistance test was conducted in compliance with the specifications of standard DIN 4102 with traditional sealbags and with those according to the invention.
- the different sealbags were tested one by one.
- a 80x40 cm hole in the upper horizontal wall of the furnace provided with burner was sealed with various sealbags in a width of 35 cm.
- Vertical cable passages were formed in the hole.
- the passage contained three cables of 40 mm diameter and twelve cables of 8 mm diameter. The latter ones were led through the hole in metal tray.
- Thermocouples were attached to different points of the passage to sense the temperatures measured on the outside of the passage (on the surface of the bags, insulation of the cables and on the cables). The test was conducted for 1.5 hour, the furnace was heated from 0 to 1000°C in about half an hour. Some of the tested bags contained swelling pad described in example 1. This represented 25 % of the bags' content, apart from which the stuffing contained 40 volume% sand, 32 volume% perlite and 2 volume% bentonite. These were the samples marked with A.
- composition of the other part of the sealbags (samples B) according to the invention was the following:
- the textile glass bag containing the stuffing was impregnated with Alucot T-250 silicone-based fireproof plant.
- test was conducted even with sealbags available in the trade, a certain part of which contained specially treated mineral cotton stuffing (samples C), and the other part was provided with mineral cotton cushion stuffing coated by thermo-foaming material (samples D).
- the sealbags according to the invention have more favourable characteristics in every respect than those now available in the trade: the sealing is safe, efficient and durable, in case of fire the padding materials swell socner and to a greater extent than those used earlier, and they form a solidifying, tight wall in the hole.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Fireproofing Substances (AREA)
- Sealing Material Composition (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Packages (AREA)
- Installation Of Indoor Wiring (AREA)
- Building Environments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU872146A HU204111B (en) | 1987-05-13 | 1987-05-13 | Fire-blocking sealing bag and method for producing insert swelling by the effect of heat |
| HU214687 | 1987-05-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0317599A1 true EP0317599A1 (en) | 1989-05-31 |
Family
ID=10958009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88904601A Withdrawn EP0317599A1 (en) | 1987-05-13 | 1988-05-13 | Fireproof sealbag and process for the production of thermo-swelling pad |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0317599A1 (cs) |
| CN (1) | CN1030601A (cs) |
| AU (1) | AU1782188A (cs) |
| CS (1) | CS270587B2 (cs) |
| DD (1) | DD272327A5 (cs) |
| DK (1) | DK12789A (cs) |
| HU (1) | HU204111B (cs) |
| IL (1) | IL86239A0 (cs) |
| RU (1) | RU2005764C1 (cs) |
| UA (1) | UA15655A1 (cs) |
| WO (1) | WO1988008790A1 (cs) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2715165B1 (fr) * | 1994-01-14 | 1996-03-22 | Rhone Poulenc Chimie | Produit utilisable en détergence comprenant du silicate vitreux hydraté. |
| RU2168342C1 (ru) * | 1999-12-02 | 2001-06-10 | Феськов Евгений Михайлович | Пожаробезопасное устройство для прокладки кабелей |
| RU2170751C1 (ru) * | 2000-01-26 | 2001-07-20 | Открытое акционерное общество Акционерная компания "Туламашзавод" | Способ уплотнения резьбовых соединений и герметизирующая смесь для его осуществления |
| US6698146B2 (en) | 2001-10-31 | 2004-03-02 | W. R. Grace & Co.-Conn. | In situ molded thermal barriers |
| US7152385B2 (en) | 2001-10-31 | 2006-12-26 | W.R. Grace & Co.-Conn. | In situ molded thermal barriers |
| RU2506378C2 (ru) * | 2012-03-05 | 2014-02-10 | Юрий Владимирович Кривцов | Подушка противопожарная уплотнительная "ппву-1" |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1245519B (de) * | 1963-04-01 | 1967-07-27 | Herberts & Co Gmbh Dr Kurt | Brandschutzueberzugsmittel |
| US4113989A (en) * | 1977-03-01 | 1978-09-12 | Siemens Aktiengesellschaft | Electronic telephone system featuring switching networks having thyristors for single-wire switching |
| ZA817057B (en) * | 1980-10-25 | 1982-09-29 | Foseco Int | Gel forming compositions |
| DE3419352C2 (de) * | 1984-05-24 | 1986-08-28 | Werner 7925 Dischingen Hauff | Durchführung für mindestens eine Leitung, insbesondere ein elektrisches Kabel |
-
1987
- 1987-05-13 HU HU872146A patent/HU204111B/hu unknown
-
1988
- 1988-05-02 IL IL86239A patent/IL86239A0/xx unknown
- 1988-05-06 CS CS883096A patent/CS270587B2/cs unknown
- 1988-05-12 DD DD88315718A patent/DD272327A5/de not_active IP Right Cessation
- 1988-05-13 AU AU17821/88A patent/AU1782188A/en not_active Abandoned
- 1988-05-13 UA UA4613431A patent/UA15655A1/uk unknown
- 1988-05-13 WO PCT/HU1988/000034 patent/WO1988008790A1/en not_active Ceased
- 1988-05-13 EP EP88904601A patent/EP0317599A1/en not_active Withdrawn
- 1988-05-13 CN CN88102793A patent/CN1030601A/zh active Pending
-
1989
- 1989-01-12 DK DK012789A patent/DK12789A/da not_active Application Discontinuation
- 1989-01-12 RU SU894613431A patent/RU2005764C1/ru active
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8808790A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DK12789D0 (da) | 1989-01-12 |
| IL86239A0 (en) | 1988-11-15 |
| HU204111B (en) | 1991-11-28 |
| HUT55471A (en) | 1991-05-28 |
| CN1030601A (zh) | 1989-01-25 |
| UA15655A1 (uk) | 1997-06-30 |
| WO1988008790A1 (en) | 1988-11-17 |
| CS270587B2 (en) | 1990-07-12 |
| DD272327A5 (de) | 1989-10-04 |
| CS309688A2 (en) | 1989-11-14 |
| RU2005764C1 (ru) | 1994-01-15 |
| DK12789A (da) | 1989-03-13 |
| AU1782188A (en) | 1988-12-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
| 17P | Request for examination filed |
Effective date: 19890516 |
|
| 17Q | First examination report despatched |
Effective date: 19910206 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19911231 |