EP0312447A1 - Verfahren und Anlage zur Herstellung dünner Schichten mittels eines Plasmas für elektronische bzw. opto-elektronische Anwendungen - Google Patents

Verfahren und Anlage zur Herstellung dünner Schichten mittels eines Plasmas für elektronische bzw. opto-elektronische Anwendungen Download PDF

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Publication number
EP0312447A1
EP0312447A1 EP88402570A EP88402570A EP0312447A1 EP 0312447 A1 EP0312447 A1 EP 0312447A1 EP 88402570 A EP88402570 A EP 88402570A EP 88402570 A EP88402570 A EP 88402570A EP 0312447 A1 EP0312447 A1 EP 0312447A1
Authority
EP
European Patent Office
Prior art keywords
enclosure
chamber
layers
plasma
walls
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88402570A
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English (en)
French (fr)
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EP0312447B1 (de
Inventor
Jacques Schmitt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solems Sa Dite Ste
Solems SA
Original Assignee
Solems Sa Dite Ste
Solems SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solems Sa Dite Ste, Solems SA filed Critical Solems Sa Dite Ste
Priority to AT88402570T priority Critical patent/ATE78880T1/de
Publication of EP0312447A1 publication Critical patent/EP0312447A1/de
Application granted granted Critical
Publication of EP0312447B1 publication Critical patent/EP0312447B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/3244Gas supply means
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/4412Details relating to the exhausts, e.g. pumps, filters, scrubbers, particle traps
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45587Mechanical means for changing the gas flow
    • C23C16/45591Fixed means, e.g. wings, baffles

Definitions

  • the invention relates to a method for operating an apparatus intended for producing all kinds of thin layers for electronic and / or optoelectronic use, such as in particular amorphous or crystalline semiconductor thin layers, using a plasma deposition process. .
  • the invention also relates to the device itself.
  • apparatuses of this category comprising: - an enclosure in which there is a pressure below atmospheric pressure, means for creating a plasma zone in the enclosure, these means comprising at least one electrode connected to a source of electrical power, at least one substrate and means for introducing reactive gases into the plasma zone, means for evacuating to the outside of the enclosure a residual part of the reactive gases after stay in the plasma zone, - And a sealed chamber in which is housed said enclosure and where there is a pressure lower than that of the enclosure.
  • this deposition zone also called plasma zone
  • the surface "decomposition”, or degassing, of the components of the device near this deposition zone could alter the electronic properties of the semiconductors, this situation being aggravated by the fact in fact "semi-sealed" of the inner reaction chamber whose substrate carrier plates on which the substrates are mounted, simply come to bear, in a non-sealed manner, towards their peripheral end, on side walls of the enclosure, which side walls are connected, in leaktight manner, to front and rear closure walls of this same enclosure, themselves connected, also in leaktight manner, to the reactive gas inlet conduits respectively and for evacuating the non-deposited residual part of these same gases.
  • the impurities present in the chamber cannot penetrate into the enclosure, in particular at critical moments, namely during the layer deposition phase.
  • the heating of the interior enclosure will advantageously be accompanied by maintaining the walls of the sealed outer chamber at a temperature of the order of 80 ° C, at most.
  • heating means which may be arranged in the intermediate space separating the sealed outer chamber enclosure.
  • the UHV technique provides for drying the whole machine, which must be able to be subjected to a vacuum of less than 10, up to 250 ° C. or even 450 ° C. ⁇ 5 Pa (regularly around 10 ⁇ 7 Pa).
  • the apparatus for producing amorphous layers which operates according to a plasma deposition process is generally of the same type as that described in the aforementioned French application FR-A-2,589,168 to which we can refer.
  • This device therefore comprises a sealed outer chamber 2 which can withstand a partial vacuum of approximately 10 ⁇ 4 to 10 ⁇ 5 Pa.
  • a relatively elongated enclosure 3 In this enclosure, a double plasma zone 4, 4 ′ can be created between a central electrode 5 and two substrates 7 and 7 ′.
  • the electrode 5 extends substantially in the general axis 6 of the enclosure and is connected by its head 5 ′ to a high voltage source. Plates 17, 17 ′ substrate holders on which the substrates 7, 7 ′ are mounted, bear towards their periphery at 17a, 17′a, respectively, on the side walls 13, 23 of the enclosure, which are connected in a sealed manner at the front 33 and rear 43 closing walls onto which also open in a sealed manner, ducts 8 and 11 respectively.
  • the substrates are here directed substantially parallel to each other and face the plasma zone.
  • the conduit 8 which opens at the rear longitudinal end of the enclosure after having passed 12 in leaktight manner through the wall of the chamber 2, supplies the plasma zone with reactive gases for producing the layers.
  • FIG. 1 the front and rear sides of the enclosure have been identified by the letters AV and AR, with reference to the circulation of reactive gases in the apparatus, as shown diagrammatically by arrow 9.
  • the reactive gases meet on their way a first constriction 10, or distributor, intended to improve the distribution of the gases in the enclosure.
  • the non-deposited residual part is evacuated towards the outside of the enclosure by the conduit 11 which is connected to the enclosure towards its front longitudinal end and which crosses in a sealed manner, at 22, the wall of the chamber 2.
  • a pump such as a vacuum pump, can be used to suck up the residual material to be evacuated.
  • the material for producing the layers will be a support, in general a gas, admitted at a pressure of approximately 101 Pa which will supply the plasma regions with the elementary constituents, which, after decomposition of the support by electrical discharge, will come deposit on the substrates in the form of thin films.
  • a support in general a gas, admitted at a pressure of approximately 101 Pa which will supply the plasma regions with the elementary constituents, which, after decomposition of the support by electrical discharge, will come deposit on the substrates in the form of thin films.
  • silicon tetrafluoride and silane could be used as a production material layers of silicon.
  • different types of dopants could be retained.
  • the invention provides in particular to raise the temperature of the enclosure by means such as resistors in the form of a ramp housed in the intermediate space 18 which separates the chamber enclosure.
  • resistors 16 are connected to suitable electrical sources and their supply wires marked 16 ′ pass through chamber 2 in a sealed manner.
  • the selected heating elements must be able to bring the walls of the enclosure 3 to a temperature between approximately 100 and 300 ° C. during the phase of depositing the films on the substrates.
  • the temperature range will in fact be between approximately 150 and 250 ° C.
  • the upper limit may be exceeded. In fact, the more the enclosure is heated (without, of course, going so far as to damage it by overheating), the more the degassing flow harmful to the electronic quality of the semiconductors in formation will decrease.
  • Such preheating of the enclosure will in particular ensure surface stripping further limiting the subsequent degassing of the walls.
  • the conduit 11 for discharging residual materials is itself heated by resistors 20, always preferably at a temperature between 150 and 250 °. C approx.
  • the preferred solution has been in the invention and as illustrated in the figures, to cover most, if not all, of the interior face of the walls of the chamber 2 by heat screens 19.
  • These screens may in particular be made of polished aluminum and have their face of "mirror" directed towards the interior of the room.
  • cooling means for the walls of the chamber could complement the thermal screen, or even replace it.
  • the leakage rate at the junction between the substrate holders and enclosure walls should be less than about 10 ⁇ 3 m3 / s, and preferably be below about 0.3.10 ⁇ 3 m3 / s. This corresponds substantially to the leakage rate authorized by a slit approximately 3 m long by 10 ⁇ 2 m deep and 50 ⁇ m (50 x 10 ⁇ 5 m) thick.
  • the substrate holders must be able to be replaced. Their mobility is therefore necessary.
  • the device is, in a conventional manner, provided with two airlocks 28, 29.
  • These airlocks are arranged against the wall of the chamber 2 and each comprise, as known per se, a share a first access door, respectively 28a and 29a, which allows the airlock to communicate with the outside and, secondly, a second access door, respectively 28b, 29b which allows the airlock to communicate with the interior of room 2. Thanks to these airlock, the establishment and removal of the substrate holders can be carried out under the best conditions.
  • mechanical vacuum conveyors (not shown) transport the substrate holders and allow either to recover the substrates on which the films are deposited, or to introduce and place the substrates in the enclosure " virgins ".
  • the bellows 30 are connected to conduits 31 sealingly passing through the wall of the chamber 2 and which are themselves connected to pressurizing means, such as one or more air compressors 32 allowing d '' act if necessary independently on each bellows, for example by means of regulation valves 34.
  • the enclosure 3 opens, towards its front longitudinal end directly into the interior volume of the chamber 2. There is no longer a conduit 11 for discharging the residual material towards the exterior of the chamber.
  • the vacuum duct 15 in this case draws in not only the degassing flows from the walls of the enclosure and from the chamber, but also the residual materials which circulate in said enclosure.
  • FIG. 2 also shows a means for adjusting the throttle 14 leaving the enclosure.
  • This is a shutter 21 in the form of a truncated cone which can engage on bearing surfaces 26 of cooperating shape formed in a part 27 fixed towards the front end of the enclosure.
  • An operating rod 24 extends the shutter 21 towards the outside of the chamber, the wall of which it crosses at 25 in a sealed manner.
  • other adjustment means such as valve devices that can be operated from outside the chamber, for example by a control linkage, could have been envisaged. It is easy to understand that these same means could also have been provided for adjusting the inlet throttle 10 in the enclosure and that, of course, the embodiment of FIG. 1 could also have benefited from the implementation of such means.
  • the enclosure 3 is here provided on the side of its end where it opens on the discharge duct 11, with a solenoid valve 35 whose valve 36 with adjustable opening is placed under the control of a control unit 37 to which it is connected by a cable 38.
  • the morphology of the semiconductor layers can be, depending on the deposition conditions and the nature of the substrate. - amorphous - microcrystalline - monocrystalline (epitaxy)
  • the filler gases are organometallic, volatile fluorides or even metalcarbonyls.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Vapour Deposition (AREA)
  • Inorganic Insulating Materials (AREA)
  • Photovoltaic Devices (AREA)
EP88402570A 1987-10-15 1988-10-11 Verfahren und Anlage zur Herstellung dünner Schichten mittels eines Plasmas für elektronische bzw. opto-elektronische Anwendungen Expired - Lifetime EP0312447B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88402570T ATE78880T1 (de) 1987-10-15 1988-10-11 Verfahren und anlage zur herstellung duenner schichten mittels eines plasmas fuer elektronische bzw. opto-elektronische anwendungen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8714245 1987-10-15
FR8714245A FR2621930B1 (fr) 1987-10-15 1987-10-15 Procede et appareil pour la production par plasma de couches minces a usage electronique et/ou optoelectronique

Publications (2)

Publication Number Publication Date
EP0312447A1 true EP0312447A1 (de) 1989-04-19
EP0312447B1 EP0312447B1 (de) 1992-07-29

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Family Applications (1)

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EP88402570A Expired - Lifetime EP0312447B1 (de) 1987-10-15 1988-10-11 Verfahren und Anlage zur Herstellung dünner Schichten mittels eines Plasmas für elektronische bzw. opto-elektronische Anwendungen

Country Status (6)

Country Link
US (1) US4989543A (de)
EP (1) EP0312447B1 (de)
JP (1) JP2905855B2 (de)
AT (1) ATE78880T1 (de)
DE (1) DE3873250T2 (de)
FR (1) FR2621930B1 (de)

Cited By (4)

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EP0563748A2 (de) * 1992-03-30 1993-10-06 Matsushita Electric Industrial Co., Ltd. Verfahren zur Herstellung eines Überzuges durch chemische Abscheidung aus der Dampfphase mittels Plasma
DE4412915B4 (de) * 1993-05-03 2005-12-15 Unaxis Balzers Ag Plasmabehandlungsanlage, Verfahren zu deren Betrieb und Verwendung derselben
DE4412902B4 (de) * 1993-05-03 2007-02-08 Oc Oerlikon Balzers Ag Verfahren zur plasmaunterstützten, chemischen Dampfabscheidung und Vakuumplasmakammer
DE102009020436A1 (de) 2008-11-04 2010-09-16 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und Vorrichtung zur Plasmabehandlung eines flachen Substrats

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AU2005309226B2 (en) * 2004-11-24 2010-06-03 Oerlikon Solar Ag, Truebbach Vacuum processing chamber for very large area substrates
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US20080251019A1 (en) * 2007-04-12 2008-10-16 Sriram Krishnaswami System and method for transferring a substrate into and out of a reduced volume chamber accommodating multiple substrates
DE102007022431A1 (de) 2007-05-09 2008-11-13 Leybold Optics Gmbh Behandlungssystem für flache Substrate
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JP6303733B2 (ja) * 2014-03-31 2018-04-04 ソニー株式会社 磁気記録媒体およびその製造方法、ならびに成膜装置
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0563748A2 (de) * 1992-03-30 1993-10-06 Matsushita Electric Industrial Co., Ltd. Verfahren zur Herstellung eines Überzuges durch chemische Abscheidung aus der Dampfphase mittels Plasma
EP0563748A3 (en) * 1992-03-30 1995-03-29 Matsushita Electric Ind Co Ltd Method of forming film by plasma cvd
DE4412915B4 (de) * 1993-05-03 2005-12-15 Unaxis Balzers Ag Plasmabehandlungsanlage, Verfahren zu deren Betrieb und Verwendung derselben
DE4412902B4 (de) * 1993-05-03 2007-02-08 Oc Oerlikon Balzers Ag Verfahren zur plasmaunterstützten, chemischen Dampfabscheidung und Vakuumplasmakammer
DE4447977B4 (de) * 1993-05-03 2009-09-10 Oc Oerlikon Balzers Ag Vorrichtung und Verfahren zur Plasmabehandlung von flachen Werkstücken, insbesondere flachen, aktiven Bildschirmen, sowie Verwendung der Vorrichtung
DE102009020436A1 (de) 2008-11-04 2010-09-16 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und Vorrichtung zur Plasmabehandlung eines flachen Substrats

Also Published As

Publication number Publication date
DE3873250T2 (de) 1993-03-11
JP2905855B2 (ja) 1999-06-14
FR2621930A1 (fr) 1989-04-21
EP0312447B1 (de) 1992-07-29
DE3873250D1 (de) 1992-09-03
US4989543A (en) 1991-02-05
JPH027421A (ja) 1990-01-11
ATE78880T1 (de) 1992-08-15
FR2621930B1 (fr) 1990-02-02

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