EP0301052B1 - Auslöseelement für einen sprinkler - Google Patents
Auslöseelement für einen sprinkler Download PDFInfo
- Publication number
- EP0301052B1 EP0301052B1 EP88901221A EP88901221A EP0301052B1 EP 0301052 B1 EP0301052 B1 EP 0301052B1 EP 88901221 A EP88901221 A EP 88901221A EP 88901221 A EP88901221 A EP 88901221A EP 0301052 B1 EP0301052 B1 EP 0301052B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- trigger element
- hydrocarbons
- low
- sprinkler
- expanding liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 239000011521 glass Substances 0.000 claims abstract description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229950011008 tetrachloroethylene Drugs 0.000 claims abstract description 3
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims 1
- 239000002360 explosive Substances 0.000 abstract description 23
- -1 keto carboxylic acids Chemical class 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 150000001298 alcohols Chemical class 0.000 abstract description 2
- 229930194542 Keto Natural products 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000009434 installation Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C37/00—Control of fire-fighting equipment
- A62C37/08—Control of fire-fighting equipment comprising an outlet device containing a sensor, or itself being the sensor, i.e. self-contained sprinklers
- A62C37/10—Releasing means, e.g. electrically released
- A62C37/11—Releasing means, e.g. electrically released heat-sensitive
- A62C37/14—Releasing means, e.g. electrically released heat-sensitive with frangible vessels
Definitions
- the most commonly used extinguishing system is the sprinkler system, which is screwed to the water pipe network and is the most common extinguishing system.
- the water outlet nozzle is closed by a glass barrel filled with a suitable liquid.
- the hot flue gases heat up the explosive; this expands and bursts the glass keg when a trigger temperature specified by the filling quantity is reached. This automatically releases the nozzle and sprays the source of the fire with an extinguishing jet that is torn into droplets.
- the thermal capacity of the explosive fluid but also its thermal conductivity and viscosity play an important role. So that the spread of the trigger temperature is within the narrowest possible tolerances of approx. 5%, the explosive liquid should also cause the steepest possible rise in pressure when heated, that is, it should have a high value that is decisive for the rise in pressure with temperature (dP / dT) Have ratio of thermal expansion coefficient to compressibility (> 10 bar / K).
- the response time can be influenced by the material properties on the one hand, and by design measures on the other.
- a reduction in response time results, for example, from a reduction in the wall thickness of the glass barrel, an increase in the thermal conductivity of the glass material and / or the explosive fluid, as well as a reduction in volume of the glass barrel.
- German published patent application DE 32 20 124 A1 published in December 1983, describes a reduction in the volume of filling liquid by means of an inserted displacer.
- alcohols are mainly used as explosives for glass barrel sprinklers, namely n-butanol, isopropanol and glycerin, less often paraffin oil or more recently ethyl acetate.
- the present invention shortens the response time by using special explosive liquids, in which the heat absorption takes place particularly quickly, as the inner filling of the sprinkler glass vials. It was found experimentally that the response time of the glass vials serving as trigger elements depends on the one hand on the product of the average thermal capacity of the explosive liquid with its density and the glass barrel volume (thermal capacity of the inner filling), but on the other hand also depends on the thermal conductivity of the explosive liquid and its viscosity. The coefficient of thermal expansion, toxicity and chemical resistance of a liquid over time also play a role in its use as an explosive.
- Table II below shows the volume-related heat capacities (i.e. the products of the heat capacity and the density), the viscosities, the thermal conductivities and the calculated values of the pressure rise with the temperature (which correspond to the ratio of thermal expansion coefficient to compressibility) of some explosive liquids specified.
- the volume-related heat capacity C ' has a value ⁇ 1.5 J / ml
- the viscosity has a value ⁇ 0.8 mPa ⁇ s
- the thermal conductivity has a value> 0.025 W / cm ⁇ K
- the Pressure increase with the temperature dP / dT has a value> 10 bar / K.
- worse values for one or more properties and better values for other properties can balance each other out to some extent.
- the invention now relates to a trigger element for a sprinkler, wherein the trigger element consisting of a glass barrel and filled with an explosive liquid keeps the water outlet nozzle of the sprinkler closed, which is characterized in that the explosive liquid is composed of lower alkyl homologues of benzene, medium aliphatic hydrocarbons and lower cycloaliphatic Hydrocarbons, halogenated hydrocarbons and their mixtures with one another or with other liquids miscible therewith are selected.
- the lower alkyl homologues of benzene, the middle aliphatic hydrocarbons, that is, for example, aliphatic hydrocarbons with 5 to 12 carbon atoms, the lower cycloaliphatic hydrocarbons, that is, for example, cycloaliphatic hydrocarbons with up to 8 carbon atoms, and the halogenated hydrocarbons can, as a rule, with one another and with other liquids with organic compounds known as explosive liquids, such as lower mono- or polyhydric aliphatic alcohols and lower alkyl esters of lower alkane carboxylic acids, in any ratio in which they are miscible with one another.
- the explosive liquid can consist of toluene, xylene, n-decane, cyclohexane, trichlorethylene, tetrachlorethylene or mixtures thereof.
- the explosives can be used for different nominal opening temperatures.
- n-decane is suitable for nominal opening temperatures up to 182 ° C.
- the explosive liquid can be used as a lower mono- or polyhydric aliphatic alcohol or lower alkyl ester of a lower alkane carboxylic acid or a mixture thereof, e.g. Contain methanol, ethanol, isopropanol, glycerin or ethyl acetate or mixtures thereof, but usually no special advantages can be achieved.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH535/87A CH672745A5 (enExample) | 1987-02-13 | 1987-02-13 | |
| CH535/87 | 1987-02-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0301052A1 EP0301052A1 (de) | 1989-02-01 |
| EP0301052B1 true EP0301052B1 (de) | 1991-11-06 |
Family
ID=4189248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88901221A Expired - Lifetime EP0301052B1 (de) | 1987-02-13 | 1988-02-11 | Auslöseelement für einen sprinkler |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4938294A (enExample) |
| EP (1) | EP0301052B1 (enExample) |
| JP (1) | JP2650189B2 (enExample) |
| AU (1) | AU1222088A (enExample) |
| CH (1) | CH672745A5 (enExample) |
| DE (1) | DE3866046D1 (enExample) |
| WO (1) | WO1988006046A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19780041C1 (de) * | 1996-01-25 | 2002-02-21 | Norbulb Sprinkler Elemente Gmb | Auslöseglied für einen Sprinkler |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH672745A5 (enExample) * | 1987-02-13 | 1989-12-29 | Johann Georg Mohler | |
| GB9620598D0 (en) * | 1996-10-03 | 1996-11-20 | Grinnell Mfg Uk Ltd | Thermally responsive frangible bulb |
| US5829532A (en) | 1997-03-07 | 1998-11-03 | Central Sprinkler Corporation | Low pressure, early suppression fast response sprinklers |
| DE10219079B4 (de) * | 2002-04-29 | 2004-06-03 | Minimax Gmbh | Verfahren zum Herstellen von Glasampullen |
| DE202009007987U1 (de) | 2009-06-05 | 2010-10-28 | Job Lizenz Gmbh & Co. Kg | Thermisches Auslöseelement für Sprinkler, Ventile o.dgl. |
| US20120012190A1 (en) * | 2010-07-13 | 2012-01-19 | Barber Gerald L | Valve system for releasing pressurized fluid |
| DE202011050661U1 (de) * | 2011-07-07 | 2011-09-09 | Job Lizenz Gmbh & Co. Kg | Thermisches Auslöseelement für Sprinkler, Ventile oder dergleichen |
| DE202012100623U1 (de) | 2012-02-24 | 2012-03-22 | Job Lizenz Gmbh & Co. Kg | Brandschutzeinrichtung für elektrische Kleingeräte |
| EP4260915A3 (en) | 2018-08-24 | 2023-12-27 | Tyco Fire Products LP | Fire protection device with conformal coating |
| US11511145B1 (en) * | 2019-06-19 | 2022-11-29 | Minimax Viking Research & Development Gmbh | Fast response glass bulb thermal trigger arrangements and methods thereof for large orifice suppression fire protection sprinklers |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1771826A (en) * | 1926-02-25 | 1930-07-29 | Taylor John | Automatic sprinkler and the like |
| US1905676A (en) * | 1930-04-15 | 1933-04-25 | Gen Fire Extinguisher Co | Automatic sprinkler or fire extinguisher and other fire device |
| FR713683A (fr) * | 1930-04-15 | 1931-10-31 | Mather & Platt Ltd | Perfectionnements aux appareils automatiques de projection de fluides ou extincteursd'incendie et autres dispositifs pour la lutte contre les incendies |
| US2125510A (en) * | 1936-08-20 | 1938-08-02 | Leroy M Lewis | Automatic sprinkler |
| DE3220124A1 (de) * | 1982-05-28 | 1983-12-01 | Walther & Cie AG, 5000 Köln | Ausloeseglied fuer einen sprinkler |
| CH672745A5 (enExample) * | 1987-02-13 | 1989-12-29 | Johann Georg Mohler |
-
1987
- 1987-02-13 CH CH535/87A patent/CH672745A5/de not_active IP Right Cessation
-
1988
- 1988-02-11 DE DE8888901221T patent/DE3866046D1/de not_active Expired - Lifetime
- 1988-02-11 US US07/275,173 patent/US4938294A/en not_active Expired - Lifetime
- 1988-02-11 JP JP62506249A patent/JP2650189B2/ja not_active Expired - Lifetime
- 1988-02-11 AU AU12220/88A patent/AU1222088A/en not_active Abandoned
- 1988-02-11 EP EP88901221A patent/EP0301052B1/de not_active Expired - Lifetime
- 1988-02-11 WO PCT/CH1988/000033 patent/WO1988006046A1/de not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19780041C1 (de) * | 1996-01-25 | 2002-02-21 | Norbulb Sprinkler Elemente Gmb | Auslöseglied für einen Sprinkler |
Also Published As
| Publication number | Publication date |
|---|---|
| CH672745A5 (enExample) | 1989-12-29 |
| US4938294A (en) | 1990-07-03 |
| AU1222088A (en) | 1988-09-14 |
| EP0301052A1 (de) | 1989-02-01 |
| WO1988006046A1 (fr) | 1988-08-25 |
| JP2650189B2 (ja) | 1997-09-03 |
| DE3866046D1 (de) | 1991-12-12 |
| JPH01502238A (ja) | 1989-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| 17P | Request for examination filed |
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| 17Q | First examination report despatched |
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| REF | Corresponds to: |
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| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) | ||
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| STAA | Information on the status of an ep patent application or granted ep patent |
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