EP0248248B1 - Procédé de fabrication d'une structure plane en tissu imprégné de résine - Google Patents

Procédé de fabrication d'une structure plane en tissu imprégné de résine Download PDF

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Publication number
EP0248248B1
EP0248248B1 EP87107077A EP87107077A EP0248248B1 EP 0248248 B1 EP0248248 B1 EP 0248248B1 EP 87107077 A EP87107077 A EP 87107077A EP 87107077 A EP87107077 A EP 87107077A EP 0248248 B1 EP0248248 B1 EP 0248248B1
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EP
European Patent Office
Prior art keywords
construction
warp
resin
fabric
prepreg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP87107077A
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German (de)
English (en)
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EP0248248A2 (fr
EP0248248A3 (en
Inventor
Kenneth James Varker
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International Business Machines Corp
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International Business Machines Corp
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Publication of EP0248248A3 publication Critical patent/EP0248248A3/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/005—Compensating volume or shape change during moulding, in general
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B29B15/125—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by dipping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/545—Perforating, cutting or machining during or after moulding
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/0366—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/0011—Working of insulating substrates or insulating layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2793/00—Shaping techniques involving a cutting or machining operation
    • B29C2793/0045—Perforating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/24—Condition, form or state of moulded material or of the material to be shaped crosslinked or vulcanised
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/24—Condition, form or state of moulded material or of the material to be shaped crosslinked or vulcanised
    • B29K2105/243—Partially cured
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0275—Fibers and reinforcement materials
    • H05K2201/029—Woven fibrous reinforcement or textile
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/02—Details related to mechanical or acoustic processing, e.g. drilling, punching, cutting, using ultrasound
    • H05K2203/0228—Cutting, sawing, milling or shearing
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/10—Using electric, magnetic and electromagnetic fields; Using laser light
    • H05K2203/107—Using laser light
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/11—Treatments characterised by their effect, e.g. heating, cooling, roughening
    • H05K2203/1105—Heating or thermal processing not related to soldering, firing, curing or laminating, e.g. for shaping the substrate or during finish plating
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/0011—Working of insulating substrates or insulating layers
    • H05K3/0017—Etching of the substrate by chemical or physical means
    • H05K3/0026—Etching of the substrate by chemical or physical means by laser ablation
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/46—Manufacturing multilayer circuits
    • H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/901—Printed circuit
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1052—Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1056—Perforating lamina
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1052—Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1062—Prior to assembly
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/12—Surface bonding means and/or assembly means with cutting, punching, piercing, severing or tearing
    • Y10T156/13—Severing followed by associating with part from same source
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24298—Noncircular aperture [e.g., slit, diamond, rectangular, etc.]
    • Y10T428/24314—Slit or elongated

Definitions

  • This invention relates to the manufacture of resin impregnated fabric articles which are useful as dielectric substrates in printed circuit boards and to improvements in said manufacturing of such articles which avoid shrinking of the articles during final curing of the resin.
  • the fabric which may be made from any suitable material, is coated with a curable resin.
  • the resin is then partially cured, or "B-staged", in order to provide substantially planar cards or boards of prepreg which can be used to construct a printed circuit board.
  • the prepreg comprises glass cloth impregnated with an epoxy resin as is shown in U.S. Patent No. 3,660,199.
  • the prepreg components are laminated together to form thicker dielectric layers and are sometimes sandwiched between layers of a conductive material.
  • the conductive layers are then sometimes covered with additional layers of prepreg to form buried conductive layers.
  • holes are made by a variety of techniques such as drilling or laser cutting. They may be plated with a conductive material for use in electrical communication between the sides of the printed circuit board or they may be used to receive pins of components which are plugged into the printed circuit board.
  • the prepreg or the drilled laminate is fully cured or "C-staged".
  • C-staging after lamination helps to improve laminar adhesion in printed circuit boards comprising layers of prepreg.
  • the C-staged prepreg or laminate is then normally personalized on at least one side with an electrically conductive circuit, which may be applied by any of a variety of well-known techniques, such as silk screen printing or photomasking combined with plating and etching.
  • Such shrinking causes through holes drilled in the prepreg, or in a laminated substrate comprising such prepreg, to move toward the center of the board during C-staging.
  • Coping with this problem has been a major factor in the production of printed circuit boards.
  • shrinkage is compensated for by the complex and imprecise technique of anticipating shrinkage, such as by making through holes in locations other than where they are ultimately desired in anticipation that they will move to the desired location.
  • the invention as claimed provides a method for making substantially planar constructions of resin-impregnated fabric, which method comprises the steps of (1) coating the fabric with a curable resin, (2) partially curing the resin and (3) fully curing the resin.
  • the method comprises, between steps (2) and (3), cutting at least a plurality of the warp of the fabric in at least one location, whereby shrinkage of the construction during step (3) is reduced.
  • FIG. 1 there is shown a greatly simplified apparatus for coating a fabric with resin and for B-staging the coated fabric.
  • Fabric 1 is unwound from supply roll 2 and dipped into a curable liquid resin 3 before entering curing oven 4 where the liquid coated fabric is partially cured, usually by forced hot air.
  • fabric 1 is glass cloth and resin 3 is an epoxy or polyimide resin.
  • prepreg partially cured resin impregnated fabric
  • FIG. 2 there is shown a top view of a B-staged panel 5.
  • a single, non-continuous line of cuts 8 has been made in the warp of the fabric which forms the core of panel 5.
  • the warp of the fabric runs lengthwise of the panel.
  • the cuts do not have to be in a line perpendicular to the warp as shown in FIG. 2, although such a configuration is normally preferred because of manufacturing convenience.
  • the cuts could be at random locations or, for example, in a diagonal line or a curve. It is important to the operation of the invention that at least a plurality of the warp be cut in at least one location, but the pattern of the cuts in the warp is not critical.
  • cuts in at least a plurality of the warp of the fabric in at least one location one embodiment of which is shown in FIG. 2, will reduce the shrinkage of prepreg more than 20% during C-staging.
  • Cuts 8 may be made by any useful means.
  • the means of making cuts 8 is not critical to the invention.
  • a knife edge, a laser or a roller embossed with a pattern of knife edges may be used.
  • the cutting means normally cuts through the resin coating on one side of the fabric and through the warp of the fabric, leaving a slit in the resin which is "healed" during C-staging.
  • Through holes 9 and electrically conductive circuit 10 are applied to panel 5 by conventional and well known means which are described in the literature and which will not be repeated here. Normally through holes 9 are made before C-staging and circuit 10 is applied after C-staging.
  • panel 5 in which 12 non-continuous cuts 8 have been made across a plurality of the warp of the fabric.
  • the number of cuts 8 shown in FIG. 3 provide about an 80% reduction in shrinkage of the prepreg during C-staging.
  • either or both surfaces of panel 5 may be personalized with electrically conductive circuitry and through holes may be made in the panel, as is shown in FIG. 2.
  • printed circuit board 11 which is made using the construction of the present invention.
  • Printed circuit board 11 comprises a central core 13 of three laminated layers of prepreg 12 which includes the improvement of the present invention.
  • Conductive layers 14 are on either side of central core 13 and are in turn covered by two additional layers of prepreg 12.
  • Through holes 15 have been drilled through printed circuit board 11 and have been plated with an electrically conductive metal in order to enable electrical communication between printed circuits 17, which have been applied to both sides of printed circuit board 11.
  • Warp 18 and weft 19 of the fabric of prepreg 12 is shown impregnated in resin 20. Cuts 21 in warp 18 are also shown. Resin 20 around cuts 21 has healed during C-staging of printed circuit board 11 so that no slits in the resin remain.
  • construction no. 1 is not in accordance with the present invention and constructions nos. 2-10 are examples of constructions made by the method of the invention.
  • a dielectric substrate, also known as prepreg, for use in the manufacture of printed circuit boards was made by dip-coating a 60 cm-wide web of glass cloth, commercially available from Uniglass as Style 109 Glass Cloth, in a heat curable epoxy resin, commercially available from Ciba Geigy as FR 4. An Egan treater was used.
  • the glass cloth, coated with uncured epoxy resin was run through a 148°C vertical curing oven for 2 minutes to accomplish partial curing or "B-staging", of the resin. After leaving the oven, the web was cut into 70 cm-long boards by a Moore & White slitter.
  • the boards were used to make constructions having three layers of prepreg sandwiched between 70 ⁇ m copper layers which were in turn covered by two layers of prepreg.
  • a pattern of about 2,500 through holes which is commonly used in the manufacture of printed circuit boards was drilled in nine such constructions, numbered 1 through 10, and the x and y locations of 30 of the through holes was recorded for future comparison.
  • this movement may be expressed as parts movement per million parts distance from the hole location to the centerline of the board (ppm).
  • ppm parts movement per million parts distance from the hole location to the centerline of the board
  • Construction No. 2 was made, drilled and measured as in connection with Construction No. 1 except that each prepreg component of Construction No. 2 was subjected to one non-continuous cut across its warp by an exacto knife prior to assembly.
  • the exacto knife was positioned to cut through the partially cured resin to a depth sufficient to part the warp of the glass cloth and was manipulated to cut only just over half of the warp in each component. An open slit the width of the knife thickness was also left in the resin at positions where the warp was cut.
  • Construction No. 2 was C-staged and the x and y locations of the same 30 through holes were recorded and compared to their locations before C-staging. Movement of the holes was reduced to about 420 ppm, a reduction of over 23%.
  • Each prepreg component of Construction No. 3 was subjected to two separate non-continuous cuts along the warp of the glass cloth. The cuts were evenly spaced to divide each component substantially in thirds and, as in Construction No. 2, each cut separated just over half of the warp. After being subjected to the same measurements and comparisons as Constructions 1 and 2, it was observed that in Construction 3 the migration of the holes was reduced to about 350 ppm, a reduction of over 36%.
  • Each prepreg component of Construction No. 4 was subjected to three separate non-continuous cuts along the warp of the glass cloth. The cuts were evenly spaced along the length of the component and, as before, parted just over half the warp. After being subjected to the same measurements and comparisons as Constructions 1 through 3, it was observed that in Construction No. 4 the movement of the through holes during C-staging was about 200 ppm, a reduction of over 63%.
  • Construction No. 5 Each prepreg component of Construction No. 5 was subjected to six separate non-continuous cuts along the warp of the glass cloth. The cuts were evenly spaced along the length of the component and, as before parted just over half the warp. After being subjected to the same measurements and comparisons as Constructions 1 through 4, it was observed that in Construction No. 5 the movement of the through holes during C-staging was about 180 ppm, a reduction in shrinkage of about 67%.
  • Construction No. 6 Each prepreg component of Construction No. 6 was subjected to nine separate non-continuous cuts along the warp of the glass cloth as in the previous Constructions 2 through 5. After being subjected to the same measurements and comparisons as Constructions 1 through 5, it was observed that in Construction No. 6 the movement of the through holes during C-staging was about 150 ppm, a reduction in shrinkage of about 70% over the shrinkage of Construction 1.
  • Construction No. 7 Each prepreg component of Construction No. 7 was subjected to 12 separate non-continuous cuts along the warp of the glass cloth as in previous Constructions 2 through 6. After being subjected to the same measurements and comparisons as Constructions 1 through 6 it was observed that in Construction No. 7 the movement of the through holes during C-staging was about 100 ppm, a reduction in shrinkage of about 80% over the shrinkage of Construction 1.
  • Construction No. 8 Each prepreg component of Construction No. 8 was subjected to 15 separate non-continuous cuts along the warp of the glass cloth. As in previous constructions 2 through 7, the cuts parted just over half the warp in each component. After being subjected to the same measurements and comparisons as Constructions 1 through 7, it was observed that in Construction No. 8 the movement of the through holes during C-staging was about 100 ppm, a reduction in shrinkage of about 80% over the shrinkage of Construction 1, but no further improvement over the the shrinkage of Construction No. 7.
  • Each prepreg component of Construction No. 9 was subjected to three separate non-continuous cuts along the warp of the glass cloth and three separate such cuts along the weft of the glass cloth.
  • Each prepreg component of Construction No. 10 was subjected to 15 separate such cuts along the warp and 15 separate cuts along the weft of the glass cloth. Each cut parted just over half of the warp or weft.
  • Construction No. 9 showed only marginally less movement of through holes than Construction No. 4 during C-staging and that Construction No. 10 showed no additional reduction in movement of through holes than Construction No. 8.
  • the improvement of the present invention can be used to reduce shrinkage or movement of through holes in prepreg and in printed circuit boards of a variety of sizes, comprising a variety of layers of prepreg and other materials and whenever said prepreg is made from a variety of resins and fabrics. It will also be apparent to such a technician that cutting of the fabric can be accomplished by a number of other methods, such as laser cutting or the use of a roller embossed with a pattern of knife edges.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Reinforced Plastic Materials (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)

Claims (13)

  1. Procédé de fabrication d'une structure sensiblement plane en tissu imprégné de résine, qui comprend les opérations de (1) revêtement du tissu avec une résine durcissable, (2) durcissement partiel de la résine, et (3) durcissement complet de la résine, caractérisé en ce que, entre les opérations (2) et (3), on coupe au moins une pluralité des fils de chaîne du tissu à au moins un endroit, de sorte que la contraction de la structure pendant l'opération (3) est réduite.
  2. Procédé suivant la revendication 1, dans lequel des parties de la trame du tissu sont également coupées.
  3. Procédé suivant la revendication 1, dans lequel la chaîne est coupée suivant au moins une ligne qui est sensiblement perpendiculaire à la chaîne.
  4. Procédé suivant la revendication 3, dans lequel la chaîne est coupée suffisamment pour réduire de 80% environ cette contraction de la structure.
  5. Procédé suivant la revendication 3, dans lequel la chaîne est coupée de façon discontinue.
  6. Procédé suivant la revendication 1, dans lequel, après la coupe et avant l'opération (3), la structure sensiblement plane est laminée avec au moins un autre élément plan choisi dans le groupe comprenant d'autres structures sensiblement similaires et un métal conducteur, afin de former un stratifié.
  7. Procédé suivant la revendication 6, dans lequel, après stratification et avant l'opération (3), au moins un trou de traversée est exécuté dans le stratifié.
  8. Procédé suivant la revendication 1, dans lequel un circuit imprimé est appliqué à au moins une surface de la structure.
  9. Procédé suivant la revendication 6, dans lequel le stratifié présente au moins une surface extérieure de ladite structure sensiblement similaire à laquelle est appliqué un circuit imprimé.
  10. Procédé suivant la revendication 1, dans lequel la coupe est effectuée au moyen d'une lame.
  11. Procédé suivant la revendication 1, dans lequel la coupe est effectuée par l'application d'un rayonnement laser.
  12. Procédé suivant la revendication 1, dans lequel le tissu est un tissu de verre.
  13. Procédé suivant la revendication 1, dans lequel la résine est une résine époxy thermodurcissable.
EP87107077A 1986-05-23 1987-05-15 Procédé de fabrication d'une structure plane en tissu imprégné de résine Expired - Lifetime EP0248248B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US866516 1986-05-23
US06/866,516 US4732636A (en) 1986-05-23 1986-05-23 Method for producing a prepreg having improved dimensional stability

Publications (3)

Publication Number Publication Date
EP0248248A2 EP0248248A2 (fr) 1987-12-09
EP0248248A3 EP0248248A3 (en) 1988-11-02
EP0248248B1 true EP0248248B1 (fr) 1991-08-07

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EP87107077A Expired - Lifetime EP0248248B1 (fr) 1986-05-23 1987-05-15 Procédé de fabrication d'une structure plane en tissu imprégné de résine

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Country Link
US (1) US4732636A (fr)
EP (1) EP0248248B1 (fr)
JP (1) JPH0657408B2 (fr)
DE (1) DE3771935D1 (fr)

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FR2633213A1 (fr) * 1988-06-27 1989-12-29 Europ Propulsion Procede de realisation d'une preforme fibreuse pour la fabrication de pieces en materiau composite ayant une forme complexe
EP0353564A2 (fr) * 1988-08-05 1990-02-07 Masonite Corporation Panneau à fibres de bois entaillé apte au moulage
US5306539A (en) * 1988-08-05 1994-04-26 Masonite Corporation Scored fiberboard having improved moldability
US5855610A (en) 1995-05-19 1999-01-05 Children's Medical Center Corporation Engineering of strong, pliable tissues
WO2004050750A1 (fr) * 2002-12-04 2004-06-17 Specialty Coatings (Aust) Pty Ltd Composition polymere renforcee
DE102013021124A1 (de) * 2013-12-13 2015-06-18 Eissmann Cotesa Gmbh Halbzeug, Werkstück aus Halbzeugen und Verwendung von Halbzeugen mit Fasern in ungehärteten duroplastischen Kunststoffmatrizen zur Realisierung unebener plattenförmiger Gegenstände

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US4990207A (en) * 1987-04-02 1991-02-05 Mitsui Toatsu Chemicals, Inc. Process for preparing fiber-reinforced thermoplastic molded articles
JPH01289837A (ja) * 1988-05-17 1989-11-21 Mitsui Toatsu Chem Inc 切れ目を入れた連続繊維プリプレグを使用する繊維強化熱可塑性プラスチックの製造法
US5120384A (en) * 1989-05-25 1992-06-09 Matsushita Electric Works, Ltd. Method of manufacturing multilayer laminate
US5267681A (en) * 1992-01-30 1993-12-07 Ski Tote, U.S.A. Utility rack anchor
US7056571B2 (en) * 2002-12-24 2006-06-06 Matsushita Electric Industrial Co., Ltd. Wiring board and its production process
CN101489767B (zh) * 2006-05-22 2015-04-29 尤米柯结构材料（德比）有限公司 模塑材料
WO2008038429A1 (fr) * 2006-09-28 2008-04-03 Toray Industries, Inc. Plastique renforcé par fibres et son procédé de production
US7655292B2 (en) * 2007-04-11 2010-02-02 Kaylu Industrial Corporation Electrically conductive substrate with high heat conductivity
CN101426331A (zh) * 2007-10-31 2009-05-06 富葵精密组件(深圳)有限公司 多层电路板
US8696965B2 (en) * 2008-10-20 2014-04-15 Cytec Technology Corp. Prepregs with improved processing
US8399773B2 (en) * 2009-01-27 2013-03-19 Shocking Technologies, Inc. Substrates having voltage switchable dielectric materials

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US2055002A (en) * 1936-03-28 1936-09-22 Chandler Frank Jermain Process of producing foraminous coated material
NL299684A (fr) * 1963-04-18 1900-01-01
US3558423A (en) * 1967-10-16 1971-01-26 Electronized Chem Corp Low loss electrical printed circuit board comprising polyolefin,fiberglass and metallic foil
US3660199A (en) * 1969-07-24 1972-05-02 Spaulding Fibre Co Method of preventing measling when making epoxy laminates
JPS5736127A (en) * 1980-08-14 1982-02-26 Shin Kobe Electric Mach Co Ltd Laminating molding prepreg
US4388136A (en) * 1980-09-26 1983-06-14 Sperry Corporation Method of making a polyimide/glass hybrid printed circuit board
KR860000405B1 (ko) * 1981-09-30 1986-04-17 요꼬야마 료오지 유리섬유직물
US4372347A (en) * 1981-12-28 1983-02-08 Uop Inc. Hybrid woven glass cloths
JPS58201614A (ja) * 1982-05-20 1983-11-24 Mitsubishi Rayon Co Ltd プリプレグシ−ト
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2633213A1 (fr) * 1988-06-27 1989-12-29 Europ Propulsion Procede de realisation d'une preforme fibreuse pour la fabrication de pieces en materiau composite ayant une forme complexe
EP0353564A2 (fr) * 1988-08-05 1990-02-07 Masonite Corporation Panneau à fibres de bois entaillé apte au moulage
EP0353564A3 (fr) * 1988-08-05 1992-01-02 Masonite Corporation Panneau à fibres de bois entaillé apte au moulage
US5306539A (en) * 1988-08-05 1994-04-26 Masonite Corporation Scored fiberboard having improved moldability
US5489460A (en) * 1988-08-05 1996-02-06 Masonite Corporation Molded non-planar board and method and apparatus for making same
US5855610A (en) 1995-05-19 1999-01-05 Children's Medical Center Corporation Engineering of strong, pliable tissues
WO2004050750A1 (fr) * 2002-12-04 2004-06-17 Specialty Coatings (Aust) Pty Ltd Composition polymere renforcee
DE102013021124A1 (de) * 2013-12-13 2015-06-18 Eissmann Cotesa Gmbh Halbzeug, Werkstück aus Halbzeugen und Verwendung von Halbzeugen mit Fasern in ungehärteten duroplastischen Kunststoffmatrizen zur Realisierung unebener plattenförmiger Gegenstände
DE102013021124B4 (de) * 2013-12-13 2017-06-14 Eissmann Cotesa Gmbh Halbzeug mit Endlosfasern in ungehärteten duroplastischen Kunststoffmatrizen zur Realisierung unebener plattenförmiger Gegenstände

Also Published As

Publication number Publication date
DE3771935D1 (de) 1991-09-12
JPH0657408B2 (ja) 1994-08-03
EP0248248A2 (fr) 1987-12-09
US4732636A (en) 1988-03-22
EP0248248A3 (en) 1988-11-02
JPS62280003A (ja) 1987-12-04

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