EP0193706A1 - Procédé et appareil à main pour le zingage semi-mécanique de surfaces de tôle - Google Patents
Procédé et appareil à main pour le zingage semi-mécanique de surfaces de tôle Download PDFInfo
- Publication number
- EP0193706A1 EP0193706A1 EP86100333A EP86100333A EP0193706A1 EP 0193706 A1 EP0193706 A1 EP 0193706A1 EP 86100333 A EP86100333 A EP 86100333A EP 86100333 A EP86100333 A EP 86100333A EP 0193706 A1 EP0193706 A1 EP 0193706A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- galvanizing
- tampon
- electrolyte
- hand
- processing element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 24
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 21
- 239000011701 zinc Substances 0.000 title claims abstract description 21
- 238000007747 plating Methods 0.000 title 1
- 238000005246 galvanizing Methods 0.000 claims abstract description 28
- 239000003792 electrolyte Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000012670 alkaline solution Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000003754 machining Methods 0.000 claims description 4
- 230000002745 absorbent Effects 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims description 3
- 230000002572 peristaltic effect Effects 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 230000008929 regeneration Effects 0.000 claims description 2
- 238000011069 regeneration method Methods 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 238000010422 painting Methods 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/04—Electroplating with moving electrodes
- C25D5/06—Brush or pad plating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
- C25D17/14—Electrodes, e.g. composition, counter electrode for pad-plating
Definitions
- the invention relates to a method and an apparatus for galvanizing sheet metal surfaces according to the preambles of claims 1 and 2.
- the object of the invention is to provide a method and a hand-held device for post-galvanizing, the device for performing the method being designed to be easy to handle and compact in order to carry out post-galvanizing in a simple manner even on shaped metal sheets in a strip production of motor vehicles to be able to take.
- the galvanizing should be constructed in such a way that subsequent stove enamelling is possible without post-treatment.
- the advantages achieved by the invention are essentially to be seen in the fact that the post-galvanizing process is to be carried out with an easy-to-use working device, with which the oscillating element works quickly due to its own movement. In addition to the self-movement, a free movement of the handheld device is possible.
- the device must also be used to clean the surface before galvanizing. For this purpose, only the processing element for galvanizing is exchanged for a processing element for cleaning, or two devices with the corresponding processing elements are used.
- the longitudinal and transverse grooves arranged in the working surface of the processing element preferably extend over the entire surface, so that a uniform delivery of zinc electrolyte to the coating is ensured.
- a peristaltic pump provided in the feed line enables an optimally metered delivery of the zinc electrolyte into the coating, so that the amount of liquid required for galvanizing is always available.
- a metering valve that interacts with the pump would also be possible.
- the procedure is coordinated so that the post-galvanizing layer is flush with the existing zinc layer and is constructed in such a way that further treatment of the sheets by baking is possible without bubbles or other unevenness on the painted sheet surface.
- Fig. 1 the structure of the method for galvanizing with a handheld device 1 is shown schematically.
- Zinc electrolyte is supplied to an absorbent coating 2, a so-called tampon, which is held on a processing element 3 and is absorbed by the tampon.
- the processing element 3 can consist of graphite or platinized titanium and forms an anode, the material 5 to be galvanized being designed as a cathode.
- the process is carried out at a voltage of 11 to 13 V and with a current of 10 to 15 A.
- the surface of the sheet is cleaned using an aqueous alkaline solution with a pH of around 13.
- the zinc electrolyte is based on an alkaline base and has a pH of around 8.
- a zinc layer with a thickness of 8 to 12 ⁇ m is achieved in about 2 to 3 minutes.
- the average layer thickness produced in this way can be assessed by an ampere-hour counter during application and a corresponding signal is generated after the desired layer thickness has been reached.
- the hand-held device 1 for carrying out the method essentially consists of the lower processing element 3 and an upper, manageable tool 7, which is detachably connected to the latter, and in which an oscillating part is integrated.
- the oscillating part sets the hand-held device in an automatically reciprocating movement on the workpiece 5.
- the hand-held device 1 can also be freely moved in any direction.
- the zinc electrolyte is supplied to the absorbent coating 2 via bores 8 which open into longitudinal and transverse grooves 9, 10 which are open towards the coating 2.
- the working surface 11 of the machining element 3 is adapted to the shape of the sheet 5, so that the area of the weld seam 12 with the element 3 is easily accessible.
- the shape shown is only an example, any other shape is also conceivable, for which purpose the processing element 3 must then be adapted accordingly.
- the galvanizing plant essentially comprises a line 13 for the zinc electrolyte, a peristaltic pump 14 and an upstream filter regeneration element 4.
- the method for galvanizing is carried out in such a way that the ground surfaces around the weld seam 12 are electrically cleaned, the hand-held device 1 likewise having a tampon to which a cleaning solution is fed.
- the galvanizing is then carried out by moving the hand tool 1 over the ground surfaces with a slight pressure while supplying zinc electrolyte.
- the coating 2 stampon
- the pump 14 is switched on via a relay 17 and the electrolyte circuit 13 is started up to the hand-held device 1.
- the line circuits are shown only schematically. After a deposition process, the ground surface is galvanized and flush with the rest of the zinc layer. This is followed by painting the sheet surface without post-treatment of the zinc layer.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Coating With Molten Metal (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3507927 | 1985-03-06 | ||
DE19853507927 DE3507927A1 (de) | 1985-03-06 | 1985-03-06 | Verfahren und handgeraet zum halbmechanischen verzinken von blechoberflaechen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0193706A1 true EP0193706A1 (fr) | 1986-09-10 |
EP0193706B1 EP0193706B1 (fr) | 1989-06-14 |
Family
ID=6264372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86100333A Expired EP0193706B1 (fr) | 1985-03-06 | 1986-01-13 | Procédé et appareil à main pour le zingage semi-mécanique de surfaces de tôle |
Country Status (3)
Country | Link |
---|---|
US (1) | US4879015A (fr) |
EP (1) | EP0193706B1 (fr) |
DE (2) | DE3507927A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3515807A1 (de) * | 1984-05-04 | 1985-11-07 | Diesel Kiki Co. Ltd., Tokio/Tokyo | Verfahren zur herstellung eines duennen films |
WO1990004052A1 (fr) * | 1988-10-06 | 1990-04-19 | Gut Gesellschaft Für Umweltschonende Technik Mbh | Dispositif et procede de protection longue duree de parties endommagees d'automobiles contre la corrosion |
CN109183021A (zh) * | 2018-11-19 | 2019-01-11 | 海盐力拓金属制品有限公司 | 一种金属零件机械镀锌设备 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4018649A1 (de) * | 1990-06-11 | 1991-12-12 | Hermann Dipl Chem Dr Clasen | Verfahren und vorrichtungen zum elektrolytischen verzinken |
DE4038717A1 (de) * | 1990-12-05 | 1992-06-11 | Saulius Baublys | Einrichtung zum elektro-chemischen beschriften von werkstuecken |
CH684840A5 (fr) * | 1991-06-11 | 1995-01-13 | Electroplating Eng Eesa | Cellule pour plaquer par voie électrolytique sélectivement des zones choisies de pièces métalliques disposées en bande. |
US5453174A (en) * | 1992-07-16 | 1995-09-26 | Electroplating Technologies Ltd. | Method and apparatus for depositing hard chrome coatings by brush plating |
US5225059A (en) * | 1992-08-03 | 1993-07-06 | W. R. Associates | Apparatus for single anode brush electroplating |
US5322613A (en) * | 1992-11-23 | 1994-06-21 | Tomy K.K. | Method and apparatus for marking orthodontic products |
US6171468B1 (en) | 1993-05-17 | 2001-01-09 | Electrochemicals Inc. | Direct metallization process |
US5725807A (en) * | 1993-05-17 | 1998-03-10 | Electrochemicals Inc. | Carbon containing composition for electroplating |
US5476580A (en) * | 1993-05-17 | 1995-12-19 | Electrochemicals Inc. | Processes for preparing a non-conductive substrate for electroplating |
US6303181B1 (en) | 1993-05-17 | 2001-10-16 | Electrochemicals Inc. | Direct metallization process employing a cationic conditioner and a binder |
US6710259B2 (en) | 1993-05-17 | 2004-03-23 | Electrochemicals, Inc. | Printed wiring boards and methods for making them |
US5690805A (en) * | 1993-05-17 | 1997-11-25 | Electrochemicals Inc. | Direct metallization process |
US5409593A (en) * | 1993-12-03 | 1995-04-25 | Sifco Industries, Inc. | Method and apparatus for selective electroplating using soluble anodes |
DE19809487A1 (de) * | 1998-03-06 | 1999-09-09 | Greising | Verfahren und Vorrichtung zur Aufbringung einer räumlich begrenzten metallischen Deckschicht auf einer elektrisch leitenden Materialoberfläche |
AU2003212164A1 (en) * | 2002-06-25 | 2004-01-06 | Integran Technologies Inc. | Process for in-situ electroforming a structural layer of metallic material to an outside wall of a metal tube |
US20030234181A1 (en) * | 2002-06-25 | 2003-12-25 | Gino Palumbo | Process for in-situ electroforming a structural layer of metallic material to an outside wall of a metal tube |
CN102492975A (zh) * | 2011-12-30 | 2012-06-13 | 中国科学院力学研究所 | 一种电解液喷射放电生长陶瓷涂层的装置及方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2961395A (en) * | 1950-11-03 | 1960-11-22 | Icxi Jean Jacques Georges | Portable manually operable plating device |
GB1070397A (en) * | 1963-09-03 | 1967-06-01 | Hoover Ltd | Improvements relating to the treatment of surfaces by electrolytic action |
DE1496875A1 (de) * | 1965-07-12 | 1969-04-10 | Johann Kerschgens | Geraet zum Herstellen von Metallueberzuegen auf galvanischem Wege |
AT271129B (de) * | 1966-05-27 | 1969-05-27 | Johann Kerschgens | Gerät zum Herstellen von Metallüberzügen auf galvanischem Wege |
DE1496867A1 (de) * | 1964-11-25 | 1969-10-09 | Johann Kerschgens | Handgeraet zum Herstellen galvanischer UEberzuege auf Werkstuecken |
US4304654A (en) * | 1980-10-24 | 1981-12-08 | Sifco Industries, Inc. | Apparatus for electroplating |
EP0049192A1 (fr) * | 1980-09-22 | 1982-04-07 | Dalic | Dispositif perfectionné pour l'oxydation anodique par électrolyse au tampon et électrolytes mis en oeuvre dans ce dispositif |
WO1985002869A1 (fr) * | 1983-12-20 | 1985-07-04 | Harju, Leo | Procede dispositif de nettoyage et de revetement d'une surface metallique sous-marine et instrument de deplacement pour ledit type de dispositif |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3751343A (en) * | 1971-06-14 | 1973-08-07 | A Macula | Brush electroplating metal at increased rates of deposition |
US4159934A (en) * | 1977-12-05 | 1979-07-03 | Kadija Igor V | Selective plating brush applicator |
DE3343396A1 (de) * | 1983-11-30 | 1985-06-05 | Kraftwerk Union AG, 4330 Mülheim | Verfahren zum dekontaminieren metallischer komponenten einer kerntechnischen anlage |
-
1985
- 1985-03-06 DE DE19853507927 patent/DE3507927A1/de active Granted
-
1986
- 1986-01-13 EP EP86100333A patent/EP0193706B1/fr not_active Expired
- 1986-01-13 DE DE8686100333T patent/DE3663959D1/de not_active Expired
-
1987
- 1987-09-17 US US07/097,716 patent/US4879015A/en not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2961395A (en) * | 1950-11-03 | 1960-11-22 | Icxi Jean Jacques Georges | Portable manually operable plating device |
GB1070397A (en) * | 1963-09-03 | 1967-06-01 | Hoover Ltd | Improvements relating to the treatment of surfaces by electrolytic action |
DE1496867A1 (de) * | 1964-11-25 | 1969-10-09 | Johann Kerschgens | Handgeraet zum Herstellen galvanischer UEberzuege auf Werkstuecken |
DE1496875A1 (de) * | 1965-07-12 | 1969-04-10 | Johann Kerschgens | Geraet zum Herstellen von Metallueberzuegen auf galvanischem Wege |
AT271129B (de) * | 1966-05-27 | 1969-05-27 | Johann Kerschgens | Gerät zum Herstellen von Metallüberzügen auf galvanischem Wege |
EP0049192A1 (fr) * | 1980-09-22 | 1982-04-07 | Dalic | Dispositif perfectionné pour l'oxydation anodique par électrolyse au tampon et électrolytes mis en oeuvre dans ce dispositif |
US4304654A (en) * | 1980-10-24 | 1981-12-08 | Sifco Industries, Inc. | Apparatus for electroplating |
WO1985002869A1 (fr) * | 1983-12-20 | 1985-07-04 | Harju, Leo | Procede dispositif de nettoyage et de revetement d'une surface metallique sous-marine et instrument de deplacement pour ledit type de dispositif |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3515807A1 (de) * | 1984-05-04 | 1985-11-07 | Diesel Kiki Co. Ltd., Tokio/Tokyo | Verfahren zur herstellung eines duennen films |
WO1990004052A1 (fr) * | 1988-10-06 | 1990-04-19 | Gut Gesellschaft Für Umweltschonende Technik Mbh | Dispositif et procede de protection longue duree de parties endommagees d'automobiles contre la corrosion |
CN109183021A (zh) * | 2018-11-19 | 2019-01-11 | 海盐力拓金属制品有限公司 | 一种金属零件机械镀锌设备 |
Also Published As
Publication number | Publication date |
---|---|
EP0193706B1 (fr) | 1989-06-14 |
DE3507927C2 (fr) | 1989-08-31 |
DE3507927A1 (de) | 1986-09-11 |
US4879015A (en) | 1989-11-07 |
DE3663959D1 (en) | 1989-07-20 |
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