EP0089623B1 - Verkokungsofen - Google Patents
Verkokungsofen Download PDFInfo
- Publication number
- EP0089623B1 EP0089623B1 EP83102630A EP83102630A EP0089623B1 EP 0089623 B1 EP0089623 B1 EP 0089623B1 EP 83102630 A EP83102630 A EP 83102630A EP 83102630 A EP83102630 A EP 83102630A EP 0089623 B1 EP0089623 B1 EP 0089623B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heating
- coke oven
- frame construction
- walls
- plates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000571 coke Substances 0.000 title claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 32
- 239000011449 brick Substances 0.000 claims description 17
- 238000010276 construction Methods 0.000 claims description 14
- 238000004939 coking Methods 0.000 claims description 12
- 239000011819 refractory material Substances 0.000 claims description 6
- 239000003566 sealing material Substances 0.000 claims description 3
- 206010022000 influenza Diseases 0.000 claims 2
- 239000004575 stone Substances 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 239000000463 material Substances 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 7
- 210000002105 tongue Anatomy 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 230000002441 reversible effect Effects 0.000 description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 6
- 229910010271 silicon carbide Inorganic materials 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 239000001095 magnesium carbonate Substances 0.000 description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 4
- 235000014380 magnesium carbonate Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000004566 building material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000011173 large scale experimental method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011467 thin brick Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B29/00—Other details of coke ovens
- C10B29/02—Brickwork, e.g. casings, linings, walls
Definitions
- the invention relates to a coking oven with walls between heating trains and coke chambers made of refractory material.
- the heat flow can be increased by increasing the heating draft temperatures and / or by using refractory bricks with higher thermal conductivity instead of the conventional silica material or particularly thin bricks made from such silica material (DE-PS 2161 980).
- a further reduction in the heating wall thickness is not justifiable for mechanical, especially structural reasons.
- a refractory retort module is known from a thin-walled main surface with a solid, tongue and groove frame.
- Such retort modules do have an improved heat transfer coefficient compared to uniformly thick modules, but the material thickness of the thin-walled main surfaces cannot be chosen to be as thin as desired compared to the frame, because otherwise different thermal expansions between the main surface and the frame lead to stress cracks.
- the size of such stones is limited because of their one-piece design. Particular difficulties arise when such stones are used for the walls of coke oven chambers, since they are only poorly suited for the interlocking of runner and binder stones.
- the invention is therefore based on the object of creating a coking oven of the type mentioned with heating walls with higher heat transfer rates and at the same time avoiding reversible thermal expansion of the heating walls as a whole at temperatures above 1000 ° C., and a solid connection between the binding stones separating the heating trains and to ensure the runner blocks separating the coke oven chambers from the heating trains.
- the invention is based on the basic idea of filling a lattice-like, self-supporting framework made of refractory bricks of material composition "A” with thin panels of material composition "B” that fill the free lattice areas and serve only as high a heat transfer as possible.
- This separation of the supporting function from the function of heat conduction allows the two functional elements to be optimally designed.
- the resulting frontal joints at the plate edges compared to the frame construction allow a different thermal expansion between the two functional elements without stress cracks.
- Refractory bricks have been found to be particularly favorable with regard to the stability of the lattice-shaped frame construction, which at the same time separate the individual adjacent heating cables of a heating wall of the coking oven.
- preferably two horizontally juxtaposed refractory bricks of two opposing heating walls form the binding bricks separating the heating trains from one another. This results in a particularly high strength of the frame construction.
- the heat transfer coefficient through the heating walls is improved in that they are created from a strong horizontal and vertical continuous latticework made of fireproof stones known per se and suitable for heating walls, in particular from silica stones, and plates from a likewise fire-resistant material of a reasonable size and comparatively enclose a high heat transfer coefficient, the thermal conductivity of which is higher than that of the stones used for the frame construction, e.g. B. SiC stones or SiC-containing plates (see DE-PS 2 019 078) in a frame construction made of silica stones.
- the plate format should not be larger than a justifiable tight joint can compensate for absolute changes in length and width resulting from the format dimensions. This largely prevents mechanical stress on the frame structure from the plates.
- suitable tongue and groove connections should be provided between these areas. It is advisable to only slightly chamfer the side surfaces of the tongue and groove, or even to design them at right angles to the top surfaces and mortar them. - So when the tongue is moved relative to the groove, there is only a minimal change in the joint width, so that the joint remains practically tight.
- the joints mentioned can be filled with an easily deformable sealing material in the region of their end faces lying opposite one another transversely to the wall plane, in particular cavities formed by the joints should be provided with such material.
- the top surfaces of the tongues and the bottom surfaces of the groove can be sealed against each other when bricking with ceramic fibers or possibly cardboard strips in order to keep a space for the reversible expansion of the plates after heating up the coking oven.
- the proposed construction enables the heating walls to be easily installed on a conventional substructure (sub-furnace); therefore, it can also be used in a coking oven to be repaired from the chamber bottom, e.g. H. be retrofitted.
- the heating walls are made up of approximately 50% of the plates containing at least 50% silicon carbide and, moreover, of a lattice-shaped frame construction made of silica stones, the average heating chamber temperature on the chamber side increases at the same heating draft temperature by approximately 100 ° C compared to a heating wall made of silica stones with the same average wall thickness.
- FIG. 1 shows a section of a horizontal coking furnace with walls (heating walls) 2 between heating trains 3 and coke chambers 4.
- the heating walls 2 consist of a lattice-shaped frame structure 5, of known, refractory stones 6 and the frame-filling plates 7 with a relatively high heat transfer coefficient, e.g. Silicon carbide.
- These stones can also have cavities 7a known per se on the heating-pull side to further improve the heat transfer coefficient, in particular they can be designed to be comparatively thin compared to the previously known so-called rotor stones.
- Refractory bricks 6, which form the verticals of the frame structure 5, have a depth transversely to the heating walls 2 such that opposing refractory bricks meet two heating walls and thus form the heating blocks 3 separating binder stones. Different depths of the opposing refractory bricks allow solid interlocking when laid alternately.
- Fig. 2 illustrates the lattice-shaped frame construction, in which e.g. horizontally several refractory bricks 6 are stacked on top of one another and possibly mortared, while vertical refractory bricks 6 bridge the spaces between the vertical columns in a yoke-like manner, with toothing 6a capturing the frame structure securely against shear and tensile forces at the crossing points of the latticework.
- FIG 3 shows a possible design of the joints between the refractory bricks 6 of the frame structure 5 and the plates 7.
- a tongue and groove design was selected with only slightly beveled side surfaces of the grooves 8a and the tongues 8b.
- the joint 8 runs through the wall 2 from surface to surface and is filled with mortar.
- a cavity located between the end faces 9 of the refractory bricks 6 and the plates 7 which lie opposite one another transversely to the wall plane can also be completely or partially filled by an elastic sealing material 11; this applies particularly to cavities 10, as shown on the bottom of the groove 8.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Silicon Compounds (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19823210108 DE3210108A1 (de) | 1982-03-19 | 1982-03-19 | Verkokungsofen |
DE3210108 | 1982-03-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0089623A2 EP0089623A2 (de) | 1983-09-28 |
EP0089623A3 EP0089623A3 (en) | 1985-01-09 |
EP0089623B1 true EP0089623B1 (de) | 1986-10-08 |
Family
ID=6158731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83102630A Expired EP0089623B1 (de) | 1982-03-19 | 1983-03-17 | Verkokungsofen |
Country Status (7)
Country | Link |
---|---|
US (1) | US4565605A (es) |
EP (1) | EP0089623B1 (es) |
JP (1) | JPS58168684A (es) |
AU (1) | AU551055B2 (es) |
BR (1) | BR8301382A (es) |
DE (2) | DE3210108A1 (es) |
ES (1) | ES279838Y (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6418139U (es) * | 1987-07-24 | 1989-01-30 | ||
JPH0776339B2 (ja) * | 1988-05-24 | 1995-08-16 | ルールコーレ アクチエンゲゼルシヤフト | コークス炉の天井 |
DE8910715U1 (de) * | 1989-09-08 | 1989-10-19 | Ruhrkohle Ag, 4300 Essen | Koksofenkammertür |
US5227106A (en) * | 1990-02-09 | 1993-07-13 | Tonawanda Coke Corporation | Process for making large size cast monolithic refractory repair modules suitable for use in a coke oven repair |
US5137603A (en) * | 1991-01-16 | 1992-08-11 | Resco Products, Inc. | Oven walls |
US5597452A (en) * | 1992-09-24 | 1997-01-28 | Robert Bosch Gmbh | Method of restoring heating walls of coke oven battery |
US7827689B2 (en) * | 2007-01-16 | 2010-11-09 | Vanocur Refractories, L.L.C. | Coke oven reconstruction |
US8266853B2 (en) | 2009-05-12 | 2012-09-18 | Vanocur Refractories Llc | Corbel repairs of coke ovens |
CN114989836A (zh) * | 2022-05-29 | 2022-09-02 | 中国五冶集团有限公司 | 一种热回收焦炉含填充物的膨胀缝施工方法 |
CN115449378B (zh) * | 2022-09-29 | 2024-05-14 | 中冶焦耐(大连)工程技术有限公司 | 一种电加热焦炉的加热室结构 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE143332C (es) * | ||||
US682441A (en) * | 1901-05-22 | 1901-09-10 | Samuel T Wellman | Coke-oven. |
GB299795A (en) * | 1927-04-27 | 1928-10-29 | Low Temp Carbonisation Ltd | Improvements relating to retorts for the distillation of solid carbonaceous substances |
US2091703A (en) * | 1936-02-14 | 1937-08-31 | Koppers Co Inc | Coking retort oven structure |
US2839453A (en) * | 1953-10-20 | 1958-06-17 | Koppers Co Inc | Coking retort oven with graduated liner wall |
US2850196A (en) * | 1955-06-06 | 1958-09-02 | Goodyear Tire & Rubber | Joint structure |
GB806610A (en) * | 1955-08-11 | 1958-12-31 | Carl Otto | Improvements relating to coke oven heating walls |
US3102846A (en) * | 1961-04-20 | 1963-09-03 | Koppers Co Inc | Coking retort oven with liner walls of two thicknesses |
US3496067A (en) * | 1967-01-27 | 1970-02-17 | Koppers Co Inc | Horizontal coke oven having plural types of brick linings for heating walls |
DE2019078C3 (de) * | 1970-04-21 | 1974-01-10 | Bergwerksverband Gmbh, 4300 Essen | SiC-haltiger feuerfester Stein für die Ausmauerung von diskontinuierlich betriebenen Verkokungsöfen |
US4039342A (en) * | 1970-04-21 | 1977-08-02 | Bergwerksverband Gmbh | Firebricks |
DE2056119B2 (de) * | 1970-11-14 | 1974-09-05 | Bergwerksverband Gmbh, 4300 Essen | Koksöfen mit hoher spezifischer Durchsatzleistung |
DE2161980C3 (de) * | 1971-12-14 | 1974-10-10 | Bergwerksverband Gmbh, 4300 Essen-Kray | Waagerechter Verkokungsofen |
DE2713461C2 (de) * | 1977-03-26 | 1979-05-23 | Bergwerksverband Gmbh, 4300 Essen | Horizontaler Verkokungsofen |
DE2908839C2 (de) * | 1979-03-07 | 1985-06-27 | Carl Still Gmbh & Co Kg, 4350 Recklinghausen | Vorrichtung zur Abdichtung der Kammern von Verkokungsöfen |
-
1982
- 1982-03-19 DE DE19823210108 patent/DE3210108A1/de not_active Withdrawn
-
1983
- 1983-03-07 JP JP58036074A patent/JPS58168684A/ja active Pending
- 1983-03-17 EP EP83102630A patent/EP0089623B1/de not_active Expired
- 1983-03-17 DE DE8383102630T patent/DE3366704D1/de not_active Expired
- 1983-03-18 BR BR8301382A patent/BR8301382A/pt unknown
- 1983-03-18 ES ES1983279838U patent/ES279838Y/es not_active Expired
- 1983-03-18 US US06/476,527 patent/US4565605A/en not_active Expired - Fee Related
- 1983-03-18 AU AU12593/83A patent/AU551055B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
DE3366704D1 (en) | 1986-11-13 |
DE3210108A1 (de) | 1983-09-22 |
ES279838Y (es) | 1985-11-16 |
AU1259383A (en) | 1983-09-22 |
EP0089623A2 (de) | 1983-09-28 |
JPS58168684A (ja) | 1983-10-05 |
ES279838U (es) | 1985-04-16 |
AU551055B2 (en) | 1986-04-17 |
BR8301382A (pt) | 1983-11-29 |
US4565605A (en) | 1986-01-21 |
EP0089623A3 (en) | 1985-01-09 |
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Legal Events
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