EP0078069B1 - Revêtement réfractaire pour récipients ou fours contenant du métal liquide - Google Patents
Revêtement réfractaire pour récipients ou fours contenant du métal liquide Download PDFInfo
- Publication number
- EP0078069B1 EP0078069B1 EP19820201112 EP82201112A EP0078069B1 EP 0078069 B1 EP0078069 B1 EP 0078069B1 EP 19820201112 EP19820201112 EP 19820201112 EP 82201112 A EP82201112 A EP 82201112A EP 0078069 B1 EP0078069 B1 EP 0078069B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- lining
- weight
- refractory
- expansion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910001338 liquidmetal Inorganic materials 0.000 title claims description 3
- 229910000805 Pig iron Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 6
- 235000019362 perlite Nutrition 0.000 claims description 6
- 239000011819 refractory material Substances 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010431 corundum Substances 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052839 forsterite Inorganic materials 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 229910052863 mullite Inorganic materials 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 229910052851 sillimanite Inorganic materials 0.000 claims description 2
- 239000004575 stone Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000011449 brick Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000011490 mineral wool Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001474791 Proboscis Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/02—Linings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
- F27B3/10—Details, accessories, or equipment peculiar to hearth-type furnaces
- F27B3/12—Working chambers or casings; Supports therefor
- F27B3/14—Arrangements of linings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/0003—Linings or walls
- F27D1/0023—Linings or walls comprising expansion joints or means to restrain expansion due to thermic flows
Definitions
- the invention relates to a refractory lining for vessels and ovens with a liquid metal insert, in particular for pig iron transport vessels, such as pipe pans and torpedo pans, with an expansion space provided at least in some areas between the furnace jacket or the permanent lining and the wear lining which is laid seamlessly and a mass which is arranged under pressure and is flexible that contains granular refractory material.
- the expansion space is created by introducing a compressible backfill material between the furnace jacket or the permanent lining and the wear lining laid without joints.
- the object of the invention is to avoid the disadvantages mentioned and to fill the expansion space with a mass which is resistant to treading and manipulation, but is sufficiently compressible under the pressure which occurs due to the thermal expansion of the refractory bricks, namely at a pressure which is far below the Quarry limit lies, whereby an exact laying of the wear lining is to be made possible.
- this object is achieved in that the expansion space with a compressible, hydraulically settable, water-provided backfill consisting of 4-20% by weight of expanded perlite, 15-25% by weight of alumina cement, based on the dry mass , 5-4 wt .-% plasticizers, such as cellulose ether, e.g. B. carboxymethyl cellulose, and the rest is filled to 100 wt .-% of refractory base material.
- plasticizers such as cellulose ether, e.g. B. carboxymethyl cellulose
- the fireproof base material of the backfill can consist of magnesite, mullite, corundum, chrome ore, sillimanite, forsterite or mixtures thereof.
- the backfilling mass is, depending on the desired consistency, provided with a water addition of 35-45% by weight based on the dry mass.
- Expanded perlite is used as a compressible component of the backfill.
- Perlite is around liparite or quartz porphyry glasses of volcanic origin. When this rock with many small water inclusions is heated to over 1200 ° C, it expands by 15 to 20 times its volume to form an expanded product with microfine, largely closed pores. Expanded perlite has the following typical composition:
- Expanded perlite is used for the purposes of the invention in a grain size of approximately 0-5 mm with a relatively small fine fraction below 0.5 mm.
- composition (in% by weight)
- a mass of the composition according to Example B was mixed with an addition of 40% by weight of water, based on the dry mass, and between two refractory stones of normal stone format in a layer thickness of 10 mm and under a preload of 0.2 N / mm 2 applied. After drying for 2 hours at room temperature, the mass layer in the hydraulically set state showed the following compressibility depending on the load:
- the hydraulically set mass is compressible to about 50% at a load of 10 N / mm 2 , which corresponds approximately to the pressure caused by the stone expansion and which is far below the quarry limit, which ensures a safe expansion absorption and for every occurring in practice Pressure a very good clamping of the refractory lining are guaranteed.
- the dry mass shows practically no changes or segregation during transport, despite the vibrations that occur, as well as during storage and stacking after filling in sacks or containers.
- the backing of the pig iron vessel is first freed of dust and moistened. Then the backfill compound mixed with water can be applied in the entire cylindrical part of the vessel in one step in the desired thickness. This can be done similarly to the application of a plastering mortar, which is common in the construction industry, i.e. using a trowel or a plaster. It is also possible to use a gate locking machine to apply the mass. The mass adheres so well that it adheres completely overhead and does not fall off. The required uniform application thickness - depending of the expected stone expansion - can be achieved by pulling off with a slat provided with spacer nails.
- the mass is tread-resistant about 2 hours after the application is complete, and the delivery of the wear lining made of refractory stones can then be started.
- appropriate heat must be provided for drying or longer waiting times are required.
- the mass can also be used as a hydraulically setting coating or plastering compound in other furnace units in which the wear lining should specifically move in the direction of the permanent or insulating lining or the sheet metal jacket of the furnace due to the laying without expansion inserts, e.g. B. in Mazieres furnaces, drum furnaces of the non-ferrous metal industry, proboscis of steel degassing plants.
- the mass has a similar compressibility in the dry state as in the hydraulically set state, it can also be used as a dry backfilling mass.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Ceramic Products (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Compositions Of Oxide Ceramics (AREA)
Claims (3)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT4573/81 | 1981-10-27 | ||
AT0457381A AT371425B (de) | 1981-10-27 | 1981-10-27 | Feuerfeste auskleidung fuer gefaesse und oefen mit fluessigem metalleinsatz |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0078069A2 EP0078069A2 (fr) | 1983-05-04 |
EP0078069A3 EP0078069A3 (en) | 1984-04-25 |
EP0078069B1 true EP0078069B1 (fr) | 1986-04-16 |
Family
ID=3565683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19820201112 Expired EP0078069B1 (fr) | 1981-10-27 | 1982-09-09 | Revêtement réfractaire pour récipients ou fours contenant du métal liquide |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0078069B1 (fr) |
JP (1) | JPS5884172A (fr) |
AT (1) | AT371425B (fr) |
DE (1) | DE3270642D1 (fr) |
ES (1) | ES8402354A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9012677D0 (en) * | 1990-06-07 | 1990-08-01 | Foseco Int | Refractory composition |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1463895A (fr) * | 1965-09-28 | 1966-07-22 | Matériaux thermo-isolants réfractaires | |
AT288952B (de) * | 1968-12-06 | 1971-03-25 | Veitscher Magnesitwerke Ag | Feuerfeste Auskleidung mit Dehnungsausgleich und Verfahren zur Herstellung einer Isoliermasse für solche Auskleidungen |
JPS5549033B2 (fr) * | 1974-05-15 | 1980-12-09 | ||
DE2632880C2 (de) * | 1975-08-04 | 1985-03-14 | Dr. K. Ableidiger & Co, Küsnacht | Organisch gebundene Isolierkörper für die Erstarrungslenkung von Metallen |
-
1981
- 1981-10-27 AT AT0457381A patent/AT371425B/de not_active IP Right Cessation
-
1982
- 1982-09-09 DE DE8282201112T patent/DE3270642D1/de not_active Expired
- 1982-09-09 EP EP19820201112 patent/EP0078069B1/fr not_active Expired
- 1982-10-06 ES ES516253A patent/ES8402354A1/es not_active Expired
- 1982-10-26 JP JP57188088A patent/JPS5884172A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
EP0078069A2 (fr) | 1983-05-04 |
ES516253A0 (es) | 1984-01-16 |
JPS6112872B2 (fr) | 1986-04-10 |
DE3270642D1 (en) | 1986-05-22 |
AT371425B (de) | 1983-06-27 |
EP0078069A3 (en) | 1984-04-25 |
JPS5884172A (ja) | 1983-05-20 |
ES8402354A1 (es) | 1984-01-16 |
ATA457381A (de) | 1982-11-15 |
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