EP0056881A1 - Procédé pour la phosphatation de métaux - Google Patents
Procédé pour la phosphatation de métaux Download PDFInfo
- Publication number
- EP0056881A1 EP0056881A1 EP81201244A EP81201244A EP0056881A1 EP 0056881 A1 EP0056881 A1 EP 0056881A1 EP 81201244 A EP81201244 A EP 81201244A EP 81201244 A EP81201244 A EP 81201244A EP 0056881 A1 EP0056881 A1 EP 0056881A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solutions
- metal surfaces
- contact
- brought
- contain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 24
- 239000002184 metal Substances 0.000 title claims abstract description 24
- 150000002739 metals Chemical class 0.000 title claims abstract description 7
- 239000011701 zinc Substances 0.000 claims abstract description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 9
- 239000010959 steel Substances 0.000 claims abstract description 9
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 6
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 6
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 5
- 230000002378 acidificating effect Effects 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- -1 aromatic nitro compounds Chemical class 0.000 claims description 6
- 238000004070 electrodeposition Methods 0.000 claims description 6
- 150000002222 fluorine compounds Chemical class 0.000 claims 1
- 238000007598 dipping method Methods 0.000 abstract 2
- TVWHTOUAJSGEKT-UHFFFAOYSA-N chlorine trioxide Chemical compound [O]Cl(=O)=O TVWHTOUAJSGEKT-UHFFFAOYSA-N 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 229910019142 PO4 Inorganic materials 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000009189 diving Effects 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 101100116570 Caenorhabditis elegans cup-2 gene Proteins 0.000 description 2
- 101100116572 Drosophila melanogaster Der-1 gene Proteins 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- ZLCPKMIJYMHZMJ-UHFFFAOYSA-N 2-nitrobenzene-1,3-diol Chemical compound OC1=CC=CC(O)=C1[N+]([O-])=O ZLCPKMIJYMHZMJ-UHFFFAOYSA-N 0.000 description 1
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229910004074 SiF6 Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
- C23C22/184—Orthophosphates containing manganese cations containing also zinc cations containing also nickel cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/14—Orthophosphates containing zinc cations containing also chlorate anions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations
Definitions
- the invention relates to a process for the phosphating of metals, in particular iron and steel, with aqueous acidic chlorate-containing zinc phosphate solutions at temperatures from 30 to 60 ° C. and its use for preparing the metal surfaces for electrocoating.
- the reduced zinc content compared to the usual phosphating baths leads to improved thin and uniform phosphate coatings, which are very adhesive and durable and are particularly suitable as a basis for the subsequent electrocoating. In this process, it has proven to be very advantageous to additionally use nitrite in order to achieve the desired results.
- DE-OS 30 04 927 discloses a process for phosphating metals which are subsequently electroplated, in which acidic aqueous zinc phosphate solutions are also used.
- the solutions contain nitrite ions and / or aromatic nitro compounds as accelerators.
- the phosphating is carried out in a special immersion / spray process.
- a disadvantage of the known methods is that the nitrite which is preferably used to form nitrous gases which are known to be toxic and noxious. Suction measures are therefore essential to ensure occupational safety.
- the object of the invention is to provide a method which does not have the disadvantages of the known methods, requires little heating energy because of the low application temperatures and is simple to carry out.
- the object is achieved by designing the method of the type mentioned at the outset in accordance with the invention in such a way that the metal surfaces are brought into contact with solutions which contain, to which no nitrite is added and in which the weight ratio of Zn to Ni to a value between 1: (0.5 to 1.5), Z n to P 2 O 5 to a value between 1: (8 to 85) and Free P 2 O 5 to total P 2 O 5 is set to a value between (0.005 (at approx. 30 ° C) to 0.06 (at approx. 60 ° C)): 1.
- the method according to the invention is intended in particular for the treatment of iron and steel. However, it is also suitable for the phosphating of zinc and aluminum materials as well as for steel with coatings made of zinc, zinc alloys, aluminum and aluminum alloys produced according to a wide variety of processes.
- the treatment of the metal surfaces can be carried out in the spraying process, in the flooding process and also in the immersion process Spray-dive-spray, flood-dive and the like are applicable.
- the contact times for the phosphating solution with the metal surface are in the usual range and can e.g. for spraying 45 seconds to 3 minutes, for diving 2 to 5 minutes and for spray diving 20 seconds spraying, 3 minutes diving.
- the bath temperatures are 30 to 60 ° C. The lower the bath temperature, the longer i.a. the contact time.
- nickel to the bathroom has a generally beneficial effect on the phosphating, the layer formation on heavy phosphatizable steel surfaces to which P hosphatierung of zinc surfaces and to anti-corrosive properties.
- the ratio of free P 2 O 5 to total P205 in the bath must be kept between (0.005 to 0.06): 1 in order to produce uniformly covering phosphate layers.
- the phosphating rate becomes slower, at the same time the quality of the phosphate layers decreases. Falling below the specified values leads to excessive precipitation of zinc phosphate sludge and is undesirable for this reason alone.
- the low values of the ratio of free P 2 O 5 to total P 2 O 5 (acid ratio) in the range according to the invention apply to the lower bath temperatures (low ratio Zn / P 2 O 3 and low overall concentration; higher acid ratios refer to higher bath temperatures (higher Zn / P 2 O 5 ratios and higher overall concentrations). Based on these general statements about the dependence of the acid ratio, this can be determined for one. tes bath of the invention optimal acid ratio easily estimated or determined by experiment.
- One embodiment of the invention consists in bringing the metal surfaces into contact with solution which contain 0.8 to 1.2 g / 1 Zn.
- phosphating solutions which contain up to 0.7 g / l, in particular 0.2 to 0.5 g / 1 Mn.
- the use of manganese has proven to be particularly beneficial in phosphating in the low temperature range.
- Further advantageous embodiments of the invention consist in bringing the metal surfaces into contact with solutions in which the chlorate content is 1 to 3 g / l, the further accelerator up to 4 g / 1 nitrate or the additive up to 2 g / 1, preferably contain at least 0.1 g / 1, nitro compounds.
- Na-m-nitrobenzenesulfonate has proven particularly useful as the organic aromatic nitro compound to be used.
- Nitroresorcinol or nitrobenzoic acid can be used.
- the layer formation can be improved by adding simple and / or complex fluorides.
- solutions for reducing the weight of the phosphate layer for this purpose can be known compounds such as. Hydroxycarboxylic acids (e.g. tartaric acid, citric acid), polyphosphates (e.g. triplyphosphate, hexametaphosphate).
- Hydroxycarboxylic acids e.g. tartaric acid, citric acid
- polyphosphates e.g. triplyphosphate, hexametaphosphate.
- the necessary acid ratio is essentially set, nar with alkali metal ions.
- Other cations e.g. calcium, Solies, on the other hand, only exist in minor quantities.
- the weight per unit area of the phosphate layers produced by the process according to the invention is generally in the range between 0 , 8 and 4 g / m 2 .
- activating agents for example based on titanium phosphate, in the pre-rinse bath or in the last cleaning stage is recommended.
- the phosphate layers produced by the method according to the invention are suitable in principle for all types of use of the phosphate layers known to date.
- the layers bring about an unusually strong improvement in the resistance of the coating film against the infiltration of the coating in the event of corrosive stress and a significant increase in the adhesion of the coating to the metallic substrate.
- the sheets were rinsed with water, rinsed with a rinse solution containing chromic acid and then coated with anodic and cathodic electrocoat.
- the application tests such as salt spray test, condensation test, rockfall text and outdoor exposure, led to very good results.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Paints Or Removers (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT81201244T ATE17955T1 (de) | 1981-01-22 | 1981-11-03 | Verfahren zur phosphatierung von metallen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813101866 DE3101866A1 (de) | 1981-01-22 | 1981-01-22 | Verfahren zur phosphatierung von metallen |
| DE3101866 | 1981-01-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0056881A1 true EP0056881A1 (fr) | 1982-08-04 |
| EP0056881B1 EP0056881B1 (fr) | 1986-02-12 |
Family
ID=6123050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP81201244A Expired EP0056881B1 (fr) | 1981-01-22 | 1981-11-03 | Procédé pour la phosphatation de métaux |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4389260A (fr) |
| EP (1) | EP0056881B1 (fr) |
| AT (1) | ATE17955T1 (fr) |
| CA (1) | CA1183430A (fr) |
| DE (2) | DE3101866A1 (fr) |
| ES (1) | ES508885A0 (fr) |
| GB (1) | GB2093075B (fr) |
| IT (1) | IT1190666B (fr) |
| PT (1) | PT74310B (fr) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2512840A1 (fr) * | 1981-09-17 | 1983-03-18 | Amchem Prod | Solutions aqueuses acides pour revetements de phosphate de zinc et leurs concentres, procedes de revetement les mettant en oeuvre et solutions d'activation du metal utilisables dans ces procedes |
| EP0106459A1 (fr) * | 1982-08-24 | 1984-04-25 | HENKEL CORPORATION (a Delaware Corp.) | Phosphatation de surfaces métalliques |
| EP0135622A1 (fr) * | 1983-08-22 | 1985-04-03 | Nippon Paint Co., Ltd. | Phosphatation de surfaces métalliques |
| EP0141341A1 (fr) * | 1983-10-26 | 1985-05-15 | Metallgesellschaft Ag | Procédé pour la formation de revêtements de phosphate |
| WO1986004931A1 (fr) * | 1985-02-22 | 1986-08-28 | Henkel Kommanditgesellschaft Auf Aktien | Procede de phosphatation de surfaces metalliques |
| EP0219779A2 (fr) * | 1985-10-18 | 1987-04-29 | Gerhard Collardin GmbH | Procédé de phosphatation de pièces métalliques zinguées électrolytiquement |
| EP0258922A1 (fr) * | 1986-09-05 | 1988-03-09 | Metallgesellschaft Ag | Procédé pour produire des revêtements de phosphate et leur utilisation |
| EP0264811A1 (fr) * | 1986-10-16 | 1988-04-27 | Nihon Parkerizing Co., Ltd. | Procédé d'obtention de revêtements de phosphate |
| WO1990012901A1 (fr) * | 1989-04-21 | 1990-11-01 | Henkel Kommanditgesellschaft Auf Aktien | Procede sans chlorate ni nitrite pour produire des couches de phosphate de zinc contenant du nickel et du manganese |
| WO1996017977A1 (fr) * | 1994-12-09 | 1996-06-13 | Metallgesellschaft Aktiengesellschaft | Procede d'application de revetements de phosphate sur des surfaces metalliques |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4673444A (en) * | 1981-03-16 | 1987-06-16 | Koichi Saito | Process for phosphating metal surfaces |
| DE3239088A1 (de) * | 1982-10-22 | 1984-04-26 | Chemische Werke Kluthe GmbH & Co, 6900 Heidelberg | Verfahren zur phosphatierung von metalloberflaechen |
| DE3244715A1 (de) * | 1982-12-03 | 1984-06-07 | Gerhard Collardin GmbH, 5000 Köln | Verfahren zur phosphatierung von metalloberflaechen sowie hierfuer geeignete badloesungen |
| DE3245411A1 (de) * | 1982-12-08 | 1984-07-05 | Gerhard Collardin GmbH, 5000 Köln | Verfahren zur phosphatierung elektrolytisch verzinkter metallwaren |
| GB8329250D0 (en) * | 1983-11-02 | 1983-12-07 | Pyrene Chemical Services Ltd | Phosphating processes |
| US4793867A (en) * | 1986-09-26 | 1988-12-27 | Chemfil Corporation | Phosphate coating composition and method of applying a zinc-nickel phosphate coating |
| EP0327153B1 (fr) * | 1988-02-03 | 1993-08-04 | Metallgesellschaft Ag | Procédé pour former des couches de phosphates sur des métaux |
| DE3828888A1 (de) * | 1988-08-25 | 1990-03-08 | Ford Werke Ag | Fuer die aussenseite von kraftfahrzeugkarosserieteilen bestimmtes mehrfach beschichtetes stahlblech |
| US5261973A (en) * | 1991-07-29 | 1993-11-16 | Henkel Corporation | Zinc phosphate conversion coating and process |
| US5653790A (en) * | 1994-11-23 | 1997-08-05 | Ppg Industries, Inc. | Zinc phosphate tungsten-containing coating compositions using accelerators |
| US5588989A (en) * | 1994-11-23 | 1996-12-31 | Ppg Industries, Inc. | Zinc phosphate coating compositions containing oxime accelerators |
| WO2001076811A1 (fr) * | 2000-04-07 | 2001-10-18 | Whyco Technologies, Inc. | Procede de masquage de revetements et objet resultant |
| US7815751B2 (en) * | 2005-09-28 | 2010-10-19 | Coral Chemical Company | Zirconium-vanadium conversion coating compositions for ferrous metals and a method for providing conversion coatings |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH567106A5 (fr) * | 1971-07-06 | 1975-09-30 | Parker Ste Continentale | |
| DE3004927A1 (de) * | 1979-02-13 | 1980-08-21 | Nippon Paint Co Ltd | Verfahren zur phosphatierung von metallen |
| EP0015021A1 (fr) * | 1979-02-23 | 1980-09-03 | Metallgesellschaft Ag | Procédé de préparation de surfaces métalliques avant dépôt de primaire par immersion électrophorétique |
| EP0018841A1 (fr) * | 1979-05-02 | 1980-11-12 | Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America | Composition et procédé pour revêtir de phosphate de zinc la surface d'un métal, surface revêtue d'un métal et procédé pour le vernissage de la surface enduite |
| EP0019430A1 (fr) * | 1979-05-11 | 1980-11-26 | Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America | Composition et procédé pour revêtir la surface d'un métal de phosphate de zinc et procédé pour le vernissage de la surface revêtue |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3203835A (en) * | 1962-10-25 | 1965-08-31 | Pennsalt Chemicals Corp | Chlorate accelerated zinc phosphating baths with added arsenate |
| US3533859A (en) * | 1966-06-18 | 1970-10-13 | Hooker Chemical Corp | Coating process for ferrous metal surfaces |
| US3676224A (en) * | 1970-10-16 | 1972-07-11 | Lubrizol Corp | Phosphating solution with scale suppressing characteristics |
| DE2100021A1 (de) * | 1971-01-02 | 1972-09-07 | Collardin Gmbh Gerhard | Verfahren zum Aufbringen von Phos phatschichten auf Stahl, Eisen und Zinkoberflachen |
| SE406940B (sv) * | 1974-04-13 | 1979-03-05 | Collardin Gmbh Gerhard | Forfarande for framstellning av fosfatbeleggningar med sprutningsmetoden pa jern och stal |
| JPS5339945A (en) * | 1976-09-25 | 1978-04-12 | Nippon Packaging Kk | Surface treatment of zinc or zinc alloy |
-
1981
- 1981-01-22 DE DE19813101866 patent/DE3101866A1/de not_active Withdrawn
- 1981-11-03 EP EP81201244A patent/EP0056881B1/fr not_active Expired
- 1981-11-03 AT AT81201244T patent/ATE17955T1/de not_active IP Right Cessation
- 1981-11-03 DE DE8181201244T patent/DE3173781D1/de not_active Expired
- 1981-12-21 CA CA000392764A patent/CA1183430A/fr not_active Expired
-
1982
- 1982-01-08 US US06/337,916 patent/US4389260A/en not_active Expired - Lifetime
- 1982-01-19 PT PT74310A patent/PT74310B/fr unknown
- 1982-01-20 ES ES508885A patent/ES508885A0/es active Granted
- 1982-01-21 IT IT19228/82A patent/IT1190666B/it active
- 1982-01-22 GB GB8201900A patent/GB2093075B/en not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH567106A5 (fr) * | 1971-07-06 | 1975-09-30 | Parker Ste Continentale | |
| DE3004927A1 (de) * | 1979-02-13 | 1980-08-21 | Nippon Paint Co Ltd | Verfahren zur phosphatierung von metallen |
| EP0015021A1 (fr) * | 1979-02-23 | 1980-09-03 | Metallgesellschaft Ag | Procédé de préparation de surfaces métalliques avant dépôt de primaire par immersion électrophorétique |
| EP0018841A1 (fr) * | 1979-05-02 | 1980-11-12 | Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America | Composition et procédé pour revêtir de phosphate de zinc la surface d'un métal, surface revêtue d'un métal et procédé pour le vernissage de la surface enduite |
| EP0019430A1 (fr) * | 1979-05-11 | 1980-11-26 | Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America | Composition et procédé pour revêtir la surface d'un métal de phosphate de zinc et procédé pour le vernissage de la surface revêtue |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2512840A1 (fr) * | 1981-09-17 | 1983-03-18 | Amchem Prod | Solutions aqueuses acides pour revetements de phosphate de zinc et leurs concentres, procedes de revetement les mettant en oeuvre et solutions d'activation du metal utilisables dans ces procedes |
| EP0106459A1 (fr) * | 1982-08-24 | 1984-04-25 | HENKEL CORPORATION (a Delaware Corp.) | Phosphatation de surfaces métalliques |
| EP0135622A1 (fr) * | 1983-08-22 | 1985-04-03 | Nippon Paint Co., Ltd. | Phosphatation de surfaces métalliques |
| EP0141341A1 (fr) * | 1983-10-26 | 1985-05-15 | Metallgesellschaft Ag | Procédé pour la formation de revêtements de phosphate |
| US4708744A (en) * | 1985-02-22 | 1987-11-24 | Henkel Kommanditgesellschaft Auf Aktien | Process for phosphating metal surfaces and especially iron surfaces |
| WO1986004931A1 (fr) * | 1985-02-22 | 1986-08-28 | Henkel Kommanditgesellschaft Auf Aktien | Procede de phosphatation de surfaces metalliques |
| EP0219779A2 (fr) * | 1985-10-18 | 1987-04-29 | Gerhard Collardin GmbH | Procédé de phosphatation de pièces métalliques zinguées électrolytiquement |
| EP0219779A3 (en) * | 1985-10-18 | 1988-12-21 | Gerhard Collardin Gmbh | Phosphatizing process for electrolytically galvanized metal objects |
| EP0258922A1 (fr) * | 1986-09-05 | 1988-03-09 | Metallgesellschaft Ag | Procédé pour produire des revêtements de phosphate et leur utilisation |
| EP0264811A1 (fr) * | 1986-10-16 | 1988-04-27 | Nihon Parkerizing Co., Ltd. | Procédé d'obtention de revêtements de phosphate |
| WO1990012901A1 (fr) * | 1989-04-21 | 1990-11-01 | Henkel Kommanditgesellschaft Auf Aktien | Procede sans chlorate ni nitrite pour produire des couches de phosphate de zinc contenant du nickel et du manganese |
| WO1996017977A1 (fr) * | 1994-12-09 | 1996-06-13 | Metallgesellschaft Aktiengesellschaft | Procede d'application de revetements de phosphate sur des surfaces metalliques |
| US5904786A (en) * | 1994-12-09 | 1999-05-18 | Metallgesellschaft Aktiengesellschaft | Method of applying phosphate coatings to metal surfaces |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1183430A (fr) | 1985-03-05 |
| US4389260A (en) | 1983-06-21 |
| GB2093075A (en) | 1982-08-25 |
| IT8219228A0 (it) | 1982-01-21 |
| PT74310A (fr) | 1982-02-01 |
| PT74310B (fr) | 1983-08-08 |
| DE3173781D1 (en) | 1986-03-27 |
| ATE17955T1 (de) | 1986-02-15 |
| GB2093075B (en) | 1985-05-22 |
| ES8305050A1 (es) | 1983-04-01 |
| ES508885A0 (es) | 1983-04-01 |
| EP0056881B1 (fr) | 1986-02-12 |
| DE3101866A1 (de) | 1982-08-26 |
| IT1190666B (it) | 1988-02-24 |
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