EP0049405B1 - Procédé de traitement de gaze pour tamis d'impression avec au moins un agent de blanchiment - Google Patents
Procédé de traitement de gaze pour tamis d'impression avec au moins un agent de blanchiment Download PDFInfo
- Publication number
- EP0049405B1 EP0049405B1 EP81107406A EP81107406A EP0049405B1 EP 0049405 B1 EP0049405 B1 EP 0049405B1 EP 81107406 A EP81107406 A EP 81107406A EP 81107406 A EP81107406 A EP 81107406A EP 0049405 B1 EP0049405 B1 EP 0049405B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gauzes
- dispersion
- pattern
- fibers
- films
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 31
- 238000007650 screen-printing Methods 0.000 title 1
- 230000002087 whitening effect Effects 0.000 title 1
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 239000007844 bleaching agent Substances 0.000 claims abstract 4
- 239000000243 solution Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 5
- RRHXPUCIXLAHIY-UHFFFAOYSA-N 7-aminochromen-2-one Chemical compound C1=CC(=O)OC2=CC(N)=CC=C21 RRHXPUCIXLAHIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000004677 Nylon Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 238000004904 shortening Methods 0.000 claims description 2
- PQMOXTJVIYEOQL-UHFFFAOYSA-N Cumarin Natural products CC(C)=CCC1=C(O)C(C(=O)C(C)CC)=C(O)C2=C1OC(=O)C=C2CCC PQMOXTJVIYEOQL-UHFFFAOYSA-N 0.000 claims 2
- FSOGIJPGPZWNGO-UHFFFAOYSA-N Meomammein Natural products CCC(C)C(=O)C1=C(O)C(CC=C(C)C)=C(O)C2=C1OC(=O)C=C2CCC FSOGIJPGPZWNGO-UHFFFAOYSA-N 0.000 claims 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 206010013786 Dry skin Diseases 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- XCMDVRAWAIYDEE-UHFFFAOYSA-N 1,2-diphenyl-3h-pyrazole Chemical compound C1C=CN(C=2C=CC=CC=2)N1C1=CC=CC=C1 XCMDVRAWAIYDEE-UHFFFAOYSA-N 0.000 description 2
- YTZWQUYIRHGHMJ-UHFFFAOYSA-N 3-(1,2-diamino-2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound NC(=C(C1=C(C(=CC=C1)S(=O)(=O)O)S(=O)(=O)O)N)C1=CC=CC=C1 YTZWQUYIRHGHMJ-UHFFFAOYSA-N 0.000 description 2
- HWDSXZLYIKESML-UHFFFAOYSA-N 3-phenylchromen-2-one Chemical compound O=C1OC=2C=CC=CC=2C=C1C1=CC=CC=C1 HWDSXZLYIKESML-UHFFFAOYSA-N 0.000 description 2
- -1 des 6,7-Dihydroxycumarins Chemical class 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical class OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
- CFNMUZCFSDMZPQ-GHXNOFRVSA-N 7-[(z)-3-methyl-4-(4-methyl-5-oxo-2h-furan-2-yl)but-2-enoxy]chromen-2-one Chemical compound C=1C=C2C=CC(=O)OC2=CC=1OC/C=C(/C)CC1OC(=O)C(C)=C1 CFNMUZCFSDMZPQ-GHXNOFRVSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- QNHQEUFMIKRNTB-UHFFFAOYSA-N aesculetin Natural products C1CC(=O)OC2=C1C=C(O)C(O)=C2 QNHQEUFMIKRNTB-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000004775 coumarins Chemical class 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ILEDWLMCKZNDJK-UHFFFAOYSA-N esculetin Chemical compound C1=CC(=O)OC2=C1C=C(O)C(O)=C2 ILEDWLMCKZNDJK-UHFFFAOYSA-N 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/24—Stencils; Stencil materials; Carriers therefor
- B41N1/247—Meshes, gauzes, woven or similar screen materials; Preparation thereof, e.g. by plasma treatment
Definitions
- the present invention relates to a method for shortening the exposure time during photochemical pattern transfer to photosensitive layers made of emulsions or films or combinations of layers and films, all of which are applied to stencil gauzes.
- the pattern is generally transferred to the stencil.
- the pattern can be transferred to the template in a variety of ways, with the current focus on the photochemical processes.
- These photochemical processes usually use layers of emulsions or films or combinations of layers and films. These layers usually consist of polyvinyl alcohol emulsions which have been made photosensitive with a sensitizer, for example sodium or potassium bichromate or a diazo compound.
- the films consist, for example, of a light-sensitive gelatin layer or of a polyvinyl alcohol layer. In the layers and / or films mentioned chemical reactions are caused by the acting light energy, which can be used to generate sample samples.
- the layers (emulsions) and films usually used generally have a high sensitivity to blue-green and blue-ultraviolet light in the range from approximately 390 to 450 nm. Exposure usually cures the emulsion and / or the film.
- the photochemical processes generally have the disadvantage that the exposure time is long. For example, the exposure time can be 1 to 6 minutes per exposure. It is the aim of the present invention to shorten the exposure time mentioned.
- a process of the type mentioned at the outset has now been found, which is characterized in that the stencil gauzes are brought into contact with a dispersion or a solution which contains at least one whitener, and the dispersion or solution is allowed to act on the stencil gauzes which have been treated in this way Stencil gauze dries, then applies at least one light-sensitive layer and / or at least one light-sensitive film, and then exposed for the pattern transfer, the applied layers and / or films hardening in the exposed areas.
- An aqueous dispersion or an aqueous solution of the white toner is preferably used. However, it is generally also possible to use a dispersion of the white toner in an organic medium or an organic solvent which contains the white toner.
- the dispersion or solution can additionally contain at least one leveling agent and / or in the case of a dispersion at least one emulsifier. Likewise, at least one further auxiliary can be added to the dispersion or solution.
- Coumarin derivatives are particularly preferably used as whiteners in the process according to the invention; 7-aminocoumarin is most preferably used.
- synthetic fibers made of polyester or nylon are preferably used for the template gauzes. Polyester fibers are preferred. As a rule, natural fibers are not used in the process according to the invention. However, other synthetic fibers can also be used.
- the fibers can be finished, for example, using the conventional pull-out method or the thermal insulation method, which is also known.
- optical brighteners are applied to textile fabrics, such as, for example, woven goods, knitted fabrics, nonwovens, etc., or to unprocessed fibers which are intended for use as stencil gauzes.
- the residence time of the fibers in the dispersion or in the solution depends, for example, on the type of fiber material. If the fiber is made of nylon, the dwell time in the exhaust process is usually 30 to 60 minutes; if the fiber is made of polyester, the residence time in the exhaust process is expediently 60 to 90 min.
- the temperature when applying the optical brightener is generally not critical.
- the concentration of the optical brightener in the dispersion or solution can be 1 g / l but also up to 20 g / l or 0.1 to 2% of the weight of the goods. However, because the concentration usually depends on the structure of the optical brightener and substrate used (e.g. polyester or polyamide), both larger and lower concentrations than the ranges mentioned above can be used.
- the pattern transfer by means of a photochemical process generally has the effect that energy-saving che radiation is absorbed by the applied molecules and is emitted as low-energy radiation, ie as radiation with a longer wavelength.
- This fluorescence emission is usually added to the normal reflection in the blue spectral range, so that the total reflection is much stronger, ie is above 100%.
- the excited molecules absorb ultraviolet components and the energy absorbed in this way usually radiates again as blue fluorescent light.
- the layers and / or films applied to the stencil gauzes which have been equipped in accordance with the method according to the invention cure much more quickly during the pattern transfer by means of a photochemical method, as a result of which the exposure time can be shortened considerably.
- the time saved is 20 to 30%, but can also be up to 50% in certain cases.
- great time savings are achieved, for example, when the fibers used for the stencil gauzes, which have been finished in accordance with the method according to the invention, are processed in textile printing with an add-on copying machine which is well known to the person skilled in the art or with a step-and-repeat machine.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
- Printing Plates And Materials Therefor (AREA)
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81107406T ATE8065T1 (de) | 1980-10-03 | 1981-09-18 | Verfahren zur behandlung von schablonegazen mit wenigstens einem weisstoener. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH7419/80 | 1980-10-03 | ||
CH7419/80A CH648789A5 (de) | 1980-10-03 | 1980-10-03 | Verfahren zur verkuerzung der belichtungszeit bei der photochemischen musteruebertragung auf lichtempfindliche schichten. |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0049405A2 EP0049405A2 (fr) | 1982-04-14 |
EP0049405A3 EP0049405A3 (en) | 1982-09-22 |
EP0049405B1 true EP0049405B1 (fr) | 1984-06-20 |
Family
ID=4324832
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81107406A Expired EP0049405B1 (fr) | 1980-10-03 | 1981-09-18 | Procédé de traitement de gaze pour tamis d'impression avec au moins un agent de blanchiment |
Country Status (6)
Country | Link |
---|---|
US (1) | US4472457A (fr) |
EP (1) | EP0049405B1 (fr) |
JP (1) | JPS5795496A (fr) |
AT (1) | ATE8065T1 (fr) |
CH (1) | CH648789A5 (fr) |
DE (1) | DE3164320D1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59178381U (ja) * | 1983-05-10 | 1984-11-29 | エヌ・ビ−・シ−工業株式会社 | スクリ−ン印刷版用布帛 |
WO1988006103A1 (fr) * | 1987-02-17 | 1988-08-25 | Nihon Tokushu Orimono Co., Ltd. | Tissu tisse en mailles pour cadre d'impression |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3255203A (en) * | 1966-06-07 | Ii chz xn | ||
US2370874A (en) * | 1942-03-16 | 1945-03-06 | Liberty Glass Co | Stencil screen and method of making the same |
IT439855A (fr) * | 1946-06-14 | |||
BE498447A (fr) * | 1949-10-05 | |||
US2878138A (en) * | 1955-09-28 | 1959-03-17 | Bayer Ag | Method of brightening material |
FR1435095A (fr) * | 1965-02-22 | 1966-04-15 | Union Gazes A Bluter L | Perfectionnement aux tissus utilisés pour les pochoirs d'impression au cadre et de sérigraphie |
DE1670969A1 (de) * | 1968-01-08 | 1971-02-25 | Bayer Ag | 3-[Pyrazolyl-(1)]-7-[v-triazolyl-(2)]-cumarine |
CH559757A5 (fr) * | 1971-09-01 | 1975-03-14 | Ciba Geigy Ag | |
DE2400929A1 (de) * | 1973-12-03 | 1975-07-24 | Mcgraw Colorgraph Co | Verfahren zur herstellung von drucksieben |
US4286048A (en) * | 1979-12-03 | 1981-08-25 | Arthur D. Little, Inc. | Photocrosslinkable compositions for screen printing stencils |
-
1980
- 1980-10-03 CH CH7419/80A patent/CH648789A5/de not_active IP Right Cessation
-
1981
- 1981-09-18 AT AT81107406T patent/ATE8065T1/de not_active IP Right Cessation
- 1981-09-18 DE DE8181107406T patent/DE3164320D1/de not_active Expired
- 1981-09-18 EP EP81107406A patent/EP0049405B1/fr not_active Expired
- 1981-10-02 JP JP56158025A patent/JPS5795496A/ja active Pending
-
1983
- 1983-08-23 US US06/525,270 patent/US4472457A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CH648789A5 (de) | 1985-04-15 |
EP0049405A3 (en) | 1982-09-22 |
ATE8065T1 (de) | 1984-07-15 |
US4472457A (en) | 1984-09-18 |
JPS5795496A (en) | 1982-06-14 |
EP0049405A2 (fr) | 1982-04-14 |
DE3164320D1 (en) | 1984-07-26 |
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