EA200301103A1 - Способ активации катализатора - Google Patents

Способ активации катализатора

Info

Publication number
EA200301103A1
EA200301103A1 EA200301103A EA200301103A EA200301103A1 EA 200301103 A1 EA200301103 A1 EA 200301103A1 EA 200301103 A EA200301103 A EA 200301103A EA 200301103 A EA200301103 A EA 200301103A EA 200301103 A1 EA200301103 A1 EA 200301103A1
Authority
EA
Eurasian Patent Office
Prior art keywords
temperature
gaseous stream
hydrogen
holding
reactor system
Prior art date
Application number
EA200301103A
Other languages
English (en)
Other versions
EA005120B1 (ru
Inventor
Джей Саймон Кларксон
Стивен Уилльям Колли
Original Assignee
Бп Эксплорейшн Оперейтинг Компани Лимитед
Дейви Проуцесс Технолоджи Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бп Эксплорейшн Оперейтинг Компани Лимитед, Дейви Проуцесс Технолоджи Лимитед filed Critical Бп Эксплорейшн Оперейтинг Компани Лимитед
Publication of EA200301103A1 publication Critical patent/EA200301103A1/ru
Publication of EA005120B1 publication Critical patent/EA005120B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

В заявке описан способ активации кобальтсодержащего катализатора введением этого катализатора в контакт с водородом в реакционной системе, приемлемой для применения в синтезе Фишера-Тропша, в котором в реакционную систему непрерывно вводят первый газообразный поток, включающий от 0,25 до 5 об.% водорода и от 95 до 99,75 об.% инертного газа, и из реакторной системы непрерывно отводят второй газообразный поток, причем этот способ активации включает следующие стадии: (А) нагревание содержимого реакторной системы до температуры, которая на интервал от 25 до 5°C ниже критической температуры активации; (Б) последующее повышение температуры со скоростью до 20°C/ч до первой температуры выдержки, которая находится в интервале от критической температуры активации, до температуры, которая самое большее на 20°C превышает критическую температуру активации; и (В) выдержка содержимого реакторной системы при первой температуре выдержки до тех пор, пока содержание водорода во втором газообразном потоке не приблизится к содержанию водорода в первом газообразном потоке.Отчет о международном поиске был опубликован 2003.04.24.
EA200301103A 2001-04-18 2002-04-05 Способ активации катализатора EA005120B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0109555.3A GB0109555D0 (en) 2001-04-18 2001-04-18 Process
PCT/GB2002/001621 WO2002083817A2 (en) 2001-04-18 2002-04-05 Cobalt catalyst activation process

Publications (2)

Publication Number Publication Date
EA200301103A1 true EA200301103A1 (ru) 2004-04-29
EA005120B1 EA005120B1 (ru) 2004-12-30

Family

ID=9913012

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200301103A EA005120B1 (ru) 2001-04-18 2002-04-05 Способ активации катализатора

Country Status (20)

Country Link
US (1) US6919290B2 (ru)
EP (1) EP1379605B1 (ru)
JP (1) JP4031368B2 (ru)
CN (1) CN1239677C (ru)
AR (1) AR033224A1 (ru)
AT (1) ATE296338T1 (ru)
AU (1) AU2002251248B2 (ru)
BR (1) BRPI0208953B8 (ru)
DE (1) DE60204304T2 (ru)
DK (1) DK1379605T3 (ru)
EA (1) EA005120B1 (ru)
ES (1) ES2243711T3 (ru)
GB (1) GB0109555D0 (ru)
GC (1) GC0000320A (ru)
NO (1) NO324128B1 (ru)
NZ (1) NZ528744A (ru)
OA (1) OA12595A (ru)
PT (1) PT1379605E (ru)
WO (1) WO2002083817A2 (ru)
ZA (1) ZA200307758B (ru)

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US6878655B2 (en) * 2002-09-20 2005-04-12 Conocophillips Company Method and apparatus for the regeneration of hydrocarbon synthesis catalysts
KR100516480B1 (ko) * 2003-05-16 2005-09-23 한국과학기술연구원 저온 플라즈마를 이용한 촉매 환원 방법
US7045554B2 (en) 2003-09-03 2006-05-16 Conocophillips Company Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion
DE10359538A1 (de) 2003-12-17 2005-07-14 Hans Schwarzkopf & Henkel Gmbh & Co. Kg Tönungsmittel in Tuben
DE10359557A1 (de) 2003-12-17 2005-07-14 Hans Schwarzkopf & Henkel Gmbh & Co. Kg Oxidationsfärbemittel in Tube
DE10359539A1 (de) 2003-12-17 2005-07-14 Hans Schwarzkopf & Henkel Gmbh & Co. Kg Pflegendes Oxidationsmittel in Tube
US7524787B2 (en) * 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
US20090023822A1 (en) * 2007-07-19 2009-01-22 Tijm Peter J Method for activating and regenerating catalyst for a fischer-tropsch synthesis reaction
GB201001144D0 (en) 2010-01-25 2010-03-10 Compactgtl Plc Catalytic reactor treatment process
US8372771B2 (en) 2010-02-16 2013-02-12 Chevrton Phillips Chemical Company LP System and method for catalyst activation
US9050588B2 (en) 2011-05-27 2015-06-09 Gi—Gasification International, S.A. Fischer-tropsch catalyst activation procedure
CN102872921B (zh) * 2011-07-12 2014-10-15 中国石油化工股份有限公司 用于烯烃歧化催化剂的活化方法
US9048245B2 (en) 2012-06-05 2015-06-02 International Business Machines Corporation Method for shaping a laminate substrate
US9059240B2 (en) 2012-06-05 2015-06-16 International Business Machines Corporation Fixture for shaping a laminate substrate
US9129942B2 (en) 2012-06-05 2015-09-08 International Business Machines Corporation Method for shaping a laminate substrate
WO2016046717A1 (en) * 2014-09-23 2016-03-31 Sabic Global Technologies B.V. Cobalt-based catalyst and methods related thereto
WO2016091691A1 (en) * 2014-12-12 2016-06-16 Bp P.L.C. Fischer-tropsch process using supported reduced cobalt catalyst
FR3039432B1 (fr) 2015-07-31 2017-08-04 Ifp Energies Now Procede de preparation d'un catalyseur destine a etre mis en œuvre dans une reaction fischer-tropsch.
RU2638217C1 (ru) * 2016-12-15 2017-12-12 Публичное акционерное общество "Нефтяная компания "Роснефть" Компактный реактор для получения синтетических углеводородов в процессе Фишера-Тропша, способ активации катализатора Фишера-Тропша и способ осуществления синтеза Фишера-Тропша в компактном варианте с его использованием
US10434506B1 (en) 2018-12-18 2019-10-08 Emerging Fuels Technology, Inc. Method for activation or regeneration of a catalyst
CN112645281B (zh) * 2020-12-30 2022-09-16 同济大学 一种正仲氢转化装置及正仲氢转化方法
CN115430434A (zh) * 2021-06-03 2022-12-06 国家能源投资集团有限责任公司 费托合成催化剂的还原方法和还原态费托合成催化剂以及费托合成方法
US20230015935A1 (en) * 2021-07-15 2023-01-19 Emerging Fuels Technology, Inc. Method for the activation or rejuvenation of a catalyst

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4605676A (en) * 1981-10-13 1986-08-12 Chevron Research Company Synthesis gas conversion using ROR-activated catalyst
US5283216A (en) * 1992-09-24 1994-02-01 Exxon Research And Engineering Company Rejuvenation of hydrocarbon synthesis catalyst
US6475943B1 (en) * 1995-11-08 2002-11-05 Shell Oil Company Catalyst activation process
PE31698A1 (es) * 1995-11-08 1998-06-15 Shell Int Research Proceso de activacion y rejuvenecimiento de catalizador
WO1999034917A1 (en) * 1997-12-30 1999-07-15 Shell Internationale Research Maatschappij B.V. Cobalt based fisher-tropsch catalyst
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US6465529B1 (en) * 2000-08-01 2002-10-15 Exxonmobil Research And Engineering Company Process for increasing cobalt catalyst hydrogenation activity via aqueous low temperature oxidation

Also Published As

Publication number Publication date
GB0109555D0 (en) 2001-06-06
AR033224A1 (es) 2003-12-10
ATE296338T1 (de) 2005-06-15
US6919290B2 (en) 2005-07-19
BR0208953B1 (pt) 2014-03-04
EP1379605B1 (en) 2005-05-25
NO20034628L (no) 2003-11-27
BRPI0208953B8 (pt) 2015-12-22
US20040116277A1 (en) 2004-06-17
NZ528744A (en) 2005-04-29
NO324128B1 (no) 2007-08-27
JP2004528449A (ja) 2004-09-16
WO2002083817A2 (en) 2002-10-24
EP1379605A2 (en) 2004-01-14
BR0208953A (pt) 2004-10-19
CN1239677C (zh) 2006-02-01
ZA200307758B (en) 2004-07-21
JP4031368B2 (ja) 2008-01-09
DK1379605T3 (da) 2005-09-12
DE60204304T2 (de) 2006-02-02
ES2243711T3 (es) 2005-12-01
DE60204304D1 (de) 2005-06-30
GC0000320A (en) 2006-11-01
EA005120B1 (ru) 2004-12-30
WO2002083817A3 (en) 2003-04-24
NO20034628D0 (no) 2003-10-16
PT1379605E (pt) 2005-10-31
AU2002251248B2 (en) 2007-03-01
CN1520451A (zh) 2004-08-11
OA12595A (en) 2006-06-08

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM BY MD

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AZ KZ KG TJ TM RU