ZA200307758B - Cobalt catalyst activation process. - Google Patents
Cobalt catalyst activation process. Download PDFInfo
- Publication number
- ZA200307758B ZA200307758B ZA200307758A ZA200307758A ZA200307758B ZA 200307758 B ZA200307758 B ZA 200307758B ZA 200307758 A ZA200307758 A ZA 200307758A ZA 200307758 A ZA200307758 A ZA 200307758A ZA 200307758 B ZA200307758 B ZA 200307758B
- Authority
- ZA
- South Africa
- Prior art keywords
- temperature
- gaseous stream
- catalyst
- reactor system
- hydrogen
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 81
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 30
- 229910017052 cobalt Inorganic materials 0.000 title claims description 28
- 239000010941 cobalt Substances 0.000 title claims description 28
- 238000001994 activation Methods 0.000 title description 36
- 239000001257 hydrogen Substances 0.000 claims description 76
- 229910052739 hydrogen Inorganic materials 0.000 claims description 76
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 51
- 230000004913 activation Effects 0.000 claims description 43
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 25
- 239000007789 gas Substances 0.000 claims description 24
- 238000003786 synthesis reaction Methods 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 14
- 239000011261 inert gas Substances 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000003213 activating effect Effects 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052786 argon Inorganic materials 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001307 helium Substances 0.000 claims description 5
- 229910052734 helium Inorganic materials 0.000 claims description 5
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 238000010926 purge Methods 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 238000013459 approach Methods 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 238000004458 analytical method Methods 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 238000005243 fluidization Methods 0.000 claims description 2
- 238000004817 gas chromatography Methods 0.000 claims description 2
- 238000004949 mass spectrometry Methods 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 238000010009 beating Methods 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- -1 preferably Chemical compound 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0109555.3A GB0109555D0 (en) | 2001-04-18 | 2001-04-18 | Process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200307758B true ZA200307758B (en) | 2004-07-21 |
Family
ID=9913012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200307758A ZA200307758B (en) | 2001-04-18 | 2003-10-03 | Cobalt catalyst activation process. |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6919290B2 (ru) |
| EP (1) | EP1379605B1 (ru) |
| JP (1) | JP4031368B2 (ru) |
| CN (1) | CN1239677C (ru) |
| AR (1) | AR033224A1 (ru) |
| AT (1) | ATE296338T1 (ru) |
| AU (1) | AU2002251248B2 (ru) |
| BR (1) | BRPI0208953B8 (ru) |
| DE (1) | DE60204304T2 (ru) |
| DK (1) | DK1379605T3 (ru) |
| EA (1) | EA005120B1 (ru) |
| ES (1) | ES2243711T3 (ru) |
| GB (1) | GB0109555D0 (ru) |
| GC (1) | GC0000320A (ru) |
| NO (1) | NO324128B1 (ru) |
| NZ (1) | NZ528744A (ru) |
| OA (1) | OA12595A (ru) |
| PT (1) | PT1379605E (ru) |
| WO (1) | WO2002083817A2 (ru) |
| ZA (1) | ZA200307758B (ru) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6878655B2 (en) * | 2002-09-20 | 2005-04-12 | Conocophillips Company | Method and apparatus for the regeneration of hydrocarbon synthesis catalysts |
| KR100516480B1 (ko) * | 2003-05-16 | 2005-09-23 | 한국과학기술연구원 | 저온 플라즈마를 이용한 촉매 환원 방법 |
| US7045554B2 (en) | 2003-09-03 | 2006-05-16 | Conocophillips Company | Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion |
| DE10359539A1 (de) | 2003-12-17 | 2005-07-14 | Hans Schwarzkopf & Henkel Gmbh & Co. Kg | Pflegendes Oxidationsmittel in Tube |
| DE10359557A1 (de) | 2003-12-17 | 2005-07-14 | Hans Schwarzkopf & Henkel Gmbh & Co. Kg | Oxidationsfärbemittel in Tube |
| DE10359538A1 (de) | 2003-12-17 | 2005-07-14 | Hans Schwarzkopf & Henkel Gmbh & Co. Kg | Tönungsmittel in Tuben |
| US7524787B2 (en) * | 2005-01-11 | 2009-04-28 | Sasol Technology (Proprietary Limited) | Producing supported cobalt catalysts for the Fisher-Tropsch synthesis |
| US20090023822A1 (en) * | 2007-07-19 | 2009-01-22 | Tijm Peter J | Method for activating and regenerating catalyst for a fischer-tropsch synthesis reaction |
| GB201001144D0 (en) | 2010-01-25 | 2010-03-10 | Compactgtl Plc | Catalytic reactor treatment process |
| US8372771B2 (en) | 2010-02-16 | 2013-02-12 | Chevrton Phillips Chemical Company LP | System and method for catalyst activation |
| US9050588B2 (en) * | 2011-05-27 | 2015-06-09 | Gi—Gasification International, S.A. | Fischer-tropsch catalyst activation procedure |
| CN102872921B (zh) * | 2011-07-12 | 2014-10-15 | 中国石油化工股份有限公司 | 用于烯烃歧化催化剂的活化方法 |
| US9059240B2 (en) | 2012-06-05 | 2015-06-16 | International Business Machines Corporation | Fixture for shaping a laminate substrate |
| US9048245B2 (en) | 2012-06-05 | 2015-06-02 | International Business Machines Corporation | Method for shaping a laminate substrate |
| US9129942B2 (en) | 2012-06-05 | 2015-09-08 | International Business Machines Corporation | Method for shaping a laminate substrate |
| US20170297012A1 (en) * | 2014-09-23 | 2017-10-19 | Sabic Global Technologies B.V. | Cobalt-based catalyst and methods related thereto |
| WO2016091691A1 (en) * | 2014-12-12 | 2016-06-16 | Bp P.L.C. | Fischer-tropsch process using supported reduced cobalt catalyst |
| FR3039432B1 (fr) | 2015-07-31 | 2017-08-04 | Ifp Energies Now | Procede de preparation d'un catalyseur destine a etre mis en œuvre dans une reaction fischer-tropsch. |
| RU2638217C1 (ru) * | 2016-12-15 | 2017-12-12 | Публичное акционерное общество "Нефтяная компания "Роснефть" | Компактный реактор для получения синтетических углеводородов в процессе Фишера-Тропша, способ активации катализатора Фишера-Тропша и способ осуществления синтеза Фишера-Тропша в компактном варианте с его использованием |
| US10434506B1 (en) | 2018-12-18 | 2019-10-08 | Emerging Fuels Technology, Inc. | Method for activation or regeneration of a catalyst |
| CN112645281B (zh) * | 2020-12-30 | 2022-09-16 | 同济大学 | 一种正仲氢转化装置及正仲氢转化方法 |
| CN115430434B (zh) * | 2021-06-03 | 2024-07-05 | 国家能源投资集团有限责任公司 | 费托合成催化剂的还原方法和还原态费托合成催化剂以及费托合成方法 |
| US20230015935A1 (en) * | 2021-07-15 | 2023-01-19 | Emerging Fuels Technology, Inc. | Method for the activation or rejuvenation of a catalyst |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4605676A (en) * | 1981-10-13 | 1986-08-12 | Chevron Research Company | Synthesis gas conversion using ROR-activated catalyst |
| US5283216A (en) * | 1992-09-24 | 1994-02-01 | Exxon Research And Engineering Company | Rejuvenation of hydrocarbon synthesis catalyst |
| US6475943B1 (en) * | 1995-11-08 | 2002-11-05 | Shell Oil Company | Catalyst activation process |
| PE31698A1 (es) * | 1995-11-08 | 1998-06-15 | Shell Int Research | Proceso de activacion y rejuvenecimiento de catalizador |
| WO1999034917A1 (en) * | 1997-12-30 | 1999-07-15 | Shell Internationale Research Maatschappij B.V. | Cobalt based fisher-tropsch catalyst |
| WO1999061550A1 (en) * | 1998-05-27 | 1999-12-02 | Energy International Corporation | Improved fischer-tropsch activity for 'non-promoted' cobalt-on-alumina catalysts |
| US6100304A (en) * | 1999-05-26 | 2000-08-08 | Energy International Corportion | Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis |
| US6486220B1 (en) * | 1999-11-17 | 2002-11-26 | Conoco Inc. | Regeneration procedure for Fischer-Tropsch catalyst |
| FR2801228B1 (fr) * | 1999-11-22 | 2001-12-28 | Inst Francais Du Petrole | Procede d'activation d'un catalyseur de synthese fischer tropsch |
| US6255358B1 (en) * | 2000-03-17 | 2001-07-03 | Energy International Corporation | Highly active Fischer-Tropsch synthesis using doped, thermally stable catalyst support |
| US6465529B1 (en) * | 2000-08-01 | 2002-10-15 | Exxonmobil Research And Engineering Company | Process for increasing cobalt catalyst hydrogenation activity via aqueous low temperature oxidation |
-
2001
- 2001-04-18 GB GBGB0109555.3A patent/GB0109555D0/en not_active Ceased
-
2002
- 2002-04-05 EA EA200301103A patent/EA005120B1/ru not_active IP Right Cessation
- 2002-04-05 BR BRPI0208953A patent/BRPI0208953B8/pt not_active IP Right Cessation
- 2002-04-05 PT PT02720178T patent/PT1379605E/pt unknown
- 2002-04-05 EP EP02720178A patent/EP1379605B1/en not_active Expired - Lifetime
- 2002-04-05 OA OA1200300263A patent/OA12595A/en unknown
- 2002-04-05 DK DK02720178T patent/DK1379605T3/da active
- 2002-04-05 AU AU2002251248A patent/AU2002251248B2/en not_active Ceased
- 2002-04-05 DE DE60204304T patent/DE60204304T2/de not_active Expired - Lifetime
- 2002-04-05 JP JP2002582156A patent/JP4031368B2/ja not_active Expired - Fee Related
- 2002-04-05 CN CN02808373.3A patent/CN1239677C/zh not_active Expired - Fee Related
- 2002-04-05 NZ NZ528744A patent/NZ528744A/en not_active IP Right Cessation
- 2002-04-05 WO PCT/GB2002/001621 patent/WO2002083817A2/en active IP Right Grant
- 2002-04-05 ES ES02720178T patent/ES2243711T3/es not_active Expired - Lifetime
- 2002-04-05 US US10/475,263 patent/US6919290B2/en not_active Expired - Lifetime
- 2002-04-05 AT AT02720178T patent/ATE296338T1/de not_active IP Right Cessation
- 2002-04-17 AR ARP020101405A patent/AR033224A1/es active IP Right Grant
- 2002-04-17 GC GCP20021955 patent/GC0000320A/en active
-
2003
- 2003-10-03 ZA ZA200307758A patent/ZA200307758B/en unknown
- 2003-10-16 NO NO20034628A patent/NO324128B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK1379605T3 (da) | 2005-09-12 |
| WO2002083817A3 (en) | 2003-04-24 |
| NO20034628L (no) | 2003-11-27 |
| EA005120B1 (ru) | 2004-12-30 |
| ATE296338T1 (de) | 2005-06-15 |
| EP1379605B1 (en) | 2005-05-25 |
| OA12595A (en) | 2006-06-08 |
| EP1379605A2 (en) | 2004-01-14 |
| EA200301103A1 (ru) | 2004-04-29 |
| AR033224A1 (es) | 2003-12-10 |
| NZ528744A (en) | 2005-04-29 |
| JP4031368B2 (ja) | 2008-01-09 |
| GB0109555D0 (en) | 2001-06-06 |
| PT1379605E (pt) | 2005-10-31 |
| CN1520451A (zh) | 2004-08-11 |
| AU2002251248B2 (en) | 2007-03-01 |
| BR0208953B1 (pt) | 2014-03-04 |
| WO2002083817A2 (en) | 2002-10-24 |
| NO324128B1 (no) | 2007-08-27 |
| DE60204304D1 (de) | 2005-06-30 |
| CN1239677C (zh) | 2006-02-01 |
| GC0000320A (en) | 2006-11-01 |
| ES2243711T3 (es) | 2005-12-01 |
| JP2004528449A (ja) | 2004-09-16 |
| US6919290B2 (en) | 2005-07-19 |
| NO20034628D0 (no) | 2003-10-16 |
| US20040116277A1 (en) | 2004-06-17 |
| BRPI0208953B8 (pt) | 2015-12-22 |
| DE60204304T2 (de) | 2006-02-02 |
| BR0208953A (pt) | 2004-10-19 |
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