EA035857B1 - Способ получения водорода и графитового углерода из углеводородов - Google Patents

Способ получения водорода и графитового углерода из углеводородов Download PDF

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Publication number
EA035857B1
EA035857B1 EA201792048A EA201792048A EA035857B1 EA 035857 B1 EA035857 B1 EA 035857B1 EA 201792048 A EA201792048 A EA 201792048A EA 201792048 A EA201792048 A EA 201792048A EA 035857 B1 EA035857 B1 EA 035857B1
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EA
Eurasian Patent Office
Prior art keywords
catalyst
reactor
graphite
pressure
hydrogen
Prior art date
Application number
EA201792048A
Other languages
English (en)
Russian (ru)
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EA201792048A1 (ru
Inventor
Эндрю Корнехо
Хуэй Тун Чуа
Original Assignee
Хейзер Груп Лимитед
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Priority claimed from AU2015901175A external-priority patent/AU2015901175A0/en
Application filed by Хейзер Груп Лимитед filed Critical Хейзер Груп Лимитед
Publication of EA201792048A1 publication Critical patent/EA201792048A1/ru
Publication of EA035857B1 publication Critical patent/EA035857B1/ru

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2445Stationary reactors without moving elements inside placed in parallel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/245Stationary reactors without moving elements inside placed in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0005Catalytic processes under superatmospheric pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/20Graphite
    • C01B32/205Preparation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B15/00Other processes for the manufacture of iron from iron compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2203/00Processes utilising sub- or super atmospheric pressure
    • B01J2203/06High pressure synthesis
    • B01J2203/0605Composition of the material to be processed
    • B01J2203/061Graphite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00162Controlling or regulating processes controlling the pressure
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0266Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
EA201792048A 2015-03-31 2016-03-31 Способ получения водорода и графитового углерода из углеводородов EA035857B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AU2015901175A AU2015901175A0 (en) 2015-03-31 Thermocatalytic methane decomposition
PCT/AU2016/000115 WO2016154666A1 (en) 2015-03-31 2016-03-31 A process for producing hydrogen and graphitic carbon from hydrocarbons

Publications (2)

Publication Number Publication Date
EA201792048A1 EA201792048A1 (ru) 2018-01-31
EA035857B1 true EA035857B1 (ru) 2020-08-20

Family

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EA201792048A EA035857B1 (ru) 2015-03-31 2016-03-31 Способ получения водорода и графитового углерода из углеводородов

Country Status (18)

Country Link
US (3) US11505458B2 (enExample)
EP (1) EP3277623A4 (enExample)
JP (3) JP7007256B2 (enExample)
KR (2) KR20230106169A (enExample)
CN (1) CN108064214B (enExample)
AU (4) AU2016240393B2 (enExample)
BR (1) BR112017021057B1 (enExample)
CA (2) CA3289604A1 (enExample)
CL (1) CL2017002468A1 (enExample)
EA (1) EA035857B1 (enExample)
MX (1) MX2017012559A (enExample)
MY (1) MY188748A (enExample)
NZ (1) NZ735781A (enExample)
PH (1) PH12017501770A1 (enExample)
SA (1) SA517390046B1 (enExample)
SG (1) SG11201707907SA (enExample)
WO (1) WO2016154666A1 (enExample)
ZA (1) ZA201706455B (enExample)

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AU2016240393B2 (en) 2015-03-31 2019-01-03 Hazer Group Ltd A process for producing hydrogen and graphitic carbon from hydrocarbons
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WO2018170543A1 (en) * 2017-03-20 2018-09-27 Hazer Group Limited System for the production of hydrogen and graphitic carbon
US20210114003A1 (en) 2017-04-14 2021-04-22 King Abdullah University Of Science And Technology Treated iron ore catalysts for production of hydrogen and graphene
DE102018132661B4 (de) * 2018-12-18 2020-10-01 Thyssenkrupp Ag Verfahren zur Kohlenwasserstoffpyrolyse mit räumlich getrennter Beheizungs- und Reaktionszone innerhalb des Reaktorraums
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US20210047180A1 (en) * 2019-08-14 2021-02-18 General Electric Company Production system and method for generating hydrogen gas and carbon products
JP7413704B2 (ja) * 2019-10-08 2024-01-16 戸田工業株式会社 炭化水素の熱分解用触媒並びにそれを用いたカーボンナノチューブ及び水素製造方法
US11685651B2 (en) 2019-10-25 2023-06-27 Mark Kevin Robertson Catalytic decomposition of hydrocarbons for the production of hydrogen and carbon
CN110721691B (zh) * 2019-11-12 2020-07-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用
JP7743714B2 (ja) * 2020-07-28 2025-09-25 戸田工業株式会社 触媒粒子
US11401163B2 (en) 2020-10-19 2022-08-02 Xenophon Verykios Catalytic materials for pyrolysis of methane and production of hydrogen and solid carbon with substantially zero atmospheric carbon emissions
CN116710403A (zh) * 2020-11-20 2023-09-05 卡本科技控股有限责任公司 与金属矿石的生物还原、氢生产和/或活性炭生产集成的生物质热解
KR102482738B1 (ko) * 2020-11-23 2022-12-28 노용규 탄화수소 열분해 수소 생산 장치 및 이의 운용 방법
KR102471954B1 (ko) * 2020-11-23 2022-11-29 노용규 촉매 활성 저하를 해결한 탄화수소 열분해 수소 생산 장치 및 수소 생산 방법
EP4274803A4 (en) * 2021-01-07 2025-05-21 The Johns Hopkins University PRODUCTION OF HYDROGEN FROM HYDROCARBONS
JP2023128516A (ja) * 2022-03-03 2023-09-14 三菱重工業株式会社 触媒の製造方法及びこの触媒を使用した炭化水素の直接分解方法
JP7482164B2 (ja) * 2022-03-11 2024-05-13 三菱重工業株式会社 炭化水素の直接分解方法
US20240124301A1 (en) * 2022-10-07 2024-04-18 Sk Innovation Co., Ltd. Process for producing hydrogen, carbon monoxide, and carbon from methane-containing feedstock
CN120659664A (zh) * 2022-12-09 2025-09-16 哈泽尔集团公司 配置为能够对碳氢化合物热解过程实现改善/优化控制的系统和方法
WO2025051706A1 (en) 2023-09-08 2025-03-13 Basf Se Producing renewable hydrocarbons from biomass
WO2025073664A1 (en) 2023-10-06 2025-04-10 Basf Se Pretreatment of c2-c6 alkanes-rich raw natural gas or industry off gas
WO2025073665A1 (en) 2023-10-06 2025-04-10 Basf Se Closed carbon loop process
WO2025073661A1 (en) 2023-10-06 2025-04-10 Basf Se Process for preparing methanol from pyrolytic hydrogen
WO2025073666A1 (en) 2023-10-06 2025-04-10 Basf Se Exploitation of natural hydrogen deposits using methane pyrolysis
KR102792878B1 (ko) * 2023-11-20 2025-04-09 주식회사 이엠코 수소생산방법 및 수소생산용 촉매
WO2025125974A1 (en) 2023-12-13 2025-06-19 Universidade Do Porto Catalyst and reactor for intermediate-temperature catalytic methane splitting and methods thereof
WO2025125973A1 (en) 2023-12-13 2025-06-19 Universidade Do Porto Reactor for low-temperature methane splitting and solid catalyst to use therein and methods thereof
JP2025125236A (ja) * 2024-02-15 2025-08-27 三菱重工業株式会社 水素製造装置
WO2025176518A1 (en) 2024-02-22 2025-08-28 Basf Se Producing sustainable caprolactam
WO2025219166A1 (en) 2024-04-18 2025-10-23 Basf Se Producing renewable olefins
WO2025233156A1 (en) 2024-05-08 2025-11-13 Basf Se Method for controlling synthesis gas processing from carbonaceous feedstock
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Also Published As

Publication number Publication date
SG11201707907SA (en) 2017-10-30
BR112017021057A2 (pt) 2018-07-03
BR112017021057B1 (pt) 2023-03-21
MX2017012559A (es) 2018-04-11
CN108064214B (zh) 2021-08-06
AU2018267558A1 (en) 2018-12-06
JP7623001B2 (ja) 2025-01-28
ZA201706455B (en) 2019-07-31
AU2018101788A4 (en) 2019-01-03
JP2023139231A (ja) 2023-10-03
CA2980471A1 (en) 2016-10-06
WO2016154666A1 (en) 2016-10-06
US20230227307A1 (en) 2023-07-20
CL2017002468A1 (es) 2018-05-25
AU2018101787A4 (en) 2019-01-03
EA201792048A1 (ru) 2018-01-31
JP7007256B2 (ja) 2022-01-24
EP3277623A4 (en) 2018-11-07
AU2018101787B4 (en) 2019-02-28
US11505458B2 (en) 2022-11-22
US20180065850A1 (en) 2018-03-08
MY188748A (en) 2021-12-28
KR102571186B1 (ko) 2023-08-25
JP2018516839A (ja) 2018-06-28
CA3289604A1 (en) 2025-11-29
AU2016240393A1 (en) 2017-10-12
SA517390046B1 (ar) 2022-07-31
JP2022009048A (ja) 2022-01-14
AU2018101788B4 (en) 2019-04-11
NZ735781A (en) 2019-09-27
EP3277623A1 (en) 2018-02-07
CN108064214A (zh) 2018-05-22
AU2016240393B2 (en) 2019-01-03
KR20180002619A (ko) 2018-01-08
KR20230106169A (ko) 2023-07-12
PH12017501770A1 (en) 2018-03-19
US20240327212A1 (en) 2024-10-03

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