KR20230106169A - 탄화수소로부터 수소 및 흑연 탄소의 제조 방법 - Google Patents

탄화수소로부터 수소 및 흑연 탄소의 제조 방법 Download PDF

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Publication number
KR20230106169A
KR20230106169A KR1020237019348A KR20237019348A KR20230106169A KR 20230106169 A KR20230106169 A KR 20230106169A KR 1020237019348 A KR1020237019348 A KR 1020237019348A KR 20237019348 A KR20237019348 A KR 20237019348A KR 20230106169 A KR20230106169 A KR 20230106169A
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South Korea
Prior art keywords
reactor
catalyst
pressure
hydrogen
gas
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Korean (ko)
Inventor
앤드류 코르네조
후이 통 추아
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헤이저 그룹 리미티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0005—Catalytic processes under superatmospheric pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2445—Stationary reactors without moving elements inside placed in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/205—Preparation
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B15/00—Other processes for the manufacture of iron from iron compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2203/00—Processes utilising sub- or super atmospheric pressure
    • B01J2203/06—High pressure synthesis
    • B01J2203/0605—Composition of the material to be processed
    • B01J2203/061—Graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
KR1020237019348A 2015-03-31 2016-03-31 탄화수소로부터 수소 및 흑연 탄소의 제조 방법 Ceased KR20230106169A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
AU2015901175A AU2015901175A0 (en) 2015-03-31 Thermocatalytic methane decomposition
AU2015901175 2015-03-31
PCT/AU2016/000115 WO2016154666A1 (en) 2015-03-31 2016-03-31 A process for producing hydrogen and graphitic carbon from hydrocarbons
KR1020177030318A KR102571186B1 (ko) 2015-03-31 2016-03-31 탄화수소로부터 수소 및 흑연 탄소의 제조 방법

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020177030318A Division KR102571186B1 (ko) 2015-03-31 2016-03-31 탄화수소로부터 수소 및 흑연 탄소의 제조 방법

Publications (1)

Publication Number Publication Date
KR20230106169A true KR20230106169A (ko) 2023-07-12

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KR1020237019348A Ceased KR20230106169A (ko) 2015-03-31 2016-03-31 탄화수소로부터 수소 및 흑연 탄소의 제조 방법
KR1020177030318A Active KR102571186B1 (ko) 2015-03-31 2016-03-31 탄화수소로부터 수소 및 흑연 탄소의 제조 방법

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Country Status (18)

Country Link
US (3) US11505458B2 (enExample)
EP (1) EP3277623A4 (enExample)
JP (3) JP7007256B2 (enExample)
KR (2) KR20230106169A (enExample)
CN (1) CN108064214B (enExample)
AU (4) AU2016240393B2 (enExample)
BR (1) BR112017021057B1 (enExample)
CA (2) CA3289604A1 (enExample)
CL (1) CL2017002468A1 (enExample)
EA (1) EA035857B1 (enExample)
MX (1) MX2017012559A (enExample)
MY (1) MY188748A (enExample)
NZ (1) NZ735781A (enExample)
PH (1) PH12017501770A1 (enExample)
SA (1) SA517390046B1 (enExample)
SG (1) SG11201707907SA (enExample)
WO (1) WO2016154666A1 (enExample)
ZA (1) ZA201706455B (enExample)

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KR102822440B1 (ko) 2024-08-29 2025-06-20 주식회사 이엠코 표면 개질 탄소의 제조 방법, 인조 흑연 또는 천연 흑연계 표면 개질 탄소 및 표면 개질 탄소를 포함하는 음극재

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WO2018170543A1 (en) * 2017-03-20 2018-09-27 Hazer Group Limited System for the production of hydrogen and graphitic carbon
US20210114003A1 (en) 2017-04-14 2021-04-22 King Abdullah University Of Science And Technology Treated iron ore catalysts for production of hydrogen and graphene
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JP7413704B2 (ja) * 2019-10-08 2024-01-16 戸田工業株式会社 炭化水素の熱分解用触媒並びにそれを用いたカーボンナノチューブ及び水素製造方法
US11685651B2 (en) 2019-10-25 2023-06-27 Mark Kevin Robertson Catalytic decomposition of hydrocarbons for the production of hydrogen and carbon
CN110721691B (zh) * 2019-11-12 2020-07-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用
JP7743714B2 (ja) * 2020-07-28 2025-09-25 戸田工業株式会社 触媒粒子
US11401163B2 (en) 2020-10-19 2022-08-02 Xenophon Verykios Catalytic materials for pyrolysis of methane and production of hydrogen and solid carbon with substantially zero atmospheric carbon emissions
CN116710403A (zh) * 2020-11-20 2023-09-05 卡本科技控股有限责任公司 与金属矿石的生物还原、氢生产和/或活性炭生产集成的生物质热解
KR102482738B1 (ko) * 2020-11-23 2022-12-28 노용규 탄화수소 열분해 수소 생산 장치 및 이의 운용 방법
KR102471954B1 (ko) * 2020-11-23 2022-11-29 노용규 촉매 활성 저하를 해결한 탄화수소 열분해 수소 생산 장치 및 수소 생산 방법
EP4274803A4 (en) * 2021-01-07 2025-05-21 The Johns Hopkins University PRODUCTION OF HYDROGEN FROM HYDROCARBONS
JP2023128516A (ja) * 2022-03-03 2023-09-14 三菱重工業株式会社 触媒の製造方法及びこの触媒を使用した炭化水素の直接分解方法
JP7482164B2 (ja) * 2022-03-11 2024-05-13 三菱重工業株式会社 炭化水素の直接分解方法
US20240124301A1 (en) * 2022-10-07 2024-04-18 Sk Innovation Co., Ltd. Process for producing hydrogen, carbon monoxide, and carbon from methane-containing feedstock
CN120659664A (zh) * 2022-12-09 2025-09-16 哈泽尔集团公司 配置为能够对碳氢化合物热解过程实现改善/优化控制的系统和方法
WO2025051706A1 (en) 2023-09-08 2025-03-13 Basf Se Producing renewable hydrocarbons from biomass
WO2025073664A1 (en) 2023-10-06 2025-04-10 Basf Se Pretreatment of c2-c6 alkanes-rich raw natural gas or industry off gas
WO2025073665A1 (en) 2023-10-06 2025-04-10 Basf Se Closed carbon loop process
WO2025073661A1 (en) 2023-10-06 2025-04-10 Basf Se Process for preparing methanol from pyrolytic hydrogen
WO2025073666A1 (en) 2023-10-06 2025-04-10 Basf Se Exploitation of natural hydrogen deposits using methane pyrolysis
KR102792878B1 (ko) * 2023-11-20 2025-04-09 주식회사 이엠코 수소생산방법 및 수소생산용 촉매
WO2025125974A1 (en) 2023-12-13 2025-06-19 Universidade Do Porto Catalyst and reactor for intermediate-temperature catalytic methane splitting and methods thereof
WO2025125973A1 (en) 2023-12-13 2025-06-19 Universidade Do Porto Reactor for low-temperature methane splitting and solid catalyst to use therein and methods thereof
JP2025125236A (ja) * 2024-02-15 2025-08-27 三菱重工業株式会社 水素製造装置
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102822440B1 (ko) 2024-08-29 2025-06-20 주식회사 이엠코 표면 개질 탄소의 제조 방법, 인조 흑연 또는 천연 흑연계 표면 개질 탄소 및 표면 개질 탄소를 포함하는 음극재

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SG11201707907SA (en) 2017-10-30
BR112017021057A2 (pt) 2018-07-03
BR112017021057B1 (pt) 2023-03-21
MX2017012559A (es) 2018-04-11
CN108064214B (zh) 2021-08-06
AU2018267558A1 (en) 2018-12-06
JP7623001B2 (ja) 2025-01-28
ZA201706455B (en) 2019-07-31
AU2018101788A4 (en) 2019-01-03
JP2023139231A (ja) 2023-10-03
CA2980471A1 (en) 2016-10-06
WO2016154666A1 (en) 2016-10-06
US20230227307A1 (en) 2023-07-20
CL2017002468A1 (es) 2018-05-25
AU2018101787A4 (en) 2019-01-03
EA201792048A1 (ru) 2018-01-31
JP7007256B2 (ja) 2022-01-24
EP3277623A4 (en) 2018-11-07
AU2018101787B4 (en) 2019-02-28
US11505458B2 (en) 2022-11-22
US20180065850A1 (en) 2018-03-08
MY188748A (en) 2021-12-28
KR102571186B1 (ko) 2023-08-25
JP2018516839A (ja) 2018-06-28
CA3289604A1 (en) 2025-11-29
AU2016240393A1 (en) 2017-10-12
SA517390046B1 (ar) 2022-07-31
JP2022009048A (ja) 2022-01-14
AU2018101788B4 (en) 2019-04-11
NZ735781A (en) 2019-09-27
EP3277623A1 (en) 2018-02-07
CN108064214A (zh) 2018-05-22
AU2016240393B2 (en) 2019-01-03
KR20180002619A (ko) 2018-01-08
PH12017501770A1 (en) 2018-03-19
US20240327212A1 (en) 2024-10-03
EA035857B1 (ru) 2020-08-20

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