AU2016240393B2 - A process for producing hydrogen and graphitic carbon from hydrocarbons - Google Patents

A process for producing hydrogen and graphitic carbon from hydrocarbons Download PDF

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Publication number
AU2016240393B2
AU2016240393B2 AU2016240393A AU2016240393A AU2016240393B2 AU 2016240393 B2 AU2016240393 B2 AU 2016240393B2 AU 2016240393 A AU2016240393 A AU 2016240393A AU 2016240393 A AU2016240393 A AU 2016240393A AU 2016240393 B2 AU2016240393 B2 AU 2016240393B2
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catalyst
reactor
pressure
gas
hydrogen
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AU2016240393A
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AU2016240393A1 (en
Inventor
Hui Tong Chua
Andrew Cornejo
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Hazer Group Ltd
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Hazer Group Ltd
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Priority claimed from AU2015901175A external-priority patent/AU2015901175A0/en
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Assigned to HAZER GROUP LTD reassignment HAZER GROUP LTD Alteration of Name(s) of Applicant(s) under S113 Assignors: HAZER GROUP LIMITED
Priority to AU2018101788A priority Critical patent/AU2018101788B4/en
Priority to AU2018267558A priority patent/AU2018267558A1/en
Priority to AU2018101787A priority patent/AU2018101787B4/en
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2445—Stationary reactors without moving elements inside placed in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0005—Catalytic processes under superatmospheric pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/205—Preparation
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B15/00—Other processes for the manufacture of iron from iron compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2203/00—Processes utilising sub- or super atmospheric pressure
    • B01J2203/06—High pressure synthesis
    • B01J2203/0605—Composition of the material to be processed
    • B01J2203/061—Graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
AU2016240393A 2015-03-31 2016-03-31 A process for producing hydrogen and graphitic carbon from hydrocarbons Active AU2016240393B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2018101788A AU2018101788B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphite from natural gases
AU2018267558A AU2018267558A1 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon from hydrocarbons
AU2018101787A AU2018101787B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon at elevated pressure

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AU2015901175A AU2015901175A0 (en) 2015-03-31 Thermocatalytic methane decomposition
AU2015901175 2015-03-31
PCT/AU2016/000115 WO2016154666A1 (en) 2015-03-31 2016-03-31 A process for producing hydrogen and graphitic carbon from hydrocarbons

Related Child Applications (3)

Application Number Title Priority Date Filing Date
AU2018101788A Division AU2018101788B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphite from natural gases
AU2018101787A Division AU2018101787B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon at elevated pressure
AU2018267558A Division AU2018267558A1 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon from hydrocarbons

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AU2016240393A1 AU2016240393A1 (en) 2017-10-12
AU2016240393B2 true AU2016240393B2 (en) 2019-01-03

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AU2016240393A Active AU2016240393B2 (en) 2015-03-31 2016-03-31 A process for producing hydrogen and graphitic carbon from hydrocarbons
AU2018267558A Abandoned AU2018267558A1 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon from hydrocarbons
AU2018101787A Expired AU2018101787B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon at elevated pressure
AU2018101788A Expired AU2018101788B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphite from natural gases

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AU2018267558A Abandoned AU2018267558A1 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon from hydrocarbons
AU2018101787A Expired AU2018101787B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphitic carbon at elevated pressure
AU2018101788A Expired AU2018101788B4 (en) 2015-03-31 2018-11-19 A process for producing hydrogen and graphite from natural gases

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US (3) US11505458B2 (enExample)
EP (1) EP3277623A4 (enExample)
JP (3) JP7007256B2 (enExample)
KR (2) KR20230106169A (enExample)
CN (1) CN108064214B (enExample)
AU (4) AU2016240393B2 (enExample)
BR (1) BR112017021057B1 (enExample)
CA (2) CA3289604A1 (enExample)
CL (1) CL2017002468A1 (enExample)
EA (1) EA035857B1 (enExample)
MX (1) MX2017012559A (enExample)
MY (1) MY188748A (enExample)
NZ (1) NZ735781A (enExample)
PH (1) PH12017501770A1 (enExample)
SA (1) SA517390046B1 (enExample)
SG (1) SG11201707907SA (enExample)
WO (1) WO2016154666A1 (enExample)
ZA (1) ZA201706455B (enExample)

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SG11201707907SA (en) 2017-10-30
BR112017021057A2 (pt) 2018-07-03
BR112017021057B1 (pt) 2023-03-21
MX2017012559A (es) 2018-04-11
CN108064214B (zh) 2021-08-06
AU2018267558A1 (en) 2018-12-06
JP7623001B2 (ja) 2025-01-28
ZA201706455B (en) 2019-07-31
AU2018101788A4 (en) 2019-01-03
JP2023139231A (ja) 2023-10-03
CA2980471A1 (en) 2016-10-06
WO2016154666A1 (en) 2016-10-06
US20230227307A1 (en) 2023-07-20
CL2017002468A1 (es) 2018-05-25
AU2018101787A4 (en) 2019-01-03
EA201792048A1 (ru) 2018-01-31
JP7007256B2 (ja) 2022-01-24
EP3277623A4 (en) 2018-11-07
AU2018101787B4 (en) 2019-02-28
US11505458B2 (en) 2022-11-22
US20180065850A1 (en) 2018-03-08
MY188748A (en) 2021-12-28
KR102571186B1 (ko) 2023-08-25
JP2018516839A (ja) 2018-06-28
CA3289604A1 (en) 2025-11-29
AU2016240393A1 (en) 2017-10-12
SA517390046B1 (ar) 2022-07-31
JP2022009048A (ja) 2022-01-14
AU2018101788B4 (en) 2019-04-11
NZ735781A (en) 2019-09-27
EP3277623A1 (en) 2018-02-07
CN108064214A (zh) 2018-05-22
KR20180002619A (ko) 2018-01-08
KR20230106169A (ko) 2023-07-12
PH12017501770A1 (en) 2018-03-19
US20240327212A1 (en) 2024-10-03
EA035857B1 (ru) 2020-08-20

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