CL2017002468A1 - Un proceso para la producción de hidrógeno y carbono grafítico a partir de hidrocarburos. - Google Patents
Un proceso para la producción de hidrógeno y carbono grafítico a partir de hidrocarburos.Info
- Publication number
- CL2017002468A1 CL2017002468A1 CL2017002468A CL2017002468A CL2017002468A1 CL 2017002468 A1 CL2017002468 A1 CL 2017002468A1 CL 2017002468 A CL2017002468 A CL 2017002468A CL 2017002468 A CL2017002468 A CL 2017002468A CL 2017002468 A1 CL2017002468 A1 CL 2017002468A1
- Authority
- CL
- Chile
- Prior art keywords
- hydrogen
- hydrocarbons
- graphite carbon
- production
- hydrocarbon gas
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2445—Stationary reactors without moving elements inside placed in parallel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0005—Catalytic processes under superatmospheric pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
- C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/20—Graphite
- C01B32/205—Preparation
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B15/00—Other processes for the manufacture of iron from iron compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2203/00—Processes utilising sub- or super atmospheric pressure
- B01J2203/06—High pressure synthesis
- B01J2203/0605—Composition of the material to be processed
- B01J2203/061—Graphite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
<p>De acuerdo con la presente invención, se proporciona un proceso para producir hidrógeno y carbono grafitico a partir de un gas de hidrocarburos, que comprende: contactar a una temperatura entre 600°C y 1000°C, el catalizador con el gas de hidrocarburos para convertir catalíticamente por lo menos una porción del gas de hidrocarburos a hidrógeno y carbono grafítico, en donde el catalizador es un óxido de hierro de grado bajo. También se proporciona un método para el beneficio del metal catalítico que contiene mineral, el método comprende contactar a una temperatura ente 600°C a 1000°C el metal catalitico que contiene mineral con un gas de hidrocarburos para formar una especie de metal recubierto de carbono.</p>
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2015901175A AU2015901175A0 (en) | 2015-03-31 | Thermocatalytic methane decomposition |
Publications (1)
Publication Number | Publication Date |
---|---|
CL2017002468A1 true CL2017002468A1 (es) | 2018-05-25 |
Family
ID=57003724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CL2017002468A CL2017002468A1 (es) | 2015-03-31 | 2017-09-29 | Un proceso para la producción de hidrógeno y carbono grafítico a partir de hidrocarburos. |
Country Status (18)
Country | Link |
---|---|
US (3) | US11505458B2 (es) |
EP (1) | EP3277623A4 (es) |
JP (3) | JP7007256B2 (es) |
KR (2) | KR20230106169A (es) |
CN (1) | CN108064214B (es) |
AU (4) | AU2016240393B2 (es) |
BR (1) | BR112017021057B1 (es) |
CA (1) | CA2980471A1 (es) |
CL (1) | CL2017002468A1 (es) |
EA (1) | EA035857B1 (es) |
MX (1) | MX2017012559A (es) |
MY (1) | MY188748A (es) |
NZ (1) | NZ735781A (es) |
PH (1) | PH12017501770A1 (es) |
SA (1) | SA517390046B1 (es) |
SG (1) | SG11201707907SA (es) |
WO (1) | WO2016154666A1 (es) |
ZA (1) | ZA201706455B (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7007256B2 (ja) | 2015-03-31 | 2022-01-24 | ヘイザー グループ リミテッド | 炭化水素から水素及び黒鉛状炭素を生成するプロセス |
BR112018003639B1 (pt) | 2015-08-26 | 2022-08-30 | Hazer Group Limited | Processo de controle da morfologia de grafite |
WO2018170543A1 (en) * | 2017-03-20 | 2018-09-27 | Hazer Group Limited | System for the production of hydrogen and graphitic carbon |
US20210114003A1 (en) | 2017-04-14 | 2021-04-22 | King Abdullah University Of Science And Technology | Treated iron ore catalysts for production of hydrogen and graphene |
DE102018132661B4 (de) * | 2018-12-18 | 2020-10-01 | Thyssenkrupp Ag | Verfahren zur Kohlenwasserstoffpyrolyse mit räumlich getrennter Beheizungs- und Reaktionszone innerhalb des Reaktorraums |
AT522315B1 (de) | 2019-03-28 | 2020-10-15 | Primetals Technologies Austria GmbH | Verfahren zur Herstellung von Wasserstoff und Kohlenstoff aus einem kohlenwasserstoffhaltigen Gas |
US20210047180A1 (en) * | 2019-08-14 | 2021-02-18 | General Electric Company | Production system and method for generating hydrogen gas and carbon products |
JP7413704B2 (ja) * | 2019-10-08 | 2024-01-16 | 戸田工業株式会社 | 炭化水素の熱分解用触媒並びにそれを用いたカーボンナノチューブ及び水素製造方法 |
US11685651B2 (en) | 2019-10-25 | 2023-06-27 | Mark Kevin Robertson | Catalytic decomposition of hydrocarbons for the production of hydrogen and carbon |
CN110721691B (zh) * | 2019-11-12 | 2020-07-24 | 中南大学 | 一种cfan催化剂及其制备和在甲烷制氢中的应用 |
US11401163B2 (en) | 2020-10-19 | 2022-08-02 | Xenophon Verykios | Catalytic materials for pyrolysis of methane and production of hydrogen and solid carbon with substantially zero atmospheric carbon emissions |
KR102482738B1 (ko) * | 2020-11-23 | 2022-12-28 | 노용규 | 탄화수소 열분해 수소 생산 장치 및 이의 운용 방법 |
KR102471954B1 (ko) * | 2020-11-23 | 2022-11-29 | 노용규 | 촉매 활성 저하를 해결한 탄화수소 열분해 수소 생산 장치 및 수소 생산 방법 |
JP2024502449A (ja) * | 2021-01-07 | 2024-01-19 | ザ・ジョンズ・ホプキンス・ユニバーシティ | 炭化水素からの水素の生成 |
JP2023128516A (ja) * | 2022-03-03 | 2023-09-14 | 三菱重工業株式会社 | 触媒の製造方法及びこの触媒を使用した炭化水素の直接分解方法 |
JP7482164B2 (ja) | 2022-03-11 | 2024-05-13 | 三菱重工業株式会社 | 炭化水素の直接分解方法 |
US20240124301A1 (en) * | 2022-10-07 | 2024-04-18 | Sk Innovation Co., Ltd. | Process for producing hydrogen, carbon monoxide, and carbon from methane-containing feedstock |
WO2024119237A1 (en) * | 2022-12-09 | 2024-06-13 | Hazer Group Limited | System and methods configured to enable improved/optimised control of a hydrocarbon pyrolysis process |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2810657C2 (de) * | 1978-03-11 | 1980-01-24 | Hamburger Stahlwerke Gmbh, 2103 Hamburg | Verfahren zur Direktreduktion von Eisenerzen |
BR9811068A (pt) | 1997-08-04 | 2000-08-15 | Bechtel Group Inc | Método para obter um concentrado de ferro a partir de uma carga de menério de ferro |
JP4758130B2 (ja) | 2005-04-12 | 2011-08-24 | 国立大学法人北見工業大学 | ナノ炭素の製造方法およびナノ炭素製造用触媒反応装置 |
JP4779446B2 (ja) | 2005-05-27 | 2011-09-28 | トヨタ自動車株式会社 | 触媒再生方法、水素生成装置および燃料電池システム |
KR100743189B1 (ko) | 2005-12-26 | 2007-07-27 | 주식회사 포스코 | 용철 제조 장치 및 제조 방법 |
JP2009537439A (ja) | 2006-05-19 | 2009-10-29 | マサチューセッツ・インスティテュート・オブ・テクノロジー | ナノチューブを含むナノ構造の生成のための連続処理 |
KR100888247B1 (ko) * | 2007-08-02 | 2009-03-10 | 성균관대학교산학협력단 | 탄화수소의 카본 촉매분해에 의한 이산화탄소 배출없이 수소를 연속적으로 생산할 수 있는 유동층 반응기 및 이를 포함하는 반응 장치 |
WO2011029144A1 (en) | 2009-09-10 | 2011-03-17 | The University Of Western Australia | A process for producing hydrogen from hydrocarbons |
JP2012158790A (ja) | 2011-01-31 | 2012-08-23 | Nippon Steel Corp | マイクロ波を利用した製鉄原料の還元方法 |
JP2013249496A (ja) | 2012-05-30 | 2013-12-12 | Kobe Steel Ltd | 還元鉄とスラグの混合物の製造方法 |
JP7007256B2 (ja) | 2015-03-31 | 2022-01-24 | ヘイザー グループ リミテッド | 炭化水素から水素及び黒鉛状炭素を生成するプロセス |
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2016
- 2016-03-31 JP JP2018502293A patent/JP7007256B2/ja active Active
- 2016-03-31 WO PCT/AU2016/000115 patent/WO2016154666A1/en active Application Filing
- 2016-03-31 MX MX2017012559A patent/MX2017012559A/es unknown
- 2016-03-31 AU AU2016240393A patent/AU2016240393B2/en active Active
- 2016-03-31 EP EP16771087.0A patent/EP3277623A4/en active Pending
- 2016-03-31 US US15/563,430 patent/US11505458B2/en active Active
- 2016-03-31 BR BR112017021057-6A patent/BR112017021057B1/pt active IP Right Grant
- 2016-03-31 NZ NZ73578116A patent/NZ735781A/en unknown
- 2016-03-31 SG SG11201707907SA patent/SG11201707907SA/en unknown
- 2016-03-31 EA EA201792048A patent/EA035857B1/ru unknown
- 2016-03-31 KR KR1020237019348A patent/KR20230106169A/ko not_active Application Discontinuation
- 2016-03-31 KR KR1020177030318A patent/KR102571186B1/ko active IP Right Grant
- 2016-03-31 CA CA2980471A patent/CA2980471A1/en active Pending
- 2016-03-31 CN CN201680019418.4A patent/CN108064214B/zh active Active
- 2016-03-31 MY MYPI2017703581A patent/MY188748A/en unknown
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2017
- 2017-09-26 ZA ZA2017/06455A patent/ZA201706455B/en unknown
- 2017-09-26 PH PH12017501770A patent/PH12017501770A1/en unknown
- 2017-09-28 SA SA517390046A patent/SA517390046B1/ar unknown
- 2017-09-29 CL CL2017002468A patent/CL2017002468A1/es unknown
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2018
- 2018-11-19 AU AU2018267558A patent/AU2018267558A1/en not_active Abandoned
- 2018-11-19 AU AU2018101788A patent/AU2018101788B4/en not_active Expired
- 2018-11-19 AU AU2018101787A patent/AU2018101787B4/en not_active Expired
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2021
- 2021-10-12 JP JP2021167526A patent/JP2022009048A/ja active Pending
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2022
- 2022-11-22 US US17/992,855 patent/US20230227307A1/en not_active Abandoned
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2023
- 2023-07-27 JP JP2023122178A patent/JP2023139231A/ja active Pending
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2024
- 2024-03-12 US US18/602,260 patent/US20240327212A1/en active Pending
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