MX2017009129A - Proceso para convertir metanol a hidrocarburos adecuados para el uso como gasolina o componente de mezcla. - Google Patents
Proceso para convertir metanol a hidrocarburos adecuados para el uso como gasolina o componente de mezcla.Info
- Publication number
- MX2017009129A MX2017009129A MX2017009129A MX2017009129A MX2017009129A MX 2017009129 A MX2017009129 A MX 2017009129A MX 2017009129 A MX2017009129 A MX 2017009129A MX 2017009129 A MX2017009129 A MX 2017009129A MX 2017009129 A MX2017009129 A MX 2017009129A
- Authority
- MX
- Mexico
- Prior art keywords
- stream
- conversion step
- hydrocarbons
- blendstock
- gasoline
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C9/00—Aliphatic saturated hydrocarbons
- C07C9/02—Aliphatic saturated hydrocarbons with one to four carbon atoms
- C07C9/08—Propane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C9/00—Aliphatic saturated hydrocarbons
- C07C9/02—Aliphatic saturated hydrocarbons with one to four carbon atoms
- C07C9/10—Aliphatic saturated hydrocarbons with one to four carbon atoms with four carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
- C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La presente solicitud se refiere a un proceso para la producción de hidrocarburos que comprende los pasos de: - conversión de una corriente de alimentación que comprende alcoholes, éteres o mezclas de los mismos sobre un catalizador basado en zeolita que contiene metal, activo en la deshidrogenación de hidrocarburos, en un paso de conversión para obtener en consecuencia un efluente de conversión, - separación del efluente para obtener una corriente de condensado de proceso acuoso, una corriente de hidrocarburo líquido y una corriente gaseosa, - remoción de parte del hidrógeno formado en el paso de conversión, y reciclaje de por lo menos parte de la corriente de hidrocarburo gaseoso y/o líquido al paso de conversión.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA201570042 | 2015-01-22 | ||
PCT/EP2016/051367 WO2016116612A1 (en) | 2015-01-22 | 2016-01-22 | Process for converting methanol to hydrocarbons suitable for use as gasoline or blendstock. |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2017009129A true MX2017009129A (es) | 2017-10-19 |
Family
ID=55221432
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2017009128A MX2017009128A (es) | 2015-01-22 | 2016-01-22 | Rechazo de hidrogeno en el proceso de metanol a hidrocarburo. |
MX2017009129A MX2017009129A (es) | 2015-01-22 | 2016-01-22 | Proceso para convertir metanol a hidrocarburos adecuados para el uso como gasolina o componente de mezcla. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2017009128A MX2017009128A (es) | 2015-01-22 | 2016-01-22 | Rechazo de hidrogeno en el proceso de metanol a hidrocarburo. |
Country Status (9)
Country | Link |
---|---|
US (2) | US10336673B2 (es) |
CN (2) | CN107206365A (es) |
AU (2) | AU2016208486C1 (es) |
BR (2) | BR112017015408A2 (es) |
CA (2) | CA2973639A1 (es) |
EA (2) | EA201791631A1 (es) |
MX (2) | MX2017009128A (es) |
WO (2) | WO2016116612A1 (es) |
ZA (2) | ZA201704393B (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106608784B (zh) * | 2015-10-22 | 2019-07-09 | 中国石油化工股份有限公司 | 回收甲醇制芳烃轻质产物的方法 |
CN108602731A (zh) | 2015-11-30 | 2018-09-28 | 托普索公司 | 使用双功能催化剂的甲醇制烃过程中的氢气排除 |
US10696606B2 (en) * | 2016-06-09 | 2020-06-30 | Ut-Battelle, Llc | Zeolitic catalytic conversion of alcohols to hydrocarbon fractions with reduced gaseous hydrocarbon content |
US10647623B2 (en) * | 2018-08-10 | 2020-05-12 | Uop Llc | Processes for reduced oxygenated recycle in an MTO conversion |
MX2022012224A (es) * | 2020-04-06 | 2022-10-27 | Topsoe As | Produccion selectiva de gasolina sintetica ligera. |
WO2023001695A1 (en) | 2021-07-21 | 2023-01-26 | Topsoe A/S | Process and plant for improving gasoline octane rating |
WO2023187147A1 (en) | 2022-04-01 | 2023-10-05 | Topsoe A/S | Conversion of carbon dioxide to gasoline using e-smr |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3948758A (en) | 1974-06-17 | 1976-04-06 | Mobil Oil Corporation | Production of alkyl aromatic hydrocarbons |
US4523046A (en) | 1982-02-25 | 1985-06-11 | Mobil Oil Corporation | Method for gasoline yield enhancement in the fixed bed methanol-to-gasoline process |
US4543435A (en) * | 1985-01-17 | 1985-09-24 | Mobil Oil Corporation | Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle |
US4788369A (en) | 1985-12-31 | 1988-11-29 | Mobil Oil Corporation | Conversion of methanol to gasoline |
US4684757A (en) | 1986-07-18 | 1987-08-04 | Mobil Oil Corporation | Process for converting methanol to alkyl ethers, gasoline, distillate and alkylate liquid hydrocarbons |
US4835329A (en) | 1987-12-08 | 1989-05-30 | Mobil Oil Corporation | Process for producing high octane gasoline |
US4851606A (en) * | 1988-04-25 | 1989-07-25 | Mobil Oil Corporation | Control of waste water chemical oxygen demand in an oxygenate to hydrocarbon conversion process |
US5591421A (en) | 1994-07-11 | 1997-01-07 | Chevron U.S.A. Inc. | Zeolite SSZ-41 |
US6372680B1 (en) | 1999-07-27 | 2002-04-16 | Phillips Petroleum Company | Catalyst system for converting oxygenated hydrocarbons to aromatics |
US7879749B2 (en) | 2006-08-15 | 2011-02-01 | Battelle Energy Alliance, Llc | Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons |
ES2431145T3 (es) * | 2007-09-14 | 2013-11-25 | Haldor Topsoe A/S | Proceso para conversión de compuestos oxigenados en gasolina |
CN102049292B (zh) * | 2009-10-27 | 2012-11-14 | 中国石油化工股份有限公司 | 一种甲醇制汽油催化剂和甲醇制汽油的方法 |
CN102199069A (zh) * | 2010-03-23 | 2011-09-28 | 中国海洋石油总公司 | 一种由含有甲醇的原料制备芳烃的方法 |
CN102746095B (zh) * | 2011-04-20 | 2015-04-08 | 中国石油化工股份有限公司 | 苯和甲醇或二甲醚制石油级甲苯的方法 |
US8969640B2 (en) * | 2011-11-23 | 2015-03-03 | Virent, Inc. | Dehydrogenation of alkanols to increase yield of aromatics |
US8962902B2 (en) * | 2011-11-23 | 2015-02-24 | Virent, Inc. | Dehydrogenation of alkanols to increase yield of aromatics |
US9296665B2 (en) * | 2012-12-13 | 2016-03-29 | Pioneer Energy Inc. | Synthesis of drop-in liquid fuels and chemicals from methanol, ethanol or syngas using mixed catalysts |
CN103433067B (zh) * | 2013-09-09 | 2016-08-17 | 中国科学院上海高等研究院 | 用于甲醇制汽油的催化剂及其制备与应用 |
CN103865564B (zh) * | 2014-02-24 | 2015-08-19 | 中国海洋石油总公司 | 一种甲醇或二甲醚合成汽油的集成方法 |
CN103864561B (zh) * | 2014-02-24 | 2015-04-22 | 中国海洋石油总公司 | 一种甲醇芳构化制取芳烃的工艺方法 |
CN103865562A (zh) * | 2014-02-24 | 2014-06-18 | 中国海洋石油总公司 | 一种甲醇制汽油的方法 |
-
2016
- 2016-01-22 US US15/544,670 patent/US10336673B2/en active Active
- 2016-01-22 CA CA2973639A patent/CA2973639A1/en not_active Abandoned
- 2016-01-22 WO PCT/EP2016/051367 patent/WO2016116612A1/en active Application Filing
- 2016-01-22 BR BR112017015408-0A patent/BR112017015408A2/pt not_active Application Discontinuation
- 2016-01-22 CN CN201680006520.0A patent/CN107206365A/zh active Pending
- 2016-01-22 EA EA201791631A patent/EA201791631A1/ru unknown
- 2016-01-22 MX MX2017009128A patent/MX2017009128A/es unknown
- 2016-01-22 CA CA2973638A patent/CA2973638C/en active Active
- 2016-01-22 CN CN201680006554.XA patent/CN107635952A/zh active Pending
- 2016-01-22 WO PCT/EP2016/051366 patent/WO2016116611A1/en active Application Filing
- 2016-01-22 BR BR112017014356-9A patent/BR112017014356B1/pt active IP Right Grant
- 2016-01-22 US US15/543,009 patent/US10150718B2/en active Active
- 2016-01-22 AU AU2016208486A patent/AU2016208486C1/en active Active
- 2016-01-22 AU AU2016208485A patent/AU2016208485B2/en active Active
- 2016-01-22 MX MX2017009129A patent/MX2017009129A/es unknown
- 2016-01-22 EA EA201791636A patent/EA035172B1/ru not_active IP Right Cessation
-
2017
- 2017-06-28 ZA ZA201704393A patent/ZA201704393B/en unknown
- 2017-06-28 ZA ZA201704394A patent/ZA201704394B/en unknown
Also Published As
Publication number | Publication date |
---|---|
BR112017014356A2 (pt) | 2018-04-10 |
CN107206365A (zh) | 2017-09-26 |
CA2973638A1 (en) | 2016-07-28 |
CN107635952A (zh) | 2018-01-26 |
EA201791636A1 (ru) | 2017-11-30 |
AU2016208485B2 (en) | 2021-03-04 |
US20180022673A1 (en) | 2018-01-25 |
WO2016116611A1 (en) | 2016-07-28 |
ZA201704393B (en) | 2019-10-30 |
BR112017015408A2 (pt) | 2018-07-17 |
EA201791631A1 (ru) | 2017-11-30 |
MX2017009128A (es) | 2017-10-19 |
ZA201704394B (en) | 2019-10-30 |
AU2016208486B2 (en) | 2021-06-03 |
AU2016208486C1 (en) | 2021-12-23 |
AU2016208486A1 (en) | 2017-08-03 |
CA2973638C (en) | 2021-11-09 |
US20180002610A1 (en) | 2018-01-04 |
AU2016208485A1 (en) | 2017-08-03 |
EA035172B1 (ru) | 2020-05-12 |
WO2016116612A1 (en) | 2016-07-28 |
BR112017014356B1 (pt) | 2022-04-26 |
CA2973639A1 (en) | 2016-07-28 |
US10336673B2 (en) | 2019-07-02 |
US10150718B2 (en) | 2018-12-11 |
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