EA032099B1 - Полиолефиновая труба - Google Patents
Полиолефиновая труба Download PDFInfo
- Publication number
- EA032099B1 EA032099B1 EA201692133A EA201692133A EA032099B1 EA 032099 B1 EA032099 B1 EA 032099B1 EA 201692133 A EA201692133 A EA 201692133A EA 201692133 A EA201692133 A EA 201692133A EA 032099 B1 EA032099 B1 EA 032099B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- pipe
- alkyl
- pipe according
- photoinitiator
- present
- Prior art date
Links
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- -1 polyethylene Polymers 0.000 claims abstract description 78
- 238000004132 cross linking Methods 0.000 claims abstract description 76
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- 238000001125 extrusion Methods 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims description 104
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- 125000000217 alkyl group Chemical group 0.000 claims description 56
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 37
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- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 17
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- QATSOLLSVDVSAL-UHFFFAOYSA-N 4-[hydroxy(phenyl)methyl]phenol Chemical compound C=1C=C(O)C=CC=1C(O)C1=CC=CC=C1 QATSOLLSVDVSAL-UHFFFAOYSA-N 0.000 claims description 8
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- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 2
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- WTAJUZVRCDEXDL-UHFFFAOYSA-N bis(4-hexoxyphenyl)methanone Chemical compound C1=CC(OCCCCCC)=CC=C1C(=O)C1=CC=C(OCCCCCC)C=C1 WTAJUZVRCDEXDL-UHFFFAOYSA-N 0.000 description 4
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- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 description 1
- GCNKJQRMNYNDBI-UHFFFAOYSA-N [2-(hydroxymethyl)-2-(2-methylprop-2-enoyloxymethyl)butyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CC)COC(=O)C(C)=C GCNKJQRMNYNDBI-UHFFFAOYSA-N 0.000 description 1
- TUOBEAZXHLTYLF-UHFFFAOYSA-N [2-(hydroxymethyl)-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(CC)COC(=O)C=C TUOBEAZXHLTYLF-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- UKMBKKFLJMFCSA-UHFFFAOYSA-N [3-hydroxy-2-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)OC(=O)C(C)=C UKMBKKFLJMFCSA-UHFFFAOYSA-N 0.000 description 1
- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical class C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 description 1
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- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
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- BSILAEQTGTZMIW-UHFFFAOYSA-N bis(4-phenoxyphenyl)methanone Chemical compound C=1C=C(OC=2C=CC=CC=2)C=CC=1C(=O)C(C=C1)=CC=C1OC1=CC=CC=C1 BSILAEQTGTZMIW-UHFFFAOYSA-N 0.000 description 1
- QUZSUMLPWDHKCJ-UHFFFAOYSA-N bisphenol A dimethacrylate Chemical class C1=CC(OC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OC(=O)C(C)=C)C=C1 QUZSUMLPWDHKCJ-UHFFFAOYSA-N 0.000 description 1
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- 235000012206 bottled water Nutrition 0.000 description 1
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- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
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- SNVTZAIYUGUKNI-UHFFFAOYSA-N dibenzo[1,2-a:1',2'-e][7]annulen-11-one Chemical compound C1=CC2=CC=CC=C2C(=O)C2=CC=CC=C21 SNVTZAIYUGUKNI-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
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- 125000001475 halogen functional group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
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- 125000002950 monocyclic group Chemical group 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
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- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/105—Esters; Ether-esters of monocarboxylic acids with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461983062P | 2014-04-23 | 2014-04-23 | |
| PCT/EP2015/058663 WO2015162155A1 (en) | 2014-04-23 | 2015-04-22 | Polyolefin pipe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201692133A1 EA201692133A1 (ru) | 2017-04-28 |
| EA032099B1 true EA032099B1 (ru) | 2019-04-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201692133A EA032099B1 (ru) | 2014-04-23 | 2015-04-22 | Полиолефиновая труба |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10519286B2 (enExample) |
| EP (1) | EP3134669B1 (enExample) |
| JP (1) | JP6698548B2 (enExample) |
| CA (1) | CA2945412C (enExample) |
| DK (1) | DK3134669T3 (enExample) |
| EA (1) | EA032099B1 (enExample) |
| ES (1) | ES2757957T3 (enExample) |
| GB (1) | GB2525453A (enExample) |
| PL (1) | PL3134669T3 (enExample) |
| PT (1) | PT3134669T (enExample) |
| WO (1) | WO2015162155A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3045641B1 (fr) * | 2015-12-22 | 2021-04-30 | Bluestar Silicones France | Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones |
| CA2977581A1 (en) | 2016-09-02 | 2018-03-02 | Zurn Industries, Llc | Injection molded cold-expansion compression collar |
| US11543065B2 (en) | 2016-09-02 | 2023-01-03 | Zurn Industries, Llc | Extruded cold-expansion compression collar |
| US11541581B2 (en) | 2016-09-02 | 2023-01-03 | Zurn Industries, Llc | Injection molded cold-expansion compression collar |
| US11054076B2 (en) | 2016-11-04 | 2021-07-06 | Zurn Industries, Llc | Reinforcing ring with sleeve |
| US11667762B2 (en) * | 2017-08-29 | 2023-06-06 | The General Hospital Corporation | UV-initiated reactions in polymeric materials |
| IL257535B (en) * | 2018-02-14 | 2020-01-30 | N3 Coat Ltd | Benzophenone compounds as light catalysts for polyolefins |
| CN113795368B (zh) | 2019-05-02 | 2025-03-07 | Sabic环球技术有限责任公司 | 输送氯化水的管 |
| JP7477954B2 (ja) * | 2019-10-16 | 2024-05-02 | 旭化成アドバンス株式会社 | コンクリート圧送方法 |
| CN111022786B (zh) * | 2019-12-30 | 2021-06-15 | 安徽杰蓝特新材料有限公司 | 一种玻纤增强pe给水管及其制备方法 |
| WO2021148352A1 (en) | 2020-01-21 | 2021-07-29 | Sabic Global Technologies B.V. | Pipe for transport of water containing chlorinated disinfectant |
| WO2022219672A1 (ja) * | 2021-04-12 | 2022-10-20 | 旭化成アドバンス株式会社 | コンクリート圧送管 |
| CN117597388B (zh) | 2021-07-08 | 2025-09-19 | 北欧化工公司 | 用于生产交联聚乙烯（pex）的聚乙烯 |
| GB2607979B (en) * | 2021-11-30 | 2024-01-31 | Wavin Bv | Multi-layered pipe |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0490854A2 (en) * | 1990-12-07 | 1992-06-17 | Institutet Polymerutveckling Ab | Process and equipment for continuous crosslinking of polymeric materials and useful photo-initiators for the reaction |
| US6696154B2 (en) * | 1999-07-27 | 2004-02-24 | Pirelli Cavi E Sistemi S.P.A. | Cable, in particular for transport or distribution of electrical energy and insulating composition |
| US20090149588A1 (en) * | 2007-12-05 | 2009-06-11 | Uponor Innovation Ab | Plastic pipe made of polyolefin |
| US20100084037A1 (en) * | 2008-10-03 | 2010-04-08 | Uponor Innovation Ab | Methods and compositions for coating pipe |
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|---|---|---|---|---|
| US4310650A (en) * | 1980-03-03 | 1982-01-12 | California Institute Of Technology | Ultraviolet absorbing copolymers |
| IN164745B (enExample) | 1984-05-11 | 1989-05-20 | Stamicarbon | |
| JPH03180323A (ja) | 1989-12-08 | 1991-08-06 | Toyo Echo Kk | 熱収縮性蓋の製造方法 |
| JPH03287632A (ja) * | 1990-04-05 | 1991-12-18 | Fujikura Ltd | 架橋ポリオレフィン成形物の製法 |
| US5299885A (en) * | 1992-08-14 | 1994-04-05 | Aquapore Moisture Systems, Inc. | Stabilized porous pipe |
| FR2710344B1 (fr) | 1993-09-21 | 1995-11-17 | Inst Francais Du Petrole | Compositions de polyéthylènes réticulables, utilisées notamment pour la fabrication de tubes et de gaines flexibles. |
| DE4404041C1 (de) | 1994-02-09 | 1995-03-23 | Ruesch Willy Ag | Polymermaterial von medizinischen Instrumenten und Verfahren zur Herstellung des Polymermaterials |
| NL1008960C2 (nl) | 1998-04-22 | 1999-10-25 | Wavin Bv | Kunststofbuis met een uit meerdere lagen samengestelde wand. |
| WO2000022334A1 (en) * | 1998-10-09 | 2000-04-20 | Sekisui Chemical Co., Ltd. | Composite high-pressure pipe and method of joining same |
| AR023110A1 (es) | 1999-03-22 | 2002-09-04 | Loctite Corp | Articulos roscados con revestimiento deformable curado sobre los mismos |
| CA2372056A1 (en) * | 1999-05-14 | 2000-11-23 | Morgan Mark Hughes | Highly crystalline eaodm interpolymers |
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2015
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- 2015-04-22 PL PL15718476T patent/PL3134669T3/pl unknown
- 2015-04-22 WO PCT/EP2015/058663 patent/WO2015162155A1/en not_active Ceased
- 2015-04-22 US US15/304,597 patent/US10519286B2/en active Active
- 2015-04-22 EA EA201692133A patent/EA032099B1/ru not_active IP Right Cessation
- 2015-04-22 ES ES15718476T patent/ES2757957T3/es active Active
- 2015-04-22 CA CA2945412A patent/CA2945412C/en active Active
- 2015-04-22 EP EP15718476.3A patent/EP3134669B1/en active Active
- 2015-04-22 PT PT157184763T patent/PT3134669T/pt unknown
- 2015-04-22 DK DK15718476T patent/DK3134669T3/da active
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Also Published As
| Publication number | Publication date |
|---|---|
| PT3134669T (pt) | 2019-11-29 |
| EP3134669B1 (en) | 2019-09-04 |
| CA2945412C (en) | 2023-02-21 |
| US20170114193A1 (en) | 2017-04-27 |
| JP6698548B2 (ja) | 2020-05-27 |
| EA201692133A1 (ru) | 2017-04-28 |
| DK3134669T3 (da) | 2019-11-25 |
| GB201412092D0 (en) | 2014-08-20 |
| JP2017519851A (ja) | 2017-07-20 |
| GB2525453A (en) | 2015-10-28 |
| PL3134669T3 (pl) | 2020-02-28 |
| EP3134669A1 (en) | 2017-03-01 |
| ES2757957T3 (es) | 2020-04-30 |
| WO2015162155A1 (en) | 2015-10-29 |
| US10519286B2 (en) | 2019-12-31 |
| CA2945412A1 (en) | 2015-10-29 |
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