FR3045641B1 - Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones - Google Patents

Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones Download PDF

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Publication number
FR3045641B1
FR3045641B1 FR1563147A FR1563147A FR3045641B1 FR 3045641 B1 FR3045641 B1 FR 3045641B1 FR 1563147 A FR1563147 A FR 1563147A FR 1563147 A FR1563147 A FR 1563147A FR 3045641 B1 FR3045641 B1 FR 3045641B1
Authority
FR
France
Prior art keywords
cross
type
silicone compositions
photoinitiator system
linking silicone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1563147A
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English (en)
Other versions
FR3045641A1 (fr
Inventor
Guillaume Pibre
Jean Marc Frances
Xavier Allonas
Ahmad Ibrahim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universite de Haute Alsace
Elkem Silicones France SAS
Original Assignee
Bluestar Silicones France SAS
Universite de Haute Alsace
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1563147A priority Critical patent/FR3045641B1/fr
Application filed by Bluestar Silicones France SAS, Universite de Haute Alsace filed Critical Bluestar Silicones France SAS
Priority to CN201680082028.1A priority patent/CN109072001B/zh
Priority to CA3009545A priority patent/CA3009545C/fr
Priority to EP16819932.1A priority patent/EP3408340A1/fr
Priority to JP2018533771A priority patent/JP6805256B2/ja
Priority to KR1020187021082A priority patent/KR102671096B1/ko
Priority to BR112018012849-0A priority patent/BR112018012849B1/pt
Priority to US16/065,258 priority patent/US10954384B2/en
Priority to PCT/EP2016/082456 priority patent/WO2017109116A1/fr
Publication of FR3045641A1 publication Critical patent/FR3045641A1/fr
Priority to JP2020027376A priority patent/JP2020111574A/ja
Priority to US17/159,417 priority patent/US11603468B2/en
Application granted granted Critical
Publication of FR3045641B1 publication Critical patent/FR3045641B1/fr
Priority to JP2022064106A priority patent/JP7496579B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/44—Block-or graft-polymers containing polysiloxane sequences containing only polysiloxane sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/06—Crosslinking by radiation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne une composition silicone C réticulable par exposition à un rayonnement de longueur d'onde comprise entre 200 nm et 450 nm, comprenant : - au moins un photoamorceur radicalaire A ; et - au moins un co-amorceur B choisi parmi les composés comprenant au moins un atome d'hydrogène lié à un atome de silicium.
FR1563147A 2015-12-22 2015-12-22 Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones Active FR3045641B1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
FR1563147A FR3045641B1 (fr) 2015-12-22 2015-12-22 Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones
PCT/EP2016/082456 WO2017109116A1 (fr) 2015-12-22 2016-12-22 Utilisation d'un système photoamorceur de type ii pour la réticulation de compositions silicones
EP16819932.1A EP3408340A1 (fr) 2015-12-22 2016-12-22 Utilisation d'un système photoamorceur de type ii pour la réticulation de compositions silicones
JP2018533771A JP6805256B2 (ja) 2015-12-22 2016-12-22 シリコーン組成物を架橋させるためのタイプｉｉ光開始剤系の使用
KR1020187021082A KR102671096B1 (ko) 2015-12-22 2016-12-22 실리콘 조성물을 가교결합시키기 위한 ii형 광개시제 시스템의 용도
BR112018012849-0A BR112018012849B1 (pt) 2015-12-22 2016-12-22 Composição de silicone, utilização da composição, elastômero de silicone, método de preparação de filmes de silicone com propriedades antiaderentes, método de preparação de um revestimento em um substrato, substrato revestido, compostos e utilização dos compostos
CN201680082028.1A CN109072001B (zh) 2015-12-22 2016-12-22 Ii型光引发剂体系用于交联硅酮组合物的用途
CA3009545A CA3009545C (fr) 2015-12-22 2016-12-22 Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones
US16/065,258 US10954384B2 (en) 2015-12-22 2016-12-22 Type II photoinitiator system and method for crosslinking silicone compositions
JP2020027376A JP2020111574A (ja) 2015-12-22 2020-02-20 シリコーン組成物を架橋させるためのタイプｉｉ光開始剤系の使用
US17/159,417 US11603468B2 (en) 2015-12-22 2021-01-27 Type II photoinitiator system and method for forming crosslinking silicone compositions
JP2022064106A JP7496579B2 (ja) 2015-12-22 2022-04-07 シリコーン組成物を架橋させるためのタイプｉｉ光開始剤系の使用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1563147A FR3045641B1 (fr) 2015-12-22 2015-12-22 Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones

Publications (2)

Publication Number Publication Date
FR3045641A1 FR3045641A1 (fr) 2017-06-23
FR3045641B1 true FR3045641B1 (fr) 2021-04-30

Family

ID=56101507

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1563147A Active FR3045641B1 (fr) 2015-12-22 2015-12-22 Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones

Country Status (9)

Country Link
US (2) US10954384B2 (fr)
EP (1) EP3408340A1 (fr)
JP (3) JP6805256B2 (fr)
KR (1) KR102671096B1 (fr)
CN (1) CN109072001B (fr)
BR (1) BR112018012849B1 (fr)
CA (1) CA3009545C (fr)
FR (1) FR3045641B1 (fr)
WO (1) WO2017109116A1 (fr)

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* Cited by examiner, † Cited by third party
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CN107922796B (zh) * 2015-07-06 2020-09-25 蓝星有机硅法国两合公司 自粘多层制品及其制备方法
FR3045641B1 (fr) * 2015-12-22 2021-04-30 Bluestar Silicones France Utilisation d'un systeme photoamorceur de type ii pour la reticulation de compositions silicones
KR102240076B1 (ko) * 2017-11-10 2021-04-14 주식회사 엘지화학 이형 조성물 및 이의 경화물을 포함하는 이형층을 포함하는 이형 필름
IL257535B (en) * 2018-02-14 2020-01-30 N3 Coat Ltd Benzophenone compounds as light catalysts for polyolefins
EP3902878A1 (fr) * 2018-12-28 2021-11-03 IGM Resins Italia S.r.l. Photoinitiateurs
KR102498354B1 (ko) * 2019-10-23 2023-02-08 주식회사 엘지화학 실리콘계 이형제 조성물, 이로부터 경화된 이형층을 구비하는 이형필름 및 그 제조방법
MY206973A (en) 2019-11-27 2025-01-22 Three Bond Co Ltd Primer composition
US12163068B2 (en) * 2020-05-07 2024-12-10 Dow Silicones Corporation Silicone hybrid pressure sensitive adhesive and methods for its preparation and use on uneven surfaces
JP7411500B2 (ja) 2020-05-11 2024-01-11 信越化学工業株式会社 光硬化性シリコーン組成物、接着剤、シリコーン硬化物
JP7742882B2 (ja) * 2021-01-08 2025-09-22 エルケム シリコンズ フランス ソシエテ パ アクシオンス シンプリフィエ 剥離制御添加剤を含む放射線硬化型シリコーン組成物
WO2022189757A1 (fr) * 2021-03-10 2022-09-15 Elkem Silicones France Sas Photoamorceur de type i pour la reticulation de compositions silicones
CN113173851B (zh) * 2021-04-13 2023-02-14 华南理工大学 一种uv交联单体及其制备方法与在制备含氟丙烯酸酯乳液中的应用
CN113651904B (zh) * 2021-08-12 2023-05-12 管和平 一种可光聚合单组分硫杂蒽酮类光引发剂

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Also Published As

Publication number Publication date
CA3009545A1 (fr) 2017-06-29
CA3009545C (fr) 2023-02-28
KR20180127962A (ko) 2018-11-30
JP2020111574A (ja) 2020-07-27
JP2022106747A (ja) 2022-07-20
CN109072001B (zh) 2021-09-28
US20190002695A1 (en) 2019-01-03
US20210147684A1 (en) 2021-05-20
EP3408340A1 (fr) 2018-12-05
BR112018012849A2 (pt) 2018-12-04
JP7496579B2 (ja) 2024-06-07
WO2017109116A1 (fr) 2017-06-29
JP6805256B2 (ja) 2020-12-23
BR112018012849B1 (pt) 2022-11-29
US10954384B2 (en) 2021-03-23
JP2019507205A (ja) 2019-03-14
KR102671096B1 (ko) 2024-05-30
US11603468B2 (en) 2023-03-14
CN109072001A (zh) 2018-12-21
FR3045641A1 (fr) 2017-06-23

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