EA013089B1 - Получение наноразмерных материалов - Google Patents
Получение наноразмерных материалов Download PDFInfo
- Publication number
- EA013089B1 EA013089B1 EA200801383A EA200801383A EA013089B1 EA 013089 B1 EA013089 B1 EA 013089B1 EA 200801383 A EA200801383 A EA 200801383A EA 200801383 A EA200801383 A EA 200801383A EA 013089 B1 EA013089 B1 EA 013089B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- liquids
- range
- mixing zone
- liquid
- mixing
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 53
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title description 8
- 238000000034 method Methods 0.000 claims abstract description 105
- 239000002245 particle Substances 0.000 claims abstract description 51
- 239000000725 suspension Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims description 157
- 238000002156 mixing Methods 0.000 claims description 137
- 239000000203 mixture Substances 0.000 claims description 66
- 239000002086 nanomaterial Substances 0.000 claims description 54
- 239000003153 chemical reaction reagent Substances 0.000 claims description 44
- 239000002243 precursor Substances 0.000 claims description 44
- 238000006243 chemical reaction Methods 0.000 claims description 42
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- 239000012530 fluid Substances 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 19
- 150000003839 salts Chemical class 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 238000009826 distribution Methods 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 8
- 150000004703 alkoxides Chemical class 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 6
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 230000009466 transformation Effects 0.000 claims description 4
- 230000033228 biological regulation Effects 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
- 125000005595 acetylacetonate group Chemical group 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 230000005284 excitation Effects 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 239000011234 nano-particulate material Substances 0.000 claims description 2
- 150000003891 oxalate salts Chemical class 0.000 claims description 2
- 238000001308 synthesis method Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical group Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 150000001247 metal acetylides Chemical class 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 24
- 239000011248 coating agent Substances 0.000 abstract description 17
- 239000000758 substrate Substances 0.000 abstract description 9
- 239000010409 thin film Substances 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 description 12
- 239000000376 reactant Substances 0.000 description 12
- 239000012071 phase Substances 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000010408 film Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- -1 electronic coatings Substances 0.000 description 8
- 229910044991 metal oxide Inorganic materials 0.000 description 8
- 150000004706 metal oxides Chemical class 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 230000008021 deposition Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 5
- 238000003980 solgel method Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000000634 powder X-ray diffraction Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000000235 small-angle X-ray scattering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002357 endometrial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229940046892 lead acetate Drugs 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- XPGAWFIWCWKDDL-UHFFFAOYSA-N propan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] XPGAWFIWCWKDDL-UHFFFAOYSA-N 0.000 description 1
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000002887 superconductor Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
- C01G1/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/006—Compounds containing zirconium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1216—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1254—Sol or sol-gel processing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1262—Process of deposition of the inorganic material involving particles, e.g. carbon nanotubes [CNT], flakes
- C23C18/1266—Particles formed in situ
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1283—Control of temperature, e.g. gradual temperature increase, modulation of temperature
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/14—Decomposition by irradiation, e.g. photolysis, particle radiation or by mixed irradiation sources
- C23C18/143—Radiation by light, e.g. photolysis or pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Ceramic Engineering (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200501755 | 2005-12-11 | ||
| PCT/DK2006/000706 WO2007065446A2 (en) | 2005-12-11 | 2006-12-11 | Production of nanosized materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200801383A1 EA200801383A1 (ru) | 2008-10-30 |
| EA013089B1 true EA013089B1 (ru) | 2010-02-26 |
Family
ID=37813931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200801383A EA013089B1 (ru) | 2005-12-11 | 2006-12-11 | Получение наноразмерных материалов |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7829598B2 (enExample) |
| EP (1) | EP1960098A2 (enExample) |
| JP (1) | JP2009518167A (enExample) |
| KR (1) | KR20080077680A (enExample) |
| CN (1) | CN101326001A (enExample) |
| AU (1) | AU2006322458A1 (enExample) |
| BR (1) | BRPI0619635A2 (enExample) |
| CA (1) | CA2633809A1 (enExample) |
| EA (1) | EA013089B1 (enExample) |
| WO (1) | WO2007065446A2 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2474010C2 (ru) * | 2010-03-09 | 2013-01-27 | Федеральное государственное бюджетное научное учреждение "Технологический институт сверхтвердых и новых углеродных материалов" (ФГБНУ ТИСНУМ) | Нанокомпозитный термоэлектрик и способ его получения |
| RU2494045C1 (ru) * | 2012-04-27 | 2013-09-27 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Способ получения диоксида титана |
| RU2633582C1 (ru) * | 2016-06-23 | 2017-10-13 | Общество с ограниченной ответственностью "Инновационные Технологии Синтеза" | Способ получения нанодисперсных оксидов металлов |
| RU2724243C1 (ru) * | 2020-02-03 | 2020-06-22 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт химии силикатов им. И.В. Гребенщикова Российской академии наук (ИХС РАН) | Способ получения фотокаталитически активного нанокристаллического диоксида титана в кристаллической модификации анатаз |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8048192B2 (en) * | 2005-12-30 | 2011-11-01 | General Electric Company | Method of manufacturing nanoparticles |
| HU230862B1 (hu) * | 2008-04-28 | 2018-10-29 | DARHOLDING Vagyonkezelő Kft | Berendezés és eljárás nanorészecskék folyamatos üzemű előállítására |
| US8008237B2 (en) * | 2008-06-18 | 2011-08-30 | Afton Chemical Corporation | Method for making a titanium-containing lubricant additive |
| FR2940766B1 (fr) * | 2009-01-06 | 2011-05-27 | Commissariat Energie Atomique | Procede de realisation d'un depot de nanoparticules a adherence augmentee et dispositif pour la mise en oeuvre d'un tel procede |
| US9067263B2 (en) * | 2009-01-15 | 2015-06-30 | Gr Intellectual Reserve, Llc | Continuous, semicontinuous and batch methods for treating liquids and manufacturing certain constituents (e.g., nanoparticles) in liquids, apparatuses and nanoparticles and nanoparticle/liquid solution(s) and colloids resulting therefrom |
| IT1393040B1 (it) * | 2009-03-02 | 2012-04-11 | Colorobbia Italiana Spa | Processo per la preparazione di sospensioni stabili di nanoparticelle metalliche e sospensioni colloidali stabili cosi' ottenute |
| KR101009583B1 (ko) * | 2009-03-10 | 2011-01-20 | 충남대학교산학협력단 | 전이금속산화물 나노입자의 제조방법 |
| ES2457546T3 (es) * | 2009-03-23 | 2014-04-28 | Välinge Photocatalytic Ab | Producción de suspensiones coloidales de nanopartículas de titania con cristalinidad mantenida usando un molino de perlas con perlas de tamaño micrométrico |
| CN101618308B (zh) * | 2009-06-09 | 2011-12-21 | 宋玉军 | 用于纳米颗粒制备的微流体反应器及颗粒的可控制备工艺 |
| JP5479790B2 (ja) * | 2009-07-06 | 2014-04-23 | 紀本電子工業株式会社 | 超臨界マイクロ波反応装置 |
| TWI398469B (zh) * | 2009-10-19 | 2013-06-11 | Ind Tech Res Inst | 一階段固定ＴｉＯ2奈米結晶粒於高分子基材的方法及其應用 |
| US8101680B1 (en) | 2010-10-12 | 2012-01-24 | Sabic Innovative Plastics Ip B.V. | Methods of preparing polymer nanocomposites |
| CN102173452B (zh) * | 2011-03-04 | 2012-12-26 | 北京工业大学 | 一种单一材料ZrO2纳米点、制备方法及应用 |
| KR101308020B1 (ko) | 2011-09-22 | 2013-09-12 | 한국과학기술연구원 | 코어-셀 구조의 복합 분말 및 그 제조 방법 |
| CN103917494B (zh) | 2011-10-26 | 2015-10-14 | 公立大学法人高知工科大学 | 球形多孔氧化钛纳米粒子的合成方法及由该合成方法制造的球形多孔氧化钛纳米粒子以及含有该球形多孔氧化钛纳米粒子的基因枪用载体 |
| JP6044756B2 (ja) * | 2012-05-25 | 2016-12-14 | 高知県公立大学法人 | 多孔質無機酸化物ナノ粒子の合成方法、並びに該合成方法により製造される多孔質無機酸化物ナノ粒子及び球状多孔質無機酸化物ナノ粒子 |
| US11065588B2 (en) | 2013-04-30 | 2021-07-20 | M. Technique Co., Ltd. | Fluid processing method |
| WO2015012715A1 (ru) * | 2013-07-26 | 2015-01-29 | Общество С Ограниченной Ответственностью "Плазма-Ск" | Способ и устройство наноструктурированного углеродного покрытия |
| KR101455040B1 (ko) * | 2014-07-29 | 2014-10-27 | (주)일신오토클레이브 | 초고압 균질기를 이용한 연속식 금속산화물 나노입자의 제조 장치 및 이를 이용한 제조 방법 |
| JP2018508440A (ja) * | 2014-12-23 | 2018-03-29 | エシロール アンテルナシオナル （コンパニー ジェネラル ドプティック） | 超臨界溶媒熱合成により表面変性金属酸化物ナノ粒子を製造するための連続フロー式プロセス |
| CA3026454C (en) | 2015-06-04 | 2023-07-04 | Crititech, Inc. | Collection device and methods for use |
| BR112018069628A2 (pt) | 2016-04-04 | 2019-02-12 | Crititech, Inc. | métodos para tratamento de tumor sólido |
| SG11201909840TA (en) | 2017-06-09 | 2019-11-28 | Crititech Inc | Treatment of epithelial cysts by intracystic injection of antineoplastic particles |
| KR102303762B1 (ko) | 2017-06-14 | 2021-09-23 | 크리티테크, 인크. | 폐 장애의 치료 방법 |
| WO2019070850A1 (en) | 2017-10-03 | 2019-04-11 | Crititech, Inc. | LOCAL ADMINISTRATION OF ANINEOPLASTIC PARTICLES IN COMBINATION WITH SYSTEMIC DELIVERY OF IMMUNOTHERAPEUTIC AGENTS FOR THE TREATMENT OF CANCER |
| CN108149229B (zh) * | 2017-12-29 | 2020-04-10 | 南京理工大学 | 一种用于纳米薄膜沉积的液相基板火焰合成装置和方法 |
| JP2023061896A (ja) * | 2021-10-20 | 2023-05-02 | 財團法人工業技術研究院 | コアシェル型量子ドットの調製装置および調製方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5433878A (en) * | 1993-04-19 | 1995-07-18 | Nissan Chemical Industries Ltd. | Method for producing fine particles of barium ferrite |
| EP0783921A2 (en) * | 1996-01-10 | 1997-07-16 | Nakamichi Yamasaki | Method of and apparatus for performing continuous hydrothermal synthesis |
| WO2003048403A1 (fr) * | 2001-12-04 | 2003-06-12 | Centre De Recherches Metallurgiques Asbl - Centrum Voor Research In De Metallurgie Vzw | Procede de revetement de surface metallique |
| US20040228967A1 (en) * | 2002-07-03 | 2004-11-18 | Roger Leung | Dielectric films for narrow gap-fill applications |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US203207A (en) | 1878-04-30 | Improvement in seed-drill teeth | ||
| US4338199A (en) * | 1980-05-08 | 1982-07-06 | Modar, Inc. | Processing methods for the oxidation of organics in supercritical water |
| JP3047110B2 (ja) * | 1990-06-15 | 2000-05-29 | 株式会社東北テクノアーチ | 金属酸化物微粒子の製造方法 |
| JP3483282B2 (ja) * | 1993-11-12 | 2004-01-06 | 高周波熱錬株式会社 | 超微粒子二酸化酸化チタン複合化酸化物の製造方法 |
| JP4102872B2 (ja) * | 2002-03-08 | 2008-06-18 | 独立行政法人産業技術総合研究所 | 高結晶性チタン酸バリウム超微粒子とその製造方法 |
| KR100460102B1 (ko) * | 2002-07-15 | 2004-12-03 | 한화석유화학 주식회사 | 금속산화물 초미립자의 제조방법 |
| GB0402963D0 (en) * | 2004-02-11 | 2004-03-17 | Univ Nottingham | Counter current mixing device for two different fluids |
| DE102004030104A1 (de) | 2004-06-22 | 2006-01-12 | Degussa Ag | Wässerig/organische Metalloxid-Dispersion und mit damit hergestellte beschichtete Substrate und Formkörper |
| EP1809793A2 (en) | 2004-09-27 | 2007-07-25 | Auburn University | Selection and deposition of nanoparticles using co2-expanded liquids |
-
2006
- 2006-12-11 US US12/096,897 patent/US7829598B2/en not_active Expired - Fee Related
- 2006-12-11 WO PCT/DK2006/000706 patent/WO2007065446A2/en not_active Ceased
- 2006-12-11 KR KR1020087016996A patent/KR20080077680A/ko not_active Ceased
- 2006-12-11 AU AU2006322458A patent/AU2006322458A1/en not_active Abandoned
- 2006-12-11 EA EA200801383A patent/EA013089B1/ru not_active IP Right Cessation
- 2006-12-11 CA CA002633809A patent/CA2633809A1/en not_active Abandoned
- 2006-12-11 CN CNA2006800465591A patent/CN101326001A/zh active Pending
- 2006-12-11 EP EP06818165A patent/EP1960098A2/en not_active Withdrawn
- 2006-12-11 BR BRPI0619635-7A patent/BRPI0619635A2/pt not_active IP Right Cessation
- 2006-12-11 JP JP2008543663A patent/JP2009518167A/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5433878A (en) * | 1993-04-19 | 1995-07-18 | Nissan Chemical Industries Ltd. | Method for producing fine particles of barium ferrite |
| EP0783921A2 (en) * | 1996-01-10 | 1997-07-16 | Nakamichi Yamasaki | Method of and apparatus for performing continuous hydrothermal synthesis |
| WO2003048403A1 (fr) * | 2001-12-04 | 2003-06-12 | Centre De Recherches Metallurgiques Asbl - Centrum Voor Research In De Metallurgie Vzw | Procede de revetement de surface metallique |
| US20040228967A1 (en) * | 2002-07-03 | 2004-11-18 | Roger Leung | Dielectric films for narrow gap-fill applications |
Non-Patent Citations (6)
| Title |
|---|
| HERTZ ET AL.: "Synthesis and encapsulation of yttria stabilized zirconia particles in supercritical carbon dioxide", JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, ELSEVIER SCIENCE PUBLISHERS, BARKING, ESSEX, GB, no. 7, 23 February 2005 (2005-02-23), pages 1195-1203, XP005277373, ISSN: 0955-2219, the whole document * |
| J.F. BOCQUET, K. CHHOR, C. POMMIER: "A new TiO2 film deposition process in a supercritical fluid", * |
| J.I. BRAND, D.R. MILLER: "Ceramic Beams and thin film growth", THIN SOLID FILMS, vol. 166, 1988, pages 139-148, XP002436562, abstract, paragraphs [0001] - [0003] * |
| SURFACE AND COATINGS TECHNOLOGY, vol. 70, 1994, pages 73-78, XP002436561, bstract, paragraphs [0001], [0002], [0005]; table 1 * |
| T. ADSCHIRI, Y. HAKUTA AND K. ARAI: "Hydrothermal synthesis of metal oxide fine particles at supercritical conditions", IND. ENG. CHEM. RES., vol. 39, 2000, pages 4901-4907, XP002424714, abstract, page 4901 - page 4906; figures 3-6, 8, 9, 14; table 2 * |
| W. YU, W. TU AND H. LIU: "Synthesis of nanoscale platinum colloids by microwave dielectric heating", LANGMUIR, vol. 15, 1999, pages 6-9, XP002424715, the whole document * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2474010C2 (ru) * | 2010-03-09 | 2013-01-27 | Федеральное государственное бюджетное научное учреждение "Технологический институт сверхтвердых и новых углеродных материалов" (ФГБНУ ТИСНУМ) | Нанокомпозитный термоэлектрик и способ его получения |
| RU2494045C1 (ru) * | 2012-04-27 | 2013-09-27 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Способ получения диоксида титана |
| RU2633582C1 (ru) * | 2016-06-23 | 2017-10-13 | Общество с ограниченной ответственностью "Инновационные Технологии Синтеза" | Способ получения нанодисперсных оксидов металлов |
| RU2724243C1 (ru) * | 2020-02-03 | 2020-06-22 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт химии силикатов им. И.В. Гребенщикова Российской академии наук (ИХС РАН) | Способ получения фотокаталитически активного нанокристаллического диоксида титана в кристаллической модификации анатаз |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0619635A2 (pt) | 2011-10-04 |
| US7829598B2 (en) | 2010-11-09 |
| KR20080077680A (ko) | 2008-08-25 |
| CA2633809A1 (en) | 2007-06-14 |
| AU2006322458A1 (en) | 2007-06-14 |
| WO2007065446A2 (en) | 2007-06-14 |
| CN101326001A (zh) | 2008-12-17 |
| WO2007065446A3 (en) | 2007-09-13 |
| EP1960098A2 (en) | 2008-08-27 |
| US20090004099A1 (en) | 2009-01-01 |
| EA200801383A1 (ru) | 2008-10-30 |
| JP2009518167A (ja) | 2009-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EA013089B1 (ru) | Получение наноразмерных материалов | |
| Pach et al. | Nucleation of alpha alumina in boehmite gel | |
| KR100514107B1 (ko) | 마이크로파를 이용한 나노크기 지르코니아 수화물 졸의연속 제조방법 | |
| JP2003225900A (ja) | ナノ粒子製造方法 | |
| Proskurina et al. | Role of hydroxide precipitation conditions in the formation of nanocrystalline BiFeO3 | |
| KR100544628B1 (ko) | 지르코니아 수화물 나노입자 졸의 연속 제조방법 | |
| Qin et al. | Size-controlled synthesis of spherical ZrO2 nanoparticles by reverse micelles-mediated sol-gel process | |
| Rezaei et al. | Investigation of the parameters affecting the morphology of zinc oxide (ZnO) nanoparticles synthesized by precipitation method | |
| US20070151418A1 (en) | Method of manufacturing nanoparticles | |
| Matijević | Preparation and characterization of well defined powders and their applications in technology | |
| Tripathi | Hydrothermal method for synthesis of materials | |
| Li et al. | High-Throughput Synthesis of Superparamagnetic Fe3O4 Nanoparticles in Chaotic Convection Mode | |
| KR100753773B1 (ko) | 페로브스카이트 구조를 갖는 산화물 나노 분말 제조 방법 | |
| CN109809482B (zh) | 一种单分散、多形貌氧化锆粉体的制备方法 | |
| Liu et al. | Heat-induced fast hydrolysis to produce rutile TiO2 nanoparticles in a capillary microreactor | |
| Chen et al. | Fabrication of monodisperse zirconia-coated core–shell and hollow spheres in mixed solvents | |
| Rives | From Solid‐State Chemistry to Soft Chemistry Routes | |
| Ohya | Aqueous precursors | |
| Chen et al. | Preparation of monodispersed spherical barium titanate particles | |
| Stoller et al. | Production of nanoparticles of titanium dioxide by using a spinning disc reactor | |
| KR100417694B1 (ko) | 단분산 구상 바륨티타네이트 미립자의 제조방법 | |
| KR101277294B1 (ko) | 탄산세륨의 제조 방법 | |
| Zhu et al. | Synthesis of full spectrum responsive photocatalysts | |
| CN107352582A (zh) | 一种PrVO4纳米纤维光催化剂及其制备方法 | |
| CN107601538A (zh) | 一种低温制备氧化铝超细球形粉体的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM RU |