DK2954588T3 - Elektrolyt til en elektrokemisk battericelle indeholdende samme - Google Patents

Elektrolyt til en elektrokemisk battericelle indeholdende samme Download PDF

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Publication number
DK2954588T3
DK2954588T3 DK13704715.5T DK13704715T DK2954588T3 DK 2954588 T3 DK2954588 T3 DK 2954588T3 DK 13704715 T DK13704715 T DK 13704715T DK 2954588 T3 DK2954588 T3 DK 2954588T3
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Denmark
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electrolyte
mol
maximum
metal
per liter
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DK13704715.5T
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English (en)
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Laurent Zinck
Christian Pszolla
Claus Dambach
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Alevo Int S A
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/002—Inorganic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Claims (15)

1. Elektrolyt til en elektrokemisk battericelle, indeholdende svovldioxid og et ledende salt, kendetegnet ved, at den molære koncentration af hydroxidgrupper i elektrolytten maksimalt er 50 mmol pr. liter, og at den molære koncentration af chlorsulfonatgrupper i elektrolytten maksimalt er 350 mmol pr. liter.
2. Elektrolyt ifølge krav 1, kendetegnet ved, at den molære koncentration af hydroxidgrupper i elektrolytten maksimalt er 45 mmol pr. liter, fortrinsvis 25 mmol pr. liter, yderligere foretrukket er 15 mmol pr. liter, og særligt foretrukket maksimalt 5 mmol pr. liter.
3. Elektrolyt ifølge krav 1, kendetegnet ved, at den molære koncentration af chlorsulfonatgrupper i elektrolytten maksimalt er 250 mmol pr. liter, fortrinsvis maksimalt 200 mmol pr. liter, og særligt foretrukket maksimalt 100 mmol pr. liter.
4. Elektrolyt ifølge et af de foregående krav, kendetegnet ved at elektrolytten indeholder mindst 1 Mol SO2, fortrinsvis mindst 2 Mol SO2, yderligere foretrukket mindst 3 Mol S02, endnu yderligere foretrukket mindst 4 Mol S02, og særligt foretrukket mindst 6 Mol S02, pr. Mol ledende salt.
5. Elektrolyt ifølge et af de foregående krav, kendetegnet ved, at det ledende salt er en Lewis-syre/Lewis-base-adduktforbindelse, og at elektrolytten indeholder fri Lewis-base.
6. Elektrolyt ifølge et af de foregående krav, kendetegnet ved, at det ledende salt er et aluminat, halogenid, oxalat, borat, phosphat, arsenat eller gallat af et alkalimetal, især af lithium, fortrinsvis af lithiumtetrahalogenoaluminat, særligt foretrukket lithiumtetrachloroaluminat.
7. Elektrolyt ifølge et af de foregående krav, kendetegnet ved, at den i forhold til stofmængden af alle i elektrolytten opløste salte indeholder maksimalt 30 mol%, fortrinsvis maksimalt 20 mol%, yderligere foretrukket maksimalt 10 mol%, og særligt foretrukket maksimalt 1 mol% opløst salt med en fra det aktive metals kation forskellig kation.
8. Elektrokemisk battericelle indeholdende en elektrolyt ifølge et af de foregående krav, en positiv elektrode og en negativ elektrode.
9. Battericelle ifølge krav 8, kendetegnet ved, at det aktive metal er et alkalimetal, et jordalkalimetal eller et metal fra gruppe 12 i det periodiske system, eller aluminium eller fortrinsvis lithium, natrium, calcium eller zink.
10. Battericelle ifølge krav 8 eller 9, kendetegnet ved, at den negative elektrode er en indføringselektrode og fortrinsvis indeholder kulstof.
11. Battericelle ifølge et af de foregående krav, kendetegnet ved, at den positive elektrode indeholder en metalforbindelse, fortrinsvis et metaloxid eller et metalhalogenid eller et metalphosphat, og at metallet fortrinsvis er et overgangsmetal med ordenstallene 22 til 28, især kobolt, nikkel, mangan eller jern, og at den positive elektrode fortrinsvis indeholder en interkalationsforbindelse, som fortrinsvis indeholder lithiumjernphosphat.
12. Fremgangsmåde til fremstilling af en elektrolyt ifølge et af kravene 1 til 8, hvor en Lewis-syre, en Lewis-base og aluminium blandes, og at blandingen i en periode på mindst 6 timer opvarmes til en temperatur over en mindstetemperatur, som er mindst 200° C og ligger over blandingens smeltepunkt, og at der dannes en addukt-forbindelse af Lewis-syre og Lewis-base.
13. Fremgangsmåde ifølge krav 12, kendetegnet ved, at mindstetemperaturen er 250° C, fortrinsvis 300° C, yderligere foretrukket 350° C, yderligere foretrukket 400° C, yderligere foretrukket 450° C og endnu yderligere foretrukket 500° C.
14. Fremgangsmåde ifølge et af kravene 12 eller 13, kendetegnet ved, at den mindste varighed er 12 timer, fortrinsvis 18 timer, yderligere foretrukket 24 timer, yderligere foretrukket 48 timer og særligt foretrukket 72 timer.
15. Fremgangsmåde ifølge et af kravene 12 til 14, kendetegnet ved, at blandingen for hvert mol Lewis-syre indeholder mindst 40 mmol, fortrinsvis mindst 200 mmol og særligt foretrukket 400 mmol aluminium.
DK13704715.5T 2013-02-07 2013-02-07 Elektrolyt til en elektrokemisk battericelle indeholdende samme DK2954588T3 (da)

Applications Claiming Priority (1)

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PCT/EP2013/000366 WO2014121803A1 (de) 2013-02-07 2013-02-07 Elektrolyt für eine elektrochemische batteriezelle und den elektrolyten enthaltende batteriezelle

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US (2) US9023538B2 (da)
EP (1) EP2954588B1 (da)
JP (1) JP6381553B2 (da)
KR (1) KR101947370B1 (da)
CN (1) CN104969404B (da)
AU (2) AU2013377470A1 (da)
BR (1) BR112015018315B1 (da)
CA (1) CA2898245C (da)
DK (1) DK2954588T3 (da)
EC (1) ECSP15033398A (da)
ES (1) ES2625775T3 (da)
HK (1) HK1215760A1 (da)
IL (1) IL239696A0 (da)
MX (1) MX365048B (da)
PL (1) PL2954588T3 (da)
RU (1) RU2629556C2 (da)
SG (1) SG11201506223WA (da)
WO (1) WO2014121803A1 (da)

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ES2625775T3 (es) 2017-07-20
EP2954588A1 (de) 2015-12-16
ECSP15033398A (es) 2016-01-29
EP2954588B1 (de) 2017-04-12
JP6381553B2 (ja) 2018-08-29
WO2014121803A1 (de) 2014-08-14
KR20150115788A (ko) 2015-10-14
CA2898245A1 (en) 2014-08-14
SG11201506223WA (en) 2015-09-29
RU2629556C2 (ru) 2017-08-30
CA2898245C (en) 2020-09-22
BR112015018315A2 (pt) 2017-07-18
KR101947370B1 (ko) 2019-02-13
US9515349B2 (en) 2016-12-06
JP2016511922A (ja) 2016-04-21
AU2018253519B2 (en) 2019-12-05
BR112015018315B1 (pt) 2021-07-06
HK1215760A1 (zh) 2016-09-09
AU2013377470A1 (en) 2015-07-16
PL2954588T3 (pl) 2017-07-31
US9023538B2 (en) 2015-05-05
US20150207172A1 (en) 2015-07-23
AU2018253519A1 (en) 2018-11-15
CN104969404A (zh) 2015-10-07
MX2015009865A (es) 2015-10-05
RU2015137755A (ru) 2017-03-14
CN104969404B (zh) 2019-06-14
US20140220428A1 (en) 2014-08-07
MX365048B (es) 2019-05-16
IL239696A0 (en) 2015-08-31

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