DK2582694T3 - Fremgangsmåde til fremstilling af tetrazol-substituerede anthranilsyrediamidderivater og ny krystallinsk modifikation af disse derivater - Google Patents
Fremgangsmåde til fremstilling af tetrazol-substituerede anthranilsyrediamidderivater og ny krystallinsk modifikation af disse derivater Download PDFInfo
- Publication number
- DK2582694T3 DK2582694T3 DK11726391.3T DK11726391T DK2582694T3 DK 2582694 T3 DK2582694 T3 DK 2582694T3 DK 11726391 T DK11726391 T DK 11726391T DK 2582694 T3 DK2582694 T3 DK 2582694T3
- Authority
- DK
- Denmark
- Prior art keywords
- formula
- crystalline modification
- compound
- stands
- methyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pharmacology & Pharmacy (AREA)
- Tropical Medicine & Parasitology (AREA)
- Public Health (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Medicinal Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Catching Or Destruction (AREA)
Claims (7)
1. Fremgangsmåde til fremstilling af den krystallinske modifikation B af forbindelsen med formel (I—1)
kendetegnet ved, at man omsætter N-aryl og N-hetarylsubstituerede pyrazoler med formel (II)
hvor R står for (Ci-C6) alkyl, aryl (Ci-C6) -alkyl eller aryl, R2 står for chlor, Z står for N, og X står for fluor, chlor, brom, rod, CH3SO2O, CF3SO3 eller p-CH3-C6H4SO3, med tetrazoler med formel (III)
til pvrazolcarboxvlsvreestere med formel (IV)
hvor R, R2, Z har de ovenfor anførte betegnelser, og R5 står for CF3, og omsætter disse i givet fald uden forudgående isolering til pyrazolcarboxylsyrer med formel (V)
hvor R2, R5 og Z har de ovenfor anførte betegnelser, og omsætter disse med forbindelser med den almene formel (VI)
hvor R1, R3 står for methyl, og R4 står for cyano.
2. Krystallinsk modifikation B af forbindelsen med formel (1-1)
kendetegnet ved, at den røntgen-pulverdiffraktogram ved anvendelse af Cu Κα-stråling har i det mindste følgende reflekspositioner:
3. Krystallinsk modifikation B ifølge krav 2, kendetegnet ved, at dens røntgen-pulverdiffraktogram ved anvendelse af Cu Ka-stråling har i det mindste følgende yderligere reflekspositioner:
4. Krystallinsk modifikation B af forbindelsen med formel (I — 1) ifølge et eller flere af kravene 2 til 3, kendetegnet ved, at dens
Raman-spektrum har i det mindste følgende bander:
5. Agrokemisk sammensætning omfattende forbindelsen med formel (I — 1) af den krystallinske modifikation B ifølge et eller flere af kravene 2 til 4.
6. Anvendelse af forbindelsen med formel (1-1) af den krystallinske modifikation B ifølge et eller flere af kravene 2 til 4 til fremstilling af insekticidt effektive sammensætninger.
7. Fremgangsmåde til bekæmpelse af uønskede insekter undtagen til terapeutisk behandling af det animalske eller menneskelige legeme, kendetegnet ved, at en agrokemisk sammensætning omfattende forbindelsen med formel (I — 1) af den krystallinske modifikation B ifølge et eller flere af kravene 2 til 4 udbringes til insekterne og/eller deres levesteder og/eller såsæd.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35492010P | 2010-06-15 | 2010-06-15 | |
| EP10166059 | 2010-06-15 | ||
| PCT/EP2011/059735 WO2011157664A1 (de) | 2010-06-15 | 2011-06-10 | Verfahren zur herstellung von tetrazol-substituierten anthranilsäurediamid-derivaten und neue kristalline modifikation dieser derivate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2582694T3 true DK2582694T3 (da) | 2015-10-26 |
Family
ID=42989671
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK15171321.1T DK2955176T3 (da) | 2010-06-15 | 2011-06-10 | Sammensætning indeholdende krystallinsk modifikation B af (3-chloropyridin-2-yl)-N-[4-cyano-2-methyl-6-(methylcarbamoyl)phenyl]-3-([5-(trifluormethyl)-2H-tetrazol-2-yl]methyl)-1H-pyrazol-5-carboxamid og anvendelse heraf |
| DK11726391.3T DK2582694T3 (da) | 2010-06-15 | 2011-06-10 | Fremgangsmåde til fremstilling af tetrazol-substituerede anthranilsyrediamidderivater og ny krystallinsk modifikation af disse derivater |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK15171321.1T DK2955176T3 (da) | 2010-06-15 | 2011-06-10 | Sammensætning indeholdende krystallinsk modifikation B af (3-chloropyridin-2-yl)-N-[4-cyano-2-methyl-6-(methylcarbamoyl)phenyl]-3-([5-(trifluormethyl)-2H-tetrazol-2-yl]methyl)-1H-pyrazol-5-carboxamid og anvendelse heraf |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US8969572B2 (da) |
| EP (2) | EP2582694B1 (da) |
| JP (3) | JP6199739B2 (da) |
| KR (1) | KR101790305B1 (da) |
| CN (1) | CN103261187B (da) |
| BR (1) | BR112012032244A2 (da) |
| DK (2) | DK2955176T3 (da) |
| ES (2) | ES2547314T3 (da) |
| HR (1) | HRP20151088T1 (da) |
| HU (1) | HUE027943T2 (da) |
| MX (2) | MX347841B (da) |
| PL (1) | PL2582694T3 (da) |
| PT (1) | PT2582694E (da) |
| RS (1) | RS54277B1 (da) |
| SI (1) | SI2582694T1 (da) |
| TW (1) | TWI511668B (da) |
| WO (1) | WO2011157664A1 (da) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RS54277B1 (en) * | 2010-06-15 | 2016-02-29 | Bayer Intellectual Property Gmbh | PROCEDURE FOR THE PRODUCTION OF TETRAZOLOM SUBSTITUTED ANTHRANILIC ACID DIAMID DERIVATIVES AND THE NEW CRYSTAL MODIFICATION OF THESE DERIVATIVES |
| CA2802787C (en) * | 2010-06-18 | 2020-02-25 | Bayer Intellectual Property Gmbh | Active substance combinations with insecticide and acaricide properties |
| UA111593C2 (uk) * | 2010-07-07 | 2016-05-25 | Баєр Інтеллекчуел Проперті Гмбх | Аміди антранілової кислоти у комбінації з фунгіцидами |
| WO2012004208A1 (de) * | 2010-07-09 | 2012-01-12 | Bayer Cropscience Ag | Anthranilsäurediamid-derivate als pestizide |
| EP2812310A1 (de) * | 2012-02-07 | 2014-12-17 | Bayer Intellectual Property GmbH | Verfahren zur herstellung von substituierten anthranilsäure-derivaten |
| EP2649879A1 (en) | 2012-04-10 | 2013-10-16 | Basf Se | Pesticidal mixtures containing fluxapyroxad |
| WO2013156331A1 (en) | 2012-04-16 | 2013-10-24 | Basf Se | Synergistic compositions comprising pyraclostrobin and an insecticidal compound |
| KR102191469B1 (ko) * | 2013-02-06 | 2020-12-16 | 바이엘 애니멀 헬스 게엠베하 | 해충 방제제로서의 할로겐-치환된 피라졸 유도체 |
| EP3416489A1 (en) | 2016-02-19 | 2018-12-26 | Basf Se | Pesticidally active mixtures comprising anthranilamide compounds |
| TWI679197B (zh) * | 2016-05-05 | 2019-12-11 | 瑞士商伊蘭科動物健康公司 | 雜芳基-1,2,4-三唑及雜芳基-三唑化合物 |
| WO2019123195A1 (en) | 2017-12-20 | 2019-06-27 | Pi Industries Ltd. | Pyrazolopyridine-diamides, their use as insecticide and processes for preparing the same. |
| WO2019123194A1 (en) | 2017-12-20 | 2019-06-27 | Pi Industries Ltd. | Anthranilamides, their use as insecticide and processes for preparing the same. |
| KR20200131226A (ko) | 2018-01-30 | 2020-11-23 | 피아이 인더스트리스 엘티디. | 새로운 안트라닐아미드, 살충제로서 그의 용도 및 그의 제조 방법 |
| KR20210011918A (ko) * | 2018-05-21 | 2021-02-02 | 피아이 인더스트리스 엘티디. | 안트라닐산 디아미드의 새로운 제조 방법 |
| WO2020016841A1 (en) | 2018-07-20 | 2020-01-23 | Pi Industries Ltd. | A novel process for the preparation of anthranilic diamides |
| CN113692406A (zh) | 2019-02-18 | 2021-11-23 | Pi工业有限公司 | 制备邻甲酰胺基苯甲酰胺类化合物及其中间体的方法 |
| MX2021010098A (es) | 2019-02-22 | 2021-09-28 | Pi Industries Ltd | Un proceso para la sintesis de compuestos de diamida antranilica y compuestos intermedios de los mismos. |
| EP3964506A1 (de) | 2020-09-04 | 2022-03-09 | Bayer Aktiengesellschaft | Verfahren zur herstellung eines tetrazol-substituierten anthranilsäurediamid-derivates |
| CA3191827A1 (en) | 2020-09-17 | 2022-03-24 | Tridib MAHAPATRA | A process for the synthesis of anthranilic acid/amide compounds and intermediates thereof |
| AR123593A1 (es) | 2020-09-26 | 2022-12-21 | Pi Industries Ltd | Un proceso para la síntesis de compuestos antranílicos de ácido / amida e intermedios de los mismos |
| WO2023006634A1 (en) | 2021-07-27 | 2023-02-02 | Syngenta Crop Protection Ag | Method for controlling diamide resistant pests & compounds therefor |
| WO2023012081A1 (en) | 2021-08-05 | 2023-02-09 | Syngenta Crop Protection Ag | Method for controlling diamide resistant pests & compounds therefor |
| WO2023021020A1 (en) | 2021-08-19 | 2023-02-23 | Syngenta Crop Protection Ag | Method for controlling diamide resistant pests & compounds therefor |
| WO2023110710A1 (en) | 2021-12-13 | 2023-06-22 | Syngenta Crop Protection Ag | Method for controlling diamide resistant pests & compounds therefor |
| EP4197333A1 (en) | 2021-12-15 | 2023-06-21 | Syngenta Crop Protection AG | Method for controlling diamide resistant pests & compounds therefor |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR043048A1 (es) | 2002-08-30 | 2005-07-13 | Syngenta Participations Ag | Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidas |
| CA2536253A1 (en) * | 2003-08-20 | 2005-03-03 | Vertex Pharmaceuticals Incorporated | Aminofurazan compounds useful as protein kinase inhibitors |
| BRPI0515221A (pt) | 2004-08-17 | 2008-07-15 | Du Pont | composto, composição para controlar uma peste invertebrada, composições spray e de isca, dispositivo de armadilha, métodos para controlar uma peste invertebrada e métodos de controle |
| BRPI0712923A2 (pt) * | 2006-06-13 | 2012-10-02 | Bayer Cropscience Ag | derivados de diamida de ácido antranìlico com substituintes heteroaromáticos e heterocìclicos |
| DE102006032168A1 (de) * | 2006-06-13 | 2007-12-20 | Bayer Cropscience Ag | Anthranilsäurediamid-Derivate mit heteroaromatischen Substituenten |
| ES2544490T3 (es) | 2008-12-18 | 2015-08-31 | Bayer Intellectual Property Gmbh | Amidas del ácido antranílico sustituidas con tetrazol como pesticidas |
| RS54277B1 (en) * | 2010-06-15 | 2016-02-29 | Bayer Intellectual Property Gmbh | PROCEDURE FOR THE PRODUCTION OF TETRAZOLOM SUBSTITUTED ANTHRANILIC ACID DIAMID DERIVATIVES AND THE NEW CRYSTAL MODIFICATION OF THESE DERIVATIVES |
-
2011
- 2011-06-10 RS RS20150651A patent/RS54277B1/en unknown
- 2011-06-10 KR KR1020137000731A patent/KR101790305B1/ko active IP Right Grant
- 2011-06-10 HU HUE11726391A patent/HUE027943T2/en unknown
- 2011-06-10 EP EP11726391.3A patent/EP2582694B1/de active Active
- 2011-06-10 WO PCT/EP2011/059735 patent/WO2011157664A1/de active Application Filing
- 2011-06-10 MX MX2015009721A patent/MX347841B/es unknown
- 2011-06-10 PT PT117263913T patent/PT2582694E/pt unknown
- 2011-06-10 MX MX2012014775A patent/MX2012014775A/es active IP Right Grant
- 2011-06-10 BR BR112012032244A patent/BR112012032244A2/pt not_active Application Discontinuation
- 2011-06-10 ES ES11726391.3T patent/ES2547314T3/es active Active
- 2011-06-10 PL PL11726391T patent/PL2582694T3/pl unknown
- 2011-06-10 ES ES15171321.1T patent/ES2660305T3/es active Active
- 2011-06-10 DK DK15171321.1T patent/DK2955176T3/da active
- 2011-06-10 CN CN201180039525.0A patent/CN103261187B/zh active Active
- 2011-06-10 EP EP15171321.1A patent/EP2955176B1/de active Active
- 2011-06-10 DK DK11726391.3T patent/DK2582694T3/da active
- 2011-06-10 SI SI201130627T patent/SI2582694T1/sl unknown
- 2011-06-10 JP JP2013514665A patent/JP6199739B2/ja active Active
- 2011-06-14 TW TW100120623A patent/TWI511668B/zh active
- 2011-06-14 US US13/159,961 patent/US8969572B2/en active Active
-
2014
- 2014-09-22 US US14/492,264 patent/US9056861B2/en active Active
-
2015
- 2015-10-15 HR HRP20151088TT patent/HRP20151088T1/hr unknown
- 2015-11-11 JP JP2015221282A patent/JP6170118B2/ja active Active
-
2016
- 2016-07-20 JP JP2016142220A patent/JP6254646B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MX2012014775A (es) | 2013-01-29 |
| KR101790305B1 (ko) | 2017-10-25 |
| HUE027943T2 (en) | 2016-11-28 |
| US9056861B2 (en) | 2015-06-16 |
| JP2016065076A (ja) | 2016-04-28 |
| DK2955176T3 (da) | 2018-03-12 |
| JP6254646B2 (ja) | 2017-12-27 |
| HRP20151088T1 (hr) | 2015-11-20 |
| EP2582694B1 (de) | 2015-07-22 |
| EP2582694A1 (de) | 2013-04-24 |
| MX347841B (es) | 2017-05-16 |
| WO2011157664A1 (de) | 2011-12-22 |
| US20120101133A1 (en) | 2012-04-26 |
| JP2013530175A (ja) | 2013-07-25 |
| CN103261187B (zh) | 2016-08-03 |
| PL2582694T3 (pl) | 2015-12-31 |
| RS54277B1 (en) | 2016-02-29 |
| SI2582694T1 (sl) | 2015-11-30 |
| EP2955176A1 (de) | 2015-12-16 |
| BR112012032244A2 (pt) | 2016-09-27 |
| EP2955176B1 (de) | 2017-12-06 |
| US20150025116A1 (en) | 2015-01-22 |
| JP2017008062A (ja) | 2017-01-12 |
| ES2547314T3 (es) | 2015-10-05 |
| KR20130112860A (ko) | 2013-10-14 |
| CN103261187A (zh) | 2013-08-21 |
| JP6199739B2 (ja) | 2017-09-20 |
| TWI511668B (zh) | 2015-12-11 |
| PT2582694E (pt) | 2015-10-15 |
| ES2660305T3 (es) | 2018-03-21 |
| TW201212820A (en) | 2012-04-01 |
| US8969572B2 (en) | 2015-03-03 |
| JP6170118B2 (ja) | 2017-07-26 |
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