DK2576052T3 - Hydrobehandlingskatalysatorer og deres fremstilling - Google Patents

Hydrobehandlingskatalysatorer og deres fremstilling Download PDF

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DK2576052T3
DK2576052T3 DK11727014.0T DK11727014T DK2576052T3 DK 2576052 T3 DK2576052 T3 DK 2576052T3 DK 11727014 T DK11727014 T DK 11727014T DK 2576052 T3 DK2576052 T3 DK 2576052T3
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catalyst
carbon atoms
organic compound
catalyst precursor
precursor composition
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DK11727014.0T
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Stuart L Soled
Sabato Miseo
Joseph E Baumgartner
Iulian G Nistor
Pallassana S Venkataraman
Chris E Kliewer
Robert J Chimenti
Javier Guzman
Gordon Kennedy
Doron Levin
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Exxonmobil Res & Eng Co
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Claims (12)

1. Bulk-katalysatorprecursorsammensætning, der omfatter mindst ét metal fra gruppe 6 i grundstoffernes periodiske system, mindst ét metal fra gruppe 8-10 i grundstoffernes periodiske system og et reaktionsprodukt, der er frembragt af (i) en første organisk forbindelse, der indeholder mindst én amingruppe, og (ii) en anden organisk forbindelse, der er adskilte fra den første organiske forbindelse og indeholder mindst én carboxylsyregruppe, hvilket reaktionsprodukt omfatter både et amid og yderligere in situ umættede carbonatomer, der ikke er til stede i den første eller anden organiske forbindelse, hvor katalysatorprecursoren omfatter 20 vægt- % eller mindre bæremateriale eller et andet støttemateriale, og hvor reaktionsproduktet opnås ved opvarmning af den første og anden organiske forbindelse til en temperatur fra 195 °C til 250 °C i et tidsrum, der er tilstrækkeligt til, at den første og anden organiske forbindelse kan danne et amid og en yderligere umættethed in situ.
2. Katalysatorprecursorsammensætning ifølge krav 1, hvor det mindst ene metal fra gruppe 6 er Mo, W eller en kombination deraf, og hvor det mindst ene metal fra gruppe 8-10 er Co, Ni eller en kombination deraf, fortrinsvis hvor katalysatorprecursorsammensætningen yderligere omfatter mindst ét metal fra gruppe 5 i grundstoffernes periodiske system, mere fortrinsvis V, Nb eller en kombination deraf.
3. Katalysatorprecursorsammensætning ifølge krav 1 eller 2, hvor den første organiske forbindelse omfatter mindst 10 carbonatomer, fortrinsvis omfatter en primær monoamin, der har fra 10 til 30 carbonatomer, og/eller hvor den anden organiske forbindelse omfatter mindst 10 carbonatomer, fortrinsvis omfatter kun én carboxylsyregruppe og har fra 10 til 30 carbonatomer.
4. Katalysatorprecursorsammensætning ifølge et hvilket som helst af kravene 1 til 3, der i det væsentlige består af reaktionsproduktet, en oxidform af det mindst ene metal fra gruppe 6, en oxidform af det mindst ene metal fra gruppe 8-10 og eventuelt 20 vægt- % eller mindre af et bindemiddel.
5. Katalysatorprecursorsammensætning ifølge et hvilket som helst af kravene 1 til 3, hvor et eller flere af følgende er opfyldt: katalysatorprecursorsammensætningen fremviser et indhold af umættede carbonatomer, der indbefatter aromatiske carbonatomer, målt ved toparealsammenligninger ved anvendelse af 13C-NMR-teknikker på mindst 29 %; katalysatorprecursorsammensætningen fremviser et indhold af umættede carbonatomer, der indbefatter aromatiske carbonatomer, målt ved toparealsammenligninger ved anvendelse af 13C-NMR-teknikker på op til 70 %; katalysatorprecursorsammensætningen fremviser en stigning i indholdet af umættede carbonatomer, der indbefatter aromatiske carbonatomer, målt ved toparealsammenligninger ved anvendelse af 13C-NMR-teknikker på mindst 17 % sammenlignet med et samlet indhold af umættede carbonatomer, der er til stede i den første og anden organiske forbindelse; katalysatorprecursorsammensætningen fremviser en stigning i indholdet af umættede carbonatomer, der indbefatter aromatiske carbonatomer, målt ved toparealsammenligninger ved anvendelse af 13C-NMR-teknikker på op til 60 % sammenlignet med et samlet indhold af umættede carbonatomer, der er til stede i den første og anden organiske forbindelse; katalysatorprecursorsammensætningen fremviser et forhold mellem umættede carbonatomer og aromatiske carbonatomer målt ved toparealforhold ved anvendelse af teknikker med infrarød spektroskopi mellem en udfoldet top, der er centreret fra 1700 cm-1 til 1730 cm-1, sammenlignet med en udfoldet top, der er centreret fra 1380 cm-1 til 1450 cm-1, på mindst 0,9; og katalysatorprecursorsammensætningen fremviser et forhold mellem umættede carbonatomer og aromatiske carbonatomer målt ved toparealforhold ved anvendelse af teknikker med infrarød spektroskopi mellem en udfoldet top, der er centreret fra 1700 cm-1 til 1730 cm-1, sammenlignet med en ufoldet top, der er centreret fra 1380 cm-1 til 1450 cm-1, på op til 15.
6. Bulk blandet metalhydrobehandlingskatalysatorsammensætning, der er fremstillet ved sulfidering af katalysatorprecursorsammensætningen ifølge et hvilket som helst af kravene 1 til 5.
7. Fremgangsmåde til fremstilling af en bulk-katalysatorprecursorsammensætning, der indeholder et in situ-dannet amid og in situ-dannede umættede carbonatomer, hvilken fremgangsmåde omfatter: (a) behandling af en katalysatorprecursorsammensætning, der omfatter mindst ét metal fra gruppe 6 i grundstoffernes periodiske system, mindst ét metal fra gruppe 8-10 i grundstoffernes periodiske system, med en første organisk forbindelse, der indeholder mindst én amingruppe, og en anden organisk forbindelse, der er adskilt fra den første organiske forbindelse og indeholder mindst én carboxylsyregruppe, til fremstilling af en organisk behandlet precursorkatalysatorsammensætning; og (b) opvarmning af den organisk behandlede precursorkatalysatorsammensætning ved en temperatur fra 195 °C til 250 °C i et tidsrum, der er tilstrækkeligt til, at den første og anden organiske forbindelse kan reagere til frembringelse af både et in situ-amid og yderligere in situ-umættede carbonatomer, der ikke er til stede i den første eller anden organiske forbindelse, men ikke i så lang tid, at: (i) eventuelt amid i det væsentlige nedbrydes og/eller (ii) mere end 50 vægt-% af de kombinerede første og anden organiske forbindelser fordamper til derved frembringelse af en katalysatorprecursorsammensætning, der indeholder et in situ-dannet amid og in situ-dannede umættede carbonatomer.
8. Fremgangsmåde ifølge krav 7, hvor (a) udføres ved hjælp af et eller flere af: en første behandling af katalysatorprecursorsammensætningen med den første organiske forbindelse og en anden med den anden organiske forbindelse; en første behandling af katalysatorprecursorsammensætningen med den anden organiske forbindelse og en anden med den første organiske forbindelse; og behandling af katalysatorprecursorsammensætningen samtidigt med den første organiske forbindelse og med den anden organiske forbindelse.
9. Fremgangsmåde ifølge krav 7 eller 8, hvor det mindst ene metal fra gruppe 6 er Mo, W eller en kombination deraf, og hvor det mindst ene metal fra gruppe 8-10 er Co, Ni eller en kombination deraf.
10. Fremgangsmåde ifølge et hvilket som helst af kravene 7 til 9, hvor katalysatorprecursorsammensætningen yderligere omfatter mindst ét metal fra gruppe 5 i grundstoffernes periodiske system, for eksempel V, Nb eller en kombination deraf.
11. Fremgangsmåde ifølge et hvilket som helst af kravene 7 til 10, hvor den første organiske forbindelse omfatter mindst 10 carbonatomer, fortrinsvis omfatter en primær monoamin, der har fra 10 til 30 carbonatomer, og/eller hvor den anden organiske forbindelse omfatter mindst 10 carbonatomer, fortrinsvis omfatter kun én carboxylsyregruppe og har fra 10 til 30 carbonatomer, især hvor den første og anden organiske forbindelse samlet omfatter i alt mindst 15 carbonatomer.
12. Fremgangsmåde til fremstilling af en sulfideret hydrobehandlings-katalysatorsammensætning, som omfatter sulfidering af katalysatorprecursorsammensætningen fremstillet i henhold til fremgangsmåden ifølge et hvilket som helst af kravene 7 til 11 under sulfideringbetingelser, der er passende til frembringelse af den sulfiderede hydrobehandlings-katalysatorsammensætning.
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SG185596A1 (en) 2012-12-28
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US8722564B2 (en) 2014-05-13
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RU2012154273A (ru) 2014-07-20
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