DK2194778T3 - Forbedringer af eller i relation til organiske forbindelser - Google Patents
Forbedringer af eller i relation til organiske forbindelser Download PDFInfo
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- DK2194778T3 DK2194778T3 DK08788299.9T DK08788299T DK2194778T3 DK 2194778 T3 DK2194778 T3 DK 2194778T3 DK 08788299 T DK08788299 T DK 08788299T DK 2194778 T3 DK2194778 T3 DK 2194778T3
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
- A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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Claims (24)
1. Sammensætning, der omfatter en forbindelse med formel I CHsCH (OH) C (=0)NR1R2 (I) hvor R1 og R2 hver for sig er hydrogen; eller Ci-salkyl, C2-6alkenyl eller C3-6cycloalkyl, som hver eventuelt er substitueret med op til tre substituenter, der er udvalgt uafhængigt blandt phenyl, hydroxy, Ci-salkoxy, morpholinyl og NR3R4, hvor R3 og R4 hver for sig er Ci-3alkyl; eller phenyl, der eventuelt er substitueret med op til tre substituenter, der er udvalgt uafhængigt blandt Ci-3alkyl; eller R1 og R2 sammen med nitrogenatomet, hvortil de er bundet, danner en morpholinyl-, pyrrolidinyl-, piperidinyl- eller azepanylring, som hver eventuelt er substitueret med op til tre substituenter, der er udvalgt uafhængigt blandt Ci-3alkyl; og mindst én biologisk aktiv forbindelse, der omfatter mindst én aromatisk 5 og/eller 6-leddet ring, hvor ringen indeholder mindst ét nitrogen som et ringled, med de forbehold (i) at sammensætningen ikke indeholder cyproconazol, når forbindelsen med formel 1 er udvalgt fra gruppen, der består af N-butoxypropyllactamid; 1-(hydroxyethyl)- piperidinyllactamid; N-methyl-N-propyllactamid; N-(l- ethylpropyl)lactamid; N,N-dimethyllactamid; N-1,4- dimethylpentyllactamid; N-(2-hydroxyethyl)-N-benzyllactamid; N-morpholinyllactamid; N-methyl-N-butyllactamid; N- isobutyllactamid; N-allyllactamid; N-ethyllactamid; N-ethyl-N-(2-hydroxyethyl)lactamid; og N-isopropyllactamid; og (ii) at den biologisk aktive forbindelse ikke er nicotinsyre, når forbindelsen med formel 1 er diethyllactamid.
2. Sammensætning ifølge krav 1, hvor den aktive forbindelse er et agrokemikalie.
3. Sammensætning ifølge et hvilket som helst af ovennævnte krav, hvor R1 i forbindelsen med formel 1 ikke er hydrogen, methyl, ethyl, propyl, n-butyl, sec-butyl, iso-butyl, n-amyl, iso-amyl, iso-butylenyl, n-hexyl, 1-3-dimethylbutyl, allyl, CH2CH2OH, 2-hydroxypropyl, 2-hydroxyisobutyl, 1,3-dihydroxy-2-methyl-2-propyl, tris-hydroxymethylmethyl, CH2CH2OCH3, cyclohexyl, phenyl, benzyl, α-methylbenzyl, β-phenylethyl, 3-hydroxypropyl eller l-hydroxy-2-butyl, når R2 er hydrogen; R1 ikke er methyl, allyl eller phenyl, når R2 er methyl; R1 ikke er ethyl, når R2 er ethyl; R1 ikke er n-butyl, når R2 er n-butyl; R1 ikke er iso-butyl, når R2 er iso-butyl; R1 ikke er n-amyl, når R2 er n-amyl; R1 ikke er iso-amyl, når R2 er iso-amyl; R1 ikke er n-hexyl, når R2 er n-hexyl; R1 ikke er allyl, når R2 er allyl; R1 ikke er butyl eller phenyl, når R2 er phenyl; R1 ikke er benzyl, når R2 er benzyl; R1 ikke er CH2CH2OH eller ethyl, når R2 er CH2CH2OH; R1 ikke er 2-hydroxypropyl, når R2 er 2-hydroxypropyl; og R1 og R2 sammen med nitrogenatomet, hvortil de er bundet, ikke danner en usubstitueret morpholinyl-, pyrrolidinyl- eller piperidinylring.
4. Sammensætning ifølge et hvilket som helst af ovennævnte krav, der yderligere omfatter et opløsningsmiddel udvalgt fra gruppen, der består af alifatiske opløsningsmidler; ligekædede eller forgrenede paraffiner; cykliske carbonhydrider; aromatiske opløsningsmidler; phosphorholdige opløsningsmidler; svovlholdige opløsningsmidler; nitrogenholdige opløsningsmidler; alifatiske mono-, di- eller triestere; aromatiske mono- og diestere; cykliske estere; cykliske, alifatiske og aromatiske ketoner; alkylcyclohexanoner, dialkylketoner, acetoacetater, benzylketoner; acetophenon; akylalkoholer; cycloalkoholer; glycoler; glycolethere og deres polymerer; propylenglycoler; glycoletheracetater; aromatiske alkoholer; carbonater; ethere og halogenerede opløsningsmidler.
5. Sammensætning ifølge ovennævnte krav, hvor opløsningsmidlet er udvalgt fra gruppen, der består af hvid olie; decalin; mono-, di- eller trialkylerede benzener; Solvesso 100 eller 200ND (t); triethylphosphat, tributylphosphat eller tris-2-ethylhexylphosphat; methyloleat; linolsyre; linolensyre; oliesyre; dimethyldecanamid; tetramethylsulfon; dimethylsulfoxid; alkylurinstoffer; alkanolaminer; morpholiner; amider; alkylalkanoater, lactater og acetoacetater; fumarater; succinater; adipater; maleater; glycerol og citronsyreestere; alkylbenzoater; benzylalkanoater; alkylsalicylater; phthalater og dibenzoater; gamma-butyrolacton; caprolacton; terpenfenchon; cyclohexanon; alkylcyclohexanoner; 2-ethylhexanol; cyclohexanol; tetrahydrofurfurylalkohol; ethylen- og propylenglycol og deres polymerer; dipropylenglycol; monomethyl- eller monobutylether; dipropylenglycoldiacetat eller tripropylenglycolmonobutylether; benzylalkohol; propylen-eller butylencarbonat; dimethylisosorbid; alkoxyalkanoler; diphenylether; chlorbenzen og chloralkaner.
6. Sammensætning ifølge et hvilket som helst af ovennævnte krav, hvor den 5-leddede nitrogenholdige aromatiske ring er udvalgt fra gruppen, der består af pyrrol, pyrazol, imidazol, 1,2,3-triazoler og 1,2,4-triazol.
7. Sammensætning ifølge et hvilket som helst af ovennævnte krav, hvor den 6-leddede nitrogenholdige aromatiske ring er udvalgt fra gruppen, der består af pyridin, pyridazin, pyrimidin, pyrazin, 1,2,3-triazin, 1,2,4-triazin og 1,3,5-triazin.
8. Sammensætning ifølge et hvilket som helst af ovennævnte krav, hvor agrokemikaliet er udvalgt fra gruppen, der består af insekticider, herbicider, plantevækstregulatorer, planteaktivatorer, acaricider, nematocider, miticider og fungicider.
9. Sammensætning ifølge ovennævnte krav, hvor insekticidet er udvalgt fra gruppen, der består af neonikotinoider, bisamider, benzoylurinstoffer og carbamater; herbicidet er udvalgt fra gruppen, der består af triaziner og andre fotosystem-2-inhibitorer, 2,6-dinitroaniliner, ACCase-inhibitorer, PPO-inhibitorer, syntetiske auxiner, sulfonylurinstoffer, bipyrilliumherbicider, chloracetanilider, triazolopyrimidiner, pyrazoler og herbicidsafenere; plantevækstregulatorerne er udvalgt fra gruppen, der består af paclobutrazol og maleinhydrazid; og fungiciderne er udvalgt fra gruppen, der består af pyrimidiner, anilinpyrimidiner, triazoler og andre steroldemethylerings-inhibitorer, triazolpyrimidiner ΜΔΡ-kinase-inhibitorer, strobiluriner, adenosindeaminase-inhibitorer, pyrazoler og carboxamider.
10. Sammensætning ifølge ovennævnte krav, hvor neonikotinoider er thiamethoxam og imidiacloprid, bisamidet er rynaxypyr, benzoylurinstoffet er chlorfluazuron, carbamaten er pirimicarb; triazinerne er atrazin, simazin og cyanazin, de andre fotosystem-2-inhibitorer er diuron, prometryn og ametryn, 2,4-dinitroanilinen er fluazinam, ACCase-inhibitorerne er fluazifop-P-butyl og clodinafoppropargyl, PPO-inhibitoren er butafenacil, de syntetiske auxiner er fluroxypyrmeptyl, sulfonylurinstofferne er nicosulfuron, cinosulfuron, imazosulfuron, primisulfuronmethyl, prosulfuron og imazosulfuron, bipyrilliumherbiciderne er paraquat og diquat, chloracetanilidet er metazachlor, triazolpyrimidinerne er cloransulammethyl, florasulam, og penoxsulam, pyrazolen er benzofenap, herbicidsafeneren er cloquintocet, plantevækstregulatorerne er paclobutrazol og maleinhydrazid; planteaktivatoren er acibenzolar-s-methyl; pyrimidinere er bupirimat, dimethirimol og ethirimol, anilinpyrimidinerne er cyprodinil og pyrimethanil, triazolpyrimidinfungicidet har strukturen, der er vist i figur 1, triazolerne er bitertanol, diniconazol, epoxiconazol, fenbuconazol, fluquinconazol, flutriafol, penconazol, tebuconazol, triadimefon, triadimenol, difenoconazol, propiconazol og hexaconazol, de andre steroldemethylerings-inhibitorer er flutriafol, imazalil og prochloraz, MAP-kinase-inhibitoren er fludioxonil, strobilurinerne er azoxystrobin og picoxystrobin, adenosindeaminase-inhibitoren er ethirimol, pyrazolen er bixafen, og carboxamiderne er boscalidfurametpyr, penthiopyrad, thifluzamid, fluopyram og forbindelsen 3-difluormethyl-1-methyl-lH-pyrazol-4-carboxylsyre-(9-isopropyl- I, 2,3,4-tetrahydro-l,4-methannaphthalen-5-yl)-amid, som vist i figur 2.
II. Sammensætning ifølge et hvilket som helst af ovennævnte krav, der yderligere omfatter mindst én forbindelse udvalgt fra gruppen, der består af adjuvanser, overfladeaktive stoffer, polymerer, fortykningsmidler, farvestoffer eller pigmenter, ultraviolet lys-absorbere, antibakterielle midler, salte, densitetsmodificerende midler, stank- eller odørforbedrende midler, smagsmodificerende midler, cosolventer og fugtighedsbevarende midler.
12. Sammensætning ifølge et hvilket som helst af ovennævnte krav, hvor forbindelsen med formel 1 er til stede i en mængde fra 0,1 til 99 vægt-% af sammensætningen, og agrokemikaliet er til stede i en mængde fra 0,1 til 75 vægt-%.
13. Sammensætning ifølge et hvilket som helst af kravene 2 til 12, hvor forbindelsen med formel 1 er til stede i en mængde fra 0,1 til 99 vægt-% af sammensætningen, agrokemikaliet er til stede i en mængde fra 0,1 til 75 vægt-%, og opløsningsmidlet er til stede i en mængde fra 0,1 til 90 vægt-%.
14. Sammensætning ifølge ovennævnte krav, hvor forholdet mellem forbindelsen med formel 1 og agrokemikalie og opløsningsmiddel er defineret inden for grænserne 0,01-1:0,01-1:0,01-1.
15. Sammensætning ifølge ovennævnte krav, hvor forholdet mellem forbindelsen med formel 1 og agrokemikalie og opløsningsmiddel er 1:1:1 eller 2:1:1 eller 2:1:2 eller 3:1:1 eller 3:1:2 eller 4,5:1:4,5 eller 6:1:3.
16. Sammensætning ifølge et hvilket som helst af ovennævnte krav, hvor forbindelsen med formel 1 er dimethyllactamid, og agrokemikaliet er 3-difluormethyl-l-methyl-lH-pyrazol-4-carboxylsyre-(9-isopropyl-l,2,3,4-tetrahydro-l, 4-methannaphthalen-5-yl)-amid (vist i figur 2).
17. Sammensætning ifølge ovennævnte krav, der omfatter 5 til 95 % DML, 0,5 til 50 % 3-difluormethyl-l-methyl-lH-pyrazol-4-carboxylsyre-(9-isopropyl-l,2,3,4-tetrahydro-l,4-methannaphthalen-5-yl)-amid (figur 2) og 5 til 95 % opløsningsmiddel udvalgt fra gruppen, der består af opløsningsmidlerne ifølge krav 4.
18. Sammensætning ifølge krav 17, hvor opløsningsmidlet er udvalgt fra gruppen, der består af Solvesso 200ND, dipropylenglycolmonobutylether, dipropylenglycoldiacetat, methylbenzoat, benzylbenzoat, dimethyldecanamid, dipropylenglycolmonomethylether og butylbenzoat.
19. Sammensætning ifølge et hvilket som helst af ovennævnte krav, når den er formuleret som et emulsionskoncentrat (EC).
20. Fremgangsmåde til fremstilling af en sammensætning ifølge et hvilket som helst af ovennævnte krav, der omfatter blanding af en forbindelse med formel 1 ifølge krav 1 med et biologisk aktivt middel ifølge krav 1.
21. Fremgangsmåde, eksklusive terapeutiske fremgangsmåder, til bekæmpelse af en skadelig organisme i landbruget, der omfatter påføring på den skadelige organisme eller en overflade, hvor den kan være til stede, af en pesticidvirkende effektiv mængde af en sammensætning ifølge et hvilket som helst af kravene 1 til 19.
22. Fremgangsmåde ifølge ovennævnte krav, hvor den skadelige organisme er en svamp, og agrokemikaliet er et fungicid.
23. Fremgangsmåde ifølge ovennævnte krav, hvor fungicidet har strukturen, der er vist i figur 2 (3-difluormethyl-l-methyl- ΙΗ-pyrazol-4-carboxylsyre-(9-isopropyl-l,2,3,4-tetrahydro-l,4-methannaphthalen-5-yl)-amid)
24. Anvendelse af en sammensætning ifølge et hvilket som helst af kravene 1 til 19 til bekæmpelse af en skadelig organisme for planter.
25. Anvendelse ifølge ovennævnte krav, hvor den skadelige organisme er en fytopatogen svamp, forbindelsen med formel 1 er dimethyllactamid, agrokemikaliet har strukturen ifølge figur 2, og sammensætningen omfatter et opløsningsmiddel udvalgt fra gruppen, der består af Solvesso 200ND, dipropylenglycolmonobutylether eller dipropylenglycoldiacetat, methylbenzoat, benzylbenzoat, dimethyldecanamid, dipropylenglycolmonomethylether og butylbenzoat.
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GBGB0716592.1A GB0716592D0 (en) | 2007-08-24 | 2007-08-24 | Improvements in or relating to organic compounds |
PCT/GB2008/002730 WO2009027624A2 (en) | 2007-08-24 | 2008-08-13 | Improvements in or relating to organic compounds |
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US (1) | US20110190129A1 (da) |
EP (1) | EP2194778B1 (da) |
JP (1) | JP5539873B2 (da) |
KR (1) | KR20100065292A (da) |
CN (1) | CN101784186B (da) |
AP (1) | AP2713A (da) |
AR (1) | AR068615A1 (da) |
AU (1) | AU2008292009B2 (da) |
BR (1) | BRPI0816238B1 (da) |
CA (1) | CA2695171C (da) |
CO (2) | CO6260004A2 (da) |
CR (1) | CR11245A (da) |
DK (1) | DK2194778T3 (da) |
DO (1) | DOP2010000065A (da) |
EA (1) | EA017314B1 (da) |
EC (1) | ECSP109990A (da) |
EG (1) | EG26581A (da) |
ES (1) | ES2621360T3 (da) |
GB (1) | GB0716592D0 (da) |
GE (1) | GEP20156292B (da) |
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HU (1) | HUE031139T2 (da) |
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MA (1) | MA31621B1 (da) |
MX (1) | MX2010001915A (da) |
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GB0817513D0 (en) * | 2008-09-24 | 2008-10-29 | Syngenta Ltd | Co-crystals |
GB0817976D0 (en) * | 2008-10-01 | 2008-11-05 | Syngenta Ltd | Co-crystals |
EP2272346A1 (de) | 2009-07-08 | 2011-01-12 | LANXESS Deutschland GmbH | Penthiopyrad für den Holzschutz |
FR2951447B1 (fr) | 2009-10-19 | 2012-10-19 | Rhodia Operations | Composes de type ether-amide et utilisattions |
WO2011147822A2 (en) | 2010-05-27 | 2011-12-01 | Akzo Nobel Chemicals International B.V. | Agricultural formulations with acyl morpholines and polar aprotic co-solvents |
MX2012014304A (es) | 2010-06-07 | 2013-05-30 | Dow Agrosciences Llc | Carboxamidas de pirazinilo como fungicidas. |
UA118214C2 (uk) * | 2014-02-14 | 2018-12-10 | Басф Агро Б.В. | Здатний до емульгування концентрат, що включає пестицид, жирний амід і лактамід |
WO2015121119A1 (en) * | 2014-02-14 | 2015-08-20 | BASF Agro B.V. | Emulsifiable concentrate comprising pesticide, alkyl lactate, and lactamide |
EP3364756B1 (en) * | 2015-10-21 | 2021-12-08 | Basf Se | Liquid pesticidal composition |
AU2017397235B2 (en) | 2017-01-31 | 2023-09-21 | Kimberly-Clark Worldwide, Inc. | Antibacterial composition including benzoic acid ester and methods of inhibiting bacterial growth utilizing the same |
US11805776B2 (en) * | 2018-01-16 | 2023-11-07 | The United States Of America, As Represented By The Secretary Of Agriculture | Compositions and methods for killing insect and non-insect pests |
US11701316B2 (en) | 2020-12-18 | 2023-07-18 | The Procter & Gamble Company | Synergistic anti-inflammatory compositions |
US20220192956A1 (en) * | 2020-12-18 | 2022-06-23 | The Procter & Gamble Company | Superior efficacy of azoxystrobin and other strobilurins |
GB202114743D0 (en) * | 2021-10-15 | 2021-12-01 | Syngenta Crop Protection Ag | Composition |
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DE1083501B (de) * | 1959-03-26 | 1960-06-15 | Merck Ag E | Verfahren zur Herstellung von Loesungen in Wasser schwer- oder unloeslicher Arzneimittel |
US4837242A (en) * | 1987-01-20 | 1989-06-06 | Sumitomo Chemical Company, Limited | Thiazoles and pyrazoles as fungicides |
DE4130189A1 (de) * | 1991-04-19 | 1993-03-18 | Sehring Richard H Dr | Neue emulsionskonzentrate fuer den einsatz im pflanzenschutz |
DE4112873A1 (de) * | 1991-04-19 | 1992-10-22 | Richard H Dr Sehring | Fungicides pflanzenschutzmittel mit wirkung im zierpflanzen und obstbau sowie gegen echten mehltau an getreide, gurken, reben und hopfen |
JP3066291B2 (ja) * | 1994-07-07 | 2000-07-17 | 麒麟麦酒株式会社 | 抗腫瘍薬物の用時調合型セット製剤 |
AUPQ875700A0 (en) * | 2000-07-13 | 2000-08-03 | Reflex Research Limited | Combination compositions |
GB0605780D0 (en) * | 2006-03-22 | 2006-05-03 | Syngenta Ltd | Formulations |
EP1961301A1 (en) * | 2007-02-22 | 2008-08-27 | Cognis IP Management GmbH | Biocide compositions comprising a dialkylamide of a hydroxycarboxylic acid |
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2007
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