DEG0014816MA - - Google Patents

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Publication number

DEG0014816MA

DEG0014816MA DEG0014816MA DE G0014816M A DEG0014816M A DE G0014816MA DE G0014816M A DEG0014816M A DE G0014816MA

Authority

DE

Germany

Prior art keywords

silica

water

mixture according

acid

compound

Prior art date

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 51
• 239000000377 silicon dioxide Substances 0.000 claims description 24
• 239000000203 mixture Substances 0.000 claims description 15
• 229920002472 Starch Polymers 0.000 claims description 11
• 239000000463 material Substances 0.000 claims description 11
• 235000019698 starch Nutrition 0.000 claims description 10
• 150000001875 compounds Chemical class 0.000 claims description 9
• 239000008107 starch Substances 0.000 claims description 9
• 239000006185 dispersion Substances 0.000 claims description 8
• 239000002245 particle Substances 0.000 claims description 8
• 239000007864 aqueous solution Substances 0.000 claims description 6
• 150000001989 diazonium salts Chemical class 0.000 claims description 6
• 238000004519 manufacturing process Methods 0.000 claims description 6
• 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
• 229920001888 polyacrylic acid Polymers 0.000 claims description 3
• 239000004584 polyacrylic acid Substances 0.000 claims description 3
• 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
• 229920002554 vinyl polymer Polymers 0.000 claims description 3
• 238000006149 azo coupling reaction Methods 0.000 claims 1
• 239000000243 solution Substances 0.000 description 22
• 238000000034 method Methods 0.000 description 13
• 239000011230 binding agent Substances 0.000 description 12
• 239000011248 coating agent Substances 0.000 description 11
• 238000000576 coating method Methods 0.000 description 11
• 150000008049 diazo compounds Chemical class 0.000 description 11
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
• 230000001235 sensitizing Effects 0.000 description 9
• 231100000202 sensitizing Toxicity 0.000 description 8
• 239000011780 sodium chloride Substances 0.000 description 7
• 239000000126 substance Substances 0.000 description 7
• JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
• 150000003839 salts Chemical class 0.000 description 6
• 230000035945 sensitivity Effects 0.000 description 6
• LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
• 229910052757 nitrogen Inorganic materials 0.000 description 5
• GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
• 239000000654 additive Substances 0.000 description 4
• 238000010168 coupling process Methods 0.000 description 4
• 238000005859 coupling reaction Methods 0.000 description 4
• KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
• 239000000123 paper Substances 0.000 description 4
• RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
• UMGDCJDMYOKAJW-UHFFFAOYSA-N Thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 3
• 238000005299 abrasion Methods 0.000 description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• 239000002253 acid Substances 0.000 description 3
• 230000001808 coupling Effects 0.000 description 3
• 230000000694 effects Effects 0.000 description 3
• PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
• 235000011187 glycerol Nutrition 0.000 description 3
• 239000001397 quillaja saponaria molina bark Substances 0.000 description 3
• 150000007949 saponins Chemical class 0.000 description 3
• 235000012239 silicon dioxide Nutrition 0.000 description 3
• 239000005031 sulfite paper Substances 0.000 description 3
• 239000011592 zinc chloride Substances 0.000 description 3
• 235000005074 zinc chloride Nutrition 0.000 description 3
• DYRDKSSFIWVSNM-UHFFFAOYSA-N Acetoacetanilide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1 DYRDKSSFIWVSNM-UHFFFAOYSA-N 0.000 description 2
• 229920002301 Cellulose acetate Polymers 0.000 description 2
• 229920002261 Corn starch Polymers 0.000 description 2
• NROKBHXJSPEDAR-UHFFFAOYSA-M Potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
• KVBCYCWRDBDGBG-UHFFFAOYSA-N azane;dihydrofluoride Chemical compound [NH4+].F.[F-] KVBCYCWRDBDGBG-UHFFFAOYSA-N 0.000 description 2
• 239000008120 corn starch Substances 0.000 description 2
• 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
• 238000005516 engineering process Methods 0.000 description 2
• 239000004744 fabric Substances 0.000 description 2
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• 238000002360 preparation method Methods 0.000 description 2
• CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
• FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
• PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-dimethylphenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 1
• YCIYKQSGEUKDSZ-UHFFFAOYSA-N 2-(4-methylphenyl)-1H-pyrazol-5-one Chemical compound C1=CC(C)=CC=C1N1N=C(O)C=C1 YCIYKQSGEUKDSZ-UHFFFAOYSA-N 0.000 description 1
• SUZRRICLUFMAQD-UHFFFAOYSA-N 2-(methylamino)ethanesulfonic acid Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
• QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-N,4-N-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
• JPUHXNRAGDKQRD-UHFFFAOYSA-N 4-octylbenzene-1,3-diol Chemical compound CCCCCCCCC1=CC=C(O)C=C1O JPUHXNRAGDKQRD-UHFFFAOYSA-N 0.000 description 1
• YJISHJVIRFPGGN-UHFFFAOYSA-N 5-[5-[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxy-6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)O)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 YJISHJVIRFPGGN-UHFFFAOYSA-N 0.000 description 1
• PTKWYSNDTXDBIZ-UHFFFAOYSA-N 9,10-dioxoanthracene-1,2-disulfonic acid Chemical compound C1=CC=C2C(=O)C3=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C3C(=O)C2=C1 PTKWYSNDTXDBIZ-UHFFFAOYSA-N 0.000 description 1
• DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
• BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
• KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
• YKYOUMDCQGMQQO-UHFFFAOYSA-L Cadmium chloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 1
• 229920000742 Cotton Polymers 0.000 description 1
• LDMOEFOXLIZJOW-UHFFFAOYSA-M DODECANESULFONATE ION Chemical compound CCCCCCCCCCCCS([O-])(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-M 0.000 description 1
• FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 1
• -1 N, N-disubstituted p-phenylenediamines Chemical class 0.000 description 1
• VPUVJSYUOHKTOC-UHFFFAOYSA-N NC1=CC(=C(N(CC)CC)C=C1)OCC Chemical compound NC1=CC(=C(N(CC)CC)C=C1)OCC VPUVJSYUOHKTOC-UHFFFAOYSA-N 0.000 description 1
• FATBGEAMYMYZAF-KTKRTIGZSA-N Oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
• 229960001553 Phloroglucinol Drugs 0.000 description 1
• QCDYQQDYXPDABM-UHFFFAOYSA-N Phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
• 206010034960 Photophobia Diseases 0.000 description 1
• 206010034972 Photosensitivity reaction Diseases 0.000 description 1
• 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
• 206010070834 Sensitisation Diseases 0.000 description 1
• AKHNMLFCWUSKQB-UHFFFAOYSA-L Sodium thiosulphate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
• HPGGPRDJHPYFRM-UHFFFAOYSA-J Tin(IV) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
• 229940100445 WHEAT STARCH Drugs 0.000 description 1
• 150000007513 acids Chemical class 0.000 description 1
• 238000007792 addition Methods 0.000 description 1
• HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
• 150000001408 amides Chemical class 0.000 description 1
• QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
• DAPUDVOJPZKTSI-UHFFFAOYSA-L ammonium nickel sulfate Chemical compound [NH4+].[NH4+].[Ni+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DAPUDVOJPZKTSI-UHFFFAOYSA-L 0.000 description 1
• 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
• 235000011130 ammonium sulphate Nutrition 0.000 description 1
• 239000007900 aqueous suspension Substances 0.000 description 1
• UMNYVEBMAZPMAK-UHFFFAOYSA-N azanium;zinc;chloride Chemical compound [NH4+].[Cl-].[Zn+2] UMNYVEBMAZPMAK-UHFFFAOYSA-N 0.000 description 1
• 239000000987 azo dye Substances 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 239000004327 boric acid Substances 0.000 description 1
• 235000013339 cereals Nutrition 0.000 description 1
• 239000008119 colloidal silica Substances 0.000 description 1
• 230000000052 comparative effect Effects 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 239000000975 dye Substances 0.000 description 1
• 230000002708 enhancing Effects 0.000 description 1
• IMROMDMJAWUWLK-UHFFFAOYSA-N ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
• 238000005562 fading Methods 0.000 description 1
• KRHYYFGTRYWZRS-UHFFFAOYSA-M fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
• 238000005755 formation reaction Methods 0.000 description 1
• 239000004615 ingredient Substances 0.000 description 1
• 238000009114 investigational therapy Methods 0.000 description 1
• 125000000468 ketone group Chemical group 0.000 description 1
• 239000007788 liquid Substances 0.000 description 1
• 229910052751 metal Inorganic materials 0.000 description 1
• 239000002184 metal Substances 0.000 description 1
• GPUMPJNVOBTUFM-UHFFFAOYSA-N naphthalene-1,2,3-trisulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC2=C1 GPUMPJNVOBTUFM-UHFFFAOYSA-N 0.000 description 1
• KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
• 125000004433 nitrogen atoms Chemical group N* 0.000 description 1
• ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
• 150000004989 p-phenylenediamines Chemical class 0.000 description 1
• 101700086038 pat-2 Proteins 0.000 description 1
• 230000036211 photosensitivity Effects 0.000 description 1
• 239000011698 potassium fluoride Substances 0.000 description 1
• 235000003270 potassium fluoride Nutrition 0.000 description 1
• 229920001592 potato starch Polymers 0.000 description 1
• 238000001556 precipitation Methods 0.000 description 1
• 230000002028 premature Effects 0.000 description 1
• 239000004627 regenerated cellulose Substances 0.000 description 1
• 230000033458 reproduction Effects 0.000 description 1
• 230000008313 sensitization Effects 0.000 description 1
• 239000001187 sodium carbonate Substances 0.000 description 1
• 229910000029 sodium carbonate Inorganic materials 0.000 description 1
• 239000011775 sodium fluoride Substances 0.000 description 1
• 235000013024 sodium fluoride Nutrition 0.000 description 1
• 239000001488 sodium phosphate Substances 0.000 description 1
• 229910000162 sodium phosphate Inorganic materials 0.000 description 1
• 235000019345 sodium thiosulphate Nutrition 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000003381 stabilizer Substances 0.000 description 1
• 239000000758 substrate Substances 0.000 description 1
• 150000003462 sulfoxides Chemical class 0.000 description 1
• 230000002195 synergetic Effects 0.000 description 1
• 229920003002 synthetic resin Polymers 0.000 description 1
• 239000000057 synthetic resin Substances 0.000 description 1
• 239000011975 tartaric acid Substances 0.000 description 1
• 229960001367 tartaric acid Drugs 0.000 description 1
• 235000002906 tartaric acid Nutrition 0.000 description 1
• 150000003585 thioureas Chemical class 0.000 description 1
• RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
• 239000000080 wetting agent Substances 0.000 description 1