DEA0016605MA - - Google Patents
Info
- Publication number
- DEA0016605MA DEA0016605MA DEA0016605MA DE A0016605M A DEA0016605M A DE A0016605MA DE A0016605M A DEA0016605M A DE A0016605MA
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- hours
- weight
- fluorine
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 claims description 42
- 239000011737 fluorine Substances 0.000 claims description 23
- 229910052731 fluorine Inorganic materials 0.000 claims description 23
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- 239000000969 carrier Substances 0.000 claims description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- 229910052803 cobalt Inorganic materials 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 239000011593 sulfur Substances 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 239000011733 molybdenum Substances 0.000 claims description 9
- 239000012263 liquid product Substances 0.000 claims description 7
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 7
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 7
- WZJQNLGQTOCWDS-UHFFFAOYSA-K Cobalt(III) fluoride Chemical compound F[Co](F)F WZJQNLGQTOCWDS-UHFFFAOYSA-K 0.000 claims description 5
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 5
- LBFUKZWYPLNNJC-UHFFFAOYSA-N Cobalt(II,III) oxide Chemical compound [Co]=O.O=[Co]O[Co]=O LBFUKZWYPLNNJC-UHFFFAOYSA-N 0.000 claims description 4
- 229910015621 MoO Inorganic materials 0.000 claims description 4
- 239000012153 distilled water Substances 0.000 claims description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- 230000000875 corresponding Effects 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000004698 Polyethylene (PE) Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 2
- 125000001741 organic sulfur group Chemical group 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 101710006768 PGRMC1 Proteins 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000010779 crude oil Substances 0.000 claims 1
- 108060002971 flz Proteins 0.000 claims 1
- 239000000243 solution Substances 0.000 description 20
- QGAVSDVURUSLQK-UHFFFAOYSA-N Ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 9
- 239000011609 ammonium molybdate Substances 0.000 description 9
- 229940010552 ammonium molybdate Drugs 0.000 description 9
- 235000018660 ammonium molybdate Nutrition 0.000 description 9
- UFMZWBIQTDUYBN-UHFFFAOYSA-N Cobalt(II) nitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 8
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 8
- 238000006477 desulfuration reaction Methods 0.000 description 7
- 230000003009 desulfurizing Effects 0.000 description 7
- 229910001570 bauxite Inorganic materials 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 2
- 231100000078 corrosive Toxicity 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000011240 wet gel Substances 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K AlF3 Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N Ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- OKHBRCHLOMDDAC-UHFFFAOYSA-L dialuminum;dichlorocobalt;oxygen(2-);hydrofluoride Chemical compound [O-2].[O-2].[O-2].F.[Al+3].[Al+3].Cl[Co]Cl OKHBRCHLOMDDAC-UHFFFAOYSA-L 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000010414 supernatant solution Substances 0.000 description 1
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3446038C2 (xx) | ||
| DE1545397C3 (de) | Verfahren zur hydrierenden Entfernung von Stickstoff- und Schwefelverbindungen aus einem Kohlenwasserstoffrückstände enthaltenden schwermetallhaltigen Erdölausgangsmaterial | |
| DE2831815A1 (de) | Verfahren zur herstellung von einem eine bestimmte porositaet aufweisenden aluminiumoxyd und verwendung des aluminiumoxydes | |
| DE2130743A1 (de) | Verfahren zur Herstellung eines Katalysators | |
| DE3878210T2 (de) | Verfahren zur herstellung eines entschwefelelungsmittels. | |
| DE2330385A1 (de) | Verfahren zum hydrierenden entschwefeln von rohoel, abgetopptem rohoel oder schwerem gasoel | |
| DE2252332A1 (de) | Katalysator aus einem oder mehreren hydrierungsaktiven metallen auf einem traegermaterial, verfahren zu seiner herstellung und seine verwendung | |
| DE69207832T2 (de) | Katalysator und Verfahren zur Behandlung von Schwefelkomponenten enthaltenden Gasen | |
| DE1811062A1 (de) | Verfahren zur Herstellung von Acrylnitril | |
| DE1667283A1 (de) | Verfahren zur Herstellung eines Katalysators fuer die hydrierende Spaltung von Kohlenwasserstoffoelen | |
| DE2512294C2 (xx) | ||
| EP0383132A1 (de) | Kobaltkatalysatoren | |
| DE2411986C3 (xx) | ||
| DEA0016605MA (xx) | ||
| DE2653884A1 (de) | Traeger fuer katalysatoren, verfahren zu ihrer herstellung und deren verwendung | |
| DE2515919C2 (de) | Verfahren zur katalytischen hydrierenden Entschwefelung von Vanadium und Nickel enthaltenden Kohlenwasserstoff- Rückstandsölen ohne Katalysatornachbeschickung | |
| DE977010C (de) | Verfahren zur hydrierenden Entschwefelung von Erdoelkohlenwasserstoffen | |
| DE1201818B (de) | Verfahren zur Herstellung von Katalysatoren fuer die Umwandlung von Kohlenwasserstoffoelen | |
| DE930889C (de) | Verfahren zur Herstellung von Benzin aus Erdoelen | |
| DE1200990C2 (de) | Verfahren zur hydrierenden spaltung eines kohlenwasserstoffoels | |
| DE69024930T2 (de) | Verfahren zur Aminierung von Phenolen | |
| DE2513756A1 (de) | Katalysator fuer die wasserstoffbehandlung von kohlenwasserstoffen und dessen herstellung | |
| DE2819088C2 (xx) | ||
| DE2216975C3 (de) | Verfahren zur Herstellung eines hydrieraktiven Katalysators | |
| DE2351136A1 (de) | Verfahren zur katalytischen hydrierenden entschwefelung von kohlenwasserstoffrueckstandsoelen |