DE940005C - Verfahren zum Suessen von Merkaptane enthaltenden Erdoelen - Google Patents
Verfahren zum Suessen von Merkaptane enthaltenden ErdoelenInfo
- Publication number
- DE940005C DE940005C DEA16031A DEA0016031A DE940005C DE 940005 C DE940005 C DE 940005C DE A16031 A DEA16031 A DE A16031A DE A0016031 A DEA0016031 A DE A0016031A DE 940005 C DE940005 C DE 940005C
- Authority
- DE
- Germany
- Prior art keywords
- oxygen
- solution
- mercaptans
- treatment
- petroleum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 13
- 239000003921 oil Substances 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 9
- 239000003208 petroleum Substances 0.000 title claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 16
- 239000003518 caustics Substances 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 239000011593 sulfur Substances 0.000 claims description 9
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000003209 petroleum derivative Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000002019 disulfides Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 229940031826 phenolate Drugs 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Liquid Carbonaceous Fuels (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB15827/51A GB728586A (en) | 1951-07-04 | 1951-07-04 | Improvements relating to the sweetening of petroleum oils containing mercaptans |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE940005C true DE940005C (de) | 1956-03-08 |
Family
ID=10066248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA16031A Expired DE940005C (de) | 1951-07-04 | 1952-06-22 | Verfahren zum Suessen von Merkaptane enthaltenden Erdoelen |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2729591A (he) |
| BE (1) | BE512549A (he) |
| DE (1) | DE940005C (he) |
| FR (1) | FR1059231A (he) |
| GB (1) | GB728586A (he) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3063935A (en) * | 1959-09-08 | 1962-11-13 | Shell Oil Co | Hydrocarbon sweetening process |
| US4428828A (en) | 1981-01-02 | 1984-01-31 | Chevron Research Company | Upgrading hydrocarbonaceous oils with an aqueous liquid |
| US4481106A (en) * | 1983-12-05 | 1984-11-06 | Uop Inc. | Hydrocarbon treating process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2015038A (en) * | 1932-07-23 | 1935-09-17 | Texas Co | Process of sweetening petroleum hydrocarbons |
| US2329616A (en) * | 1942-04-27 | 1943-09-14 | Air Reduction | Treatment of hydrocarbon oils |
| US2346497A (en) * | 1941-09-02 | 1944-04-11 | Shell Dev | Solutizer process |
| US2413945A (en) * | 1944-03-09 | 1947-01-07 | Standard Oil Co | Treating petroleum distillates |
| US2552399A (en) * | 1949-02-19 | 1951-05-08 | Standard Oil Dev Co | Treating petroleum distillates |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA471373A (en) * | 1951-02-06 | C. Bond Donald | Removal of acidic sulfur compounds from hydrocarbon oils | |
| CA475538A (en) * | 1951-07-24 | C. Bond Donald | Sweetening of hydrocarbon liquids | |
| US2427212A (en) * | 1944-12-02 | 1947-09-09 | Pure Oil Co | Removal of peroxides from hydrocarbon oils |
| GB629914A (en) * | 1944-12-06 | 1949-09-30 | Pure Oil Co | A method for sweetening hydrocarbon liquids containing mercaptans |
| US2474028A (en) * | 1946-04-06 | 1949-06-21 | Inventors Guild | Recovery of phenol salts from aqueous solutions |
| US2638439A (en) * | 1951-04-18 | 1953-05-12 | Standard Oil Dev Co | Treatment of petroleum distillates |
-
0
- BE BE512549D patent/BE512549A/xx unknown
-
1951
- 1951-07-04 GB GB15827/51A patent/GB728586A/en not_active Expired
-
1952
- 1952-06-20 US US294722A patent/US2729591A/en not_active Expired - Lifetime
- 1952-06-22 DE DEA16031A patent/DE940005C/de not_active Expired
- 1952-06-26 FR FR1059231D patent/FR1059231A/fr not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2015038A (en) * | 1932-07-23 | 1935-09-17 | Texas Co | Process of sweetening petroleum hydrocarbons |
| US2346497A (en) * | 1941-09-02 | 1944-04-11 | Shell Dev | Solutizer process |
| US2329616A (en) * | 1942-04-27 | 1943-09-14 | Air Reduction | Treatment of hydrocarbon oils |
| US2413945A (en) * | 1944-03-09 | 1947-01-07 | Standard Oil Co | Treating petroleum distillates |
| US2552399A (en) * | 1949-02-19 | 1951-05-08 | Standard Oil Dev Co | Treating petroleum distillates |
Also Published As
| Publication number | Publication date |
|---|---|
| US2729591A (en) | 1956-01-03 |
| GB728586A (en) | 1955-04-20 |
| BE512549A (he) | |
| FR1059231A (fr) | 1954-03-23 |
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