DE878472T1 - Reaktive, durch Strahlung oder Wärme kationisch härtbare Epoxidmonomere und diese enthaltende Zusammensetzungen - Google Patents

Reaktive, durch Strahlung oder Wärme kationisch härtbare Epoxidmonomere und diese enthaltende Zusammensetzungen

Info

Publication number
DE878472T1
DE878472T1 DE1998108862 DE98108862T DE878472T1 DE 878472 T1 DE878472 T1 DE 878472T1 DE 1998108862 DE1998108862 DE 1998108862 DE 98108862 T DE98108862 T DE 98108862T DE 878472 T1 DE878472 T1 DE 878472T1
Authority
DE
Germany
Prior art keywords
radiation
integer
cationically curable
cationic
curable adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE1998108862
Other languages
English (en)
Other versions
DE19808862A1 (de
Inventor
Nikola A. Three Bridges New Jersey 08887 Nikolic
Rose Ann Box 431 Princeton New Jersey 08540 Schultz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Starch and Chemical Investment Holding Corp
Original Assignee
National Starch and Chemical Investment Holding Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26760911&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE878472(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US09/078,768 external-priority patent/US5962547A/en
Application filed by National Starch and Chemical Investment Holding Corp filed Critical National Starch and Chemical Investment Holding Corp
Publication of DE878472T1 publication Critical patent/DE878472T1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C08G59/245—Di-epoxy compounds carbocyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (5)

Patentansprüche
1. Kationisch, durch Strahlung oder thermisch initiiert, aushärtbare Verbindung mit der Struktur
in der R1 bis R4 unabhängig Wasserstoff oder aliphatische, alicyclische oder aromatische Gruppen verkörpern, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung noch durch die Wirkung einer Lewis-Base behindern, und y eine ganze Zahl von 1 bis 6 ist, w eine ganze Zahl von 0 bis 5 ist, mit der Maßgabe, daß y + w < 6 ist.
2. Kationisch aushärtbare Klebstoff- oder Beschichtungszusammensetzung, umfassend
(a) eine, durch Strahlung oder thermisch initiiert, kationisch aushärtbare Verbindung mit der Struktur
in der R1 bis R4 unabhängig Wasserstoff oder aliphatische, alicyclische oder aromatische Gruppen verkörpern, die Heteroatome enthalten können, dadurch gekennzeichnet, daß sie die kationische Polymerisation der Epoxyfunktionalität weder durch sterische Wechselwirkung
noch durch die Wirkung einer Lewis-Base behindern, y eine ganze Zahl von 1 bis 6 ist, w eine ganze Zahl von 0 bis 5 ist, mit der Maßgabe, daß y + w < 6, und
(b) einen kationischen Photo- oder Thermo-Initiator und
(c) einen oder mehrere Alkohole oder Polyole.
3. Kationisch aushärtbare Klebstoff- oder Beschichtungszusammensetzung gemäß Anspruch 2, in der die kationische Aushärtung mit sichtbarem Licht initiiert wird und die Zusammensetzung des weiteren einen Photosensibilisator umfaßt.
4. Kationisch aushärtbare Klebstoff- oder Beschichtungs-
zusammensetzung gemäß Anspruch 3, die darüber hinaus ein oder mehrere Urethane oder Polyurethane umfaßt.
5. Kationisch aushärtbare Klebstoff- oder Beschichtungs-
zusammensetzung gemäß Anspruch 3 oder 4, in der der Photosensibilisator 9-Anthracenmethanol ist.
20
DE1998108862 1997-05-16 1998-05-15 Reaktive, durch Strahlung oder Wärme kationisch härtbare Epoxidmonomere und diese enthaltende Zusammensetzungen Pending DE878472T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US85766797A 1997-05-16 1997-05-16
US09/078,768 US5962547A (en) 1997-05-16 1998-05-14 Reactive radiation- or thermally-initiated cationically-curable epoxide monomers and compositions made from those monomers

Publications (1)

Publication Number Publication Date
DE878472T1 true DE878472T1 (de) 1999-05-06

Family

ID=26760911

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1998108862 Pending DE878472T1 (de) 1997-05-16 1998-05-15 Reaktive, durch Strahlung oder Wärme kationisch härtbare Epoxidmonomere und diese enthaltende Zusammensetzungen

Country Status (6)

Country Link
EP (1) EP0878472A1 (de)
JP (1) JP3026557B2 (de)
AU (1) AU700835B2 (de)
CA (1) CA2237881A1 (de)
DE (1) DE878472T1 (de)
ES (1) ES2126545T1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6020508A (en) * 1997-05-16 2000-02-01 National Starch And Chemical Investment Holding Corporation Radiation- or thermally-initiated cationically-curable epoxide compounds and compositions made from those compounds
US6441121B1 (en) * 2001-09-28 2002-08-27 National Starch And Chemical Investment Holding Corporation Epoxy compounds containing styrenic or cinnamyl functionality
KR101522346B1 (ko) * 2008-03-27 2015-05-21 신닛테츠 수미킨 가가쿠 가부시키가이샤 에폭시수지 조성물 및 경화물
CN102272113A (zh) * 2008-12-30 2011-12-07 陶氏环球技术有限责任公司 用于制备二乙烯基芳烃二氧化物的方法
JP5478603B2 (ja) * 2009-03-05 2014-04-23 新日鉄住金化学株式会社 エポキシ樹脂組成物
JP2010229284A (ja) 2009-03-27 2010-10-14 Fujifilm Corp 光硬化性組成物
KR101716634B1 (ko) * 2009-03-31 2017-03-14 신닛테츠 수미킨 가가쿠 가부시키가이샤 에폭시수지, 에폭시수지 조성물 및 경화물
BR112012013135A8 (pt) * 2009-12-08 2017-10-24 Dow Global Technologies Inc Composição de resina, processo para preparar um resina de poliésyer com funcionalidade hidroxila e processo para preparar uma composição de resina de poliéster com funcionalidade hidroxila curável
CN102666520B (zh) 2009-12-09 2015-05-20 陶氏环球技术有限责任公司 二乙烯基芳烃二氧化物树脂
JP5670048B2 (ja) * 2009-12-21 2015-02-18 株式会社Ｄｎｐファインケミカル 接着組成物および硬化性接着シートの製造方法
CN102762628A (zh) 2010-02-19 2012-10-31 陶氏环球技术有限责任公司 二乙烯基芳烃二氧化物树脂组合物
CN103025719B (zh) * 2010-03-10 2016-01-20 陶氏环球技术有限责任公司 制备二乙烯基芳烃二氧化物的方法
JP2013522317A (ja) * 2010-03-18 2013-06-13 ダウ グローバル テクノロジーズ エルエルシー ジビニルアレーンジオキシドの製造方法
TW201200504A (en) * 2010-03-18 2012-01-01 Dow Global Technologies Llc Process for preparing divinylarene dioxides
CN102958972A (zh) * 2010-06-25 2013-03-06 陶氏环球技术有限责任公司 聚合物混凝土组合物
WO2011163282A2 (en) * 2010-06-25 2011-12-29 Dow Global Technologies Llc Curable epoxy resin compositions and composites made therefrom
JP5778768B2 (ja) * 2010-06-28 2015-09-16 ダウ グローバル テクノロジーズ エルエルシー 硬化性樹脂組成物
KR20130039330A (ko) * 2010-06-28 2013-04-19 다우 글로벌 테크놀로지스 엘엘씨 경화성 수지 조성물
JP5676008B2 (ja) * 2010-11-22 2015-02-25 ダウ グローバル テクノロジーズ エルエルシー 強靱化剤としてｄｖｂｄｏの付加物を含むエポキシ樹脂
CN103917570A (zh) * 2011-11-08 2014-07-09 陶氏环球技术有限责任公司 可固化组合物
EP3271428B1 (de) * 2015-03-20 2020-11-11 Blue Cube IP LLC Härtbare zusammensetzungen
EP3271429B1 (de) * 2015-03-20 2020-05-06 Blue Cube IP LLC Härtbare zusammensetzungen

Family Cites Families (15)

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US3455967A (en) * 1965-09-23 1969-07-15 Dow Chemical Co Synthesis of aromatic epoxides from benzylic sulfonium salts
US3506612A (en) * 1967-05-10 1970-04-14 North American Rockwell Diepoxy polyaryl monomers and polymers and method for making same
US3635843A (en) * 1969-07-17 1972-01-18 Shell Oil Co Crystalline 1,5-diglycidylnaphthalene and cured products thereof
CH583668A5 (de) * 1972-06-30 1977-01-14 Ciba Geigy Ag
US4256828A (en) * 1975-09-02 1981-03-17 Minnesota Mining And Manufacturing Company Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials
GB2012780B (en) * 1978-01-20 1982-03-17 Ciba Geigy Ag Epoxide containing compositions and their polymerisation
FR2508451A1 (fr) * 1981-06-26 1982-12-31 Interox Procede pour la fabrication d'epoxydes
DE3622610A1 (de) * 1986-07-05 1988-01-14 Bayer Ag Fluessig-kristalline diglycidylverbindungen, ihre herstellung und verwendung in haertbaren epoxid-gemischen
US5118822A (en) * 1991-09-30 1992-06-02 Arco Chemical Technology, L.P. Olefin epoxidation using a perrhenate catalyst and an organic hydroperoxide
DE4340949A1 (de) * 1993-12-01 1995-06-08 Thera Ges Fuer Patente Lichtinitiiert kationisch härtende Epoxidmasse und ihre Verwendung
ES2154352T3 (es) * 1994-10-31 2001-04-01 Minnesota Mining & Mfg Sistema epoxi, curable con luz visible, con profundidad de curado aumentada.
US5952457A (en) * 1995-09-12 1999-09-14 Mitsui Chemicals, Inc. Polymerization catalyst for alkylene oxide compound and production process of poly(alkylene oxide)
DE19534668A1 (de) * 1995-09-19 1997-03-20 Thera Ges Fuer Patente Kettenverlängerte Epoxidharze enthaltende, vorwiegend kationisch härtende Masse
DE19534594B4 (de) * 1995-09-19 2007-07-26 Delo Industrieklebstoffe Gmbh & Co. Kg Kationisch härtende, flexible Epoxidharzmassen und ihre Verwendung zum Auftragen dünner Schichten
US6020508A (en) * 1997-05-16 2000-02-01 National Starch And Chemical Investment Holding Corporation Radiation- or thermally-initiated cationically-curable epoxide compounds and compositions made from those compounds

Also Published As

Publication number Publication date
JPH1171364A (ja) 1999-03-16
EP0878472A1 (de) 1998-11-18
CA2237881A1 (en) 1998-11-16
AU6599598A (en) 1998-11-19
ES2126545T1 (es) 1999-04-01
AU700835B2 (en) 1999-01-14
JP3026557B2 (ja) 2000-03-27

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