DE714146C - Fabric softeners - Google Patents

Fabric softeners

Info

Publication number
DE714146C
DE714146C DEI59794D DEI0059794D DE714146C DE 714146 C DE714146 C DE 714146C DE I59794 D DEI59794 D DE I59794D DE I0059794 D DEI0059794 D DE I0059794D DE 714146 C DE714146 C DE 714146C
Authority
DE
Germany
Prior art keywords
fabric softeners
esters
stearic acid
softeners
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI59794D
Other languages
German (de)
Inventor
Dr Karl Brodersen
Dr Matthias Quaedvlieg
Albert Schneider
Dr Max Zabel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE1937I0057358 priority Critical patent/DE699028C/en
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI59794D priority patent/DE714146C/en
Priority to NL86510A priority patent/NL49425C/xx
Priority to GB5752/38A priority patent/GB511545A/en
Priority to NL86650A priority patent/NL49991C/xx
Priority to FR834763D priority patent/FR834763A/en
Priority to US193924A priority patent/US2197464A/en
Priority to BE426845D priority patent/BE426845A/xx
Application granted granted Critical
Publication of DE714146C publication Critical patent/DE714146C/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C279/20—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylguanidines
    • C07C279/24—Y being a hetero atom
    • C07C279/26—X and Y being nitrogen atoms, i.e. biguanides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Textilweichmachungsmittel Die Verwendung von hochmolekularen aliphatischen Biguaniden als Weichmacher für Textilien ist bekannt. Man hat hierbei diese Biguarüde auch bereits zusammen mit Schutzkolloiden verwendet, um unerwünschte Ausscheidungen in den Behandlungsbädern zu verhindern.Fabric softener The use of high molecular weight aliphatic Biguanides are known as softeners for textiles. You have this bigu male also already used together with protective colloids to avoid unwanted excretions to prevent in the treatment baths.

Es wurde nun gefunden, daß man besonders wertvolle Textilweichmachungsmittel durch Mischen von höheren Alhylbiguaniden bzw. ihren Salzen mit Oxygruppen enthaltenden Estern seifenbildender Fettsäuren erhält. Letztere Ester sind als Textihveichmachungsmittel an sich ebenfalls bekannt; sie können gesättigt oder ungesättigt, gerad- oder verzweigtkettig und gegebenenfalls substituiert sein. Ester dieser Art sind z. B. Mono- und Polyglyceride, Glykol- und Polyglykolester, Ester des Erythrits, Sorhits sowie deren Oxäthylierungsprodukte. -Von den höheren Alkyl--biguaniden, die mindestens io C-Atome im Alkylrest enthalten sollen, können beispielsweise angeführt werden: Dodecylb guanid, Tetradecylhiguanid, Cetylbiguanid, Octodecylbigu.anid und Oleylbiguanid.It has now been found that there are particularly valuable fabric softeners by mixing higher Alhylbiguaniden or their salts with containing oxy groups Contains esters of soap-forming fatty acids. The latter esters are useful as fabric softeners also known per se; they can be saturated or unsaturated, straight or branched chain and optionally substituted. Esters of this type are e.g. B. mono- and polyglycerides, Glycol and polyglycol esters, esters of erythritol, sorbitol and their oxethylation products. -From the higher alkyl - biguanides, which contain at least 10 carbon atoms in the alkyl radical are, for example: Dodecylb guanid, Tetradecylhiguanid, Cetyl biguanide, octodecyl bigu.anide and oleyl biguanide.

Die weichmachende Wirkung solcher Mischungen, die auch aus mehr a1"§ zwei Bestandteilen bestehen können, ist besser als die der Einzelbestandteile. Während zur Erzielung eines brauchbaren Effektes beispielsweise o, i g/1 eines 50% Stearylbiguanidchlorhydrat enthaltenden Handelsproduktes erforderlich sind und vom Stearinsäurepolyglykolester sogar 2g/1,. benötigt man bei Anwendung eines Gemisches gleicher Teile beider Komponenten nur 0,05 g/1 für die gleiche weichmachende Wirkung. Je nach Wahl und 1VIengenverhältnis der Mischungsteilnehmer kann man den Charakter der Veredelung auf den verschiedenen Textilien, wie pflanzlichen und tierischen Fasern, Kunstfasern und allerlei Mischgeweben, ändern und Waren mit unterschiedlicher Glätte, Fülle und Griffigkeit herstellen.The softening effect of such mixtures, which can also consist of more than two components, is better than that of the individual components. While to achieve a useful effect, for example, o, ig / 1 of a commercial product containing 50% stearyl biguanide chlorohydrate are required and of the stearic acid polyglycol ester even 2 g When using a mixture of the same parts of both components, you only need 0.05 g / 1 for the same softening effect , Synthetic fibers and all kinds of blended fabrics, change and produce goods with different smoothness, fullness and grip.

Die neuen Mischungen ermöglichen es also, einen großen Teil der als hochwertige Weichinacher bekannten Biguanide durch geringwertige, technisch leicht zugängliche Erzeugnisse zu ersetzen, ohne daß eine Beeinträchtigung der weichmachenden Wirkung eintritt. B cispiel 50 Teile Stearylbigua,nidchlo,rhydrat, 5o Teile des Umsetzungsproduktes von i Mol Stearinsäure mit 6 Mol :@thylenoxyd, werde miteinander verschmolzen. o,o5 gll dieses Präparats geben Viscosekunstseide einen weichen, fließenden Griff: das Produkt ist gegen Sulfationen, Säuren und Laugen beständig. Ersetzt man diesen StearinsäLn-epolyglykolester durch Stearinsäurepolyglycerid. so erhält man Weichmacher, die in derselben niedrigen Konzentration Kunstseide neben großer @@"eichheit eine gute Fülle verleihen.The new mixtures thus make it possible to replace a large part of the biguanides known as high-quality softeners with low-quality, technically easily accessible products without impairing the softening effect. B cexample 50 parts of stearyl bigua, nidchlo, rhydrate, 50 parts of the reaction product of 1 mole of stearic acid with 6 moles of ethylene oxide are fused together. O, o5 gll of this preparation gives viscose rayon a soft, flowing handle: the product is resistant to sulphate ions, acids and alkalis. If this stearic acid polyglycol ester is replaced by stearic acid polyglyceride. In this way, plasticizers are obtained which, in the same low concentration, give artificial silk, in addition to being very calibrated, a good body.

An Stelle der genannten Ester kann man auch den Monoester höherer Fettsäuren mit z. B. Di- oder Triäthanolamin sowie deren Oxäthylierun:gsprodukte verwenden.Instead of the esters mentioned, it is also possible to use higher monoesters Fatty acids with z. B. Di- or triethanolamine and their Oxäthylierun: gsprodukte use.

Man kann Stearylbiguanidchlorhydrat z. F3. auch mit Mischungen der genannten Körper stellen, wodurch sich der Charakter des Griffes in weiten Grenzen abändern läßt. Eine sehr wertvolle Mischung besteht z. S. aus 3 ; Teilen Stearylbiguanidchlorhydrat, 33 Teilen Stearinsäurepolyglycerid, 33 Teilen des Polyglykoläthers des Stearinsäuretriäthanolaminesters.One can stearyl biguanide chlorohydrate e.g. F3. also with mixtures of the bodies mentioned, whereby the character of the handle can be changed within wide limits. A very valuable mixture consists e.g. S. from 3; Parts of stearyl biguanide chlorohydrate, 33 parts of stearic acid polyglyceride, 33 parts of the polyglycol ether of the stearic acid triethanolamine ester.

Claims (1)

PA-rEN-rA N s111;1'(11 Die Verwendung von höheren Alkylbiguaniden bzw. von deren Salzen zusaininen mit Oxygruppen enthaltenden Estern seifenbildender Fettsäuren als Weichinachungsmittel für Textilien.PA-rEN-rA N s111; 1 '(11 The use of higher alkyl biguanides or of their salts together with esters containing oxy groups soap-forming Fatty acids as softeners for textiles.
DEI59794D 1937-03-10 1937-12-04 Fabric softeners Expired DE714146C (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE1937I0057358 DE699028C (en) 1937-03-10 1937-03-10 Softening of textile goods
DEI59794D DE714146C (en) 1937-03-10 1937-12-04 Fabric softeners
NL86510A NL49425C (en) 1937-03-10 1938-02-18
GB5752/38A GB511545A (en) 1937-03-10 1938-02-23 Process for softening and improving the feel of textiles
NL86650A NL49991C (en) 1937-03-10 1938-02-28
FR834763D FR834763A (en) 1937-03-10 1938-03-04 Process for refining textiles
US193924A US2197464A (en) 1937-03-10 1938-03-04 Treating artificial fabrics
BE426845D BE426845A (en) 1937-03-10 1938-03-09

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE1937I0057358 DE699028C (en) 1937-03-10 1937-03-10 Softening of textile goods
DEI59794D DE714146C (en) 1937-03-10 1937-12-04 Fabric softeners
GB5752/38A GB511545A (en) 1937-03-10 1938-02-23 Process for softening and improving the feel of textiles

Publications (1)

Publication Number Publication Date
DE714146C true DE714146C (en) 1941-11-22

Family

ID=32073741

Family Applications (2)

Application Number Title Priority Date Filing Date
DE1937I0057358 Expired DE699028C (en) 1937-03-10 1937-03-10 Softening of textile goods
DEI59794D Expired DE714146C (en) 1937-03-10 1937-12-04 Fabric softeners

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE1937I0057358 Expired DE699028C (en) 1937-03-10 1937-03-10 Softening of textile goods

Country Status (6)

Country Link
US (1) US2197464A (en)
BE (1) BE426845A (en)
DE (2) DE699028C (en)
FR (1) FR834763A (en)
GB (1) GB511545A (en)
NL (2) NL49425C (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2730498A (en) * 1952-01-09 1956-01-10 Celanese Corp Textile lubricants
US2925639A (en) * 1953-11-30 1960-02-23 Deering Milliken Res Corp Method of fulling and scouring wool
DE2927027A1 (en) * 1979-07-04 1981-01-08 Hoechst Ag AGENT FOR LIQUID PARAFFINING YARN
JP5368561B2 (en) 2008-08-15 2013-12-18 ザ プロクター アンド ギャンブル カンパニー Beneficial composition comprising polyglycerol ester

Also Published As

Publication number Publication date
FR834763A (en) 1938-12-01
NL49425C (en) 1940-10-15
US2197464A (en) 1940-04-16
GB511545A (en) 1939-08-21
NL49991C (en) 1941-03-15
DE699028C (en) 1940-11-21
BE426845A (en) 1938-04-30

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