DE69919730D1 - Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen - Google Patents

Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen

Info

Publication number
DE69919730D1
DE69919730D1 DE69919730T DE69919730T DE69919730D1 DE 69919730 D1 DE69919730 D1 DE 69919730D1 DE 69919730 T DE69919730 T DE 69919730T DE 69919730 T DE69919730 T DE 69919730T DE 69919730 D1 DE69919730 D1 DE 69919730D1
Authority
DE
Germany
Prior art keywords
diol
acid
hydroxyl
branched
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69919730T
Other languages
English (en)
Other versions
DE69919730T2 (de
Inventor
P Panandiker
Michael Bronk
Paul Spitler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexion Inc
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of DE69919730D1 publication Critical patent/DE69919730D1/de
Publication of DE69919730T2 publication Critical patent/DE69919730T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4263Polycondensates having carboxylic or carbonic ester groups in the main chain containing carboxylic acid groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/798Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/20Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00Compositions for coatings
    • C08G2150/20Compositions for powder coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyurethanes Or Polyureas (AREA)
DE69919730T 1998-09-18 1999-09-09 Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen Expired - Fee Related DE69919730T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US156254 1998-09-18
US09/156,254 US6255523B1 (en) 1998-09-18 1998-09-18 Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates
PCT/US1999/020654 WO2000017148A1 (en) 1998-09-18 1999-09-09 Powder coatings based on branched oligoesters and non-emissive uretdione polyisocyanates

Publications (2)

Publication Number Publication Date
DE69919730D1 true DE69919730D1 (de) 2004-09-30
DE69919730T2 DE69919730T2 (de) 2005-09-01

Family

ID=22558776

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69919730T Expired - Fee Related DE69919730T2 (de) 1998-09-18 1999-09-09 Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen

Country Status (13)

Country Link
US (2) US6255523B1 (de)
EP (2) EP1481963A1 (de)
JP (1) JP2002526569A (de)
KR (1) KR100650829B1 (de)
CN (1) CN100357247C (de)
AT (1) ATE274488T1 (de)
AU (1) AU769617B2 (de)
BR (1) BR9913799B1 (de)
CA (1) CA2344540A1 (de)
CZ (1) CZ2001980A3 (de)
DE (1) DE69919730T2 (de)
WO (1) WO2000017148A1 (de)
ZA (1) ZA200102125B (de)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6255523B1 (en) * 1998-09-18 2001-07-03 Mcwhorter Technologies, Inc. Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates
US7192994B2 (en) * 2001-04-25 2007-03-20 Mitsubishi Gas Chemical Co., Inc. Method of producing polyester powdery coating material
DE60201700T2 (de) * 2001-04-25 2005-12-15 Mitsubishi Gas Chemical Co., Inc. Verfahren zur Herstellung von Pulverbeschichtungsstoff aus Polyester
DE10140156A1 (de) * 2001-08-16 2003-03-20 Basf Coatings Ag Thermisch und mit aktinischer Strahlung härtbare Beschichtungsstoffe und ihre Verwendung
DE10233104A1 (de) * 2002-07-20 2004-01-29 Degussa Ag Verwendung von PUR-Pulverlacken für Coil Coating-Beschichtungen mit mattem Erscheinungsbild
DE102004020451A1 (de) * 2004-04-27 2005-12-01 Degussa Ag Uretdiongruppenhaltige Polyurethanzusammensetzungen, welche bei niedriger Temperatur härtbar sind und (teil-)kristalline Harze enthalten
US7893187B2 (en) * 2005-06-17 2011-02-22 Eastman Chemical Company Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
DE102005013401A1 (de) * 2005-03-23 2006-09-28 Degussa Ag Niedrigviskose uretdiongruppenhaltige Polyadditionsverbindungen, Verfahren zur Herstellung und Verwendung
US20060270773A1 (en) * 2005-05-26 2006-11-30 Hale Wesley R Polyester-polycarbonate blends for diffuser sheets with improved luminance
US7704605B2 (en) 2006-03-28 2010-04-27 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US20130072628A1 (en) * 2005-06-17 2013-03-21 Eastman Chemical Company Coating compositions containing cyclobutanediol
RU2008116616A (ru) * 2005-09-27 2009-11-10 Дау Глобал Текнолоджиз Инк. (Us) Полимеры, включающие в себя 1,3- и 1,4-циклогександиметанолы
CA2625842A1 (en) 2005-10-28 2007-05-10 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
US8193302B2 (en) 2005-10-28 2012-06-05 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US9598533B2 (en) 2005-11-22 2017-03-21 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7737246B2 (en) 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
CN101365670B (zh) * 2006-02-03 2012-12-26 陶氏环球技术有限责任公司 基于1,3/1,4-环己烷二甲醇的单体及聚合物
US9169388B2 (en) 2006-03-28 2015-10-27 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
BRPI0711012A2 (pt) * 2006-05-18 2011-08-23 Dow Global Technologies Inc processo para preparar um elastÈmero, solado de calçado e prepolìmero terminado por isocianato
BRPI0806435A2 (pt) * 2007-01-31 2011-09-06 Dow Global Technologies Inc composição curável para revestimento de bobinas e processo para preparar uma composição curável para revestimento de bobinas melhorada
US8501287B2 (en) 2007-11-21 2013-08-06 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
EP2225084B1 (de) 2007-11-21 2013-05-29 Eastman Chemical Company Babyflaschen aus kunststoff, andere blasgeformte artikel und verfahren für ihre herstellung
US8198371B2 (en) 2008-06-27 2012-06-12 Eastman Chemical Company Blends of polyesters and ABS copolymers
US8895654B2 (en) 2008-12-18 2014-11-25 Eastman Chemical Company Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid
KR101492401B1 (ko) 2008-12-23 2015-02-13 에스케이케미칼주식회사 플라스틱 코팅용 에스테르계 폴리올
TWI448482B (zh) * 2009-02-02 2014-08-11 Ind Tech Res Inst 聚酯材料及其製造方法
US8420868B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US20130217830A1 (en) 2012-02-16 2013-08-22 Eastman Chemical Company Clear Semi-Crystalline Articles with Improved Heat Resistance
CN103992468B (zh) * 2014-05-23 2016-01-20 三棵树涂料股份有限公司 超支化改性醇酸树脂及其制备方法
CN107868235A (zh) * 2017-10-30 2018-04-03 广州擎天材料科技有限公司 一种粉末涂料用双官能团聚酯树脂及其制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3721645A (en) 1971-02-25 1973-03-20 Liner Technology Inc Polyurethanes stabilized with 1,2,3-,1,2,4-1,2,5-,and 1,3,4-triazoles
US3857818A (en) 1972-09-18 1974-12-31 Cook Paint & Varnish Co Blocked polyurethane powder coating compositions
DE2812252A1 (de) 1978-03-21 1979-10-04 Bayer Ag 1,2,4-triazol-blockierte polyisocyanate als vernetzer fuer lackbindemittel
US4197353A (en) 1978-04-14 1980-04-08 Mobil Oil Corporation Thermosetting powder coating polyesters
DE3030588A1 (de) 1980-08-13 1982-03-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von blockierungsmittelfreien polyurethan-pulverlacken mit hoher lagerstabilitaet, die oberhalb 120(grad) c haertbar sind, sowie die danach hergestellten polyurethan-pulverlacke
US4442270A (en) 1981-06-29 1984-04-10 Eastman Kodak Company Thermosetting powder coating compositions
US4375539A (en) 1981-07-22 1983-03-01 Eastman Kodak Company Solid blocked crosslinking agents based on 1,4-cyclohexane bis(methylisocyanate)
DE4114800A1 (de) 1991-05-07 1992-11-12 Bayer Ag Neue polyesterpolyole sowie deren verwendung als haftvermittler fuer polymersysteme und als polymerweichmacher
BE1005819A3 (nl) 1992-05-15 1994-02-08 Dsm Nv Bindmiddelsamenstelling voor poedercoatings toepasbaar in de automobielindustrie.
DE4327573A1 (de) 1993-08-17 1995-02-23 Bayer Ag Uretdion-Pulverlackvernetzer mit niedriger Schmelzviskosität
DE4335845C3 (de) * 1993-10-20 2001-06-13 Inventa Ag Wärmehärtende Beschichtungsmasse, deren Herstellung und Verwendung
DE4339367A1 (de) 1993-11-18 1995-05-24 Bayer Ag Blockierte Polyisocyanate
US5610263A (en) 1994-01-25 1997-03-11 Eastern Michigan University Water thinned polymeric vehicle for coating compositions with low amounts of volatile oragnic compounds
US5910563A (en) 1994-01-25 1999-06-08 Exxon Chemical Patents, Inc. Water thinned polymeric vehicle for coating compositions with low amounts of volatile organic compounds
WO1995020004A1 (en) 1994-01-25 1995-07-27 Eastern Michigan University Polymeric vehicle for high solids coatings
US5955550A (en) * 1994-01-25 1999-09-21 Exxon Chemical Patents, Inc. Polymeric vehicle for providing solventless coating compositions
AU1733395A (en) 1994-01-25 1995-08-08 Eastern Michigan University Polymeric vehicle effective for providing solventless coating compositions
DE19616496A1 (de) * 1996-04-25 1997-10-30 Bayer Ag Abspaltfreier Polyurethan-Pulverlack mit niedriger Einbrenntemperatur
US5637654A (en) * 1996-08-12 1997-06-10 Mcwhorter Technologies Low temperature cure carboxyl terminated polyesters
US6255523B1 (en) * 1998-09-18 2001-07-03 Mcwhorter Technologies, Inc. Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates

Also Published As

Publication number Publication date
DE69919730T2 (de) 2005-09-01
CA2344540A1 (en) 2000-03-30
EP1114020A4 (de) 2001-12-12
CN1318045A (zh) 2001-10-17
US6255523B1 (en) 2001-07-03
EP1114020A1 (de) 2001-07-11
BR9913799B1 (pt) 2012-02-07
KR20010075172A (ko) 2001-08-09
ATE274488T1 (de) 2004-09-15
JP2002526569A (ja) 2002-08-20
AU769617B2 (en) 2004-01-29
CN100357247C (zh) 2007-12-26
CZ2001980A3 (cs) 2001-08-15
AU5818599A (en) 2000-04-10
ZA200102125B (en) 2002-06-14
US6541595B2 (en) 2003-04-01
WO2000017148A1 (en) 2000-03-30
BR9913799A (pt) 2001-05-29
US20020091206A1 (en) 2002-07-11
KR100650829B1 (ko) 2006-11-27
EP1481963A1 (de) 2004-12-01
EP1114020B1 (de) 2004-08-25

Similar Documents

Publication Publication Date Title
DE69919730D1 (de) Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen
JP3674938B2 (ja) 塗料組成物及びその製造方法
US4374181A (en) Vapor permeation curable coatings for reaction injection molded parts
US20020077444A1 (en) Method for producing liquid urethane prepolymer and resin composition
JPH08208790A (ja) 末端閉鎖ポリイソシアネートプレポリマー
US4200762A (en) Actinic radiation curable polymers
ZA200102127B (en) Powder coatings based on branched oligoesters and triazole blocked polyisocyanates.
US4395529A (en) Coating powders for protective films based on epsilon-caprolactam blocked isocyanates
US3349049A (en) Urethane coatings from hydroxyl terminated polyesters prepared from dimer acids
US5277945A (en) Resin composition for coating
JP4029231B2 (ja) 印刷インキ用バインダー
JPS6198733A (ja) 品質を改良したポリウレタン及びその原料ポリオ−ル
JP3144435B2 (ja) ポリエステルポリオールの製造方法及び硬化性樹脂組成物
JPH09100459A (ja) 湿分硬化性ウレタン接着剤組成物
JPS6386715A (ja) 樹脂組成物およびそれを硬化してなる樹脂
JP3564921B2 (ja) 熱硬化型生分解性重合体およびその製造方法
JPH07196759A (ja) ウレタンプレポリマーの製造方法
JPS64425B2 (de)
JP2860183B2 (ja) ウレタン結合を含むポリエステルの製造方法
JPS63118377A (ja) ウレタン塗膜の硬化方法
CA1137973A (en) Actinic radiation curable polymers
JPS5811523A (ja) ポリウレタン組成物
JPS6386762A (ja) 耐擦傷性塗料組成物
JPH05155971A (ja) 品質を改良したポリウレタンの製造法
KR800001484B1 (ko) 2액형 에폭시 우레탄 바니스의 제조방법

Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: RESOLUTION SPECIALTY MATERIALS LLC, HOUSTON, TEX.,

8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee